arXiv subjects

Ekkes Brück

Publications and source records attributed to Ekkes Brück.

5 recordsLinked to original sources

arXiv2020

Ab initio modeling and experimental investigation of Fe$_2$P by DFT and spin spectroscopies

Fe$_2$P alloys have been identified as promising candidates for magnetic refrigeration at room-temperature and for custom magnetostatic applications. The intent of this study is to accurately characterize the magnetic ground state of the parent compound, Fe$_2$P, with two spectroscopic techniques, $μ$SR and NMR, in order to provide solid bases for further experimental analysis of Fe$_2$P-type transition metal based alloys. We perform zero applied field measurements using both techniques below the ferromagnetic transition $T_C=220~\mathrm K$. The experimental results are reproduced and interpreted using first principles simulations validating this approach for quantitative estimates in alloys of interest for technological applications.

cond-mat.mtrl-sci↗

arXiv2019

Design of reversible low-field magnetocaloric effect at room temperature in hexagonal MnMX ferromagnets

Giant magnetocaloric effect is widely achieved in hexagonal MnMX-based (M = Co or Ni, X = Si or Ge) ferromagnets at their first-order magnetostructural transition. However, the thermal hysteresis and the low sensitivity of the magnetostructural transition to the magnetic field inevitably lead to a sizeable irreversibility of the low-field magnetocaloric effect. In this work, we show an alternative way to realize a reversible low-field magnetocaloric effect in MnMX-based alloys by taking advantage of the second-order phase transition. With introducing Cu into Co in MnCoGe alloy, the martensitic transition is stabilized at high temperature, while the Curie temperature of the orthorhombic phase is reduced to room temperature. As a result, a second-order magnetic transition with negligible thermal hysteresis and a large magnetization change can be observed, enabling a large reversible magnetocaloric effect. By both calorimetric and direct measurements, a reversible adiabatic temperature change of about 1 K is obtained under a field change of 0-1 T at 304 K, which is larger than that obtained in a first-order magnetostructural transition. To get a better insight into the origin of these experimental results, first-principles calculations are carried out to characterize the chemical bonds and the magnetic exchange interaction. Our work provides a new understanding of the MnCoGe alloy and indicates a feasible route to improve the reversibility of the low-field magnetocaloric effect in the MnMX system.

cond-mat.mtrl-sci↗

arXiv2018

Nature of the positron state in CdSe quantum dots

Previous studies have shown that positron-annihilation spectroscopy is a highly sensitive probe of the electronic structure and surface composition of ligand-capped semiconductor Quantum Dots (QDs) embedded in thin films. Nature of the associated positron state, however, whether the positron is confined inside the QDs or localized at their surfaces, has so far remained unresolved. Our positron-annihilation lifetime spectroscopy (PALS) studies of CdSe QDs reveal the presence of a strong lifetime component in the narrow range of 358-371 ps, indicating abundant trapping and annihilation of positrons at the surfaces of the QDs. Furthermore, our ab-initio calculations of the positron wave function and lifetime employing a recent formulation of the Weighted Density Approximation (WDA) demonstrate the presence of a positron surface state and predict positron lifetimes close to experimental values. Our study thus resolves the longstanding question regarding the nature of the positron state in semiconductor QDs, and opens the way to extract quantitative information on surface composition and ligand-surface interactions of colloidal semiconductor QDs through highly sensitive positron-annihilation techniques.

cond-mat.mes-hall↗

arXiv2016

Ligand-Surface Interactions and Surface Oxidation of Colloidal PbSe Quantum Dots Revealed by Thin-film Positron Annihilation Methods

Positron Two Dimensional Angular Correlation of Annihilation Radiation (2D-ACAR) measurements reveal modifications of the electronic structure and composition at the surfaces of PbSe quantum dots (QDs), deposited as thin films, produced by various ligands containing either oxygen or nitrogen atoms. In particular, the 2D-ACAR measurements on thin films of colloidal PbSe QDs capped with oleic acid ligands yield an increased intensity in the electron momentum density (EMD) at high momenta compared to PbSe quantum dots capped with oleylamine. Moreover, the EMD of PbSe QDs is strongly affected by the small ethylediamine ligands, since these molecules lead to small distances between QDs and favor neck formation between near neighbor QDs, inducing electronic coupling between neighboring QDs. The high sensitivity to the presence of oxygen atoms at the surface can be also exploited to monitor the surface oxidation of PbSe QDs upon exposure to air. Our study clearly demonstrates that positron annihilation spectroscopy applied to thin films can probe surface transformations of colloidal semiconductor QDs embedded in functional layers.

cond-mat.mtrl-sci↗

arXiv2009

Magnetic cooling at Risoe DTU

Magnetic refrigeration at room temperature is of great interest due to a long-term goal of making refrigeration more energy-efficient, less noisy and free of any environmentally hostile materials. A refrigerator utilizing an active magnetic regenerator (AMR) is based on the magnetocaloric effect, which manifests itself as a temperature change in magnetic materials when subjected to a varying magnetic field. In this work we present the current state of magnetic refrigeration research at Risoe DTU with emphasis on the numerical modeling of an existing AMR test machine. A 2D numerical heat-transfer and fluid-flow model that represents the experimental setup is presented. Experimental data of both no-heat load and heat load situations are compared to the model. Moreover, results from the numerical modeling of the permanent magnet design used in the system are presented.

cond-mat.mtrl-sci↗