arXiv subjects

Elspeth K. H. Lee

Publications and source records attributed to Elspeth K. H. Lee.

At least 37 records · Page 2Linked to original sources

arXiv2024

A Measurement of the Water Abundance in the Atmosphere of the Hot Jupiter WASP-43b with High-resolution Cross-correlation Spectroscopy

Measuring the abundances of carbon- and oxygen-bearing molecules has been a primary focus in studying the atmospheres of hot Jupiters, as doing so can help constrain the carbon-to-oxygen (C/O) ratio. The C/O ratio can help reveal the evolution and formation pathways of hot Jupiters and provide a strong understanding of the atmospheric composition. In the last decade, high-resolution spectral analyses have become increasingly useful in measuring precise abundances of several carbon- and oxygen-bearing molecules. This allows for a more precise constraint of the C/O ratio. We present four transits of the hot Jupiter WASP-43b observed between 1.45 $-$ 2.45 $μ$m with the high-resolution Immersion GRating InfraRed Spectrometer (IGRINS) on the Gemini-S telescope. We detected H$_2$O at a signal-to-noise ratio (SNR) of 3.51. We tested for the presence of CH$_4$, CO, and CO$_2$, but we did not detect these carbon-bearing species. We ran a retrieval for all four molecules and obtained a water abundance of $\log_{10}(\text{H}_2\text{O}) = -2.24^{+0.57}_{-0.48}$. We obtained an upper limit on the C/O ratio of C/O $<$ 0.95. These findings are consistent with previous observations from the Hubble Space Telescope and the James Webb Space Telescope.

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arXiv2024

A photochemical PHO network for hydrogen-dominated exoplanet atmospheres

Due to the detection of phosphine PH3 in the Solar System gas giants Jupiter and Saturn, PH3 has long been suggested to be detectable in exosolar substellar atmospheres too. However, to date, a direct detection of phosphine has proven to be elusive in exoplanet atmosphere surveys. We construct an updated phosphorus-hydrogen-oxygen (PHO) photochemical network suitable for simulation of gas giant hydrogen-dominated atmospheres. Using this network, we examine PHO photochemistry in hot Jupiter and warm Neptune exoplanet atmospheres at Solar and enriched metallicities. Our results show for HD 189733b-like hot Jupiters that HOPO, PO and P2 are typically the dominant P carriers at pressures important for transit and emission spectra, rather than PH3. For GJ1214b-like warm Neptune atmospheres our results suggest that at Solar metallicity PH3 is dominant in the absence of photochemistry, but is generally not in high abundance for all other chemical environments. At 10 and 100 times Solar, small oxygenated phosphorus molecules such as HOPO and PO dominate for both thermochemical and photochemical simulations. The network is able to reproduce well the observed PH3 abundances on Jupiter and Saturn. Despite progress in improving the accuracy of the PHO network, large portions of the reaction rate data remain with approximate, uncertain or missing values, which could change the conclusions of the current study significantly. Improving understanding of the kinetics of phosphorus-bearing chemical reactions will be a key undertaking for astronomers aiming to detect phosphine and other phosphorus species in both rocky and gaseous exoplanetary atmospheres in the near future.

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arXiv2024

Effects of the internal temperature on vertical mixing and on cloud structures in Ultra Hot Jupiters

The vertical mixing in hot Jupiter atmospheres plays a critical role in the formation and spacial distribution of cloud particles in their atmospheres. This affects the observed spectra of a planet through cloud opacity, which can be influenced by the degree of cold trapping of refractory species in the deep atmosphere. We aim to isolate the effects of the internal temperature on the mixing efficiency in the atmospheres of Ultra Hot Jupiters (UHJ) and the spacial distribution of cloud particles across the globe. We couple a simplified tracer based cloud model, picket fence radiative-transfer scheme and mixing length theory to the Exo-FMS general circulation model. We run the model for five different internal temperatures at typical UHJ atmosphere system parameters. Our results show the convective eddy diffusion coefficient remains low throughout the vast majority of the atmosphere, with mixing dominated by advective flows. However, some regions can show convective mixing in the upper atmosphere for colder interior temperatures. The vertical extent of the clouds is reduced as the internal temperature is increased. Additionally, a global cloud layer gets formed below the radiative-convective boundary (RCB) in the cooler cases. Convection is generally strongly inhibited in UHJ atmospheres above the RCB due to their strong irradiation. Convective mixing plays a minor role compared to advective mixing in keeping cloud particles aloft in ultra hot Jupiters with warm interiors. Higher vertical turbulent heat fluxes and the advection of potential temperature inhibit convection in warmer interiors. Our results suggest isolated upper atmosphere regions above cold interiors may exhibit strong convective mixing in isolated regions around Rossby gyres, allowing aerosols to be better retained in these areas.

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arXiv2024

Phase-resolving the absorption signatures of water and carbon monoxide in the atmosphere of the ultra-hot Jupiter WASP-121b with GEMINI-S/IGRINS

Ultra-hot Jupiters are among the best targets for atmospheric characterization at high spectral resolution. Resolving their transmission spectra as a function of orbital phase offers a unique window into the 3D nature of these objects. In this work, we present three transits of the ultra-hot Jupiter WASP-121b observed with Gemini-S/IGRINS. For the first time, we measure the phase-dependent absorption signals of CO and H$_{\text{2}}$O in the atmosphere of an exoplanet, and we find that they are different. While the blueshift of CO increases during the transit, the absorption lines of H$_{\text{2}}$O become less blueshifted with phase, and even show a redshift in the second half of the transit. These measurements reveal the distinct spatial distributions of both molecules across the atmospheres of ultra-hot Jupiters. Also, we find that the H$_{\text{2}}$O signal is absent in the first quarter of the transit, potentially hinting at cloud formation on the evening terminator of WASP-121b. To further interpret the absorption trails of CO and H$_{\text{2}}$O, as well as the Doppler shifts of Fe previously measured with VLT/ESPRESSO, we compare the data to simulated transits of WASP-121b. To this end, we post-processes the outputs of global circulation models with a 3D Monte-Carlo radiative transfer code. Our analysis shows that the atmosphere of WASP-121b is subject to atmospheric drag, as previously suggested by small hotspot offsets inferred from phase-curve observations. Our study highlights the importance of phase-resolved spectroscopy in unravelling the complex atmospheric structure of ultra-hot Jupiters and sets the stage for further investigations into their chemistry and dynamics.

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arXiv2024

Sulphur dioxide in the mid-infrared transmission spectrum of WASP-39b

The recent inference of sulphur dioxide (SO$_2$) in the atmosphere of the hot ($\sim$1100 K), Saturn-mass exoplanet WASP-39b from near-infrared JWST observations suggests that photochemistry is a key process in high temperature exoplanet atmospheres. This is due to the low ($<$1 ppb) abundance of SO$_2$ under thermochemical equilibrium, compared to that produced from the photochemistry of H$_2$O and H$_2$S (1-10 ppm). However, the SO$_2$ inference was made from a single, small molecular feature in the transmission spectrum of WASP-39b at 4.05 $μ$m, and therefore the detection of other SO$_2$ absorption bands at different wavelengths is needed to better constrain the SO$_2$ abundance. Here we report the detection of SO$_2$ spectral features at 7.7 and 8.5 $μ$m in the 5-12 $μ$m transmission spectrum of WASP-39b measured by the JWST Mid-Infrared Instrument (MIRI) Low Resolution Spectrometer (LRS). Our observations suggest an abundance of SO$_2$ of 0.5-25 ppm (1$σ$ range), consistent with previous findings. In addition to SO$_2$, we find broad water vapour absorption features, as well as an unexplained decrease in the transit depth at wavelengths longer than 10 $μ$m. Fitting the spectrum with a grid of atmospheric forward models, we derive an atmospheric heavy element content (metallicity) for WASP-39b of $\sim$7.1-8.0 $\times$ solar and demonstrate that photochemistry shapes the spectra of WASP-39b across a broad wavelength range.

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arXiv2024

Latitudinal Asymmetry in the Dayside Atmosphere of WASP-43b

We present two-dimensional near-infrared temperature maps of the canonical hot Jupiter WASP-43b using a phase-curve observation with JWST NIRSpec/G395H. From the white-light planetary transit, we improve constraints on the planet's orbital parameters and measure a planet-to-star radius ratio of $0.15883^{+0.00056}_{-0.00053}$. Using the white-light phase curve, we measure a longitude of maximum brightness of $6.9^{+0^\circ.5}_{-0^\circ.5}$ east of the substellar point and a phase-curve offset of $10.0^{+0^\circ.8}_{-0^\circ.8}$. We also find an $\approx4σ$ detection of a latitudinal hotspot offset of $-13.4^{+3^\circ.2}_{-1^\circ.7}$, the first significant detection of a non-equatorial hotspot in an exoplanet atmosphere. We show that this detection is robust to variations within planetary parameter uncertainties, but only if the transit is used to improve constraints, showing the importance of transit observations to eclipse mapping. Maps retrieved from the NRS1 and NRS2 detectors are similar, with hotspot locations consistent between the two detectors at the $1σ$ level. Our JWST data show brighter (hotter) nightsides and a dimmer (colder) dayside at the shorter wavelengths relative to fits to \textit{Spitzer} 3.6 and 4.5 \microns\ phase curves. Through comparison between our phase curves and a set of general circulation models, we find evidence for clouds on the nightside and atmospheric drag or high metallicity reducing the eastward hotspot offset.

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arXiv2024

A warm Neptune's methane reveals core mass and vigorous atmospheric mixing

Observations of transiting gas giant exoplanets have revealed a pervasive depletion of methane, which has only recently been identified atmospherically. The depletion is thought to be maintained by disequilibrium processes such as photochemistry or mixing from a hotter interior. However, the interiors are largely unconstrained along with the vertical mixing strength and only upper limits on the CH$_4$ depletion have been available. The warm Neptune WASP-107 b stands out among exoplanets with an unusually low density, reported low core mass, and temperatures amenable to CH$_4$ though previous observations have yet to find the molecule. Here we present a JWST NIRSpec transmission spectrum of WASP-107 b which shows features from both SO$_2$ and CH$_4$ along with H$_2$O, CO$_2$, and CO. We detect methane with 4.2$σ$ significance at an abundance of 1.0$\pm$0.5 ppm, which is depleted by 3 orders of magnitude relative to equilibrium expectations. Our results are highly constraining for the atmosphere and interior, which indicate the envelope has a super-solar metallicity of 43$\pm$8$\times$ solar, a hot interior with an intrinsic temperature of T$_{\rm int}$=460$\pm$40 K, and vigorous vertical mixing which depletes CH4 with a diffusion coefficient of Kzz = 10$^{11.6\pm0.1}$ cm$^2$/s. Photochemistry has a negligible effect on the CH$_4$ abundance, but is needed to account for the SO$_2$. We infer a core mass of 11.5$_{-3.6}^{+3.0}$ M$_{\odot}$, which is much higher than previous upper limits, releasing a tension with core-accretion models.

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arXiv2024

Day-night transport induced chemistry and clouds on WASP-39b I: Gas-phase composition

JWST has recently detected the first robust photochemical product on an exoplanet: sulfur dioxide (SO$_2$) on WASP-39b (Rustamkulov et al. 2023; Alderson et al. 2023; Tsai et al. 2023b). The data from the NIRISS instrument also reveal signs of partial coverage of clouds (Feinstein et al. 2023). Most of the previous studies have focused on interpreting spectral data with 1D models. To explore how the chemical species and cloud particles are altered by global circulation, we applied a 2D photochemical model and a 2D microphysical cloud model separately to post-process the thermal and dynamical structures simulated by a 3D general circulation model (GCM) of WASP-39b. We found that SO$_2$ produced by photochemistry on the dayside can be transported to the nightside owing to the efficient replenishment of horizontal transport. The morning-evening limb differences in methane (CH$_4$) abundances predicted by the 1D models disappeared after horizontal transport is included. Similarly, the inclusion of horizontal transport also reduced the limb differences in SO$_2$. Our modeling results suggest that the fast zonal wind results in minimal or negligible limb asymmetry in composition. Based on the synthetic spectra generated by our 2D atmosphere simulations, we propose that observing SO$_2$ absorption in the emission spectra of WASP-39b at different phases may offer opportunities to probe the horizontal quenching process of photochemical products. We will focus on the gas-phase chemistry in this paper and leave the results regarding clouds in the subsequent paper as part of the series.

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arXiv2024

Testing approximate infrared scattering radiative-transfer methods for hot Jupiter atmospheres

The calculation of internal atmospheric (longwave) fluxes is a key component of any model of exoplanet atmospheres that requires radiative-transfer (RT) calculations. For atmospheres containing a strong scattering component such as cloud particles, most 1D multiple-scattering RT methods typically involve numerically expensive matrix inversions. This computational bottleneck is exacerbated when multitudes of RT calculations are required, such as in general circulation models (GCMs) and retrieval methods. In an effort to increase the speed of RT calculations without sacrificing too much accuracy, we investigate the applicability of approximate longwave scattering methods developed for the Earth science community to hot Jupiter atmospheres. We test the absorption approximation (AA) and variational iteration method (VIM) applied to typical cloudy hot Jupiter scenarios, using 64 stream DISORT calculations as reference solutions. We find the four-stream VIM variant is a highly promising method to explore using for hot Jupiter GCM and retrieval modelling, showing excellent speed characteristics, with typical errors $\sim$1\% for outgoing fluxes and within $\sim$50\%, but with larger errors in the deep cloud layer test case, for vertical heating rates. Other methods explored in this study were found to typically produce similar error characteristics in vertical heating rates.

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arXiv2024

A Direct Comparison between the use of Double Gray and Multiwavelength Radiative Transfer in a General Circulation Model with and without Radiatively Active Clouds

Inhomogeneous cloud formation and wavelength-dependent phenomena are expected to shape hot Jupiter atmospheres. We present a General Circulation Model (GCM) with multiwavelength "picket fence" radiative transfer and radiatively active, temperature dependent clouds, and compare the results to a double gray routine. The double gray method inherently fails to model polychromatic effects in hot Jupiter atmospheres, while picket fence captures these non-gray aspects and performs well compared to fully wavelength-dependent methods. We compare both methods with radiatively active clouds and cloud-free models, assessing the limitations of the double gray method. Although there are broad similarities, the picket fence models have larger day-night side temperature differences, non-isothermal upper atmospheres, and multiwavelength effects in the presence of radiatively active clouds. We model the well-known hot Jupiters HD 189733 b and HD 209458 b. For the hotter HD 209458 b, the picket fence method prevents clouds from thermostating dayside temperatures, resulting in hotter upper atmospheres and the dissipation of dayside clouds. Differences in the temperature structures are then associated with nuanced differences in the circulation patterns and clouds. Models of the cooler HD 189733 b have global cloud coverage, regardless of radiative transfer scheme, whereas there are larger differences in the models of HD 209458 b, particularly in the extent of the partial cloud coverage on its dayside. This results in minor changes to the thermal and reflected light phase curves of HD 189733 b, but more significant differences for the picket fence and double gray versions of HD 209458 b.

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arXiv2024

Dynamically coupled kinetic chemistry in brown dwarf atmospheres -- II. Cloud and chemistry connections in directly imaged sub-Jupiter exoplanets

With JWST slated to gain high fidelity time dependent data on brown dwarf atmospheres, it is highly anticipated to do the same for directly imaged, sub-Jupiter exoplanets. With this new capability, the need for a full 3D understanding to explain spectral features and their time dependence is becoming a vital aspect for consideration. To examine the atmospheric properties of directly imaged sub-Jupiter exoplanets, we use the three dimensional Exo-FMS general circulation model (GCM) to simulate a metal enhanced generic young sub-Jupiter object. We couple Exo-FMS to a kinetic chemistry scheme, a tracer based cloud formation scheme and a spectral radiative-transfer model to take into account the chemical and cloud feedback on the atmospheric thermochemical and dynamical properties. Our results show a highly complex feedback between clouds and chemistry onto the 3D temperature structure of the atmosphere, bringing about latitudinal differences and inducing time-dependent stormy features at photospheric pressures. This suggests a strong connection and feedback between the spatial cloud coverage and chemical composition of the atmosphere, with the temperature changes and dynamical motions induced by cloud opacity and triggered convection feedback driving chemical species behaviour. In addition, we also produce synthetic latitude dependent and time dependent spectra of our model to investigate atmospheric variability and periodicity in commonly used photometric bands. Overall, our efforts put the included physics in 3D simulations of exoplanets on par with contemporary 1D radiative-convective equilibrium modelling.

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arXiv2024

Modeling Atmospheric Lines By the Exoplanet Community (MALBEC) version 1.0: A CUISINES radiative transfer intercomparison project

Radiative transfer (RT) models are critical in the interpretation of exoplanetary spectra, in simulating exoplanet climates and when designing the specifications of future flagship observatories. However, most models differ in methodologies and input data, which can lead to significantly different spectra. In this paper, we present the experimental protocol of the MALBEC (Modeling Atmospheric Lines By the Exoplanet Community) project. MALBEC is an exoplanet model intercomparison project (exoMIP) that belongs to the CUISINES (Climates Using Interactive Suites of Intercomparisons Nested for Exoplanet Studies) framework which aims to provide the exoplanet community with a large and diverse set of comparison and validation of models. The proposed protocol tests include a large set of initial participating RT models, a broad range of atmospheres (from Hot Jupiters to temperate terrestrials) and several observation geometries, which would allow us to quantify and compare the differences between different RT models used by the exoplanetary community. Two types of tests are proposed: transit spectroscopy and direct imaging modeling, with results from the proposed tests to be published in dedicated follow-up papers. To encourage the community to join this comparison effort and as an example, we present simulation results for one specific transit case (GJ-1214 b), in which we find notable differences in how the various codes handle the discretization of the atmospheres (e.g., sub-layering), the treatment of molecular opacities (e.g., correlated-k, line-by-line) and the default spectroscopic repositories generally used by each model (e.g., HITRAN, HITEMP, ExoMol).

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arXiv2024

Nightside clouds and disequilibrium chemistry on the hot Jupiter WASP-43b

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $μ$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$σ$ upper limit of 1-6 parts per million, depending on model assumptions).

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arXiv2023

Modelling the effect of 3D temperature and chemistry on the cross-correlation signal of transiting ultra-hot Jupiters: A study of 5 chemical species on WASP-76b

Ultra-hot Jupiters are perfect targets for transmission spectroscopy. However, their atmospheres feature strong spatial variations in temperature, chemistry, dynamics, cloud coverage, and scale height. This makes transit observations at high spectral resolution challenging to interpret. In this work, we model the cross-correlation signal of five chemical species (Fe, CO, H$_\text{2}$O, OH, and TiO) on WASP-76b, a benchmark ultra-hot Jupiter. We compute phase-dependent high-resolution transmission spectra of 3D SPARC/MITgcm models. The spectra are obtained with gCMCRT, a 3D Monte-Carlo radiative-transfer code. We find that, on top of atmospheric dynamics, the phase-dependent Doppler shift of the absorption lines in the planetary rest frame is shaped by the combined effect of planetary rotation and the unique 3D spatial distribution of chemical species. For species probing the dayside (e.g., refractories or molecules like CO and OH), the two effects act in tandem, leading to increasing blueshifts with orbital phase. For species that are depleted on the dayside (e.g., H$_\text{2}$O and TiO), the two effects act in an opposite manner, and could lead to increasing redshifts during the transit. This behaviour yields species-dependent offsets from a planet's expected $K_\text{p}$ value that can be much larger than planetary wind speeds. The offsets are usually negative for refractory species. We provide an analytical formula to estimate the size of a planet's $K_\text{p}$ offsets, which can serve as a prior for atmospheric retrievals. We conclude that observing the phase-resolved absorption signal of multiple species is key to constraining the 3D thermochemical structure and dynamics of ultra-hot Jupiters.

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arXiv2023

Modelling dynamically driven global cloud formation microphysics in the HAT-P-1b atmosphere

Insight into the formation and global distribution of cloud particles in exoplanet atmospheres continues to be a key problem to tackle going into the JWST era. Understanding microphysical cloud processes and atmospheric feedback mechanisms in 3D has proven to be a challenging prospect for exoplaneteers. In an effort to address the large computational burden of coupling these models in 3D simulations, we develop an open source, lightweight and efficient microphysical cloud model for exoplanet atmospheres. `Mini-cloud' is a microphysical based cloud model for exoplanet condensate clouds that can be coupled to contemporary general circulation models (GCMs) and other time dependent simulations. We couple mini-cloud to the Exo-FMS GCM and use a prime JWST target, the hot Jupiter HAT-P-1b, as a test case for the cloud formation module. After 1000+ of days of integration with mini-cloud, our results show a complex 3D cloud structure with cloud properties relating closely the dynamical and temperature properties of the atmosphere. Current transit and emission spectra data are best fit with a reduced cloud particle number density compared to the nominal simulation, with our simulated JWST NIRISS SOSS spectra showing promising prospects for characterising the atmosphere in detail. Overall, our study is another small step in first principles 3D exoplanet cloud formation microphysical modelling. We suggest that additional physics not included in the present model, such as coagulation, are required to reduce the number density of particles to appropriately observed levels.

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arXiv2023

Examining NHD vs QHD in the GCM THOR with non-grey radiative transfer for the hot Jupiter regime

Global circulation models (GCMs) play an important role in contemporary investigations of exoplanet atmospheres. Different GCMs evolve various sets of dynamical equations which can result in obtaining different atmospheric properties between models. In this study, we investigate the effect of different dynamical equation sets on the atmospheres of hot Jupiter exoplanets. We compare GCM simulations using the quasi-primitive dynamical equations (QHD) and the deep Navier-Stokes equations (NHD) in the GCM THOR. We utilise a two-stream non-grey "picket-fence" scheme to increase the realism of the radiative transfer calculations. We perform GCM simulations covering a wide parameter range grid of system parameters in the population of exoplanets. Our results show significant differences between simulations with the NHD and QHD equation sets at lower gravity, higher rotation rates or at higher irradiation temperatures. The chosen parameter range shows the relevance of choosing dynamical equation sets dependent on system and planetary properties. Our results show the climate states of hot Jupiters seem to be very diverse, where exceptions to prograde superrotation can often occur. Overall, our study shows the evolution of different climate states which arise just due to different selections of Navier-Stokes equations and approximations. We show the divergent behaviour of approximations used in GCMs for Earth, but applied for non Earth-like planets.

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arXiv2023

Dynamically coupled kinetic chemistry in brown dwarf atmospheres I. Performing global scale kinetic modelling

The atmospheres of brown dwarfs have been long observed to exhibit a multitude of non-equilibrium chemical signatures and spectral variability across the L, T and Y spectral types. We aim to investigate the link between the large-scale 3D atmospheric dynamics and time-dependent chemistry in the brown dwarf regime, and to assess its impact on spectral variability. We couple the miniature kinetic chemistry module `mini-chem' to the Exo-FMS general circulation model (GCM). We then perform a series of idealised brown dwarf regime atmospheric models to investigate the dynamical 3D chemical structures produced by our simulations. The GCM output is post-processed using a 3D radiative-transfer model to investigate hemisphere-dependent spectral signatures and rotational variability. Our results show the expected strong non-equilibrium chemical behaviour brought on by vertical mixing as well as global spacial variations due to zonal flows. Chemical species are generally globally homogenised, showing variations of $\pm$10\% or less, dependent on pressure level, and follow the dynamical structures present in the atmosphere. However, we find localised storm regions and eddies can show higher contrasts, up to $\pm$100\%, in mixing ratio compared to the background global mean. This initial study represents another step in understanding the connection between three-dimensional atmospheric flows in brown dwarfs and their rich chemical inventories.

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arXiv2023

Carbon monoxide emission lines reveal an inverted atmosphere in the ultra hot Jupiter WASP-33 b consistent with an eastward hot spot

We report the first detection of CO emission at high spectral resolution in the day-side infrared thermal spectrum of an exoplanet. These emission lines, found in the atmosphere of the transiting ultra hot Jupiter (UHJ) WASP-33 b, provide unambiguous evidence of its thermal inversion. Using spectra from the MMT Exoplanet Atmosphere Survey (MEASURE, $R\sim15,000$), covering pre- and post-eclipse phases, we cross-correlate with 1D PHOENIX spectral templates to detect CO at S/N = 7.9 ($v_{sys}=0.15^{+0.64}_{-0.65}$ km/s, $K_{p}=229.5^{+1.1}_{-1.0}$ km/s). Moreover, using cross-correlation-to-log-likelihood mapping, we find that the scaling parameter which controls the spectral line contrast changes with phase. We thus use the general circulation model SPARC/MITgcm post-processed by the 3D gCMCRT radiative transfer code to interpret this variation, finding it consistent with an eastward-shifted hot spot. Pre-eclipse, when the hot spot faces Earth, the thermal profiles are shallower leading to smaller line contrast despite greater overall flux. Post-eclipse, the western part of the day-side faces Earth and has much steeper thermal profiles, leading to larger line contrast despite less overall flux. This demonstrates that within the log-likelihood framework, even relatively moderate resolution spectra can be used to understand the 3D nature of close-in exoplanets, and that resolution can be traded for photon-collecting power when the induced Doppler-shift is sufficiently large. We highlight CO as a good probe of UHJ thermal structure and dynamics that does not suffer from stellar activity, unlike species that are also present in the host star e.g. iron lines.

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