arXiv subjects

Emily Z. Zhang

Publications and source records attributed to Emily Z. Zhang.

14 recordsLinked to original sources

arXiv2026

Hall conductivity reveals the nature of quantum coherence in strongly correlated metals

Linear-in-temperature resistivity is a hallmark for strange metallic transport, and appears universally in many strongly correlated electron systems. However, the focus on the longitudinal channel often overshadows the profound microscopic insights contained within the transverse response. Here, we utilize numerically exact determinantal quantum Monte Carlo simulations of the doped Hubbard model in a magnetic field to calculate longitudinal and transverse transport. We demonstrate that while the resistivity is robustly $T$-linear across parameter sets, the Hall response is highly sensitive to particle-hole asymmetry, Fermi surface topology, and many-body correlation effects. Specifically, the combination of these effects determine a crossover scale in which the system becomes quantum-coherent, and is reflected in the Hall conductivity. Our results demonstrate that while the $T$-linearity in resistivity appears universal, the Hall response reveals a crossover from semi-classical to quantum-coherent transport otherwise masked in the longitudinal channel.

cond-mat.str-el↗

arXiv2026

Electric field control of a quantum spin liquid in weak Mott insulators

The triangular lattice Hubbard model at strong coupling, whose effective spin model contains both Heisenberg and ring exchange interactions, exhibits a rich phase diagram as the ratio of the hopping $t$ to onsite Coulomb repulsion $U$ is tuned. This includes a chiral spin liquid (CSL) phase. Nevertheless, this exotic phase remains challenging to realize experimentally because a given material has a fixed value of $t/U$ that can difficultly be tuned with external stimuli. One approach to address this problem is applying a DC electric field, which renormalizes the exchange interactions as electrons undergo virtual hopping processes; in addition to creating virtual doubly occupied sites, electrons must overcome electric potential energy differences. Performing a small $t/U$ expansion to fourth order, we derive the ring exchange model in the presence of an electric field and find that it not only introduces spatial anisotropy but also tends to enhance the ring exchange term compared to the dominant nearest-neighbor Heisenberg interaction. Thus, increasing the electric field serves as a way to increase the importance of the ring exchange at constant $t/U$. Through density matrix renormalization group calculations, we compute the ground state phase diagram of the ring exchange model for two different electric field directions. In both cases, we find that the electric field shifts the phase boundary of the CSL towards a smaller ratio of $t/U$. Therefore, the electric field can drive a magnetically ordered state into the CSL. This explicit demonstration opens the door to tuning other quantum spin systems into spin liquid phases via the application of an electric field.

cond-mat.str-el↗

arXiv2025

Spin excitation continuum to topological magnon crossover and thermal Hall conductivity in Kitaev magnets

There has been great interest in identifying a Kitaev quantum spin liquid state in frustrated magnets with bond-dependent interactions. In particular, the experimental report of a half-quantized thermal Hall conductivity in $α$-RuCl$_3$ in the presence of a magnetic field has generated excitement as it could be strong evidence for a field-induced chiral spin liquid. More recent experiments, however, provide a conflicting interpretation advocating for topological magnons in the field-polarized state as the origin of the non-quantized thermal Hall conductivity observed in their experiments. An inherent difficulty in distinguishing between the two scenarios is the phase transition between a putative two-dimensional spin liquid and the field-polarized state exists only at zero temperature, while the behaviour at finite temperature is mostly crossover phenomena. In this work, we provide insights into the finite temperature crossover behavior between the spin excitation continuum in a quantum spin liquid and topological magnons in the field-polarized state in three different theoretical models with large Kitaev interactions. These models allow for a field-induced phase transition from a spin liquid (or an intermediate field-induced spin liquid) to the field-polarized state in the quantum model. We obtain the dynamical spin structure factor as a function of magnetic field using molecular dynamics simulations and compute thermal Hall conductivity in the field-polarized regime. We demonstrate the gradual evolution of the dynamical spin structure factor exhibiting crossover behaviour near magnetic fields where zero-temperature phase transitions occur in the quantum model. We also examine nonlinear effects on topological magnons and the validity of thermal Hall conductivity computed using linear spin wave theory. We discuss the implications of our results to existing and future experiments.

cond-mat.str-el↗

arXiv2025

Disentangling spin excitation continua in classical and quantum magnets using 2D nonlinear spectroscopy

Inelastic neutron scattering (INS) has traditionally been one of the primary methods for investigating quantum magnets, particularly in identifying a continuum of excitations as a hallmark of spin fractionalization in quantum spin liquids (QSLs). However, INS faces severe limitations due to its inability to distinguish between such QSL signatures and similar excitation continua arising from highly frustrated magnetic orders with large unit cells or classical spin liquids. In contrast, two-dimensional coherent spectroscopy (2DCS) has emerged as a powerful tool to probe nonlinear excitation dynamics, offering insights into the underlying mechanisms behind these broad spectral features. In this paper, we utilize classical molecular dynamics (MD) techniques to explore the 2DCS responses of frustrated magnets with dominant Kitaev interactions. Comparing the classical and quantum versions of the pure Kitaev model our results indicate both clear similarities, in the form of sharp line features, and clear distinctions, in the locations of these features and in selection rules. Moreover, in the extended $KΓΓ'$ model, we show that the 2DCS response of the Kitaev spin liquid is completely distinct from that of large unit cell magnetic orders, despite both generating a broad continuum in INS. Additionally, we demonstrate the extreme sensitivity of classical 2DCS to thermal fluctuations and discuss the potential significance of quantum coherence in experimental settings. Overall, our work illustrates the potential of 2DCS in resolving the complex physics underlying ambiguous spin excitation continua, thereby enhancing our understanding of the dynamics in these frustrated systems.

cond-mat.str-el↗

arXiv2025

Intrinsic Thermal Hall Effect in Mott Insulators

In light of recent experimental data indicating a substantial thermal Hall effect in square lattice antiferromagnetic Mott insulators, we investigate whether a simple Mott insulator can sustain a finite thermal Hall effect. We verify that the answer is "no" if one performs calculations within a spin-only low-energy effective spin model with non-interacting magnons. However, by performing determinant quantum Monte Carlo simulations, we show the single-band $t$-$t'$-$U$ Hubbard model coupled to an orbital magnetic field does support a finite thermal Hall effect when $t' \neq 0$ and $B \neq 0$ in the Mott insulating phase. We argue that the (carrier agnostic) necessary conditions for observing a finite thermal Hall effect are time-reversal and particle-hole symmetry breaking. By considering magnon-magnon scattering using a semi-classical Boltzmann analysis, we illustrate a physical mechanism by which finite transverse thermal conductivity may arise, consistent with our symmetry argument and numerical results. Our results contradict the conventional wisdom that square and triangular lattices with SU(2) symmetry do not support a finite thermal Hall effect and call for a critical re-examination of thermal Hall effect data in insulating magnets, as the magnon contribution should not be excluded a priori.

cond-mat.str-el↗

arXiv2025

Detection of chiral spin fluctuations driven by frustration in Mott insulators

Topologically ordered states, such as chiral spin liquids, have been proposed as candidates that host fractionalized excitations. However, detecting chiral character or proximity to these non-trivial states remains a challenge. Resonant Raman scattering can be a powerful tool for detecting chiral fluctuations, as the $A_{2g}$ channel probes excitations with broken time-reversal symmetry and local chiral order. Here, we use exact diagonalization to characterize the resonant $A_{2g}$ channel, alongside two-magnon scattering in $B_{1g}$ and $E_g$ channels, for the Hubbard model on lattices with increasing levels of geometric spin frustration, where tuning the incident energy near the Mott gap reveals strong chiral spin excitation intensity. Increased spin frustration in the Mott insulator results in an overall softening of the Raman $A_{2g}$ response, indicating a tendency toward low energy chiral-chiral fluctuations in Mott insulators with magnetic frustration and proximity to chiral spin liquid states that can potentially be tuned by external perturbations.

cond-mat.str-el↗

arXiv2024

Microscopic Roadmap to a Yao-Lee Spin-Orbital Liquid

The exactly solvable spin-1/2 Kitaev model on a honeycomb lattice has drawn significant interest, as it offers a pathway to realizing the long-sought after quantum spin liquid. Building upon the Kitaev model, Yao and Lee introduced another exactly solvable model on an unusual star lattice featuring non-abelian spinons. The additional pseudospin degrees of freedom in this model could provide greater stability against perturbations, making this model appealing. However, a mechanism to realize such an interaction in a standard honeycomb lattice remains unknown. Here we provide a microscopic theory to obtain the Yao-Lee model on a honeycomb lattice by utilizing strong spin-orbit coupling of anions edge-shared between two $e_g$ ions in the exchange processes. This mechanism leads to the desired bond-dependent interaction among spins rather than orbitals, unique to our model, implying that the orbitals fractionalize into gapless Majorana fermions and fermionic octupolar excitations emerge. Since the conventional Kugel-Khomskii interaction also appears, we examine the phase diagram including these interactions using classical Monte Carlo simulations and exact diagonalization techniques. Our findings reveal a broad region of disordered states that break rotational symmetry in the bond energy, suggesting intriguing behavior reminiscent of a spin-orbital liquid.

cond-mat.str-el↗

arXiv2024

Quantum Fluctuations Suppress the Critical Fields in BaCo$_2$(AsO$_4$)$_2$

Early efforts to realize exotic quantum ground states in frustrated magnets focused on frustration arising from the lattice geometry alone. Attention has shifted to bond-dependent anisotropic interactions, as well as further-neighbor interactions, on non-geometrically-frustrated lattices due to their greater versatility. The honeycomb magnet BaCo$_2$(AsO$_4$)$_2$ recently emerged as a candidate host for both bond-dependent (e.g. Kitaev) and third-neighbor ($J_3$) interactions, and has become a model experimental system due to its relatively low levels of disorder. Understanding the relative importance of different exchange interactions holds the key to achieving novel ground states, such as quantum spin liquids. Here, we use the magnetotropic susceptibility to map out the intermediate and high-field phase diagram of BaCo$_2$(AsO$_4$)$_2$ as a function of the out-of-plane magnetic field direction at $T = 1.6$ K. We show that the experimental data are qualitatively consistent with classical Monte Carlo results of the XXZ-$J_1$-$J_3$ model with small Kitaev and off-diagonal exchange couplings included. However, the calculated critical fields are systematically larger than the experimental values. Infinite-DMRG computations on the quantum model reveal that quantum corrections from a nearby ferromagnetic state are likely responsible for the suppressed critical fields. Together, our experiment and theory analyses demonstrate that, while quantum fluctuations play an important role in determining the phase diagram, most of the physics of BaCo$_2$(AsO$_4$)$_2$ can be understood in terms of the classical dynamics of long-range ordered states, leaving little room for the possibility of a quantum spin liquid.

cond-mat.str-el↗

arXiv2023

Topological magnons for thermal Hall transport in frustrated magnets with bond-dependent interactions

Thermal transport in topologically-ordered phases of matter provides valuable insights as it can detect the charge-neutral quasiparticles that would not directly couple to electromagnetic probes. An important example is edge heat transport of Majorana fermions in a chiral spin liquid, which leads to a half-quantized thermal Hall conductivity. This signature is precisely what has recently been measured in $α$-RuCl$_3$ under external magnetic fields. The plateau-like behavior of the half-quantized thermal Hall conductivity as a function of external magnetic field, and the peculiar sign change depending on the magnetic field orientation, has been proposed as strong evidence for the non-Abelian Kitaev spin liquid. Alternatively, for in-plane magnetic fields, it was theoretically shown that such a sign structure can also arise from topological magnons in the field-polarized state. In this work, we investigate the full implications of topological magnons as heat carriers on thermal transport measurements. We first prove analytically that for any commensurate order with a finite magnetic unit cell, reversing the field direction leads to a sign change in the magnon thermal Hall conductivity in two-dimensional systems. We verify this proof numerically with nontrivial magnetic orders as well as the field-polarized state in Kitaev magnets subjected to an in-plane field. In the case of a tilted magnetic field, whereby there exist both finite in-plane and out-of-plane field components, we find that the plateau-like behavior of the thermal Hall conductivity and the sign change upon reversing the in-plane component of the magnetic field arise in the partially-polarized state, as long as the in-plane field contribution to the Zeeman energy is significant. While these results are consistent with the experimental observations, we comment on other aspects requiring investigation in future studies.

cond-mat.str-el↗

arXiv2023

Uncovering footprints of dipolar-octupolar quantum spin ice from neutron scattering signatures

Recent experiments on Ce$_2$Zr$_2$O$_7$ suggest that this material may host a novel form of quantum spin ice, a three-dimensional quantum spin liquid with an emergent photon. The Ce$^{3+}$ local moments on the pyrochlore lattice are described by pseudospin 1/2 degrees of freedom, whose components transform as dipolar and octupolar moments under symmetry operations. In principle, there exist four possible quantum spin ice regimes, depending on whether the Ising component is in the dipolar/octupolar channel, and two possible flux configurations of the emergent gauge field. In this work, using exact diagonalization and molecular dynamics, we investigate the equal-time and dynamical spin structure factors in all four quantum spin ice regimes using quantum and classical computations. Contrasting the distinct signatures of quantum and classical results for the four possible quantum spin ice regimes and elucidating the role of quantum fluctuations, we show that the quantum structure factor computed for the $π$-flux octupolar quantum spin ice regime is most compatible with the neutron scattering results on Ce$_2$Zr$_2$O$_7$.

cond-mat.str-el↗

arXiv2022

Geometrical frustration versus Kitaev interactions in BaCo$_2$(AsO$_4$)$_2$

Recently, Co-based honeycomb magnets have been proposed as promising candidate materials to host the Kitaev spin liquid state. One of the front-runners is BaCo$_2$(AsO$_4$)$_2$ (BCAO), where it was suggested that the exchange processes between Co$^{2+}$ ions via the surrounding edge-sharing oxygen octahedra could give rise to bond-dependent Kitaev interactions. In this work, we present and analyze comprehensive inelastic neutron scattering studies of BCAO with fields in the honeycomb plane. Combining the constraints from the magnon excitations in the high-field polarized state and the inelastic spin structure factor measured in zero magnetic field, we examine two leading theoretical models: the Kitaev-type \JKG model and the \XXZ model. We show that the existing experimental data can be consistently accounted for by the \XXZ model but not by the \JKG model, and we discuss the implications of these results for the realization of a spin liquid phase in BCAO and more generally for the realization of the Kitaev model in cobaltates.

cond-mat.str-el↗

arXiv2021

Dynamical Signatures of Rank-2 $U(1)$ Spin Liquids

Emergent $U(1)$ gauge theories and artificial photons in frustrated magnets are outstanding examples of many-body collective phenomena. The classical and quantum regimes of these systems provide platforms for classical and quantum spin liquids, and are the subject of current active theoretical and experimental investigations. Recently, realizations of rank-2 $U(1)$ (R2-U1) gauge theories in three-dimensional frustrated magnets have been proposed. Such systems in the quantum regime may lead to the so-called fracton ordered phases -- a new class of topological order that has been associated with quantum stabilizer codes and holography. However, there exist few distinguishing characteristics of these states for their detection in real materials. Here we focus on the classical limit, and present the dynamical spin structure factor for a R2-U1 spin liquid state on a breathing pyrochlore lattice. Remarkably, we find unique signatures of the R2-U1 state, and we contrast them with the results obtained from a more conventional $U(1)$ spin liquid. These results provide a new path of investigation for future inelastic neutron scattering experiments on candidate materials.

cond-mat.str-el↗

arXiv2020

Sign structure of thermal Hall conductivity for in-plane-field polarized Kitaev magnets

The appearance of half-quantized thermal Hall conductivity in $α$-RuCl$_3$ in the presence of in-plane magnetic fields has been taken as a strong evidence for Kitaev spin liquid. Apart from the quantization, the observed sign structure of the thermal Hall conductivity is also consistent with predictions from the exact solution of the Kitaev model. Namely, the thermal Hall conductivity changes sign when the field direction is reversed with respect to the heat current, which is perpendicular to one of the three nearest neighbor bonds on the honeycomb lattice. On the other hand, it is almost zero when the field is applied along the bond direction. Here, we show that such a peculiar sign structure of the thermal Hall conductivity is a generic property of the polarized state in the presence of in-plane magnetic-fields. In this case, thermal Hall effect arises from topological magnons with finite Chern numbers and the sign structure follows from the symmetries of the momentum space Berry curvature. Using a realistic spin model with bond-dependent interactions, we show that the thermal Hall conductivity can have a magnitude comparable to that observed in the experiments. Hence the sign structure alone cannot make a strong case for Kitaev spin liquid. The quantization at very low temperatures, however, will be a decisive test as the magnon contribution vanishes in the zero temperature limit.

cond-mat.str-el↗

arXiv2019

Efficiency limits of electronically-coupled upconverter and quantum ratchet solar cells using detailed balance

The intermediate band solar cell (IBSC) and quantum ratchet solar cell (QRSC) have the potential to surpass the efficiency of standard single-junction solar cells by allowing sub-gap photon absorption through states deep inside the band gap. High efficiency IBSC and QRSC devices have not yet been achieved, however, since introducing mid-gap states also increases recombination, which can harm the device. We consider the electronically coupled upconverter (ECUC) solar cell and show that it can achieve the same efficiencies as the QRSC. Although they are equivalent in the detailed balance limit, the ECUC is less sensitive to nonradiative processes, which makes it a more practical implementation for IB devices. We perform a case study of crystalline-silicon based ECUC cells, focusing on hydrogenated amorphous silicon as the upconverter material and highlighting potential dopants for the ECUC. These results illustrate a new path for the development of IB-based devices.

physics.app-ph↗