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Emmanuelle Rio

Publications and source records attributed to Emmanuelle Rio.

At least 19 recordsLinked to original sources

Stabilising Evaporating Soap Films with Salt

We investigate the effect of a high concentration (32.5 g.L$^{-1}$) of sodium chloride (NaCl) on TTAB (tetradecyltrimethylammonium bromide) vertical soap films also called foam films, pulled out of a bath under controlled humidity conditions. We observe that the film lifetime increases with relative humidity, both in the presence and absence of salt. At any given humidity, the presence of NaCl systematically enhances film stability. Our film thickness measurements show that the thinning dynamics with or without salt are nearly identical down to 100 nm. Down to that thickness, the effect of evaporation can be rationalised by a constant evaporation rate, which becomes non-negligible compared to the drainage rate at film thicknesses below 400 nm. The main effect of salt is the stabilisation of a Newton black film at a thickness of approximately 5~nm, whereas in the absence of salt, the film ruptures upon reaching a critical thickness of about 10 nm.

physics.flu-dyn

Air entrainment by an inclined smooth water jet

Air entrainment can occur when a water jet impacts a water/air interface, a process central in various real systems, ranging from dam spills to breaking waves. Despite its prevalence, a comprehensive description of the mechanism controlling bubble size distribution remains elusive. Here, we establish a link between the geometry and the dynamics of the cavity observed when an inclined impinging jet impacts a water interface and the resulting bubble cloud. We show that the bubbles result from the destabilization of the wavefield developing at the interface of the cavity. The origin of this wave field is the creation of a shear layer, due to the asymmetric detachment of the flow field from the interface.

physics.flu-dyn

Shape of an interface hit by an oblique jet

We report on the shape taken by the interface of a liquid bath when hit by a smooth oblique steady jet. When the angle between the jet and the bath decreases below $50^\circ$, a cavity is formed in front of the jet. In the inertial regime we explore, the jet boundary layer detaches in the impact region, thereby delimiting a core jet region outside of which the liquid is mainly in hydrostatic equilibrium. The shape of the outer meniscus is shown to be related to the one outside a tilted fiber piercing the fluid interface. In order to unravel the flow features and separation, we perform direct numerical simulations and show that the flow detachment displays an asymmetry, which results in the acceleration of the liquid below the surface, thereby creating a depression. With this observation, we propose a model balancing the suction force of this depression with the weight of the displaced water and the surface tension force to obtain a prediction for the typical width of the cavity.

physics.flu-dyn

White light interferometry analysis for measuring thin film thickness down to few nanometers

We present a practical white-light interferometric method, supported by an open-source Python library \textit{optifik} for automated spectrum-to-thickness deduction, enabling foam film measurements down to a few nanometers. We describe three typical spectral scenarii encountered in this method: spectra exhibiting numerous interference fringes, spectra with a moderate number of peaks, and spectra with only a few identifiable features, providing illustrative examples for each case. We also discuss the main limitations of the technique, including spectral range constraints, the necessity of knowing the refractive index, and the influence of spectral resolution and signal quality. Finally, we demonstrate the application of the method in a time-resolved study of a TTAB (tetradecyltrimethylammonium bromide) foam film undergoing elongation and thinning. This method can be adapted to measure any thin non-opaque layer.

physics.optics

Enhanced Coalescence in Driven Foams

External driving leads to the emergence of unique phenomena and properties in soft matter systems. We show that driving quasi-2D foams by mechanical vibration results in significant bubble coalescence, which is enhanced by the continuous phase yield stress. The competition between coarsening and coalescence can be modulated through vibration amplitude and foam liquid fraction, which can be used to create unusual structural motifs. The combined effect of coarsening and coalescence is captured through a statistical model that quantitatively describes the time evolution of the number of bubbles.

cond-mat.soft

Capillary jet in a slab of foam

A capillary jet plunging into a quasi-2D slab of monodisperse foam of the same solution is studied experimentally. We show that the jet can have a drastic impact on the foam. At small speeds it inflates the channels separating the bubbles. At intermediate speeds, impact with channels creates very small bubbles. At higher speeds, the jet thins the foam films, which can result in bubble rupture. We study the mechanisms behind these processes using an elementary foam formed by three soap films in contact through a Plateau border. We obtain scaling laws, which transfer quantitatively from the elementary foam to the 2D foam.

cond-mat.soft

Reducing Foam Friction with Self Slippery Liquid-Infused Porous Surfaces

Acquiring a comprehensive understanding of the interplay between foam friction and surface roughness is essential for achieving precise control over their flow dynamics. In particular, a major challenge is to reduce friction, which can be achieved with rough surfaces in the situation where a liquid infuses the asperities. In this study, we propose to explore self-infused surfaces. We first present simple observations to demonstrate the effectiveness of our surface design by recording the motion of a foam puddle on a smooth surface and a self-SLIPS. To quantify friction reduction, we conduct stress measurements on surfaces moved at a constant velocity. Finally, we interpret the variation of the friction force with the velocity by a model considering an effective slip length of the surface. This research paves the way for a novel approach to mitigate dissipation in liquid foam flows, holding significant implications for reducing energy consumption in conveying foams for industrial processes and various end-use applications.

physics.flu-dyn

Hydrodynamic thinning of a coating film induced by a small solid defect: evidence of a time-minimum thickness

During coating processes, dust deposition can lead to an uneven thickness in the resulting film, posing significant problems in industrial processes. Our study explores the effects of solid defects using a vertical cylindrical fiber deposited on a silicone oil film coating a horizontal solid substrate. We use a hyperspectral camera to measure the film thickness by interferometry in the vicinity of the defect. As predicted and observed in many studies in various geometries, a circular groove appears around the fiber because of the capillary suction induced by the meniscus that grows at the bottom of the fiber. We measure the evolution of the thickness of the film at the groove over time. The thickness decreases before increasing again leading to the healing of the perturbation at long time. We propose that healing is due to the arrest of the suction when the meniscus reaches its equilibrium shape. By combining geometric analysis with the thin film equation, we have developed scaling laws that predict both the minimum thickness of the groove, that we call the time-minimum thickness, and the time required to reach this minimum. If the time-minimum thickness reaches the thickness at which intermolecular forces begin to play a role prior to healing, the thickness of the groove will stop decreasing and saturate due to the competition between drainage and repulsive intermolecular forces. Based on the previous scaling law, we developed a scaling law accounting for the critical initial thickness of the film below which the intermolecular repulsion will start to have an effect, which is in good agreement with our experiments. These results thus offer valuable insights into predicting and preventing defects in coating processes, thereby improving the quality and reliability of coated products in various industries.

cond-mat.soft

Anomalous relaxation of coarsening foams with viscoelastic continuous phase

We investigate the ultraslow structural relaxation of ageing foams with rheologically-tunable continuous phases. We probe the bubble dynamics associated with pressure-driven foam coarsening using differential dynamic microscopy, which allows characterizing the sample dynamics in the reciprocal space with imaging experiments. Similar to other out-of-equilibrium jammed soft systems, these foams exhibit compressed exponential relaxations, with a ballistic-like linear dependency of the relaxation rate on the scattering wavevector. By tuning the rheology of the continuous phase we observe changes in the relaxation shape, where stiffer matrices yield larger compressing exponents. Our results corroborate recent real-space observations obtained with bubble tracking, providing a comprehensive overview of structural relaxation in these complex systems, both in direct and reciprocal space.

cond-mat.soft

Matrix viscoelasticity decouples bubble growth and dynamics in coarsening foams

Pressure-driven coarsening triggers bubble rearrangements in liquid foams. Our experiments show that changing the continuous phase rheology can alter these internal bubble dynamics without influencing the coarsening kinetics. Through bubble tracking, we find that increasing the matrix yield stress permits bubble growth without stress relaxation via neighbor-switching events, promoting more spatially homogeneous rearrangements and decoupling bubble growth from dynamics. This eventually leads to a structural change which directly impacts the foam mechanical and stability properties, essential for applications in various technological and industrial contexts.

cond-mat.soft

Straight to zigzag transition of foam pseudo Plateau borders on textured surfaces

The structure of liquid foams follows simple geometric rules formulated by Plateau 150 years ago. By placing such foam on a microtextured hydrophilic surface, we show that the bubble footprint exhibits a morphological transition. This transition concerns the liquid channels, also called pseudo Plateau borders, which are straight between vertices on a smooth surface. We demonstrate experimentally that for a sufficiently large roughness size compared to the width of the liquid channels, the footprint adopts a zigzag shape. This transition is associated with the absence of a wetting film between the pillars caused by capillary suction of the foam, observed by confocal microscopy. We rationalize the number of zigzag segments by a geometric distribution describing the observations made with the footprint perimeter and the mesh size of the asperities.

cond-mat.soft

Lifetime of vertical giant soap films: role of the relative humidity and film dimensions

We consider the lifetime of rectangular vertical soap films and we explore the influence of relative humidity and both dimensions on the stability of large soap films, reaching heights of up to 1.2 m. Using an automated rupture detection system, we achieve a robust statistical measurement of their lifetimes and we also measure the film thinning dynamics. We demonstrate that drainage has a negligible impact on the film stability as opposed to evaporation. To do so, we compare the measured lifetimes with predictions from the Boulogne \& Dollet model \cite{BoulogneDollet2018}, originally designed to describe the convective evaporation of hydrogels. Interestingly, we show that this model can predict a maximum film lifetime for all sizes.

cond-mat.soft

Effective water/water contact angle at the base of an impinging jet

The base of a jet impinging on an ultrapure water bath is studied experimentally. At the impact point, a train of capillary waves develops along the jet. By performing Particle Tracking Velocity measurements, we show that there is a boundary layer separation between the jet and the meniscus. We thus describe the shape of this meniscus with a hydrostatic model. A striking observation is the existence of an effective non-zero water/water contact angle between the jet and the meniscus. The rationalization of this finite contact angle requires a full description of the shape of the interface. By doing an analytical matching between the meniscus and the jet, we show that the capillary waves can be considered as reflected waves present to ensure pressure continuity. It is finally shown that the value of the apparent contact angle is fixed by energy minimization, with an excellent agreement between prediction and experiment for small jets.

physics.flu-dyn

Evaporation-induced temperature gradient in a foam column

Various parameters affect the foam stability: surface and bulk rheology of the solution, gravitational drainage, mechanical vibrations, bubble gas composition, and also evaporation. Evaporation is often considered through the prism of a liquid loss, but it also induces a cooling effect due to the enthalpy of vaporization. In this study, we combine a theoretical and experimental approach to explore the temperature field in a foam column evaporating from the top. We show that a measurable temperature profile exists in this geometry with temperatures at the interface lower than the environmental temperature by few degrees. We demonstrate that the temperature profile is the result of a balance between the enthalpy of vaporization and heat fluxes originating from the thermal conduction of foam and air and the thermal radiation. For small foam thicknesses compared to the radius, we found that the temperature gradient is established over the foam thickness while for large aspect ratios, the gradient is spanning over a lengthscale comparable to the tube radius.

cond-mat.soft

Dynamics of bubbles spontaneously entering in a tube

When an open tube of small diameter touches a bubble of a larger diameter, the bubble spontaneously shrinks and pushes a soap film in the tube. We characterize the dynamics for different bubble sizes and number of soap films in the tube. We rationalize this observation from a mechanical force balance involving the Laplace pressure of the bubble and the viscous force from the advancing soap lamellae in the tube. We propose a numerical resolution of this model, and an analytical solution in an asymptotic regime. These predictions are then compared to the experiments. The emptying duration is primarily affected by the initial bubble to tube diameter ratio and by the number of soap films in the tube.

cond-mat.soft

Hierarchical bubble size distributions in coarsening wet liquid foams

Coarsening of two-phase systems is crucial for the stability of dense particle packings such as alloys, foams, emulsions or supersaturated solutions. Mean field theories predict an asymptotic scaling state with a broad particle size distribution. Aqueous foams are good model systems for investigations of coarsening-induced structures, because the continuous liquid as well as the dispersed gas phases are uniform and isotropic. We present coarsening experiments on wet foams, with liquid fractions up to their unjamming point and beyond, that are performed under microgravity to avoid gravitational drainage. As time elapses, a self-similar regime is reached where the normalized bubble size distribution is invariant. Unexpectedly, the distribution features an excess of small \textit{roaming} bubbles, mobile within the network of \textit{jammed} larger bubbles. These roaming bubbles are reminiscent of rattlers in granular materials (grains not subjected to contact forces). We identify a critical liquid fraction $\phi^*$, above which the bubble assembly unjams and the two bubble populations merge into a single narrow distribution of bubbly liquids. Unexpectedly, $\phi^*$ is larger than the random close packing fraction of the foam $\phi_{rcp}$. This is because, between $\phi_{rcp}$ and $\phi^*$, the large bubbles remain connected due to a weak adhesion between bubbles. We present models that identify the physical mechanisms explaining our observations. We propose a new comprehensive view of the coarsening phenomenon in wet foams. Our results should be applicable to other phase-separating systems and they may also help to control the elaboration of solid foams with hierarchical structures.

cond-mat.soft

Coarsening transitions of wet liquid foams under microgravity conditions

We report foam coarsening studies which were performed in the International Space Station (ISS) to suppress drainage due to gravity. Foams and bubbly liquids with controlled liquid fractions $\phi$ between 15 and 50\% were investigated to study the transition between bubble growth laws previously reported near the dry limit $\phi \rightarrow 0$ and the dilute limit $\phi \rightarrow 1$ (Ostwald ripening). We determined the coarsening rates; for the driest foams and the bubbly liquids, they are in close agreement with theoretical predictions. We observe a sharp cross-over between the respective laws at a critical value $\phi^*$. At liquid fractions beyond this transition, neighboring bubbles are no longer all in contact, like at a jamming transition. Remarkably $\phi^*$ is significantly larger than the random close packing volume fraction of the bubbles $\phi_{\text{rcp}}$ which was determined independently. We attribute the differences between $\phi^*$ and $\phi_{\text{rcp}}$ to a weakly adhesive bubble interaction that we have studied in complementary ground-based experiments.

cond-mat.soft

Measurement of the temperature decrease in evaporating soap films

Recent advances have demonstrated that evaporation can play a significant role on soap film stability, which is a key concern in many industrial areas but also for children playing with bubbles. Thus, evaporation leads to a film thinning but also to a film cooling, which has been overlooked for soapy objects. Here, we study the temperature variation of an evaporating soap film for different values of relative humidity and glycerol concentrations. We evidence that the temperature of soap films can decrease after their creation up to 8$~^\text{o}$C. We propose a model describing the temperature drop of soap films after their formation that is in quantitative agreement with our experiments. We emphasize that this cooling effect is significant and must be carefully considered in future studies on the dynamics of soap films.

cond-mat.soft