arXiv subjects

Enrico Gnecco

Publications and source records attributed to Enrico Gnecco.

7 recordsLinked to original sources

arXiv2026

Velocity Weakening in Anisotropic Friction on a Tilted Titania Nanorod Forest

In this study, we demonstrate velocity-dependent directional friction on a surface structured with tilted (~57°) titania nanorods using standard and colloidal probe force microscopy. Friction is measured at four different sliding speeds in two configurations, along and opposite to the tilt and perpendicular to the tilt direction, exhibiting anisotropic friction. Furthermore, friction decreases logarithmically with increasing sliding speed, which is attributed to the viscoelastic bending of the nanorods caused by stress-induced defect migration. The velocity weakening is more pronounced in the direction perpendicular to the tilt than along and opposite to it. The experimental findings are corroborated by creep measurements, which are well-reproduced by the Standard Linear Solid (SLS) model of viscoelasticity. Our results may be applied to the development of direction- and velocity-dependent sensors for microscale sliding motion as a robust alternative to structured interfaces based on polymeric materials.

cond-mat.soft↗

arXiv2025

A comparative nanotribological investigation on amorphous and polycrystalline forms of MoS2

The wear behavior of two amorphous and polycrystalline forms of MoS2 prepared by magnetron sputtering has been characterized in a combined nanoindentation and atomic force microscopy study. From the analysis of the depth and width of wear tracks estimated after scratching the surfaces with a Berkovich indenter and a loading force up to 2 mN, we conclude that both forms follow the Archard wear equation, and the wear resistance is about four times higher on the amorphous MoS2. Moreover, a comparison of lateral force maps on pristine and worn areas shows a considerable reduction of friction on both forms, which is possibly due to the significant smoothing of the surfaces caused by scratching. With normal forces in the micro N range, the analysis is made difficult by the fact that the linear dimensions of the wear tracks are comparable to those of the granular structures forming the surfaces. Even if the Archard equation could not be tested in this case, the wear resistance is considerably larger on amorphous MoS2 also on the nanoscale. In this way, our results disclose information on the nanotribology of MoS2 thin films in forms different from the layered structures commonly discussed in the literature. The amorphous form outperforms the polycrystalline one.

cond-mat.mtrl-sci↗

arXiv2025

Avalanche Dynamics in Stick-Slip Cutting of Molybdenum Disulfide

We have investigated nanoscale wear on multilayered MoS2, the flagship transition metal dichalcogenide, by elastically driving sharp diamond tips under normal loads sufficient to induce in-plane fracture. The accompanying friction and the resulting wear structures were first characterized by atomic force microscopy (AFM), revealing a stick-slip regime that drives progressive exfoliation of MoS2 chips. At high normal forces, the slip phase displays hallmark signatures of avalanche dynamics, observed for the first time at the nanoscale, evidenced by a Generalized Extreme Value distribution of friction force drops. The AFM characterization is corroborated by molecular dynamics simulations, which reproduce experimental trends and uncover atomistic details of the wear process, including local amorphization, layer curving, and the involvement of distinct dissipative channels. Notably, it appears that only one-fifth of the energy inputted into the system is used to damage the MoS2 surface irreversibly. These results offer new insight into the physical mechanisms governing friction and wear in layered solids and provide a framework for precision cutting and nanomachining in van der Waals materials, relevant to next-generation devices at sub-micrometer scales.

cond-mat.mtrl-sci↗

arXiv2021

Anisotropic Frictional Response of Texture Induced Strained Graphene

Friction-induced energy dissipation impedes the performance of nanoscale devices during their relative motion. Nevertheless, an ingeniously designed structure which utilizes graphene topping can tune the friction force signal by inducing local strain. The present work reports capping of graphene over Si grooved surfaces of different pitch lengths from sub-nanoscale (P=40 nm) to a quarter of a micron (P= 250 nm). The variation in the pitch lengths induces different strains in graphene revealed by scanning probe techniques, Raman spectroscopy and molecular dynamics (MD) simulation. The asymmetric straining of C-C bonds over the groove architecture is exploited through friction force microscopy in different directions of orthogonal and parallel to groove axis. The presence of graphene lubricates the textured surface by a factor of 10 and periodically dissipated friction force, which was found to be stochastic over the bare surface. For the first time, we presented transformation of the lubrication into an ultra-low friction force by a factor of 20 over the crest scanning parallel to the groove axis. Such anisotropy is found to be insignificant at the bare textured system, clearly demonstrating the strain-dependent regulation of friction force. Our results are applicable for graphene, and other 2D materials covered corrugated structures with movable components such as NEMS, nanoscale gears and robotics.

cond-mat.mtrl-sci↗

arXiv2018

Large-area fabrication of low- and high-spatial-frequency laser-induced periodic surface structures on carbon fibers

The formation and properties of laser-induced periodic surface structures (LIPSS) were investigated on carbon fibers under irradiation of fs-laser pulses characterized by a pulse duration $τ$ = 300 fs and a laser wavelength $λ$ = 1025 nm. The LIPSS were fabricated in an air environment at normal incidence with different values of the laser peak fluence and number of pulses per spot. The morphology of the generated structures was characterized by using scanning electron microscopy, atomic force microscopy and Fast-Fourier transform analyses. Moreover, the material structure and the surface chemistry of the carbon fibers before and after laser irradiation was analyzed by micro Raman spectroscopy and X-ray photoelectron spectroscopy. Large areas in the cm$^{2}$ range of carbon fiber arrangements were successfully processed with homogenously distributed high- and low-spatial frequency LIPSS. Beyond those distinct nanostructures, hybrid structures were realized for the very first time by a superposition of both types of LIPSS in a two-step process. The findings facilitate the fabrication of tailored LIPSS-based surface structures on carbon fibers that could be of particular interest for e.g. fiber reinforced polymers and concretes.

cond-mat.mtrl-sci↗

arXiv2018

Conformation And Mechanical Response of Spray Deposited Single Strand DNA on Gold

Single molecule force spectroscopy of DNA strands adsorbed at surfaces is a powerful technique used in air or liquid environments to quantify their mechanical properties. Although the force responses are limited to unfolding events so far, single base detection might be possible in more drastic cleanliness conditions such as ultra high vacuum. Here, we report on high resolution imaging and pulling attempts at low temperature (5K) of a single strand DNA (ssDNA) molecules composed of 20 cytosine bases adsorbed on Au(111) by scanning probe microscopy and numerical calculations. Using electrospray deposition technique, the ssDNA were successfully transferred from solution onto a surface kept in ultra high vacuum. Real space characterizations reveal that the ssDNA have an amorphous structure on gold in agreement with numerical calculations. Subsequent substrate annealing promotes the desorption of solvent molecules, DNA as individual molecules as well as the formation of DNA self assemblies. Furthermore, pulling experiments by force spectroscopy have been conducted to measure the mechanical response of the ssDNA while detaching. A periodic pattern of 0.2 to 0.3nm is observed in the force curve which arises from the stick slip of single nucleotide bases over the gold. Although an intra molecular response is obtained in the force curve, a clear distinction of each nucleotide detachment is not possible due the complex structure of ssDNA adsorbed on gold.

cond-mat.soft↗

arXiv2016

Superlubricity of Graphene Nanoribbons on Gold Surfaces

The state of vanishing friction known as superlubricity has important applications for energy saving and increasing the lifetime of devices. Superlubricity detected with atomic force microscopy appears in examples like sliding large graphite flakes or gold nanoclusters across surfaces. However, the origin of the behavior is poorly understood due to the lack of a controllable nano-contact. We demonstrate graphene nanoribbons superlubricity when sliding on gold with a joint experimental and computational approach. The atomically well-defined contact allows us to trace the origin of superlubricity, unravelling the role played by edges, surface reconstruction and ribbon elasticity. Our results pave the way to the scale-up of superlubricity toward the realization of frictionless coatings.

cond-mat.mes-hall↗