SearcharxivSearch

arXiv subjects

Enyuan Hu

Publications and source records attributed to Enyuan Hu.

3 recordsLinked to original sources

Pattern-Enhanced RT-DETR for Multi-Class Battery Detection

Accurate and efficient battery detection is increasingly important for applications in electronic waste recycling, industrial quality control, and automated sorting systems. In this paper, we present both a comprehensive benchmark and a novel method for multi-class battery detection. We systematically compare three CNN-based detectors (YOLOv8n, YOLOv8s, YOLO11n) and two transformer-based detectors (RT-DETR-L, RT-DETR-X) on a publicly available dataset of approximately 8,591 annotated images under identical experimental conditions, and further propose PaQ-RT-DETR, which introduces pattern-based dynamic query generation into RT-DETR to alleviate query activation imbalance with negligible computational overhead. Among baselines, YOLO11n achieves the best CNN-based accuracy (mAP@50: 0.779) at only 2.6M parameters, while YOLOv8n delivers the fastest inference at ~1,667 FPS. PaQ-RT-DETR-X achieves the highest overall mAP@50 of 0.782, surpassing RT-DETR-X by +2.8% with consistent per-class gains across all six battery categories including the data-scarce Bike Battery class. Our findings provide practical guidance for selecting object detection models in battery-related industrial applications.

cs.CV

Localized High-Concentration Electrolytes Get More Localized Through Micelle-Like Structures

Liquid electrolytes in batteries are typically treated as macroscopically homogeneous ionic transport media despite having complex chemical composition and atomistic solvation structures, leaving a knowledge gap of microstructural characteristics. Here, we reveal a unique micelle-like structure in a localized high-concentration electrolyte (LHCE), in which the solvent acts as a surfactant between an insoluble salt in diluent. The miscibility of the solvent with the diluent and simultaneous solubility of the salt results in a micelle-like structure with a smeared interface and an increased salt concentration at the centre of the salt-solvent clusters that extends the salt solubility. These intermingling miscibility effects have temperature dependencies, wherein an exemplified LHCE peaks in localized cluster salt concentration near room temperature and is utilized to form a stable solid-electrolyte interphase (SEI) on Li-metal anode. These findings serve as a guide to predicting a stable ternary phase diagram and connecting the electrolyte microstructure with electrolyte formulation and formation protocols to form stable SEI for enhanced battery cyclability.

cond-mat.mtrl-sci

Simultaneous Single Crystal Growth and Segregation of Ni-Rich Cathode Enabled by Nanoscale Phase Separation for Advanced Lithium-Ion Batteries

Synthesis of high-performance single crystal LiNi0.8Mn0.1Co0.1O2 (NMC811) in the absence of molten salt is challenging with no success yet. An innovative drop-in approach is discovered to synthesize single crystal NMC811 by controlling the morphology of transition metal hydroxide TM(OH)2 precursors followed by a simple decomposition step to form transition metal oxide (TMO) intermediates. Ni redistribution in TMO, as a result of the concurrent formation of mixed spinel and rock salt phases, helps deagglomerate the later formed NMC811 clusters of single crystals. As-prepared single crystal NMC811 is validated in a 2Ah pouch cell demonstrating 1000 stable cycling. The fundamentally new reaction mechanism of single crystal growth and segregation without molten salt provides a new direction towards cost-efficient manufacturing of single crystal NMC811 cathode for advanced lithium-based batteries.

cond-mat.mtrl-sci