arXiv subjects

Eric D. Bauer

Publications and source records attributed to Eric D. Bauer.

At least 37 records · Page 2Linked to original sources

arXiv2024

Stabilization of U 5$f^2$ configuration in UTe$_2$ through U 6d dimers in the presence of Te2 chains

We investigate the topological superconductor candidate UTe$_2$ using high-resolution valence-band resonant inelastic x-ray scattering at the U $M_{4,5}$-edges. We observe atomic-like low-energy excitations that support the correlated nature of this unconventional superconductor. These excitations originate from the U $5f^2$ configuration, which is unexpected since the short Te2-Te2 distances exclude Te2 being 2-. By utilizing the photoionization cross-section dependence of the photoemission spectra in combination with band structure calculations, we infer that the stabilization of the U $5f^2$ configuration is due to the U $6d$ bonding states in the U-dimers acting as a charge reservoir. Our results emphasize that the description of the physical properties should commence with a $5f^2$ $ansatz$.

cond-mat.str-el↗

arXiv2024

Spectroscopic evidence of Kondo-induced quasi-quartet in CeRh$_2$As$_2$

CeRh$_2$As$_2$ is a new multiphase superconductor with strong suggestions for an additional itinerant multipolar ordered phase. The modeling of the low temperature properties of this heavy fermion compound requires a quartet Ce$^{3+}$ crystal-field ground state. Here we provide the evidence for the formation of such a quartet state using x-ray spectroscopy. Core-level photoelectron and x-ray absorption spectroscopy confirm the presence of Kondo hybridization in CeRh$_2$As$_2$. The temperature dependence of the linear dichroism unambiguously reveils the impact of Kondo physics for coupling the Kramer's doublets into an effective quasi-quartet. Non-resonant inelastic x-ray scattering data find that the $|Γ_7^- \rangle$ state with its lobes along the 110 direction of the tetragonal structure ($xy$ orientation) contributes most to the multi-orbital ground state of CeRh$_2$As$_2$.

cond-mat.str-el↗

arXiv2023

Triple-sinusoid hedgehog lattice in a centrosymmetric Kondo metal

Superposed symmetry-equivalent magnetic ordering wave vectors can lead to topologically non-trivial spin textures, such as magnetic skyrmions and hedgehogs, and give rise to novel quantum phenomena due to fictitious magnetic fields associated with a non-zero Berry curvature of these spin textures. To date, all known spin textures are constructed through the superposition of multiple spiral orders, where spins vary in directions with constant amplitude. Recent theoretical studies have suggested that multiple sinusoidal orders, where collinear spins vary in amplitude, can construct distinct topological spin textures regarding chirality properties. However, such textures have yet to be experimentally realised. In this work, we report the observation of a zero-field magnetic hedgehog lattice from a superposition of triple sinusoidal wave vectors in the magnetically frustrated Kondo lattice CePtAl4Ge2. Notably, we also observe the emergence of anomalous electrical and thermodynamic behaviours near the field-induced transition from the zero-field topological hedgehog lattice to a non-topological sinusoidal state. These observations highlight the role of Kondo coupling in stabilising the zero-field hedgehog state in the Kondo lattice and warrant an expedited search for other topological magnetic structures coupled with Kondo coupling.

cond-mat.str-el↗

arXiv2023

Evidence for charge delocalization crossover in the quantum critical superconductor CeRhIn$_5$

The nature of charge degrees-of-freedom distinguishes scenarios for interpreting the character of a second order magnetic transition at zero temperature, that is, a magnetic quantum critical point (QCP). Heavy-fermion systems are prototypes of this paradigm, and in those, the relevant question is where, relative to a magnetic QCP, does the Kondo effect delocalize their $f$-electron degrees-of-freedom. Herein, we use pressure-dependent Hall measurements to identify a finite-temperature scale $E_\text{loc}$ that signals a crossover from $f$-localized to $f$-delocalized character. As a function of pressure, $E_\text{loc}(P)$ extrapolates smoothly to zero temperature at the antiferromagnetic QCP of CeRhIn$_5$ where its Fermi surface reconstructs, hallmarks of Kondo-breakdown criticality that generates critical magnetic and charge fluctuations. In 4.4% Sn-doped CeRhIn$_5$, however, $E_\text{loc}(P)$ extrapolates into its magnetically ordered phase and is decoupled from the pressure-induced magnetic QCP, which implies a spin-density-wave (SDW) type of criticality that produces only critical fluctuations of the SDW order parameter. Our results demonstrate the importance of experimentally determining $E_\text{loc}$ to characterize quantum criticality and the associated consequences for understanding the pairing mechanism of superconductivity that reaches a maximum $T_\text{c}$ in both materials at their respective magnetic QCP.

cond-mat.str-el↗

arXiv2023

Thermal Equation of State of U$_6$Fe from Experiments and Calculations

Actinide-bearing intermetallics display unusual electronic, magnetic, and physical properties which arise from the complex behavior of their 5$f$ electron orbitals. Temperature ($T$) effects on actinide intermetallics are well studied, but high pressure ($P$) properties and phase stabilities are known for only a handful of compositions. Furthermore, almost no data exist for simultaneous high $P$ and high $T$. We performed ambient-$T$ diamond anvil cell X-ray diffraction experiments to study the behavior of the intermetallic U$_6$Fe upon compression up to 82 GPa. U$_6$Fe remains stable in the tetragonal $I4/mcm$ structure over this pressure range. We also performed ambient $P$, low-$T$ diffraction and heat capacity measurements to constrain U$_6$Fe's thermal behavior. These data were combined with calculations and fitted to a Mie-Gruneisen/Birch-Murnaghan thermal equation of state with the following parameter values at ambient $P$: bulk modulus $B_0$ = 124.0 GPa, pressure derivative $B'_0$ = 5.6, Gruneisen parameter $Γ_0$ = 2.028, volume exponent $q$ = 0.934, Debye temperature $θ_0$ = 175 K, and unit cell volume $V_0$ = 554.4 angstrom$^3$. We report $T$-dependent thermal expansion coefficients and bond lengths of U$_6$Fe, which demonstrate the anisotropic compressibility and negative thermal expansion of the crystallographic $c$ axis. Additionally, density-functional theory calculations indicate increased delocalization of U$_6$Fe bonds at high $P$.

cond-mat.mtrl-sci↗

arXiv2023

Complex electronic structure evolution of NdSb across the magnetic transition

The rare-earth monopnictide (REM) family, which hosts magnetic ground states with extreme magnetoresistance, has established itself as a fruitful playground for the discovery of interesting topological phases. Here, by using high-resolution angle-resolved photoemission spectroscopy complemented by first-principles density functional-theory based modeling, we examine the evolution of the electronic structure of the candidate REM Dirac semimetal NdSb across the magnetic transition. A complex angel-wing-like band structure near the zone center and three arc-like features at the zone corner have been observed. This dramatic reconstruction of the itinerant bands around the zone center is shown to be driven by the magnetic transition: Specifically,, the Nd 5d electron band backfolds at the Gamma point and hybridizes with the Sb 5p hole bands in the antiferromagnetic phase. Our study indicates that antiferromagnetism plays an intricate role in the electronic structure of the REM family.

cond-mat.mtrl-sci↗

arXiv2023

Nesting-driven antiferromagnetic order in Kondo lattice CePd5Al2

We investigated the electronic structure of the antiferromagnetic Kondo lattice CePd5Al2 using high-resolution angle-resolved photoemission spectroscopy. The experimentally determined band structure of the conduction electrons is predominated by the Pd 4d character. It contains multiple hole and electron Fermi pockets, in good agreement with density functional theory calculations. The Fermi surface is folded over Q0 = (0, 0, 1), manifested by Fermi surface reconstruction and band folding. Our results suggest that Fermi surface nesting drives the formation of antiferromagnetic order in CePd5Al2.

cond-mat.str-el↗

arXiv2023

Reply to: Low-frequency quantum oscillations in LaRhIn$_5$: Dirac point or nodal line?

We thank G.P. Mikitik and Yu.V. Sharlai for contributing this note and the cordial exchange about it. First and foremost, we note that the aim of our paper is to report a methodology to diagnose topological (semi)metals using magnetic quantum oscillations. Thus far, such diagnosis has been based on the phase offset of quantum oscillations, which is extracted from a "Landau fan plot". A thorough analysis of the Onsager-Lifshitz-Roth quantization rules has shown that the famous $π$-phase shift can equally well arise from orbital- or spin magnetic moments in topologically trivial systems with strong spin-orbit coupling or small effective masses. Therefore, the "Landau fan plot" does not by itself constitute a proof of a topologically nontrivial Fermi surface. In the paper at hand, we report an improved analysis method that exploits the strong energy-dependence of the effective mass in linearly dispersing bands. This leads to a characteristic temperature dependence of the oscillation frequency which is a strong indicator of nontrivial topology, even for multi-band metals with complex Fermi surfaces. Three materials, Cd$_3$As$_2$, Bi$_2$O$_2$Se and LaRhIn$_5$ served as test cases for this method. Linear band dispersions were detected for Cd$_3$As$_2$, as well as the $F$ $\approx$ 7 T pocket in LaRhIn$_5$.

cond-mat.str-el↗

arXiv2023

One-dimensionality signature in optical conductivity of heavy-fermion CeIr$_{3}$B$_{2}$

In low dimensions, the combined effects of interactions and quantum fluctuations can lead to dramatically new physics distinct from that existing in higher dimensions. Here, we investigate the electronic and optical properties of CeIr$_{3}$B$_{2}$, a quasi-one-dimensional (1D) Kondo lattice system, using $ab\ initio$ calculations. The Ce atoms in the hexagonal crystal structure form 1D chains along the $c$-axis, with extremely short Ce-Ce distances. The quasi-1D nature of the crystal structure is well reflected in its electronic structure. Extremely flat bands emerge within the $ab$-plane of the Brillouin zone, yielding sharp optical transitions in the corresponding optical conductivity. Our calculations indicate that these prominent peaks in the optical conductivity provide a clear signature of quasi-1D heavy fermion systems.

cond-mat.str-el↗

arXiv2022

Interwoven atypical quantum states in CeLiBi$_2$

We report the discovery of CeLiBi$_2$, the first example of a material in the tetragonal Ce$TX_2$ ($T$ = transition metal; $X$ = pnictogen) family wherein an alkali cation replaces the typical transition metal. Magnetic susceptibility and neutron powder diffraction measurements are consistent with a crystal-field $Γ_6$ ground state Kramers doublet that orders antiferromagnetically below $T_N = 3.4$ K with an incommensurate propagation wave vector ${\bf{k}} = (0, 0.0724(4), 0.5)$ that generates a nanometric modulation of the magnetic structure. The best model of the ordered state is an elliptical cycloid with Ce moments primarily residing in the $ab$ plane. This is highly unusual, as all other $Γ_6$ Ce$TX_2$ members order ferromagnetically. Further, we observe an atypical hard-axis metamagnetic transition at $2$ T in magnetostriction, magnetization, and resistivity measurements. CeLiBi$_2$ is a rare example of a highly conductive material with dominant skew scattering leading to a large anomalous Hall effect. Quantum oscillations with five frequencies arise in magnetostriction and magnetic susceptibility data to $T = 30$ K and $μ_0H = 55$ T, which indicate small Fermi pockets of light carriers with effective masses as low as 0.07$m_e$. Density functional theory calculations indicate that square-net Dirac-like Bi$-p$ bands are responsible for these ultralight carriers. Together, our results show that CeLiBi$_2$ enables multiple atypical magnetic and electronic properties in a single clean material.

cond-mat.str-el↗

arXiv2022

Anisotropic magnetotransport properties of the heavy-fermion superconductor CeRh$_2$As$_2$

We report anisotropic resistivity measurements of the heavy-fermion superconductor CeRh$_2$As$_2$ in magnetic fields up to 16 T and temperatures down to 0.35 K. The measured CeRh$_2$As$_2$ resistivity shows a signature corresponding to the suggested quadrupole density wave order state at $T_0 \sim$ 0.5 K for both measured directions. For a magnetic field applied along the tetragonal $a$ axis, $T_0$ is enhanced with magnetic field reaching $\sim$1.75 K at 16 T. Further, a magnetic field-induced transition occurs at $B_m \sim $ 8.1 T corresponding to a change to a new broken symmetry state. For a magnetic field applied along the $c$ axis, $T_0$ is suppressed below our base temperature $\sim$0.35 K by $B \sim$ 4.5 T, a field close to the previously reported field-induced transition within the superconducting state suggested to be from an even-parity to an odd-parity state. Our results indicate that the multiple superconducting phases in CeRh$_2$As$_2$ are intimately tied to the suppression of the proposed quadrupole-density-wave phase at $T_0$.

cond-mat.supr-con↗

arXiv2022

Role of Local Ru Hexamers in Superconductivity of Ruthenium Phosphide

Superconductivity in binary ruthenium pnictides occurs proximal to and upon suppression of a mysterious non-magnetic ground state, preceded by a pseudogap phase associated with Fermi surface instability, and its critical temperature, T$_{c}$, is maximized around the pseudogap quantum critical point. By analogy with isoelectronic iron based counterparts, antiferromagnetic fluctuations became "usual suspects" as putative mediators of superconducting pairing. Here we report on a high temperature local symmetry breaking in RuP, the parent of the maximum-Tc branch of these novel superconductors, revealed by combined nanostructure-sensitive powder and single crystal X-ray total scattering experiments. Large local Ru$_{6}$ hexamer distortions associated with orbital-charge trimerization form above the two-stage electronic transition in RuP. While hexamer ordering enables the nonmagnetic ground state and presumed complex oligomerization, the relevance of pseudogap fluctuations for superconductivity emerges as a distinct prospect. As a transition metal system in which partial d-manifold filling combined with high crystal symmetry promotes electronic instabilities, this represents a further example of local electronic precursors underpinning the macroscopic collective behavior of quantum materials.

cond-mat.supr-con↗

arXiv2022

Coexisting Kondo hybridization and itinerant f-electron ferromagnetism in UGe2

Kondo hybridization in partially filled f-electron systems conveys significant amount of electronic states sharply near the Fermi energy leading to various instabilities from superconductivity to exotic electronic orders. UGe2 is a 5f heavy fermion system, where the Kondo hybridization is interrupted by the formation of two ferromagnetic phases below a 2nd order transition Tc ~ 52 K and a crossover transition Tx ~ 32 K. These two ferromagnetic phases are concomitantly related to a spin-triplet superconductivity that only emerges and persists inside the magnetically ordered phase at high pressure. The origin of the two ferromagnetic phases and how they form within a Kondo-lattice remain ambiguous. Using scanning tunneling microscopy and spectroscopy, we probe the spatial electronic states in the UGe2 as a function of temperature. We find a Kondo resonance and sharp 5f-electron states near the chemical potential that form at high temperatures above Tc in accordance with our density functional theory (DFT) + Gutzwiller calculations. As temperature is lowered below Tc, the resonance narrows and eventually splits below Tx dumping itinerant f-electron spectral weight right at the Fermi energy. Our findings suggest a Stoner mechanism forming the highly polarized ferromagnetic phase below Tx that itself sets the stage for the emergence of unconventional superconductivity at high pressure.

cond-mat.str-el↗

arXiv2022

Thermodynamic and electrical transport properties of UTe$_2$ under uniaxial stress

Despite intense experimental efforts, the nature of the unconventional superconducting order parameter of UTe$_2$ remains elusive. This puzzle stems from different reported numbers of superconducting transitions at ambient pressure, as well as a complex pressure-temperature phase diagram. To bring new insights into the superconducting properties of UTe$_2$, we measured the heat capacity and electrical resistivity of single crystals under compressive uniaxial stress $σ$ applied along different crystallographic directions. We find that the critical temperature $T_{\rm c}$ of the single observed bulk superconducting transition decreases with $σ$ along $[100]$ and $[110]$ but increases with $σ$ along $[001]$. Aside from its effect on $T_{\rm c}$, we notice that $c$-axis stress leads to a significant piezoresistivity, which we associate with the shift of the zero-pressure resistivity peak at $T^\star \approx 15\, \rm K$ to lower temperatures under stress. Finally, we show that an in-plane shear stress $σ_{xy}$ does not induce any observable splitting of the superconducting transition over a stress range of $σ_{xy}\approx 0.17 \, \rm GPa$. This result suggests that the superconducting order parameter of UTe$_2$ may be single-component at ambient pressure.

cond-mat.supr-con↗

arXiv2022

Temperature dependence of quantum oscillations from non-parabolic dispersions

The phase offset of quantum oscillations is commonly used to experimentally diagnose topologically non-trivial Fermi surfaces. This methodology, however, is inconclusive for spin-orbit-coupled metals where $π$-phase-shifts can also arise from non-topological origins. Here, we show that the linear dispersion in topological metals leads to a $T^2$-temperature correction to the oscillation frequency that is absent for parabolic dispersions. We confirm this effect experimentally in the Dirac semi-metal Cd$_3$As$_2$ and the multiband Dirac metal LaRhIn$_5$. Both materials match a tuning-parameter-free theoretical prediction, emphasizing their unified origin. For topologically trivial Bi$_2$O$_2$Se, no frequency shift associated to linear bands is observed as expected. However, the $π$-phase shift in Bi$_2$O$_2$Se would lead to a false positive in a Landau-fan plot analysis. Our frequency-focused methodology does not require any input from ab-initio calculations, and hence is promising for identifying correlated topological materials.

cond-mat.str-el↗

arXiv2022

Electrical and thermal transport in van der Waals magnets 2H-M$_x$TaS$_2$ (M = Mn, Co)

We report a detailed study of electrical and thermal transport properties in 2H-M$_x$TaS$_2$ (M = Mn, Co) magnets where M atoms are intercalated in the van der Waals gap. The intercalation induces ferromagentism with an easy-plane anisotropy in 2H-Mn$_x$TaS$_2$, but ferromagnetism with a strong uniaxial anisotropy in 2H-Co$_{0.22}$TaS$_2$, which finally evolves into a three-dimensional antiferromagnetism in 2H-Co$_{0.34}$TaS$_2$. Temperature-dependent electrical resistivity shows metallic behavior for all samples. Thermopower is negative in the whole temperature range for 2H-Co$_x$TaS$_2$, whereas the sign changes from negative to positive with increasing Mn for 2H-Mn$_x$TaS$_2$. The diffusive thermoelectric response dominates in both high- and low-temperature ranges for all samples. A clear kink in electrical resistivity, a weak anomaly in thermal conductivity, as well as a slope change in thermopower were observed at the magnetic transitions for 2H-Mn$_{0.28}$TaS$_2$ ($T_\textrm{c}$ $\approx$ 82 K) and 2H-Co$_{0.34}$TaS$_2$ ($T_\textrm{N}$ $\approx$ 36 K), respectively, albeit weaker for lower $x$ crystals. Co-intercalation promoted ferromagnetic to antiferromagnetic transition is further confirmed by the Hall resistivity; the sign change of the ordinary Hall coefficient indicates a multi-band behavior in 2H-Co$_x$TaS$_2$.

cond-mat.str-el↗

arXiv2022

Anisotropy of Kondo-lattice coherence in momentum space for CeCoIn5

We study the electronic and phononic excitations of heavy-fermion metal CeCoIn$_5$ by polarization-resolved Raman spectroscopy to explore the Kondo-lattice coherence. Below the coherence temperature T*\,=\,45\,K, the continuum of electronic excitations in the XY scattering geometry is suppressed at frequencies below 50\,cm$^{-1}$, whereas the low-frequency continuum in the X'Y' geometry exhibits no change across T*. We relate the suppression to the reduced electron-electron scattering rate resulting from the coherence effect. The presence of suppression in the XY geometry and absence of it in the X'Y' geometry implies that the $α$ and $β$ bands become coherent below T*, whereas the $γ$ band remains largely incoherent down to 10\,K. Moreover, two optical phonon modes exhibit anomalies in their temperature dependence of the frequency and linewidth below T*, which results from developing coherent spectral weight near the Fermi level and reduced electron-phonon scattering rate. Our results further support the key role of anisotropic hybridization in CeCoIn$_5$.

cond-mat.str-el↗

arXiv2021

Plastic vortex creep and dimensional crossovers in the highly anisotropic superconductor HgBa$_2$CuO$_{4+x}$

In type-II superconductors exposed to magnetic fields between upper and lower critical values, $H_{c1}$ and $H_{c2}$, penetrating magnetic flux forms a lattice of vortices whose motion can induce dissipation. Consequently, the magnetization $M$ of superconductors is typically progressively weakened with increasing magnetic field $B \propto n_v$ (for vortex density $n_v$). However, some materials exhibit a non-monotonic $M(B)$, presenting a maximum in $M$ at what is known as the second magnetization peak. This phenomenon appears in most classes of superconductors, including low $T_c$ materials, iron-based, and cuprates, complicating pinpointing its origin and garnering intense interest. Here, we report on vortex dynamics in optimally doped and overdoped HgBa$_2$CuO$_{4+x}$ crystals, with a focus on a regime in which plastic deformations of the vortex lattice govern magnetic properties. Specifically, we find that both crystals exhibit conspicuous second magnetization peaks and, from measurements of the field- and temperature- dependent vortex creep rates, identify and characterize phase boundaries between elastic and plastic vortex dynamics, as well as multiple previously unreported transitions within the plastic flow regime. We find that the second magnetization peak coincides with the elastic-to-plastic crossover for a very small range of high fields, and a sharp crossover within the plastic flow regime for a wider range of lower fields. We find evidence that this transition in the plastic flow regime is due to a dimensional crossover, specifically a transition from 3D to 2D plastic dynamics.

cond-mat.supr-con↗