arXiv subjects

Eric Herbst

Publications and source records attributed to Eric Herbst.

At least 109 records · Page 6Linked to original sources

arXiv2010

Interstellar OH+, H2O+ and H3O+ along the sight-line to G10.6-0.4

We report the detection of absorption lines by the reactive ions OH+, H2O+ and H3O+ along the line of sight to the submillimeter continuum source G10.6$-$0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe the ground state rotational transitions of OH+ at 971 GHz, H2O+ at 1115 and 607 GHz, and H3O+ at 984 GHz. The resultant spectra show deep absorption over a broad velocity range that originates in the interstellar matter along the line of sight to G10.6$-$0.4 as well as in the molecular gas directly associated with that source. The OH+ spectrum reaches saturation over most velocities corresponding to the foreground gas, while the opacity of the H2O+ lines remains lower than 1 in the same velocity range, and the H3O+ line shows only weak absorption. For LSR velocities between 7 and 50 kms$^{-1}$ we estimate total column densities of $N$(OH+) $> 2.5 \times 10^{14}$ cm$^{-2}$, $N$(H2O+) $\sim 6 \times 10^{13}$ cm$^{-2}$ and $N$(H3O+) $\sim 4.0 \times 10^{13}$ cm$^{-2}$. These detections confirm the role of O$^+$ and OH$^+$ in initiating the oxygen chemistry in diffuse molecular gas and strengthen our understanding of the gas phase production of water. The high ratio of the OH+ by the H2O+ column density implies that these species predominantly trace low-density gas with a small fraction of hydrogen in molecular form.

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arXiv2009

Laboratory Studies for Planetary Sciences. A Planetary Decadal Survey White Paper Prepared by the American Astronomical Society (AAS) Working Group on Laboratory Astrophysics (WGLA)

The WGLA of the AAS (http://www.aas.org/labastro/) promotes collaboration and exchange of knowledge between astronomy and planetary sciences and the laboratory sciences (physics, chemistry, and biology). Laboratory data needs of ongoing and next generation planetary science missions are carefully evaluated and recommended in this white paper submitted by the WGLA to Planetary Decadal Survey.

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arXiv2009

The Effects of Molecular Anions on the Chemistry of Dark Clouds

We have investigated the role of molecular anion chemistry in pseudo-time dependent chemical models of dark clouds. With oxygen-rich elemental abundances, the addition of anions results in a slight improvement in the overall agreement between model results and observations of molecular abundances in TMC-1 (CP). More importantly, with the inclusion of anions, we see an enhanced production efficiency of unsaturated carbon-chain neutral molecules, especially in the longer members of the families CnH, CnH2, and HCnN. The use of carbon-rich elemental abundances in models of TMC-1 (CP) with anion chemistry worsens the agreement with observations obtained in the absence of anions.

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arXiv2009

Roles and Needs of Laboratory Astrophysics in NASA's Space and Earth Science Mission

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The mission enabling impact of laboratory astrophysics ranges from the scientific conception stage for airborne and space-based observatories, all the way through to the scientific return of these missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA. These efforts are necessary for the success of astronomical research being funded by NASA. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics (WGLA), have prepared this White Paper on the laboratory astrophysics infrastructure needed to maximize the scientific return from NASA's space and Earth sciences program.

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arXiv2009

Laboratory Astrophysics and the State of Astronomy and Astrophysics

Laboratory astrophysics and complementary theoretical calculations are the foundations of astronomy and astrophysics and will remain so into the foreseeable future. The impact of laboratory astrophysics ranges from the scientific conception stage for ground-based, airborne, and space-based observatories, all the way through to the scientific return of these projects and missions. It is our understanding of the under-lying physical processes and the measurements of critical physical parameters that allows us to address fundamental questions in astronomy and astrophysics. In this regard, laboratory astrophysics is much like detector and instrument development at NASA, NSF, and DOE. These efforts are necessary for the success of astronomical research being funded by the agencies. Without concomitant efforts in all three directions (observational facilities, detector/instrument development, and laboratory astrophysics) the future progress of astronomy and astrophysics is imperiled. In addition, new developments in experimental technologies have allowed laboratory studies to take on a new role as some questions which previously could only be studied theoretically can now be addressed directly in the lab. With this in mind we, the members of the AAS Working Group on Laboratory Astrophysics, have prepared this State of the Profession Position Paper on the laboratory astrophysics infrastructure needed to ensure the advancement of astronomy and astrophysics in the next decade.

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arXiv2009

New Discoveries in the Galactic Neighborhood through Advances in Laboratory Astrophysics

As the Galactic Neighborhood (GAN) panel is fully aware, the next decade will see major advances in our understanding of this area of research. To quote from their charge, these advances will occur in studies of the galactic neighborhood, including the structure and properties of the Milky Way and nearby galaxies, and their stellar populations and evolution, as well as interstellar media and star clusters. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GAN scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry that produces the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the GAN panel are atomic, molecular, solid matter, plasma, and nuclear physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GAN scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6.

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arXiv2009

New Discoveries in Planetary Systems and Star Formation through Advances in Laboratory Astrophysics

As the panel on Planetary Systems and Star Formation (PSF) is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of solar system bodies (other than the Sun) and extrasolar planets, debris disks, exobiology, the formation of individual stars, protostellar and protoplanetary disks, molecular clouds and the cold ISM, dust, and astrochemistry. Central to the progress in these areas are the corresponding advances in laboratory astro- physics which are required for fully realizing the PSF scientific opportunities in the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics and chemistry which produce the observed spectra and describe the astrophysical processes. We discuss four areas of laboratory astrophysics relevant to the PSF panel: atomic, molecular, solid matter, and plasma physics. Section 2 describes some of the new opportunities and compelling themes which will be enabled by advances in laboratory astrophysics. Section 3 provides the scientific context for these opportunities. Section 4 discusses some experimental and theoretical advances in laboratory astrophysics required to realize the PSF scientific opportunities of the next decade. As requested in the Call for White Papers, we present in Section 5 four central questions and one area with unusual discovery potential. We give a short postlude in Section 6.

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arXiv2009

New Discoveries in Cosmology and Fundamental Physics through Advances in Laboratory Astrophysics

As the Cosmology and Fundamental Physics (CFP) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the early universe, the microwave background, the reionization and galaxy formation up to virialization of protogalaxies, large scale structure, the intergalactic medium, the determination of cosmological parameters, dark matter, dark energy, tests of gravity, astronomically determined physical constants, and high energy physics using astronomical messengers. Central to the progress in these areas are the corresponding advances in laboratory astrophysics which are required for fully realizing the CFP scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics which produce the observed astrophysical processes. The 5 areas of laboratory astrophysics which we have identified as relevant to the CFP panel are atomic, molecular, plasma, nuclear, and particle physics. Here, Section 2 describes some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the CFP scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6.

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arXiv2009

New Discoveries in Galaxies across Cosmic Time through Advances in Laboratory Astrophysics

As the Galaxies across Cosmic Time (GCT) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the formation, evolution, and global properties of galaxies and galaxy clusters, as well as active galactic nuclei and QSOs, mergers, star formation rate, gas accretion, and supermassive black holes. Central to the progress in these areas are the corresponding advances in laboratory astrophysics that are required for fully realizing the GCT scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produce the observed astrophysical processes. The 5 areas of laboratory astrophysics that we have identified as relevant to the CFP panel are atomic, molecular, solid matter, plasma, nuclear, and particle physics. In this white paper, we describe in Section 2 some of the new scientific opportunities and compelling scientific themes that will be enabled by advances in laboratory astrophysics. In Section 3, we provide the scientific context for these opportunities. Section 4 briefly discusses some of the experimental and theoretical advances in laboratory astrophysics required to realize the GCT scientific opportunities of the next decade. As requested in the Call for White Papers, Section 5 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 6.

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arXiv2009

New Discoveries in Stars and Stellar Evolution through Advances in Laboratory Astrophysics

As the Stars and Stellar Evolution (SSE) panel is fully aware, the next decade will see major advances in our understanding of these areas of research. To quote from their charge, these advances will occur in studies of the Sun as a star, stellar astrophysics, the structure and evolution of single and multiple stars, compact objects, SNe, gamma-ray bursts, solar neutrinos, and extreme physics on stellar scales. Central to the progress in these areas are the corresponding advances in laboratory astrophysics, required to fully realize the SSE scientific opportunities within the decade 2010-2020. Laboratory astrophysics comprises both theoretical and experimental studies of the underlying physics that produces the observed astrophysical processes. The 6 areas of laboratory astrophysics, which we have identified as relevant to the CFP panel, are atomic, molecular, solid matter, plasma, nuclear physics, and particle physics. In this white paper, we describe in Section 2 the scientific context and some of the new scientific opportunities and compelling scientific themes which will be enabled by advances in laboratory astrophysics. In Section 3, we discuss some of the experimental and theoretical advances in laboratory astrophysics required to realize the SSE scientific opportunities of the next decade. As requested in the Call for White Papers, Section 4 presents four central questions and one area with unusual discovery potential. Lastly, we give a short postlude in Section 5.

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arXiv2009

A sensitivity study of the neutral-neutral reactions C + C3 and C + C5 in cold dense interstellar clouds

Chemical networks used for models of interstellar clouds contain many reactions, some of them with poorly determined rate coefficients and/or products. In this work, we report a method for improving the predictions of molecular abundances using sensitivity methods and ab initio calculations. Based on the chemical network osu.2003, we used two different sensitivity methods to determine the most important reactions as a function of time for models of dense cold clouds. Of these reactions, we concentrated on those between C and C3 and between C and C5, both for their effect on specific important species such as CO and for their general effect on large numbers of species. We then used ab initio and kinetic methods to determine an improved rate coefficient for the former reaction and a new set of products, plus a slightly changed rate coefficient for the latter. Putting our new results in a pseudo-time-dependent model of cold dense clouds, we found that the abundances of many species are altered at early times, based on large changes in the abundances of CO and atomic C. We compared the effect of these new rate coefficients/products on the comparison with observed abundances and found that they shift the best agreement from 3e4 yr to (1-3)e5 yr.

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arXiv2008

Modeling Carbon Chain Anions in L1527

The low-mass protostellar region L1527 is unusual because it contains observable abundances of unsaturated carbon-chain molecules including CnH radicals, H2Cn carbenes, cyanopolyynes, and the negative ions C4H- and C6H-, all of which are more associated with cold cores than with protostellar regions. Sakai et al. suggested that these molecules are formed in L1527 from the chemical precursor methane, which evaporates from the grains during the heat-up of the region. With the gas-phase osu.03.2008 network extended to include negative ions of the families Cn-, and CnH-, as well as the newly detected C3N-, we modeled the chemistry that occurs following methane evaporation at T~ 25-30 K. We are able to reproduce most of the observed molecular abundances in L1527 at a time of ~5000 yr. At later times, the overall abundance of anions become greater than that of electrons, which has an impact on many organic species and ions. The anion-to-neutral ratio in our calculation is in good agreement with observation for C6H- but exceeds the observed ratio by more than three orders of magnitude for C4H-. In order to explain this difference, further investigation is needed on the rate coefficients for electron attachment and other reactions regarding anions.

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arXiv2008

Modeling the Lukewarm Corino Phase - is L1527 unique?

Sakai et al. have observed long-chain unsaturated hydrocarbons and cyanopolyynes in the low-mass star-forming region L1527, and have attributed this result to a gas-phase ion-molecule chemistry, termed ``Warm Carbon Chain Chemistry'', which occurs during and after the evaporation of methane from warming grains. The source L1527 is an envelope surrounding a Class 0/I protostar with regions that possess a slightly elevated temperature of ~30 K. The molecules detected by Sakai et al. are typically associated only with dark molecular clouds, and not with the more evolved hot corino phase. In order to determine if L1527 is chemically distinct from a dark cloud, we compute models including various degrees of heating. The results indicate that the composition of L1527 is somewhat more likely to be due to ``Warm Carbon Chain Chemistry'' than to be a remnant of a colder phase. If so, the molecular products provide a signature of a previously uncharacterized early phase of low mass star formation, which can be characterized as a ``lukewarm'' corino. We also include predictions for other molecular species that might be observed toward candidate lukewarm corino sources. Although our calculations show that unsaturated hydrocarbons and cyanopolyynes can be produced in the gas phase as the grains warm up to 30 K, they also show that such species do not disappear rapidly from the gas as the temperature reaches 200 K, implying that such species might be detected in hot corinos and hot cores.

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arXiv2008

Complex Chemistry in Star-Forming Regions: An Expanded Gas-Grain Warm-up Chemical Model

Gas-phase processes were long thought to be the key formation mechanisms for complex organic molecules in star-forming regions. However, recent experimental and theoretical evidence has cast doubt on the efficiency of such processes. Grain-surface chemistry is frequently invoked as a solution, but until now there have been no quantitative models taking into account both the high degree of chemical complexity and the evolving physical conditions of star-forming regions. Here, we introduce a new gas-grain chemical network, wherein a wide array of complex species may be formed by reactions involving radicals. The radicals we consider (H, OH, CO, HCO, CH3, CH3O, CH2OH, NH and NH2) are produced primarily by cosmic ray-induced photodissociation of the granular ices formed during the colder, earlier stages of evolution. The gradual warm-up of the hot core is crucial to the formation of complex molecules, allowing the more strongly-bound radicals to become mobile on grain surfaces. This type of chemistry is capable of reproducing the high degree of complexity seen in Sgr B2(N), and can explain the observed abundances and temperatures of a variety of previously detected complex organic molecules, including structural isomers. Many other complex species are predicted by this model, and several of these species may be detectable in hot cores. Differences in the chemistry of high- and low-mass star-formation are also addressed; greater chemical complexity is expected where evolution timescales are longer.

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arXiv2008

Polycylcic Aromatic Hydrocarbons (PAH's) in dense cloud chemistry

Virtually all detailed gas-phase models of the chemistry of dense interstellar clouds exclude polycyclic aromatic hydrocarbons (PAH's). This omission is unfortunate because from the few studies that have been done on the subject, it is known that the inclusion of PAH's can affect the gas-phase chemistry strongly. We have added PAH's to our network to determine the role they play in the chemistry of cold dense cores. In the models presented here, we include radiative attachment to form PAH-, mutual neutralization between PAH anions and small positively-charged ions, and photodetachment. We also test the sensitivity of our results to changes in the size and abundance of the PAH's. Our results confirm that the inclusion of PAH's changes many of the calculated abundances of smaller species considerably. In TMC-1, the general agreement with observations is significantly improved contrary to L134N. This may indicate a difference in PAH properties between the two regions. With the inclusion of PAH's in dense cloud chemistry, high-metal elemental abundances give a satisfactory agreement with observations. As a result, we do not need to decrease the observed elemental abundances of all metals and we do not need to vary the elemental C/O ratio in order to produce large abundances of carbon species in TMC-1 (CP).

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arXiv2007

Molecular Evolution and Star Formation: From Prestellar Cores to Protostellar Cores

We investigate molecular evolution in a star-forming core that is initially a hydrostatic starless core and collapses to form a low-mass protostar. The results of a one-dimensional radiation-hydrodynamics calculation are adopted as a physical model of the core. We first derive radii at which CO and large organic species sublimate. CO sublimation in the central region starts shortly before the formation of the first hydrostatic core. When the protostar is born, the CO sublimation radius extends to 100 AU, and the region inside $\lesssim 10$ AU is hotter than 100 K, at which some large organic species evaporate. We calculate the temporal variation of physical parameters in infalling shells, in which the molecular evolution is solved using an updated gas-grain chemical model to derive the spatial distribution of molecules in a protostellar core. The shells pass through the warm region of $10 -100$ K in several $\times$ $10^4$ yr, and fall into the central star $\sim 100$ yr after they enter the region where $T \gtrsim 100$ K. We find that large organic species are formed mainly via grain-surface reactions at temperatures of $20 -40$ K and then desorbed into the gas-phase at their sublimation temperatures. Carbon-chain species can be formed by a combination of gas-phase reactions and grain-surface reactions following the sublimation of CH$_4$. Our model also predicts that CO$_2$ is more abundant in isolated cores, while gas-phase large organic species are more abundant in cores embedded in ambient clouds.

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arXiv2007

Simulation of the Formation and Morphology of Ice Mantles on Interstellar Grains

Although still poorly understood, the chemistry that occurs on the surfaces of interstellar dust particles profoundly affects the growth of molecules in the interstellar medium. An important set of surface reactions produces icy mantles of many monolayers in cold and dense regions. The monolayers are dominated by water ice, but also contain CO, CO_{2}, and occasionally methanol as well as minor constituents. In this paper, the rate of production of water-ice dominated mantles is calculated for different physical conditions of interstellar clouds and for the first time images of the morphology of interstellar ices are presented. For this purpose, the continuous-time random-walk Monte Carlo simulation technique has been used. The visual extinction, density, and gas and grain temperatures are varied. It is shown that our stochastic approach can reproduce the important observation that ice mantles only grow in the denser regions.

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arXiv2007

Hydrocarbon anions in interstellar clouds and circumstellar envelopes

The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral abundance ratio can be quite large, on the order of at least a few percent, once the neutral has more than five carbon atoms. Detailed modeling shows that the column densities of C6H- observed in IRC+10216 and TMC-1 can be reproduced. Our calculations also predict that other hydrocarbon anions, such as C4H- and C8H-, are viable candidates for detection in IRC+10216, TMC-1 and photon-dominated regions such as the Horsehead Nebula.

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