Spontaneous Symmetry Breaking and Emergent Helicity in Achiral D4h-Symmetric Zinc Phthalocyanine Condensates
Herein it is shown spontaneous symmetry breaking in supramolecular aggregates of D4h-symmetric zinc phthalocyanine (ZnPc). Ab initio density functional theory calculations at the M06/DGDZVP level reveal that intermolecular interactions induce a subtle relaxation of the macrocyclic framework, producing a characteristic red shift of the aza-bridge (C-N-C) stretching mode and symmetric stretching of the pyrrole ring. Confocal Raman Optical Activity measurements further reveal a negative Cotton effect at 1505 cm^-1 and 1338 cm^-1, providing evidence of emergent supramolecular chirality. Our findings identify pristine ZnPc as a model system for spontaneous self-assembled chiral symmetry breaking in molecular condensates and suggest new opportunities for chiroptical, spin-selective, and quantum functional materials.