arXiv subjects

Ernesto E. Marinero

Publications and source records attributed to Ernesto E. Marinero.

12 recordsLinked to original sources

arXiv2025

Polymer-based solid-state electrolytes for lithium sulfur batteries

Lithium-sulfur (Li-S) batteries offer substantial theoretical energy density gains over Li-ion bat-teries, a crucial factor for transportation electrification. In addition, sulfur is an earth-abundant, inexpensive material obtainable from multiple resources; thus, Li-S batteries are envisioned to provide environmentally sustainable solutions to the growing demand for energy storage. A crit-ical roadblock to the realization of commercial Li-S batteries is the formation of polysulfides and their secondary reactions with liquid organic electrolytes, resulting in low coulombic efficiency for charging and fast self-discharge rates. The realization of solid-state electrolytes for Li-S bat-teries provides potential pathways to address the safety concerns of liquid electrolytes and inhib-it the formation of polysulfides and/or prevent their diffusion into the anode electrode. However, current solid-state electrolytes are limited by low ionic conductivity, inadequate electrode inter-facial compatibility, and restricted electrochemical windows. This review discusses the status of polymer-based electrolytes for Li-S batteries, and outlines current methods for their fabrication, their transport characteristics and ongoing research aimed at overcoming material properties hindering the development of all-solid-state Li-S batteries.

cond-mat.mtrl-sci↗

arXiv2025

Compositional dependence of magnetic damping in sputter-deposited CoxFe1-x thin films

Co25Fe75 ferromagnetic films exhibit ultralow magnetic damping. The magnetic damping dependence of Cobalt Iron thin films over a Co composition (23 to 36%) is here reported. The thin film structures were sputter deposited at ambient temperature and FMR measurements in both in plane and out of plane geometries were utilized to measure magnetic damping parameters, which include intrinsic damping and contributions from spin pumping. The damping parameters, decrease as the Co content is increased, except for Co31Fe69. The smallest values of damping correspond to alloys exhibiting interface perpendicular magnetic anisotropy. A value of 0.00091 was measured for Co36Fe64, whereas for Co31Fe69 was measured as 0.002, this composition exhibits the largest in-plane anisotropy. HAADF-STEM cross-section analysis of the Co36Fe64 thin film stack revealed Cu interdiffusion into the magnetic layer. The degree of interdiffusion was found to be up to 7x higher at grain boundaries as compared the bulk of the polycrystalline grains. The incorporation of Cu into the ferromagnetic layer adversely impacts magnetic damping. Reducing impurities in the magnetic layer by improving the growth chamber base pressure resulted in a reduction of magnetic damping of 18%. The diffraction analysis revealed that the primary growth direction of Co36Fe64 is [101] and that of Cu buffer layer is [111], these planes are perpendicular to their respective [101] planes and for this composition the lattice mismatch was determined to be 0.9325%. The lattice mismatch decreases with increasing Co content and hence the lattice strain. The diffusion of Cu into the ferromagnet creates magnon scattering centers and local changes in magnetic properties. Both factors negatively influence magnetic damping.

cond-mat.mtrl-sci↗

arXiv2024

Comparison of stable spin textures in in-plane vs. out-of-plane magnetized exchange-biased multilayers

This paper delves into the origins and specificity of the unique stable spin textures (360° closed loop domain walls and skyrmions) observed in exchange-biased systems, with either in-plane or out-of-plane magnetic anisotropy. In the case of skyrmions, which are nanometer-sized bubbles consisting of closed-loop 180° walls in perpendicularly-magnetized media, the stability of these spin textures arises from the existence of Dzyaloshinskii-Moriya Interactions (DMI). These interactions induce chirality of the domain walls, yielding to some extent a so-called topological protection. More complex structures such as skyrmoniums have been observed, consisting of closed loop 360° walls. Recently, skyrmions formed in the absence of an applied external magnetic field have been stabilized in exchange biased out-of-plane magnetized systems. About two decades ago, another type of stable spin-textures were observed in exchange biased systems, with in-plane magnetization, in particular in the pinned reference layer of spin-valves. These textures consist of 360°-domain-wall rings, the stability of which arises from the easy-plane shape anisotropy of these layers. In this paper, we compare these spin-textures and highlight the similarities and differences in their formation, structure and origin of their stability.

cond-mat.mes-hall↗

arXiv2023

Atomistic mechanisms underlying the maximum in diffusivity in doped Li$_7$La$_3$Zr$_2$O$_{12}$

Doped lithium lanthanum zirconium oxide (LLZO) is a promising class of solid electrolytes for lithium-ion batteries due to their good electrochemical stability and compatibility with Li metal anodes. Ionic diffusivity in these ceramics is known to occur via correlated, vacancy mediated, jumps of Li+ between alternating tetrahedral and octahedral sites. Aliovalent doping at the Zr-site increases the concentration of vacancies in the Li+ sublattice and cation diffusivity, but such an increase is universally followed by a decrease for Li+ concentration lower than 6.3 - 6.5 Li molar content. Molecular dynamics simulations based on density functional theory show that the maximum in diffusivity originates from competing effects between the increased vacancy concentration and the increasing occupancy of the low-energy tetrahedral sites by Li+, which increases the overall activation energy associated with diffusion. For the relatively high temperatures of our simulations, Li+ concentration plays a dominant role in transport as compared to dopant chemistry.

cond-mat.mtrl-sci↗

arXiv2021

Hybrid Polymer-Garnet Materials for All-Solid-State Energy Storage Devices

Hybrid electrolyte materials comprising polymer-ionic salt matrixes embedded with garnet particles constitute a promising class of materials for the realization of all-solid-state batteries. In addition to providing solutions to the safety issues inherent to current liquid electrolytes, hybrid polymer electrolytes offer advantages over other solid-state electrolytes. This is because their functional properties such as ionic conductivity, electrochemical stability, mechanical and thermal properties can be tailored to a particular application by independently optimizing the properties of the constituent materials. Thereby, providing a rational approach to solving bottlenecks currently preventing solid-state electrolytes from practical implementation into battery devices. This review starts with a survey of solid-state electrolytes, focusing on their materials and ion transport limitations. Next, we summarize the current understanding of transport mechanisms in composite polymer electrolytes (CPEs) with the purpose of identifying materials solutions for further improving their properties. The overall goal of the review is to foster heightened research interest in these hybrid structures to rapidly advance development of future all-solid-state battery devices.

physics.app-ph↗

arXiv2021

Ionic conductivity optimization of composite polymer electrolytes through filler particle chemical modification

The addition of filler particles to polymer electrolytes is known to increment their ionic conductivity (IC). A detailed understanding of how the interactions between the constituent materials are responsible for the enhancement, remains to be developed. A significant contribution is ascribed to an increment of the polymer amorphous fraction, induced by the fillers, resulting in the formation of higher ionic conductivity channels in the polymer matrix. However, the dependence of IC on the particle weight load and its composition on the polymer morphology is not fully understood. This work investigates Li ion transport in composite polymer electrolytes (CPE) comprising Bi-doped LLZO particles embedded in PEO: LiTFSI matrixes. We find that the IC optimizes for very low particle weight loads (5 to 10%) and that both its magnitude and the load required, strongly depend on the garnet particle composition. Based on structural characterization results and electrochemical impedance spectroscopy, a mechanism is proposed to explain these findings. It is suggested that the Li-molar content in the garnet particle controls its interactions with the polymer matrix, resulting at the optimum loads reported, in the formation of high ionic conductivity channels. We propose that filler particle chemical manipulation of the polymer morphology is a promising avenue for the further development of composite polymer electrolytes.

cond-mat.mtrl-sci↗

arXiv2020

Hybrid Magneto Photonic Material Structure for Plasmon Assisted Magnetic Switching

We have proposed the use of surface plasmon resonances at the interface of hybrid magneto-photonic heterostructures [Opt. Mat. Exp., 7, 4316 (2017)] for all-optical control of the macroscopic spin orientation in nanostructures in fs time scales. This requires strong spin-photon coupling for the resonant enhancement of opto-magnetic fields, generated through the inverse Faraday effect, in magnetic nanostructures with perpendicular anisotropy. Here we report on the development of nm thick interlayers to control the growth orientation of hcp-Co alloys grown on refractory plasmonic materials to align the magnetic axis out-of-plane, thereby meeting key requirements for the realization of ultrafast magneto-photonic devices.

cond-mat.mtrl-sci↗

arXiv2019

Ionic conductivity enhacements and low temperature synthesis of Li7La3Zr2O12 garnets by Bi aliovalent substitutions

We report on a novel approach to synthesize cubic-phase fast ionic conducting garnet-type solid state electrolytes based on Bi doped Li7La3Zr2O12 (LLZO). Bi aliovalent substitution into LLZO utilizing the Pechini processing method is successfully employed to synthesize Li7-xLa3Zr2-xBixO12 compounds. Ionic conductivities up to 2.0 x 10-4 S/cm are achieved in structures not fully densified. Cubic phase Li6La3ZrBiO12 powders are generated in the temperature range from 650 °C to 900 °C in air. In contrast, in the absence of Bi and under identical synthesis conditions, the cubic garnet phase of Li7La3Zr2O12 is not formed below 700 °C while a transformation to the tetragonal phase is observed at 900 °C for the un-doped compound. The critical role of Bi in lowering the formation temperature of the garnet cubic phase and the improvements in ionic conductivity is investigated in this work through microstructural studies and AC impedance measurements. We ascribe the effect of Bi doping in achieving these remarkable improvements to significant enhancements at lower temperatures in the kinetics of the solid-state reaction resulting in explosive grain growth and densification of the garnet. Moreover, XAS is utilized to identify the specific atomic site where Bi is incorporated in the LLZO garnet crystalline structure.

cond-mat.mtrl-sci↗

arXiv2017

Surface-plasmon opto-magnetic field enhancement for all-optical magnetization switching

The demand for faster magnetization switching speeds and lower energy consumption has driven the field of spintronics in recent years. The magnetic tunnel junction is the most developed spintronic memory device in which the magnetization of the storage layer is switched by spin-transfer-torque or spin-orbit torque interactions. Whereas these novel spin-torque interactions exemplify the potential of electron-spin-based devices and memory, the switching speed is limited to the ns regime by the precessional motion of the magnetization. All-optical magnetization switching, based on the inverse Faraday effect, has been shown to be an attractive method for achieving magnetization switching at ps speeds. Successful magnetization reversal in thin films has been demonstrated by using circularly polarized light. However, a method for all-optical switching of on-chip nanomagnets in high density memory modules has not been described. In this work we propose to use plasmonics, with CMOS compatible plasmonic materials, to achieve on-chip magnetization reversal in nanomagnets. Plasmonics allows light to be confined in dimensions much smaller than the diffraction limit of light. This in turn, yields higher localized electromagnetic field intensities. In this work, through simulations, we show that using localized surface plasmon resonances, it is possible to couple light to nanomagnets and achieve significantly higher opto-magnetic field values in comparison to free space light excitation.

physics.optics↗

arXiv2016

Ultrafast Spin-Transfer-Torque Switching of Synthetic Ferrimagnets

The switching speed and the write current required for spin-transfer-torque reversal of spintronic devices such as magnetic tunnel junctions (MTJ) currently hinder their wide implementation into memory and logic devices. This problem is further exacerbated as the dimensions of MTJ nanostructures are scaled down to tens of nanometers in diameter, as higher magnetic anisotropy materials are required to meet thermal stability requirements that demand higher switching current densities. Here, we propose a simple solution to these issues based on synthetic ferrimagnet (SFM) structures. It is commonly assumed that to achieve a given switching delay, the current has to exceed the critical current by a certain factor and so a higher critical current implies a higher switching current. We show that this is not the case for SFM structures which can provide significantly reduced switching delay for a given current density, even though the critical current is increased. This non-intuitive result can be understood from the requirements of angular momentum conservation. We conclude that a 20 nm diameter MTJ incorporating the proposed SFM free layer structure can be switched in tens of picosecond time scales. This remarkable switching speed can be attained by employing current perpendicular magnetic anisotropy materials with experimentally demonstrated exchange coupling strengths.

cond-mat.mes-hall↗

arXiv2011

Tuning Fano-type resonances in coupled quantum point contacts by applying asymmetric voltages

We study the ballistic magnetotransport in a double quantum point contact (QPC) device consisting of a quasi-one-dimensional quantum wire with an embedded island-like impurity - etched nano-hole as in a recently published experiment [J. C. Chen, Y. Lin, K.-T. Lin, T. Ueda and S. Komiyama, Appl. Phys. Lett. 94, 012105 (2009)]. We reproduce the zero field quantized conductance, the interference phenomenon induced by the coupled QPCs, as well as the Ramsauer-like resonances observed in the experiments. At finite magnetic fields Fano-type resonances arises in the conductance due to the formation of localized states at the impurity periphery and to an inter-edge state resonant coupling effect. It is predicted that the Fano-type resonances can be controlled by an asymmetric confinement of the QPCs.

cond-mat.mes-hall↗

arXiv2009

Zero field spin splitting in AlSb/InAs/AlSb quantum wells induced by surface proximity effects

InAs quantum well heterostructures are of considerable interest for mesoscopic device applications such as scanning probe and magnetic recording sensors, which require the channel to be close to the surface. Here we report on magnetotransport measurements of AlSb/InAs/AlSb Hall bars at a shallow depth of 20 nm. Analysis of the observed Shubnikov-de Haas oscillations and modeling show that spin splitting energies in excess of 2.3 meV occur at zero magnetic field. We conclude that the spin-splitting results from the Rashba effect due to the band bending in the quantum well. This is caused by substantial electron transfer from the surface to the quantum well and becomes significant when the quantum well is located near the surface.

cond-mat.mes-hall↗