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Ernesto S. Loscar

Publications and source records attributed to Ernesto S. Loscar.

12 recordsLinked to original sources

Finite-time effects on a first-order irreversible phase transition

The first-order irreversible phase transition (FOIPT) of the ZGB model [Ziff, Gulari, Barshad, Phys. Rev. Lett. \textbf{56} (1986) 2553] for the catalytic oxidation of carbon monoxide is studied numerically in the presence of a slowly time-dependent, spatially uniform carbon monoxide pressure, with standard constant pressure simulations. This method allows us to observe finite-time effects close to the FOIPT, as well as evidence that a dynamic phase transition occurs. The location of this transition is measured very precisely and compared with previous results in the literature.

cond-mat.stat-mech↗

Short-time dynamics in active systems: the Vicsek model

We study the short-time dynamics (STD) of the Vicsek model with vector noise. The study of STD has proved to be very useful in the determination of the critical point, critical exponents, and spinodal points in equilibrium phase transitions. Here we aim to test its applicability in active systems. We find that, despite the essential non-equilibrium characteristics of the VM (absence of detailed balance, activity), the STD presents qualitatively the same phenomenology as in equilibrium systems. From the STD one can distinguish whether the transition is continuous or discontinuous (which we have checked also computing the Binder cumulant). When the transition is continuous, one can determine the critical point and the critical exponents.

cond-mat.stat-mech↗

Noisy multistate voter model for flocking in finite dimensions

We study a model for the collective behavior of self-propelled particles subject to pairwise copying interactions and noise. Particles move at a constant speed $v$ on a two--dimensional space and, in a single step of the dynamics, each particle adopts the direction of motion of a randomly chosen neighboring particle, with the addition of a perturbation of amplitude $η$ (noise). We investigate how the global level of particles' alignment (order) is affected by their motion and the noise amplitude $η$. In the static case scenario $v=0$ where particles are fixed at the sites of a square lattice and interact with their first neighbors, we find that for any noise $η_c>0$ the system reaches a steady state of complete disorder in the thermodynamic limit, while for $η=0$ full order is eventually achieved for a system with any number of particles $N$. Therefore, the model displays a transition at zero noise when particles are static, and thus there are no ordered steady states for a finite noise ($η>0$). We show that the finite-size transition noise vanishes with $N$ as $η_c^{1D} \sim N^{-1}$ and $η_c^{2D} \sim \left(N \ln N \right)^{-1/2}$ in one and two--dimensional lattices, respectively, which is linked to known results on the behavior of a type of noisy voter model for catalytic reactions. When particles are allowed to move in the space at a finite speed $v>0$, an ordered phase emerges, characterized by a fraction of particles moving in a similar direction. The system exhibits an order-disorder phase transition at a noise amplitude $η_c>0$ that is proportional to $v$, and that scales approximately as $η_c \sim v \, (-\ln v)^{-1/2}$ for $v \ll 1$. These results show that the motion of particles is able to sustain a state of global order in a system with voter-like interactions.

physics.soc-ph↗

A multi-state voter model with imperfect copying

The voter model with multiple states has found applications in areas as diverse as population genetics, opinion formation, species competition and language dynamics, among others. In a single step of the dynamics, an individual chosen at random copies the state of a random neighbor in the population. In this basic formulation it is assumed that the copying is perfect, and thus an exact copy of an individual is generated at each time step. Here we introduce and study a variant of the multi-state voter model in mean-field that incorporates a degree of imperfection or error in the copying process, which leaves the states of the two interacting individuals similar but not exactly equal. This dynamics can also be interpreted as a perfect copying with the addition of noise; a minimalistic model for flocking. We found that the ordering properties of this multi-state noisy voter model, measured by a parameter $ψ$ in [0, 1], depend on the amplitude $η$ of the copying error or noise and the population size N. In the case of perfect copying $η=0$ the system reaches an absorbing configuration with complete order ($ψ=1$) for all values of N. However, for any degree of imperfection $η>0$, we show that the average value of $ψ$ at the stationary state decreases with N as $\langle ψ\rangle \simeq 6/(π^2 η^2 N)$ for $η\ll 1$ and $η^2 N \gtrsim 1$, and thus the system becomes totally disordered in the thermodynamic limit $N \to \infty$. We also show that $\langle ψ\rangle \simeq 1-1.64 \, η^2 N$ in the vanishing small error limit $η\to 0$, which implies that complete order is never achieved for $η> 0$. These results are supported by Monte Carlo simulations of the model, which allow to study other scenarios as well.

physics.soc-ph↗

Ageing and crystallization in a lattice glass model

We have studied a the 3-$d$ lattice glass of Pica Ciamarra, Tarzia, de Candia and Coniglio [Phys.\ Rev.\ E. 67, 057105 (2013)], which has been shown to reproduce several features of the structural glass phenomenology, such as the cage effect, exponential increase of relaxation times and ageing. We show, using short-time dynamics, that the metastability limit is above the estimated Kauzmann temperature. We also find that in the region where the metastable liquid exists the aging exponent is lower that 0.5, indicating that equilibrium is reached relatively quickly. We conclude that the usefulness of this model to study the deeply supercooled regime is rather limited.

cond-mat.dis-nn↗

Stochastic Resonance and Dynamic First-Order Pseudo-Phase Transitions in the Irreversible Growth of Thin Films under Spatially Periodic Magnetic Fields

We study the irreversible growth of magnetic thin films under the influence of spatially periodic fields by means of extensive Monte Carlo simulations. We find first-order pseudo-phase transitions that separate a dynamically disordered phase from a dynamically ordered phase. By analogy with time-dependent oscillating fields applied to Ising-type models, we qualitatively associate this dynamic transition with the localization/delocalization transition of "spatial hysteresis" loops. Depending on the relative width of the magnetic film, $L$, compared to the wavelength of the external field, $λ$, different transition regimes are observed. For small systems ($L<λ$), the transition is associated with the Standard Stochastic Resonance regime, while, for large systems ($L>λ$), the transition is driven by Anomalous Stochastic Resonance. The origin of the latter is identified as due to the emergence of an additional relevant lengthscale, namely the roughness of the spin domain switching interface. The distinction between different stochastic resonance regimes is discussed at length, both qualitatively by means of snapshot configurations, as well as quantitatively via residence-length and order-parameter probability distributions.

cond-mat.stat-mech↗

Non-equilibrium Characterization of Spinodal Points using Short Time Dynamics

Though intuitively appealing, the concept of spinodal is rigourously defined only in systems with infinite range interactions (mean field systems). In short-range systems, a pseudo-spinodal can be defined by extrapolation of metastable measurements, but the point itself is not reachable because it lies beyond the metastability limit. In this work we show that a sensible definition of spinodal points can be obtained through the short time dynamical behavior of the system deep inside the metastable phase, by looking for a point where the system shows critical behavior. We show that spinodal points obtained by this method agree both with the thermodynamical spinodal point in mean field systems and with the pseudo-spinodal point obtained by extrapolation of meta-equilibrium behavior in short range systems. With this definition, a practical determination can be achieved without regard for equilibration issues.

cond-mat.stat-mech↗

Critical Behaviour of Irreversible Reaction Systems

An introductory review on the critical behaviour of some irreversible reaction systems is given. The study of these systems has attracted great attention during the last decades due to, on the one hand, the rich and complex underlying physics, and on the other hand, their relevance for numerous technological applications in heterogeneous catalysis, corrosion and coating, development of microelectronic devices, etc. The review is focuses on recent advances in the understanding of irreversible phase transitions (IPT's) providing a survey of the theoretical development of the field during the last decade, as well as a detailed discussion of relevant numerical simulations. The Langevin formulation for the treatment of second-order IPT's is discussed. Different Monte Carlo approaches are also presented in detail and the finite-size scaling analysis of second-order IPT's is described. Special attention is devoted to the description of recent progress in the study of first-order IPT's observed upon catalytic oxidation of carbon monoxide and the reduction of nitrogen monoxide, using lattice gas reaction models. Only brief comments are given on other reactions such as the oxidation of hydrogen, ammonia synthesis, etc. Also, a discussion of relevant experiments is presented and measurement are compared with the numerical results. Furthermore, promising areas for further research and open questions are also addressed.

cond-mat.stat-mech↗

Interplay between thermal percolation and jamming upon dimer adsorption on binary alloys

Using Monte Carlo simulations we study jamming and percolation processes upon the random sequential adsorption of dimers on binary alloys with different degrees of structural order. We obtain the equimolar mixtures used as substrates by applying the isomorphism between an alloy and the Ising model (conserved order parameter). The annealing temperature $T$ of the mixture then is a continuous parameter that characterizes the different sets of substrates, shaping the deposition process. As the alloy undergoes an order-disorder phase transition at the Onsager critical temperature ($T_{c}$), the jamming and percolating properties of the dimers deposited over the substrate are subjected to non-trivial changes. These are reflected in a density-temperature phase diagram with three well-defined regions. We find that for $T < T^* = 1.22 T_{c}$ the occurrence of jamming prevents the onset of percolating clusters, while percolation is possible for $T > T^{*}$. Particular attention is focused close to $T^{*}$, where the interplay between jamming and percolation restricts fluctuations, forcing exponents seemingly different from the standard percolation universality class. By analogy with a thermal transition, we study the onset of percolation by using the {\it temperature} (in this case, the substrate annealing temperature) as a control parameter. By proposing thermal scaling Ansatzes we analyze the behavior of the percolation threshold and its thermally induced fluctuations. Also, the fractal dimension of the percolating cluster is determined. Based on these measurements and the excellent data collapsing, we conclude that the universality class of standard percolation is preserved for all temperatures.

cond-mat.stat-mech↗

On the fluctuations of jamming coverage upon random sequential adsorption on homogeneous and heterogeneous media

The fluctuations of the jamming coverage upon Random Sequential Adsorption (RSA) are studied using both analytical and numerical techniques. Our main result shows that these fluctuations (characterized by $σ_{θ_J}$) decay with the lattice size according to the power-law $σ_{θ_J} \propto L^{-1/ ν}$. The exponent $ν$ depends on the dimensionality $D$ of the substrate and the fractal dimension of the set where the RSA process actually takes place ($d_f$) according to $ν= 2 / (2D - d_f)$.This theoretical result is confirmed by means of extensive numerical simulations applied to the RSA of dimers on homogeneous and stochastic fractal substrates. Furthermore, our predictions are in excellent agreement with different previous numerical results. It is also shown that, studying correlated stochastic processes, one can define various fluctuating quantities designed to capture either the underlying physics of individual processes or that of the whole system. So, subtle differences in the definitions may lead to dramatically different physical interpretations of the results. Here, this statement is demonstrated for the case of RSA of dimers on binary alloys.

cond-mat.stat-mech↗

Scaling behavior of jamming fluctuations upon random sequential adsorption

It is shown that the fluctuations of the jamming coverage upon Random Sequential Adsorption ($σ_{θ_J}$), decay with the lattice size according to the power-law $σ_{θ_J} \propto L^{-1 / ν_J}$, with $ν_{J} = 2 / (2D - d_f)$, where $D$ is the dimension of the substrate and $d_{\rm f}$ is the fractal dimension of the set of sites belonging to the substrate where the RSA process actually takes place. This result is in excellent agreement with the figure recently reported by Vandewalle {\it et al} ({\it Eur. Phys. J.} B. {\bf 14}, 407 (2000)), namely $ν_J = 1.0 (1)$ for the RSA of needles with $D = 2$ and $d_f = 2$, that gives $ν_J = 1$. Furthermore, our prediction is in excellent agreement with different previous numerical results. The derived relationships are also confirmed by means of extensive numerical simulations applied to the RSA of dimers on both stochastic and deterministic fractal substrates.

cond-mat.stat-mech↗

Numerical study of a first-order irreversible phase transition in a CO+NO catalyzed reaction model

The first-order irreversible phase transitions (IPT) of the Yaldran-Khan model (Yaldran-Khan, J. Catal. 131, 369, 1991) for the CO+NO reaction is studied using the constant coverage (CC) ensemble and performing epidemic simulations. The CC method allows the study of hysteretic effects close to coexistence as well as the location of both the upper spinodal point and the coexistence point. Epidemic studies show that at coexistence the number of active sites decreases according to a (short-time) power law followed by a (long-time) exponential decay. It is concluded that first-order IPT's share many characteristic of their reversible counterparts, such as the development of short ranged correlations, hysteretic effects, metastabilities, etc.

cond-mat.stat-mech↗