arXiv subjects

Eva Wirström

Publications and source records attributed to Eva Wirström.

4 recordsLinked to original sources

arXiv2026

Complex organic molecules and cosmic ray ionisation rate towards the massive protostar Cepheus A HW2

Cosmic rays (CRs) are important drivers for molecular chemistry in star-forming regions, and laboratory experiments have shown that CRs can stimulate the release of complex organic molecules (COMs) such as methanol. Observationally, this has primarily been tested in cold, low-mass cores, so studying how CRs affect COM formation in a high-mass star-forming environment is of great interest. We performed a high-sensitivity wide-band spectral line survey with the Onsala 20 m telescope towards the high-mass protostar Cepheus A HW2, which is known to host an ionised jet. Consistent with previous studies, two primary velocity components ($-11$ km s$^{-1}$ and $-5$ km s$^{-1}$) were identified. Column densities and relative abundances of the detected ions and COMs were estimated from rotational diagrams, single transitions and RADEX grid searches (CH$_3$OH: $1.6\times10^{-9}$, CH$_3$CN: $5.9\times10^{-11}$, t-HCOOH: $7.9\times10^{-11}$, H$_2$CCO: $1.7\times10^{-11}$, CH$_3$CHO: $1.9\times10^{-11}$, CH$_3$OCHO: $7.6\times10^{-10}$ at $-11$ km s$^{-1}$). Deuterium fractions were also estimated (in range $0.002-0.3$ at $-11$ km s$^{-1}$), and the volume density of molecular hydrogen ($2.6\times10^5$ cm$^{-3}$ at $-11$ km s$^{-1}$) was constrained from the RADEX grid searches. Electron fractions and CR ionisation rates (CRIR, $6.8\times10^{-17}$ s$^{-1}$ at $-11$ km s$^{-1}$, $\leq9.2\times10^{-19}$ s$^{-1}$ at $-5$ km s$^{-1}$) were estimated through analytic chemistry using different ions as probes. The gas-grain chemical code Nautilus reproduced the observed abundances of CH$_3$OH, CH$_3$CN, HCO$^+$, N$_2$H$^+$ at the observed density, temperature and CRIR within the uncertainty of the model. The results indicate that the CR ionisation rate of the kinematic component associated with most of the COMs' emission in the region is locally enhanced.

astro-ph.GA↗

arXiv2023

Deep Search for Glycine Conformers in Barnard 5

One of the most fundamental hypotheses in astrochemistry and astrobiology states that crucial biotic molecules like glycine (NH$_2$CH$_2$COOH) found in meteorites and comets are inherited from early phases of star formation. Most observational searches for glycine in the interstellar medium have focused on warm, high-mass molecular cloud sources. However, recent studies suggest that it might be appropriate to shift the observational focus to cold, low-mass sources. We aim to detect glycine towards the so-called methanol hotspot in the Barnard 5 dark cloud. The hotspot is a cold source ($T_\mathrm{gas}\approx 7.5$ K) with yet high abundances of complex organic molecules (COMs) and water in the gas phase. We carried out deep, pointed observations with the Onsala 20m telescope, targeting several transitions of glycine conformers I and II (Gly-I and Gly-II) in the frequency range $70.2$-$77.9$ GHz. No glycine lines are detected towards the targeted position, but we use a line stacking procedure to derive sensitive abundance upper limits w.r.t. H$_2$ for Gly-I and Gly-II, i.e. $\leq(2$-$5)\times10^{-10}$ and $\leq(0.7$-$3)\times10^{-11}$, respectively. The obtained Gly-II upper limits are the most stringent for a cold source, while the Gly-I upper limits are mostly on the same order as previously measured limits. The measured abundances w.r.t. H$_2$ of other COMs at the B5 methanol hotspot range from $2\times10^{-10}$ (acetaldehyde) to $2\times10^{-8}$ (methanol). Hence, based on a total glycine upper limit of $(2$-$5)\times10^{-10}$, we cannot rule out that glycine is present but undetected.

astro-ph.GA↗

arXiv2017

Chemical complexity induced by efficient ice evaporation in the Barnard 5 molecular cloud

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water are consistent with a transient non-thermal evaporation process only affecting the outermost ice mantle layers, possibly triggering a more complex chemistry. We present the detection of the Complex Organic Molecules (COMs) acetaldehyde and methyl formate as well as formic acid and ketene, and the tentative detection of di-methyl ether towards the methanol hotspot of Barnard 5 located between two dense cores using the single dish OSO 20m, IRAM 30m, and NRO 45m telescopes. The high energy cis- conformer of formic acid is detected, suggesting that formic acid is mostly formed at the surface of interstellar grains and then evaporated. The detection of multiple transitions for each species allows us to constrain their abundances through LTE and non-LTE methods. All the considered COMs show similar abundances between $\sim 1$ and $\sim 10$ % relative to methanol depending on the assumed excitation temperature. The non-detection of glycolaldehyde, an isomer of methyl formate, with a [glycolaldehyde]/[methyl formate] abundance ratio lower than 6 %, favours gas phase formation pathways triggered by methanol evaporation. According to their excitation temperatures derived in massive hot cores, formic acid, ketene, and acetaldehyde have been designated as "lukewarm" COMs whereas methyl formate and di-methyl ether were defined as "warm" species. Comparison with previous observations of other types of sources confirms that "lukewarm" and "warm" COMs show similar abundances in low-density cold gas whereas the "warm" COMs tend to be more abundant than the "lukewarm" species in warm protostellar cores.

astro-ph.GA↗

arXiv2016

Formation and recondensation of complex organic molecules during protostellar luminosity outbursts

During the formation of stars, the accretion of the surrounding material toward the central object is thought to undergo strong luminosity outbursts, followed by long periods of relative quiescence, even at the early stages of star formation when the protostar is still embedded in a large envelope. We investigated the gas phase formation and the recondensation of the complex organic molecules (COMs) di-methyl ether and methyl formate, induced by sudden ice evaporation processes occurring during luminosity outbursts of different amplitudes in protostellar envelopes. For this purpose, we updated a gas phase chemical network forming complex organic molecules in which ammonia plays a key role. The model calculations presented here demonstrate that ion-molecule reactions alone could account for the observed presence of di-methyl ether and methyl formate in a large fraction of protostellar cores, without recourse to grain-surface chemistry, although they depend on uncertain ice abundances and gas phase reaction branching ratios. In spite of the short outburst timescales of about one hundred years, abundance ratios of the considered species with respect to methanol higher than 10 % are predicted during outbursts due to their low binding energies relative to water and methanol that delay their recondensation during the cooling. Although the current luminosity of most embedded protostars would be too low to produce these complex species in hot core regions that can be observable with current sub-millimetric interferometers, previous luminosity outburst events would induce a formation of COMs in extended regions of protostellar envelopes with sizes increasing by up to one order of magnitude.

astro-ph.GA↗