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F. Abbasi

Publications and source records attributed to F. Abbasi.

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Memory effects on link formation in temporal networks: A fractional calculus approach

Memory plays a vital role in the temporal evolution of interactions of complex systems. To address the impact of memory on the temporal pattern of networks, we propose a simple preferential connection model, in which nodes have a preferential tendency to establish links with most active nodes. Node activity is measured by the number of links a node observes in a given time interval. Memory is investigated using a time-fractional order derivative equation, which has proven to be a powerful method to understand phenomena with long-term memory. The memoryless case reveals a characteristic time where node activity behaves differently below and above it. We also observe that dense temporal networks (high number of events) show a clearer characteristic time than sparse ones. Interestingly, we also find that memory leads to decay of the node activity; thus, the chances of a node to receive new connections reduce with the node's age. Finally, we discuss the statistical properties of the networks for various memory-length.

physics.soc-ph

Dynamic Compression of in situ Grown Living Polymer Brush: Simulation and Experiment

A comparative dynamic Monte Carlo simulation study of polydisperse living polymer brushes, created by surface initiated living polymerization, and conventional polymer monodisperse brush, comprising linear polymer chains, grafted to a planar substrate under good solvent conditions, is presented. The living brush is created by end-monomer (de)polymerization reaction after placing an array of initiators on a grafting plane in contact with a solution of initially non-bonded segments (monomers). At equilibrium, the monomer density profile ϕ(z) of the LPB is found to decline as ϕ(z) ~ z^{-α} with the distance from the grafting plane z, while the distribution of chain lengths in the brush scales as c(N) ~ N^{-τ}. The measured values α= 0.64 and τ= 1.70 are very close to those, predicted within the framework of the Diffusion-Limited Aggregation theory, α= 2/3 and τ= 7/4. At varying mean degree of polymerization (from L = 28 to L = 170) and effective grafting density (from σ_g = 0.0625 to σ_g = 1.0), we observe a nearly perfect agreement in the force-distance behavior of the simulated LPB with own experimental data obtained from colloidal probe AFM analysis on PNIPAAm brush and with data obtained by Plunkett et. al., [Langmuir 2006, 22, 4259] from SFA measurements on same polymer.

cond-mat.soft