arXiv subjects

F. Albertini

Publications and source records attributed to F. Albertini.

9 recordsLinked to original sources

arXiv2025

In-operando test of tunable Heusler alloys for thermomagnetic harvesting of low-grade waste heat

Thermomagnetic generation stands out as a promising technology for harvesting and converting low-grade waste heat below 100 {\deg}C. Despite the exponential growth in research on thermomagnetic materials and prototypes over the last decade, there remains, to unlock the full potential of this technology, a critical gap between fundamental research on materials and the design of advanced devices. In this study, we present the in-operando assessment of thermomagnetic performance of three representative Ni,Mn-based Heusler alloys optimized for harvesting low-grade waste heat below 373 K. These materials were tested under operational conditions using a specially designed laboratory-scale prototype of a thermomagnetic motor. The mechanical power output of the motor, operated with NiMnIn, NiMnSn and NiMnCuGa alloys, was correlated with the magnetic properties of the materials, highlighting the critical role of the magnetic transition temperature and saturation magnetization in determining the efficiency of thermomagnetic energy conversion. Austenitic Heusler alloys were confirmed to be promising thermomagnetic materials due to their highly tunable Curie temperature and significant magnetization changes in the 300-360 K temperature range. Among the tested materials, the Ni48Mn36In16 alloy demonstrated the highest thermomagnetic performance, surpassing the benchmark material Gd in the 320-340 K range. From an experimental perspective, the developed prototype of thermomagnetic motor serves as a flexible test-bench for evaluating and comparing the thermomagnetic performance of small amounts (less than 0.3 g) of new materials under variable conditions. Additionally, its modular design facilitates testing and optimization of its various components, thereby contributing to the advancement of thermomagnetic motor technology.

cond-mat.mtrl-sci↗

arXiv2025

Magnetic properties of Ge, Re and Cr substituted Fe$_5$SiB$_2$

One of the possible approaches to decrease the demand for critical elements such as rare earths is to develop new sustainable magnets. Iron-based materials are suitable for gap magnets applications since iron is the most abundant ferromagnetic element on Earth. Fe$_5$SiB$_2$ is a candidate as gap magnet thanks to its high Curie temperature (T$_{\text{C}} \sim$ 800 K) and saturation magnetization (M$_{\text{S}}\sim$ 140 Am$^2$kg$^{-1}$). However its anisotropy field is too low for applications (H$_{\text{A}} \sim$ 0.8 T). In order to increase the anisotropy value, we synthesized a series of Ge, Re and Cr substituted Fe$_5$SiB$_2$ samples and studied their magnetic properties. They all crystallize in the Cr$_5$B$_3$-type tetragonal structure with the $I4/mcm$ space group. Curie temperature (T$_{\text{C}}$ = 803 K) and saturation magnetization (M$_{\text{S}}$ = 138 Am$^2$kg$^{-1}$) are slightly decreased by elemental substitution with Re having the largest effect. Despite being reduced, T$_{\text{C}}$ and M$_{\text{S}}$ still maintain significant values (T$_{\text{C}}>$ 750 K and M$_{\text{S}}$ = 118 Am$^2$kg$^{-1}$). The room temperature anisotropy field has been measured by Singular Point Detection (SPD) and increases by about 15% upon Re substitution, reaching 0.92 T for Fe$_{4.75}$Re$_{0.25}$SiB$_2$. We have also used Nuclear Magnetic Resonance and SPD measurements to study the spin reorientation transition which takes place at 172 K and we have found that it is partially suppressed by substitution of Ge from 172 K to 140 K and completely suppressed upon Cr and Re substitution.

cond-mat.mtrl-sci↗

arXiv2022

Effective decoupling of ferromagnetic sublattices by frustration in Heusler alloys

Magnetic frustration in ferromagnetic metallic systems is unusual due to the long-range and symmetric nature of the exchange interactions. In this work we prove that it is possible to obtain a highly frustrated ferromagnetic phase in a multi-sublattices cubic structure through a fine tuning of the magnetic interactions. This peculiar state is achieved in Ni-Mn-(In, Sn) Heusler alloys and results in the effective decoupling of their two intertwined ferromagnetic sublattices. One sublattice is ferromagnetic long range ordered below the macroscopic Curie temperature (TC ) whereas the second one remains disordered until a crossover to a polarized state occurs at T << TC . This result points out that a fine engineering of the magnetic interactions in metallic systems can lead to interesting novel and emergent phenomena.

cond-mat.mtrl-sci↗

arXiv2015

Evidence for In-Plane Tetragonal c-axis in Mn$_x$Ga$_{1-x}$ Thin Films using Transmission Electron Microscopy

Tetragonal Mn$_x$Ga$_{1-x}$ (x=0.70, 0.75) thin films grown on SrTiO$_3$ substrates at different temperatures and thicknesses exhibit perpendicular magnetic anisotropy with coercive fields between 1-2 T. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) reveal that 40nm samples grown at 300-350$^{o}$C lead to polycrystalline films with the tetragonal c-axis oriented primarily perpendicular to the film plane but with some fraction of the sample exhibiting the c-axis in the film plane. This structure results in a secondary magnetic component in the out of plane magnetization. Growth at 300$^{o}$C with a reduced thickness or Mn concentration significantly decreases the presence of the tetragonal c-axis in the film plane, thus improving the magnetic properties. TEM is of critical importance in characterizing these materials, since conventional XRD cannot always identify the presence of additional crystallographic orientations although they can still affect the magnetic properties. Our study points to ways that the microstructure of these thin films can be controlled, which is critical for utilization of this material in spintronic devices.

cond-mat.mtrl-sci↗

arXiv2014

Magnetic shape memory microactuator

Bimetallic composite nanotweezers based on Ti2NiCu alloy with shape memory effect (SME) have recently demonstrated the ability to manipulate real nano-objects, such as nanotubes, and bionanoparticles when heated to 40-60 C by laser radiation. The possibility of developing nanotweezers operating at constant temperature is of particular importance mainly for the manipulation of biological objects. In this work, a microactuator was produced using a composite bilayer made of a layer of rapidly quenched Ni53Mn24Ga23 ferromagnetic shape memory Heusler alloy and an elastic layer of Pt. The size of the microactuator is 25x2.3x1.7 micro-meters3. A controlled bending deformation of the actuator of 1.2 %, with a deflection of the end of the actuator higher than 2 micro-meter was obtained by applying a magnetic field of 8 T at T = 62 C. The possibility of the development of new technologies for magnetic-field-controlled nanotools operating at a constant temperature using the new multifunction magnetic shape memory alloys will be discussed.

cond-mat.mtrl-sci↗

arXiv2010

Spin configurations in hard-soft coupled bilayer systems: from rigid magnet to exchange spring transitions

We investigate equilibrium properties of an exchange-spring magnetic system constituted of a soft layer (e.g. Fe) of a given thickness on top of a hard magnetic layer (e.g. FePt). The magnetization profile M(z) as a function of the atomic position ranging from the bottom of the hard layer to the top of the soft layer is obtained in two cases with regard to the hard layer: i) in the case of a rigid interface (the FePt layer is a single layer), the profile is obtained analytically as the exact solution of a sine-Gordon equation with Cauchy's boundary conditions. Additional numerical simulations also confirm this result. Asymptotic expressions of M(z) show a linear behavior near the bottom and the top of the soft layer. In addition, a critical value of the number of atomic planes in the soft layer, that is necessary for the onset of spin deviations, is obtained in terms of the anisotropy and exchange coupling between the adjacent plane in the soft layer. ii) in the case of a relaxed interface (the FePt layer is a multilayer), the magnetization profile is obtained numerically for various Fe and FePt films thicknesses and applied field.

cond-mat.mtrl-sci↗

arXiv2002

Notions of controllability for quantum mechanical systems

In this paper, we define four different notions of controllability of physical interest for multilevel quantum mechanical systems. These notions involve the possibility of driving the evolution operator as well as the state of the system. We establish the connections among these different notions as well as methods to verify controllability. The paper also contains results on the relation between the controllability in arbitrary small time of a system varying on a compact transformation Lie group and the corresponding system on the associated homogeneous space. As an application, we prove that, for the system of two interacting spin 1/2 particles, not every state transfer can be obtained in arbitrary small time.

quant-ph↗

arXiv2002

Giant entropy change at the co-occurrence of structural and magnetic transitions in the Ni2.19Mn0.81Ga Heusler alloy

In this paper we report the existence of a giant magnetocaloric effect (MCE) in a intermetallic compound non-containing rare-earth. This effect is associated with the concomitant occurrence of a structural and a magnetic transition. The result has been compared with that obtained in a parent compound in which magnetic and structural transition occur separately.

cond-mat.mtrl-sci↗

arXiv2001

The Lie algebra Structure and Nonlinear Controllability of Spin Systems

In this paper, we study the controllability properties and the Lie algebra structure of networks of particles with spin immersed in an electro-magnetic field. We relate the Lie algebra structure to the properties of a graph whose nodes represent the particles and an edge connects two nodes if and only if the interaction between the two corresponding particles is active. For networks with different gyromagnetic ratios, we provide a necessary and sufficient condition of controllability in terms of the properties of the above mentioned graph and describe the Lie algebra structure in every case. For these systems all the controllability notions, including the possibility of driving the evolution operator and/or the state, are equivalent. For general networks (with possibly equal gyromagnetic ratios), we give a sufficient condition of controllability. A general form of interaction among the particles is assumed which includes both Ising and Heisenberg models as special cases. Assuming Heisenberg interaction we provide an analysis of low dimensional cases (number of particles less then or equal to three) which include necessary and sufficient controllability conditions as well as a study of their Lie algebra structure. This also, provides an example of quantum mechanical systems where controllability of the state is verified while controllability of the evolution operator is not.

quant-ph↗