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F. Duarte

Publications and source records attributed to F. Duarte.

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Latent patterns of urban mixing in mobility analysis across five global cities

This study leverages large-scale travel surveys for over 200,000 residents across Boston, Chicago, Hong Kong, London, and Sao Paulo. With rich individual-level data, we make systematic comparisons and reveal patterns in social mixing, which cannot be identified by analyzing high-resolution mobility data alone. Using the same set of data, inferring socioeconomic status from residential neighborhoods yield social mixing levels 16% lower than using self-reported survey data. Besides, individuals over the age of 66 experience greater social mixing than those in late working life (aged 55 to 65), lending data-driven support to the "second youth" hypothesis. Teenagers and women with caregiving responsibilities exhibit lower social mixing levels. Across the five cities, proximity to major transit stations reduces the influence of individual socioeconomic status on social mixing. Finally, we construct detailed spatio-temporal place networks for each city using a graph neural network. Inputs of home-space, activity-space and demographic attributes are embedded and fed into a supervised autoencoder to predict individual exposure vectors. Results show that the structure of individual activity space, i.e., where people travel to, explains most of the variations in place exposure, suggesting that mobility shapes experienced social mixing more than sociodemographic characteristics, home environment, and transit proximity. The ablation tests further discover that, while different income groups may experience similar levels of social mixing, their activity spaces remain stratified by income, resulting in structurally different social mixing experiences.

cs.AI

Single photon double and triple ionisation of allene

Double and triple ionization of allene are investigated using electron-electron, ion-ion, electron-electron-ion and electron-electron-ion-ion (ee, ii, eei, eeii) coincidence spectroscopies at selected photon energies. The results provide supporting evidence for a previously proposed roaming mechanism in H$_3^+$ formation by double ionisation. The lowest vertical double ionization energy is found to be 28.5 eV, while adiabatic double ionisation is not accessed by vertical ionisation at the neutral geometry. The triple ionization energy is found to be close to 50 eV in agreement with theoretical predictions. The doubly charged parent ion is stable up to about 2 eV above threshold, after which dissociations by charge separation and by double charge retention occur with comparable intensities. Fragmentation to H$^+$ + C$_3$H$_3^+$ starts immediately above threshold as a slow (metastable) decay with 130+/-10 ns mean lifetime.

physics.atom-ph

Double and triple ionization of isocyanic acid

Double and triple ionization spectra of isocyanic acid have been measured using multi-electron and ion coincidence techniques combined with synchrotron radiation and compared with high-level theoretical calculations. Vertical double ionization at an energy of 32.8+/-0.3 eV forms the 3A'' ground state in which the HNCO2+ ion is long-lived. The vertical triple ionization energy is determined as 65+/-1 eV. The core-valence double ionization spectra resemble the valence photoelectron spectrum in form, and their main features can be understood on the basis of a simple and rather widely applicable Coulomb model based on the characteristics of the molecular orbitals from which electrons are removed. Characteristics of the most important dissociation channels are examined and discussed.

physics.atm-clus