arXiv subjects

F. Kruczkiewicz

Publications and source records attributed to F. Kruczkiewicz.

5 recordsLinked to original sources

arXiv2026

Optical constants of Ih, Ic, and amorphous H$_2$O ices in the THz and IR ranges

Direct measurements of optical constants in the THz spectral region for astrophysically relevant H$_2$O ice samples are scarce. Extrapolation of optical properties in the THz spectral region from IR data can introduce uncertainties into astrophysical models. We measured the optical properties of water ice samples in the Ih and Ic forms as well as amorphous solid water (ASW) in the THz region in order to derive broad optical constants using literature and experimental data in the THz-IR range. In our experiments, the Ih, Ic, and ASW ices were grown by vapour deposition onto a cold substrate and measured by THz pulsed spectroscopy. Their THz optical properties were retrieved, compared with the THz-IR literature data, and approximated using the multiple-Lorentz model. From the existing literature data on the Ih, Ic, and ASW ices, we selected samples with the highest optical constants and classified them as compact. Their optical properties were merged in the frequency range of $\nu = 0.3$-$120$~THz (the wavelength range of $\lambda = 1$~mm-2.5$~\mu$m). The underlying absorption bands were attributed to vibrational modes and approximated using the multiple-Lorentz model while accounting for anharmonicity. Discrepancies primarily arising in low-absorption regions between the experimental data and broadband models were attributed to factors such as the model's complexity and the baseline-subtraction procedure. The THz response of all ices is formed by the low-frequency wings of the IR bands and the single broad low-intense THz peak around $1.8$~THz, which is very similar for all phases. The opacity calculation for dust grains covered by H$_2$O ice mantles based on experimental data shows discrepancies with data derived by extrapolation. The inferred THz-IR optical constants of water ice are important for future observations and modelling of cold clouds and protoplanetary disks.

astro-ph.GA↗

arXiv2026

Broadband spectroscopy of astrophysical ice analogues: IV. Optical constants of N$_2$ ice in the terahertz and mid-infrared ranges

Context. Understanding the optical properties of astrophysical ices is crucial for modeling dust continuum emission and radiative transfer in cold, dense interstellar environments. Molecular nitrogen (N$_2$), a major nitrogen reservoir in protoplanetary disks, plays a key role in nitrogen chemistry, yet the lack of direct terahertz (THz)--infrared (IR) optical constants for N$_2$ ice introduces uncertainties in radiative transfer models, snowline locations, and disk mass estimates. Aims. We present direct measurements of the optical properties of N$_2$ ice over a broad THz--IR spectral range using terahertz pulsed spectroscopy (TPS) and Fourier-transform infrared spectroscopy (FTIR), supported by density functional theory (DFT) calculations and comparison with literature data. Methods. N$_2$ ice was grown at cryogenic temperatures by gas-phase deposition onto a cold silicon window. The THz complex refractive index was directly reconstructed from TPS data, while the IR response was derived from FTIR measurements using Kramers--Kronig relations. The optical response was parameterized with a Lorentz dielectric model and validated by DFT calculations. Results. The complex refractive index of N$_2$ ice is quantified from $\nu = 0.3$--$16$~THz ($\lambda = 1$~mm--$18.75~\mu$m). Resonant absorption peaks at $\nu_\mathrm{L} = 1.47$ and $2.13$~THz with damping constants $\gamma_\mathrm{L} = 0.03$ and $0.22$~THz are attributed to optically active phonons of the $\alpha$-N$_2$ crystal. Conclusions. We provide a complete set of the THz--IR optical constants for \ce{N2} ice by combining TPS and FTIR spectroscopy. Our results have implications for future observational and modeling studies of protoplanetary disk evolution and planet formation.

astro-ph.EP↗

arXiv2024

Comprehensive laboratory constraints on thermal desorption of interstellar ice analogues

To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms determine the position of snow lines and the nature of gas emitted by and locked inside planetary bodies in star-forming regions. To interpret observations from the interplanetary and extragalactic interstellar mediums, gas phase abundances must be modelled correctly. This study presents comprehensive thermal desorption data for interstellar ice analogues, aiming to refine astrochemical models by generating a set of benchmarks to evaluate both the kinetics and thermodynamics in astrochemical models. Our experiments focused on temperature-programmed desorption of pure and mixed ices, including Ar, CO, CO2, NH3, CH3OH, and H2O, under ultrahigh vacuum (1 x 10^-10 hPa) and low temperatures (10 K). Each experiment includes the experimental parameters, ice desorption kinetics for pure species, and the desorption yield (gas--solid ratio) for ice mixtures. From the desorption yields, we find common trends in the trapping of molecules when their abundance is compared to water: compact amorphous water ices are capable of trapping up to 20 % of volatiles (Ar, CO, and CO2), ~ 3 % of CH3OH, and ~ 5% NH3 in relation to the water content within the ice matrix; ammonium formate is not trapped in the water ice films, and compact amorphous water ice formed in situ has similar trapping capabilities to a compact amorphous water ice deposited using molecular beams. Our results highlight the limited trapping capacity of compact amorphous water ice for gases, crucial for understanding the formation of interstellar complex organic molecules.

astro-ph.GA↗

arXiv2022

Broadband spectroscopy of astrophysical ice analogues: II. Optical constants of CO and CO$_2$ ices in the terahertz and infrared ranges

Context: Broadband optical constants of astrophysical ice analogues in the infrared (IR) and terahertz (THz) ranges are required for modeling the dust continuum emission and radiative transfer in dense and cold regions, where thick icy mantles are formed on the surface of dust grains. Aims: In this paper, the THz time-domain spectroscopy (TDS) and the Fourier-transform IR spectroscopy (FTIR) are combined to study optical constants of CO and CO$_2$ ices in the broad THz-IR spectral range. Methods: The measured ices are grown at cryogenic temperatures by gas deposition on a cold Si window. A method to quantify the broadband THz-IR optical constants of ices is developed based on the direct reconstruction of the complex refractive index of ices in the THz range from the TDS data, and the use of the Kramers-Kronig relation in the IR range for the reconstruction from the FTIR data. Uncertainties of the Kramers-Kronig relation are eliminated by merging the THz and IR spectra. The reconstructed THz-IR response is then analyzed using classical models of complex dielectric permittivity. Results: The complex refractive index of CO and CO$_2$ ices deposited at the temperature of $28$ K is obtained in the range of 0.3--12.0 THz. Based on the measured dielectric constants, opacities of the astrophysical dust with CO and CO$_2$ icy mantles are computed. Conclusions: The developed method can be used for a model-independent reconstruction of optical constants of various astrophysical ice analogs in a broad THz-IR range. Such data can provide important benchmarks to interpret the broadband observations from the existing and future ground-based facilities and space telescopes. The reported results will be useful to model sources that show a drastic molecular freeze-out, such as central regions of prestellar cores and mid-planes of protoplanetary disks, as well as CO and CO$_2$ snow lines in disks.

astro-ph.SR↗

arXiv2021

Ammonia snow-lines and ammonium salts desorption

Context. The nitrogen reservoir in planetary systems is a long standing problem. Part of the N-bearing molecules is probably incorporated into the ice bulk during the cold phases of the stellar evolution, and may be gradually released into the gas phase when the ice is heated, such as in active comets. The chemical nature of the N-reservoir should greatly influence how, when and in what form N returns to the gas phase, or is incorporated into the refractory material forming planetary bodies. Aims. We present the study the thermal desorption of two ammonium salts: ammonium formate and ammonium acetate from a gold surface and from a water ice substrate. Methods. Temperature-programmed desorption experiments and Fourier transform infrared reflection spectroscopy were conducted to investigate the desorption behavior of ammonium salts. Results. Ammonium salts are semi-volatile species releasing neutral species as major components upon desorption, that is ammonia and the corresponding organic acid (HCOOH and CH3COOH), at temperatures higher than the temperature of thermal desorption of water ice. Their desorption follows a first-order Wigner-Polanyi law. We find the first order kinetic parameters A = 7.7 $\pm$ 0.6 $\times$ 10$^{15}$ s$^{-1}$ and E$_{bind}$ = 68.9 $\pm$ 0.1 kJ~mol$^{-1}$ for ammonium formate and A = 3.0 $\pm$ 0.4 $\times$ 10$^{20}$ s$^{-1}$ and E$_{bind}$ = 83.0 $\pm$ 0.2 kJ~mol$^{-1}$ for ammonium acetate. The presence of a water ice substrate does not influence the desorption kinetics. Ammonia molecules locked in salts desorb as neutral molecules at temperatures much higher than previously expected that are usually attributed to refractory materials. Conclusions. Ammonia snow-line has a smaller radius than the water snow-line. As a result, the NH3/H2O ratio content in solar system bodies can be a hint as to where they formed and subsequently migrated.

astro-ph.EP↗