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F. Murgas

Publications and source records attributed to F. Murgas.

At least 109 records · Page 6Linked to original sources

Masses and compositions of three small planets orbiting the nearby M dwarf L231-32 (TOI-270) and the M dwarf radius valley

We report on precise Doppler measurements of L231-32 (TOI-270), a nearby M dwarf ($d=22$ pc, $M_\star = 0.39$ M$_\odot$, $R_\star = 0.38$ R$_\odot$), which hosts three transiting planets that were recently discovered using data from the Transiting Exoplanet Survey Satellite (TESS). The three planets are 1.2, 2.4, and 2.1 times the size of Earth and have orbital periods of 3.4, 5.7, and 11.4 days. We obtained 29 high-resolution optical spectra with the newly commissioned Echelle Spectrograph for Rocky Exoplanet and Stable Spectroscopic Observations (ESPRESSO) and 58 spectra using the High Accuracy Radial velocity Planet Searcher (HARPS). From these observations, we find the masses of the planets to be $1.58 \pm 0.26$, $6.15 \pm 0.37$, and $4.78 \pm 0.43$ M$_\oplus$, respectively. The combination of radius and mass measurements suggests that the innermost planet has a rocky composition similar to that of Earth, while the outer two planets have lower densities. Thus, the inner planet and the outer planets are on opposite sides of the `radius valley' -- a region in the radius-period diagram with relatively few members, which has been interpreted as a consequence of atmospheric photo-evaporation. We place these findings into the context of other small close-in planets orbiting M dwarf stars, and use support vector machines to determine the location and slope of the M dwarf ($T_\mathrm{eff} < 4000$ K) radius valley as a function of orbital period. We compare the location of the M dwarf radius valley to the radius valley observed for FGK stars, and find that its location is a good match to photo-evaporation and core-powered mass loss models. Finally, we show that planets below the M dwarf radius valley have compositions consistent with stripped rocky cores, whereas most planets above have a lower density consistent with the presence of a H-He atmosphere.

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TOI-674b: an oasis in the desert of exo-Neptunes transiting a nearby M dwarf

We use TESS, Spitzer, ground-based light curves and HARPS spectrograph radial velocity measurements to establish the physical properties of the transiting exoplanet candidate TOI-674b. We perform a joint fit of the light curves and radial velocity time series to measure the mass, radius, and orbital parameters of the candidate. We confirm and characterize TOI-674b, a low-density super-Neptune transiting a nearby M dwarf. The host star (TIC 158588995, $V = 14.2$ mag, $J = 10.3$ mag) is characterized by its M2V spectral type with $\mathrm{M}_\star=0.420\pm 0.010$ M$_\odot$, $\mathrm{R}_\star = 0.420\pm 0.013$ R$_\odot$, and $\mathrm{T}_{\mathrm{eff}} = 3514\pm 57$ K, and is located at a distance $d=46.16 \pm 0.03$ pc. Combining the available transit light curves plus radial velocity measurements and jointly fitting a circular orbit model, we find an orbital period of $1.977143 \pm 3\times 10^{-6}$ days, a planetary radius of $5.25 \pm 0.17$ $\mathrm{R}_\oplus$, and a mass of $23.6 \pm 3.3$ $\mathrm{M}_\oplus$ implying a mean density of $ρ_\mathrm{p} = 0.91 \pm 0.15$ [g cm$^{-3}$]. A non-circular orbit model fit delivers similar planetary mass and radius values within the uncertainties. Given the measured planetary radius and mass, TOI-674b is one of the largest and most massive super-Neptune class planets discovered around an M type star to date. It is also a resident of the so-called Neptunian desert and a promising candidate for atmospheric characterisation using the James Webb Space Telescope.

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The CARMENES search for exoplanets around M dwarfs. Two terrestrial planets orbiting G 264-012 and one terrestrial planet orbiting Gl 393

We report the discovery of two planetary systems, namely G 264-012, an M4.0 dwarf with two terrestrial planets ($M_{\rm b}\sin{i} = 2.50^{+0.29}_{-0.30}$ M$_{\oplus}$ and $M_{\rm c}\sin{i} = 3.75^{+0.48}_{-0.47}$ M$_{\oplus}$), and Gl 393, a bright M2.0 dwarf with one terrestrial planet ($M_{\rm b}\sin{i} = 1.71 \pm 0.24$ M$_{\oplus}$). Although both stars were proposed to belong to young stellar kinematic groups, we estimate their ages to be older than about 700 Ma. The two planets around G 264-012 were discovered using only radial-velocity (RV) data from the CARMENES exoplanet survey, with estimated orbital periods of $2.30$ d and $8.05$ d, respectively. Photometric monitoring and analysis of activity indicators reveal a third signal present in the RV measurements, at about 100 d, caused by stellar rotation. The planet Gl 393 b was discovered in the RV data from the HARPS, CARMENES, and HIRES instruments. Its identification was only possible after modelling, with a Gaussian process (GP), the variability produced by the magnetic activity of the star. For the earliest observations, this variability produced a forest of peaks in the periodogram of the RVs at around the 34 d rotation period determined from {\em Kepler} data, which disappeared in the latest epochs. After correcting for them with this GP model, a significant signal showed at a period of $7.03$ d. No significant signals in any of our spectral activity indicators or contemporaneous photometry were found at any of the planetary periods. Given the orbital and stellar properties, the equilibrium temperatures of the three planets are all higher than that for Earth. Current planet formation theories suggest that these two systems represent a common type of architecture. This is consistent with formation following the core accretion paradigm.

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TOI-1634 b: an Ultra-Short Period Keystone Planet Sitting Inside the M Dwarf Radius Valley

Studies of close-in planets orbiting M dwarfs have suggested that the M dwarf radius valley may be well-explained by distinct formation timescales between enveloped terrestrials, and rocky planets that form at late times in a gas-depleted environment. This scenario is at odds with the picture that close-in rocky planets form with a primordial gaseous envelope that is subsequently stripped away by some thermally-driven mass loss process. These two physical scenarios make unique predictions of the rocky/enveloped transition's dependence on orbital separation such that studying the compositions of planets within the M dwarf radius valley may be able to establish the dominant physics. Here, we present the discovery of one such keystone planet: the ultra-short period planet TOI-1634 b ($P=0.989$ days, $F=121 F_{\oplus}$, $r_p = 1.790^{+0.080}_{-0.081} R_{\oplus}$) orbiting a nearby M2 dwarf ($K_s=8.7$, $R_s=0.45 R_{\odot}$, $M_s=0.50 M_{\odot}$) and whose size and orbital period sit within the M dwarf radius valley. We confirm the TESS-discovered planet candidate using extensive ground-based follow-up campaigns, including a set of 32 precise radial velocity measurements from HARPS-N. We measure a planetary mass of $4.91^{+0.68}_{-0.70} M_{\oplus}$, which makes TOI-1634 b inconsistent with an Earth-like composition at $5.9σ$ and thus requires either an extended gaseous envelope, a large volatile-rich layer, or a rocky portion that is not dominated by iron and silicates to explain its mass and radius. The discovery that the bulk composition of TOI-1634 b is inconsistent with that of the Earth favors the gas-depleted formation mechanism to explain the emergence of the radius valley around M dwarfs with $M_s\lesssim 0.5 M_{\odot}$.

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TOI-269 b: An eccentric sub-Neptune transiting a M2 dwarf revisited with ExTrA

We present the confirmation of a new sub-Neptune close to the transition between super-Earths and sub-Neptunes transiting the M2 dwarf TOI- 269 (TIC 220479565, V = 14.4 mag, J = 10.9 mag, Rstar = 0.40 Rsun, Mstar = 0.39 Msun, d = 57 pc). The exoplanet candidate has been identified in multiple TESS sectors, and validated with high-precision spectroscopy from HARPS and ground-based photometric follow-up from ExTrA and LCO-CTIO. We determined mass, radius, and bulk density of the exoplanet by jointly modeling both photometry and radial velocities with juliet. The transiting exoplanet has an orbital period of P = 3.6977104 +- 0.0000037 days, a radius of 2.77 +- 0.12 Rearth, and a mass of 8.8 +- 1.4 Mearth. Since TOI-269 b lies among the best targets of its category for atmospheric characterization, it would be interesting to probe the atmosphere of this exoplanet with transmission spectroscopy in order to compare it to other sub-Neptunes. With an eccentricity e = 0.425+0.082-0.086, TOI-269 b has one of the highest eccentricities of the exoplanets with periods less than 10 days. The star being likely a few Gyr old, this system does not appear to be dynamically young. We surmise TOI-269 b may have acquired its high eccentricity as it migrated inward through planet-planet interactions.

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An ultra-short-period transiting super-Earth orbiting the M3 dwarf TOI-1685

Dynamical histories of planetary systems, as well as atmospheric evolution of highly irradiated planets, can be studied by characterizing the ultra-short-period planet population, which the TESS mission is particularly well suited to discover. Here, we report on the follow-up of a transit signal detected in the TESS sector 19 photometric time series of the M3.0 V star TOI-1685 (2MASS J04342248+4302148). We confirm the planetary nature of the transit signal, which has a period of P_b=0.6691403+0.0000023-0.0000021 d, using precise radial velocity measurements taken with the CARMENES spectrograph. From the joint photometry and radial velocity analysis, we estimate the following parameters for TOI-1685 b: a mass of M_b=3.78+/-0.63 M_Earth, a radius of R_b=1.70+/-0.07 R_Earth, which together result in a bulk density of rho_b=4.21+0.95-0.82 g/cm3, and an equilibrium temperature of Teq_b=1069+/-16 K. TOI-1685 b is the least dense ultra-short period planet around an M dwarf known to date. TOI-1685 b is also one of the hottest transiting Earth-size planets with accurate dynamical mass measurements, which makes it a particularly attractive target for thermal emission spectroscopy. Additionally, we report a further non-transiting planet candidate in the system, TOI-1685[c], with an orbital period of P_[c]=9.02+0.10-0.12 d.

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Simultaneous photometric and CARMENES spectroscopic monitoring of fast-rotating M dwarf GJ 3270. Discovery of a post-flare corotating feature

Context: Active M dwarfs frequently exhibit large flares, which can pose an existential threat to the habitability of any planet in orbit in addition to making said planets more difficult to detect. M dwarfs do not lose angular momentum as easily as earlier-type stars, which maintain the high levels of stellar activity for far longer. Studying young, fast-rotating M dwarfs is key to understanding their near stellar environment and the evolution of activity Aims: We study stellar activity on the fast-rotating M dwarf GJ 3270. Methods: We analyzed dedicated high cadence, simultaneous, photometric and high-resolution spectroscopic observations obtained with CARMENES of GJ 3270 over 7.7 h, covering a total of eight flares of which two are strong enough to facilitate a detailed analysis. We consult the TESS data, obtained in the month prior to our own observations, to study rotational modulation and to compare the TESS flares to those observed in our campaign. Results: The TESS data exhibit rotational modulation with a period of 0.37 d. The strongest flare covered by our observing campaign released a total energy of about 3.6e32 erg, putting it close to the superflare regime. This flare is visible in the B,V, r, i, and z photometric bands, which allows us to determine a peak temperature of about 10,000 K. The flare also leaves clear marks in the spectral time series. In particular, we observe an evolving, mainly blue asymmetry in chromospheric lines, which we attribute to a post-flare, corotating feature. To our knowledge this is the first time such a feature has been seen on a star other than our Sun. Conclusions: Our photometric and spectroscopic time series covers the eruption of a strong flare followed up by a corotating feature analogous to a post-flare arcadal loop on the Sun with a possible failed ejection of material.

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ESPRESSO Mass determination of TOI-263b: An extreme inhabitant of the brown dwarf desert

The TESS mission has reported a wealth of new planetary systems around bright and nearby stars amenable for detailed characterization of the planet properties and their atmospheres. However, not all interesting TESS planets orbit around bright host stars. TOI-263b is a validated ultra-short period substellar object in a 0.56-day orbit around a faint (V=18.97) M3.5 dwarf star. The substellar nature of TOI-263b was explored using multi-color photometry, which determined a true radius of 0.87+-0.21 Rj, establishing TOI-263b's nature ranging from an inflated Neptune to a brown dwarf. The orbital period-radius parameter space occupied by TOI-263b is quite unique, which prompted a further characterization of its true nature. Here, we report radial velocity measurements of TOI-263 obtained with 3 VLT units and the ESPRESSO spectrograph to retrieve the mass of TOI-263b. We find that TOI-263b is a brown dwarf with a mass of 61.6+-4.0 Mj. Additionally, the orbital period of the brown dwarf is found to be synchronized with the rotation period of the host star, and the system is found to be relatively active, possibly revealing a star--brown dwarf interaction. All these findings suggest that the system's formation history might be explained via disc fragmentation and later migration to close-in orbits. If the system is found to be unstable, TOI-263 is an excellent target to test the migration mechanisms before the brown dwarf becomes engulfed by its parent star.

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A nearby transiting rocky exoplanet that is suitable for atmospheric investigation

Spectroscopy of transiting exoplanets can be used to investigate their atmospheric properties and habitability. Combining radial velocity (RV) and transit data provides additional information on exoplanet physical properties. We detect a transiting rocky planet with an orbital period of 1.467 days around the nearby red dwarf star Gliese 486. The planet Gliese 486 b is 2.81 Earth masses and 1.31 Earth radii, with uncertainties of 5%, as determined from RV data and photometric light curves. The host star is at a distance of ~8.1 parsecs, has a J-band magnitude of ~7.2, and is observable from both hemispheres of Earth. On the basis of these properties and the planet's short orbital period and high equilibrium temperature, we show that this terrestrial planet is suitable for emission and transit spectroscopy.

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TOI-519 b: a short-period substellar object around an M dwarf validated using multicolour photometry and phase curve analysis

Context: We report the discovery of TOI-519 b (TIC 218795833), a transiting substellar object (R = 1.07 RJup) orbiting a faint M dwarf (V = 17.35) on a 1.26 d orbit. Brown dwarfs and massive planets orbiting M dwarfs on short-period orbits are rare, but more have already been discovered than expected from planet formation models. TOI-519 is a valuable addition into this group of unlikely systems, and adds towards our understanding of the boundaries of planet formation. Aims: We set out to determine the nature of the Transiting Exoplanet Survey Satellite (TESS ) object of interest TOI-519 b. Methods: Our analysis uses a SPOC-pipeline TESS light curve from Sector 7, multicolour transit photometry observed with MuSCAT2 and MuSCAT, and transit photometry observed with the LCOGT telescopes. We estimate the radius of the transiting object using multicolour transit modelling, and set upper limits for its mass, effective temperature, and Bond albedo using a phase curve model that includes Doppler boosting, ellipsoidal variations, thermal emission, and reflected light components. Results: TOI-519 b is a substellar object with a radius posterior median of 1.07 RJup and 5th and 95th percentiles of 0.66 and 1.20 RJup, respectively, where most of the uncertainty comes from the uncertainty in the stellar radius. The phase curve analysis sets an upper effective temperature limit of 1800 K, an upper Bond albedo limit of 0.49, and a companion mass upper limit of 14 MJup. The companion radius estimate combined with the Teff and mass limits suggests that the companion is more likely a planet than a brown dwarf, but a brown-dwarf scenario is more likely a priori given the lack of known massive planets in 1 day orbits around M dwarfs with Teff < 3800 K, and the existence of some (but few) brown dwarfs.

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An enhanced slope in the transmission spectrum of the hot Jupiter WASP-104b

We present the optical transmission spectrum of the hot Jupiter WASP-104b based on one transit observed by the blue and red channels of the DBSP spectrograph at the Palomar 200-inch telescope and 14 transits observed by the MuSCAT2 four-channel imager at the 1.52 m Telescopio Carlos Sanchez. We also analyse 45 additional K2 transits, after correcting for the flux contamination from a companion star. Together with the transit light curves acquired by DBSP and MuSCAT2, we are able to revise the system parameters and orbital ephemeris, confirming that no transit timing variations exist. Our DBSP and MuSCAT2 combined transmission spectrum reveals an enhanced slope at wavelengths shorter than 630 nm and suggests the presence of a cloud deck at longer wavelengths. While the Bayesian spectral retrieval analyses favour a hazy atmosphere, stellar spot contamination cannot be completely ruled out. Further evidence, from transmission spectroscopy and detailed characterisation of the host star's activity, is required to distinguish the physical origin of the enhanced slope.

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The CARMENES search for exoplanets around M dwarfs. Two planets on the opposite sides of the radius gap transiting the nearby M dwarf LTT 3780

We present the discovery and characterisation of two transiting planets observed by the Transiting Exoplanet Survey Satellite (TESS) orbiting the nearby (d ~ 22 pc), bright (J ~ 9 mag) M3.5 dwarf LTT 3780 (TOI-732). We confirm both planets and their association with LTT 3780 via ground-based photometry and determine their masses using precise radial velocities measured with the CARMENES spectrograph. Precise stellar parameters determined from CARMENES high resolution spectra confirm that LTT 3780 is a mid-M dwarf with an effective temperature of T_eff = 3360 +\- 51 K, a surface gravity of log(g) = 4.81 +/- 0.04 (cgs), and an iron abundance of [Fe/H] = 0.09 +/- 0.16 dex, with an inferred mass of M_star = 0.379 +/- 0.016 M_sun and a radius of R_star = 0.382 +/- 0.012 R_sun. The ultra-short-period planet LTT 3780 b (P_b = 0.77 d) with a radius of 1.35^{+0.06}_{-0.06} R_earth, a mass of 2.34^{+0.24}_{-0.23} M_earth, and a bulk density of 5.24^{+0.94}_{-0.81} g cm^{-3} joins the population of Earth-size planets with rocky, terrestrial composition. The outer planet, LTT 3780 c, with an orbital period of 12.25 d, radius of 2.42^{+0.10}_{-0.10} R_earth, mass of 6.29^{+0.63}_{-0.61} M_earth, and mean density of 2.45^{+0.44}_{-0.37} g cm^{-3} belongs to the population of dense sub-Neptunes. With the two planets located on opposite sides of the radius gap, this planetary system is an excellent target for testing planetary formation, evolution and atmospheric models. In particular, LTT 3780 c is an ideal object for atmospheric studies with the James Webb Space Telescope.

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Discovery of a hot, transiting, Earth-sized planet and a second temperate, non-transiting planet around the M4 dwarf GJ 3473 (TOI-488)

We present the confirmation and characterisation of GJ 3473 b (G 50--16, TOI-488.01), a hot Earth-sized planet orbiting an M4 dwarf star, whose transiting signal ($P=1.1980035\pm0.0000018\mathrm{\,d}$) was first detected by the Transiting Exoplanet Survey Satellite (TESS). Through a joint modelling of follow-up radial velocity observations with CARMENES, IRD, and HARPS together with extensive ground-based photometric follow-up observations with LCOGT, MuSCAT, and MuSCAT2, we determined a precise planetary mass, $M_b = 1.86\pm0.30\,\mathrm{M_\oplus},$ and radius, $R_b = {1.264\pm0.050}\,\mathrm{R_\oplus}$. Additionally, we report the discovery of a second, temperate, non-transiting planet in the system, GJ 3473 c, which has a minimum mass, $M_c \sin{i} = {7.41\pm0.91}\,\mathrm{M_\oplus,}$ and orbital period, $P_c={15.509\pm0.033}\,\mathrm{d}$. The inner planet of the system, GJ 3473 b, is one of the hottest transiting Earth-sized planets known thus far, accompanied by a dynamical mass measurement, which makes it a particularly attractive target for thermal emission spectroscopy.

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Detection of Na in WASP-21b's lower and upper atmosphere

Optical transmission spectroscopy provides crucial constraints on the reference pressure levels and scattering properties for hot Jupiter atmospheres. For certain planets, where alkali atoms are detected in the atmosphere, their line profiles could serve as a good probe to link upper and lower atmospheric layers. WASP-21b is a Saturn-mass hot Jupiter orbiting a thick disc star, with a low density and an equilibrium temperature of 1333 K, which makes it a good target for transmission spectroscopy. Here, we present a low-resolution transmission spectrum for WASP-21b based in one transit observed by the OSIRIS spectrograph at the 10.4 m Gran Telescopio Canarias (GTC), and a high-resolution transmission spectrum based in three transits observed by HARPS-N at Telescopio Nazinale Galileo (TNG) and HARPS at the ESO 3.6 m telescope. We performed spectral retrieval analysis on GTC's low-resolution transmission spectrum and report the detection of Na at a confidence level of $>$3.5-$σ$. The Na line exhibits a broad line profile that can be attributed to pressure broadening, indicating a mostly clear planetary atmosphere. The spectrum shows a tentative excess absorption at the K D$_1$ line. Using HARPS-N and HARPS, we spectrally resolved the Na doublet transmission spectrum. An excess absorption at the Na doublet is detected during the transit, and shows a radial velocity shift consistent with the planet orbital motion. We proposed a metric to quantitatively distinguish hot Jupiters with relatively clear atmospheres from others, and WASP-21b has the largest metric value among all the characterized hot Jupiters. The detection of Na at both lower and upper atmosphere of WASP-21b reveals that it is an ideal target for future follow-up observations, providing the opportunity to understand the nature of its atmosphere across a wide range of pressure levels.

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Obliquity measurement and atmospheric characterization of the WASP-74 planetary system

We present new transit observations of the hot Jupiter WASP-74 b ($T_\mathrm{eq} \sim$ 1860 K) using the high-resolution spectrograph HARPS-N and the multi-colour simultaneous imager MuSCAT2. We refine the orbital properties of the planet and its host star, and measure its obliquity for the first time. The measured sky-projected angle between the stellar spin-axis and the planet's orbital axis is compatible with an orbit well-aligned with the equator of the host star ($λ= 0.77\pm0.99 \mathrm{deg}$). We are not able to detect any absorption feature of H$α$, or any other atomic spectral features, in its high-resolution transmission spectra due to low S/N at the line cores. Despite previous claims regarding the presence of strong optical absorbers such TiO and VO gases in the atmosphere of WASP-74 b, the new ground-based photometry combined with a reanalysis of previously reported observations from the literature shows a slope in the low-resolution transmission spectrum steeper than expected from Rayleigh scattering alone.

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The GTC exoplanet transit spectroscopy survey XI. Possible detection of Rayleigh scattering in the atmosphere of the Saturn-mass planet WASP-69b

One of the main atmospheric features in exoplanet atmospheres, detectable both from ground- and space-based facilities, is Rayleigh scattering. In hydrogen-dominated planetary atmospheres, Rayleigh scattering causes the measured planetary radius to increase toward blue wavelengths in the optical range. We obtained a spectrophotometric time series of one transit of the Saturn-mass planet WASP-69b using the OSIRIS instrument at the Gran Telescopio Canarias. From the data we constructed 19 spectroscopic transit light curves representing 20 nm wide wavelength bins spanning from 515 nm to 905 nm. We derived the transit depth for each curve individually by fitting an analytical model together with a Gaussian process to account for systematic noise in the light curves. We find that the transit depth increases toward bluer wavelengths, indicative of a larger effective planet radius. Our results are consistent with space-based measurements obtained in the near infrared using the Hubble Space Telescope, which show a compatible slope of the transmission spectrum. We discuss the origin of the detected slope and argue between two possible scenarios: a Rayleigh scattering detection originating in the planet's atmosphere or a stellar activity induced signal from the host star.

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Precise mass and radius of a transiting super-Earth planet orbiting the M dwarf TOI-1235: a planet in the radius gap?

We report the confirmation of a transiting planet around the bright, inactive M0.5 V star TOI-1235 (TYC 4384-1735-1, V = 11.5 mag), whose transit signal was detected in the photometric time series of Sectors 14, 20, and 21 of the TESS space mission. We confirm the planetary nature of the transit signal, which has a period of 3.44 d, by using precise radial velocity measurements with CARMENES and HARPS-N spectrographs. A comparison of the properties derived for TOI-1235 b's with theoretical models reveals that the planet has a rocky composition, with a bulk density slightly higher than Earth's. In particular, we measure a mass of M_p = 5.9+/-0.6 M_Earth and a radius of R_p = 1.69+/-0.08 R_Earth, which together result in a density of rho_p = 6.7+1.3-1.1 g/cm3. When compared with other well-characterized exoplanetary systems, the particular combination of planetary radius and mass puts our discovery in the radius gap, a transition region between rocky planets and planets with significant atmospheric envelopes, with few known members. While the exact location of the radius gap for M dwarfs is still a matter of debate, our results constrain it to be located at around 1.7 R_Earth or larger at the insolation levels received by TOI-1235 b (~60 S_Earth), which makes it an extremely interesting object for further studies of planet formation and atmospheric evolution.

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Hot Exoplanet Atmospheres Resolved with Transit Spectroscopy (HEARTS) IV. A spectral inventory of atoms and molecules in the high-resolution transmission spectrum of WASP-121 b

Aims: We survey the transmission spectrum of WASP-121 b for line-absorption by metals and molecules at high spectral resolution, and elaborate on existing interpretations of the optical transmission spectrum observed with HST/STIS and WFC3. Methods: We use the cross-correlation technique and direct differential spectroscopy to search for sodium and other neutral and ionised atoms, TiO, VO and SH in high-resolution transit spectra obtained with the HARPS spectrograph. We inject models assuming chemical and hydrostatic equilibrium with varying temperature and composition to enable model comparison, and employ two bootstrap methods to test the robustness of our detections. Results: We detect neutral Mg, Na, Ca, Cr, Fe, Ni and V, which we predict exists in equilibrium with a significant quantity of VO, supporting earlier observations by HST/WFC3. Non-detections of Ti and TiO support the hypothesis that Ti is depleted via a cold-trap mechanism as has been proposed in the literature. Atomic line depths are under-predicted by hydrostatic models by a factor of 1.5 to 8, confirming recent findings that the atmosphere is extended. We predict the existence of significant concentrations of gas-phase TiO$_2$, VO$_2$ and TiS, which could be important absorbers at optical and NIR wavelengths in hot Jupiter atmospheres, but for which accurate line-list data is currently not available. We find no evidence for absorption by SH, and find that inflated atomic lines can plausibly explain the slope of the transmission spectrum observed in the NUV with HST/STIS. The Na D lines are significantly broadened and show a difference in their respective depths of 15 scale heights, which is not expected from isothermal hydrostatic theory.

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