arXiv subjects

F. Palmero

Publications and source records attributed to F. Palmero.

23 records · Page 2Linked to original sources

arXiv2003

Charge transport in poly(dG)-poly(dC) and poly(dA)-poly(dT) DNA polymers

We investigate the charge transport in synthetic DNA polymers built up from single types of base pairs. In the context of a polaron-like model, for which an electronic tight-binding system and bond vibrations of the double helix are coupled, we present estimates for the electron-vibration coupling strengths utilizing a quantum-chemical procedure. Subsequent studies concerning the mobility of polaron solutions, representing the state of a localized charge in unison with its associated helix deformation, show that the system for poly(dG)-poly(dC) and poly(dA)-poly(dT) DNA polymers, respectively possess quantitatively distinct transport properties. While the former supports unidirectionally moving electron breathers attributed to highly efficient long-range conductivity the breather mobility in the latter case is comparatively restrained inhibiting charge transport. Our results are in agreement with recent experimental results demonstrating that poly(dG)-poly(dC) DNA molecules acts as a semiconducting nanowire and exhibits better conductance than poly(dA)-poly(dT) ones.

nlin.PS↗

arXiv2003

Moving breathers in a bent DNA-related model

We study the properties of moving breathers in a bent DNA-related model with short range interaction, due to the stacking of the base pairs, and long range interaction, due to the finite dipole moment of the bonds within each base pair. We show that the movement of a breather is hindered by the bending of the chain as a particle in a potential barrier. We have also found that the behaviour of moving breathers in an homogeneous bent chain and in a straight chain with a small impurity is qualitatively equivalent.

nlin.PS↗

arXiv2003

Interaction of moving breathers with an impurity

We analyze the influence of an impurity in the evolution of moving discrete breathers in a Klein--Gordon chain with non-weak nonlinearity. Three different behaviours can be observed when moving breathers interact with the impurity: they pass through the impurity continuing their direction of movement; they are reflected by the impurity; they are trapped by the impurity, giving rise to chaotic breathers. Resonance with a breather centred at the impurity site is conjectured to be a necessary condition for the appearance of the trapping phenomenon.

nlin.PS↗

arXiv2002

Breathers in a system with helicity and dipole interaction

Recent papers that have studied variants of the Peyrard-Bishop model for DNA, have taken into account the long range interaction due to the dipole moments of the hydrogen bonds between base pairs. In these models the helicity of the double strand is not considered. In this particular paper we have performed an analysis of the influence of the helicity on the properties of static and moving breathers in a Klein--Gordon chain with dipole-dipole interaction. It has been found that the helicity enlarges the range of existence and stability of static breathers, although this effect is small for a typical helical structure of DNA. However the effect of the orientation of the dipole moments is considerably higher with transcendental consequences for the existence of mobile breathers.

nlin.PS↗

arXiv2002

Moving discrete breathers in a Klein--Gordon chain with an impurity

We analyze the influence of an impurity in the movement of discrete breathers in Klein--Gordon chains. We observe that the moving breather can cross the impurity, can be reflected by it, or can be trapped originating a quasi-periodic breather. We find that resonance with a nonlinear localised mode centred in the impurity is a necessary condition in order to observe the trapping phenomenon, as a difference with the resonance condition with a linear localised mode when this problem is studied within the Nonlinear Schrödinger Equation approximation.

nlin.PS↗