arXiv subjects

F. R. Donnan

Publications and source records attributed to F. R. Donnan.

12 recordsLinked to original sources

arXiv2026

Abundant hydrocarbons in a buried galactic nucleus with signs of carbonaceous grain and polycyclic aromatic hydrocarbon processing

Hydrocarbons play a key role in shaping the chemistry of the interstellar medium (ISM), but their enrichment and relationship with carbonaceous grains and polycyclic aromatic hydrocarbons (PAHs) still lack clear observational constraints. We report JWST NIRSpec+MIRI/MRS infrared (IR; 3-28 micron) observations of the local ultra-luminous IR galaxy (ULIRG) IRAS 07251-0248, revealing the extragalactic detection of small gas-phase hydrocarbons such as benzene (C$_6$H$_6$), triacetylene (C$_6$H$_2$), diacetylene (C$_4$H$_2$), acetylene (C$_2$H$_2$), methane (CH$_4$), and methyl radical (CH$_3$) as well as deep amorphous C-H absorptions in the solid phase. The unexpectedly high abundance of these molecules indicates an extremely rich hydrocarbon chemistry, not explained by high-temperature gas-phase chemistry, ice desorption or oxygen depletion. Instead, the most plausible explanation is the erosion and fragmentation of carbonaceous grains and PAHs. This scenario is supported by the correlation between the abundance of one of their main fragmentation products, C$_2$H$_2$, and cosmic ray (CR) ionization rate for a sample of local ULIRGs. These hydrocarbons are outflowing at $\sim$160 km/s, which may represent a potential formation pathway for hydrogenated amorphous grains. Our results suggest that IRAS 07251-0248 might not be unique but represents an extreme example of the commonly rich hydrocarbon chemistry prevalent in deeply obscured galactic nuclei.

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arXiv2025

The PAH 3.4 micron feature as a tracer of shielding in the Orion Bar and NGC 6240

We have carried out a detailed analysis of the 3.4 micron spectral feature arising from Polycyclic Aromatic Hydrocarbons (PAH), using JWST archival data. For the first time in an external galaxy (NGC 6240), we have identified two distinct spectral components of the PAH 3.4 micron feature: a shorter wavelength component at 3.395 micron, which we attribute to short aliphatic chains tightly attached to the aromatic rings of the PAH molecules; and a longer wavelength feature at 3.405 microns that arises from longer, more fragile, aliphatic chains that are weakly attached to the parent PAH molecule. These longer chains are more easily destroyed by far-ultraviolet photons (>5eV) and PAH thermal emission only occurs where PAH molecules are shielded from more energetic photons by dense molecular gas. We see a very strong correlation in the morphology of the PAH 3.395 micron feature with the PAH 3.3 micron emission, the latter arising from robust aromatic PAH molecules. We also see an equally strong correlation between the PAH 3.405 micron morphology and the warm molecular gas, as traced by H2 vibrational lines. We show that the flux ratio PAH_3.395/PAH_3.405 < 0.3 corresponds strongly to regions where the PAH molecules are shielded by dense molecular gas, so that only modestly energetic UV photons penetrate to excite the PAHs. Our work shows that PAH 3.405 micron and PAH 3.395 micron emission features can provide robust diagnostics of the physical conditions of the interstellar medium in external galaxies, and can be used to quantify the energies of the photon field penetrating molecular clouds.

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arXiv2025

Echo mapping of the black hole accretion flow in NGC 7469

Reverberation mapping (RM) can measure black hole accretion disc sizes and radial structure through observed time lags that should increase with wavelength as $τ\proptoλ^{4/3}$. Our 250-day RM campaign on NGC 7469 combines sub-day cadence 7-band photometry from the Las Cumbres Observatory robotic telescopes and weekly X-ray and UVOT data from Swift. By fitting these light curves, we measure the spectral energy distribution of the variable accretion disc and inter-band lags of just 1.5 days across the UV to the optical range. The disc SED is close to the expected $f_ν\proptoν^{1/3}$, and the lags are consistent with $τ\propto λ^{4/3}$, but three times larger than expected. We consider several possible modifications to standard disc assumptions. First, for a $9\times10^6$ M$_\odot$ black hole and 2 possible spins $a^\star=(0,1)$, we fit the X-ray-UV-optical SED with a compact relativistic corona at height $H_x=(46,27)R_g$ irradiating a flat disc with accretion rate $\dot{m}_{Edd}\sim(0.23,0.24)$ inclined to the line of sight by $i<20^\circ$. To fit the lags as well as the SED, this model requires a low spin $a^\star=0$ and boosts disc color temperatures by a factor $f_{col}=1.8$, which shifts reprocessed light to shorter wavelengths. Our Bowl model with $f_{col}=1$ neglects relativity near the black hole but fits the UV-optical lags and SEDs using a flat disc with $\dot{m}_{Edd}<0.06$ and a steep outer rim at $R_{out}/c\sim5-10$ days with H/R<1%. This rim occurs near the $10^3$K dust sublimation temperature in the disc atmosphere, supporting models that invoke dust opacity to thicken the disc and launch failed radiatively-driven dusty outflows at the inner edge of the broad line region (BLR). Finally, the disc lags and SEDs exhibit a significant excess in the $u$ and $r$ bands, suggesting the Balmer continuum and H$α$ emission, respectively, from the BLR.

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arXiv2025

JWST MIRI reveals the diversity of nuclear mid-infrared spectra of nearby type-2 quasars

Type-2 quasars (QSO2s) are active galactic nuclei (AGN) seen through a significant amount of dust and gas that obscures the central supermassive black hole and the broad line region. Here we present new mid-infrared spectra of the central kiloparsec of five optically-selected QSO2s at redshift z~0.1 obtained with JWST/MIRI/MRS. These QSO2s belong to the QSOFEED sample and they have log Lbol=45.5-46.0 erg/s, global SFRs that place them above the main sequence, and practically identical optical spectral shape and [OIII] luminosity, but their nuclear mid-infrared spectra exhibit an unexpected diversity of both continua and features. They show: 1) 9.7 micron silicate features going from emission (strength of S9.7=0.5) to relatively strong absorption (S9.7=-1.0) and 18 and 23 micron silicates either in emission or flat. In addition, two of the QSO2s show absorption bands of CO, H2O, and aliphatic grains, indicating different levels of nuclear obscuration across the sample. 2) [NeV]/[NeII] ratios ranging from 0.1 to 2.1 and [NeIII]/[NeII] from 1.0 to 3.5, indicating different coronal line and ionizing continuum strengths. 3) Warm molecular gas masses of 1-4x10^7 Msun and warm-to-cold gas mass ratios of 1-2%, with molecular gas excitation likely due to jet-induced shocks in J1430+1339, and to UV heating and/or turbulence in J1509+0434. 4) PAH emission features with equivalent widths ranging from <0.002 to 0.075 micron, from which we measure a larger contribution from neutral molecules (PAH 11.3/6.2=1.3-3.4) and SFRs<3-7 Msun/yr. This unprecedented dataset allowed us to start exploring the role of various AGN and galaxy properties including ionizing continuum, obscuration, electron density, and jet-ISM interactions on some of the spectral differences listed above, but larger samples are now required to fully understand the diversity of QSO2s' nuclear mid-infrared spectra.

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arXiv2025

On unveiling Buried Nuclei with JWST: a technique for hunting the most obscured galaxy nuclei from local to high redshift

We analyze JWST NIRSpec+MIRI/MRS observations of the infrared (IR) Polycyclic Aromatic Hydrocarbon (PAH) features in the central regions ($\sim$0.26'' at 6 micron; $\sim$50-440 pc depending on the source) of local luminous IR galaxies. In this work, we examine the effect of nuclear obscuration on the PAH features of deeply obscured nuclei, predominantly found in local luminous IR galaxies, and we compare these nuclei with ``normal'' star-forming regions. We extend previous work to include shorter wavelength PAH ratios now available with the NIRSpec+MIRI/MRS spectral range. We introduce a new diagnostic diagram for selecting deeply obscured nuclei based on the 3.3 and 6.2 micron PAH features and/or mid-IR continuum ratios at $\sim$3 and 5 micron. We find that the PAH equivalent width (EW) ratio of the brightest PAH features at shorter wavelengths (at 3.3 and 6.2 micron) is impacted by nuclear obscuration. Although the sample of luminous IR galaxies used in this analysis is relatively small, we find that sources exhibiting a high silicate absorption feature cluster tightly in a specific region of the diagram, whereas star-forming regions experiencing lower extinction levels occupy a different area in the diagram. This demonstrates the potential of this technique to identify buried nuclei. To leverage the excellent sensitivity of the MIRI imager onboard JWST, we extend our method of identifying deeply obscured nuclei at higher redshifts using a selection of MIRI filters. Specifically, the combination of various MIRI JWST filters enables the identification of buried sources beyond the local Universe and up to z$\sim$3, where other commonly used obscuration tracers such as the 9.7 micron silicate band, are out of the spectral range of MRS. Our results pave the way for identifying distant deeply obscured nuclei with JWST.

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arXiv2024

The Galaxy Activity, Torus, and Outflow Survey (GATOS). V: Unveiling PAH survival and resilience in the circumnuclear regions of AGN with JWST

We analyze JWST MIRI/MRS observations of the infrared PAH bands in the nuclear and circumnuclear regions of local AGN from the GATOS Survey. In this work, we examine the PAH properties in the circumnuclear regions of AGN and AGN-outflows, and compare them to those in star-forming regions and the innermost regions of AGN. This study employs 4.9-28.1 micron sub-arcsecond angular resolution data to investigate the properties of PAH in three nearby sources (DL~30-40 Mpc). Our findings align with previous JWST studies, showing that the central regions of AGN show a larger fraction of neutral PAH molecules (i.e. elevated 11.3/6.2 and 11.3/7.7 PAH ratios) compared to star-forming galaxies. We find that the AGN might affect not only the PAH population in the innermost region but also in the extended regions up to ~kpc scales. By comparing our observations to PAH diagnostic diagrams, we find that, in general, regions located in the projected direction of the AGN-outflow occupy similar positions on the PAH diagnostic diagrams as those of the innermost regions of AGN. Star-forming regions that are not affected by the AGN in these galaxies share the same part of the diagram as Star-forming galaxies. We examine the potential of the PAH-H2 diagram to disentangle AGN versus star-forming activity. Our results suggest that in Sy-like AGN, illumination and feedback from the AGN might affect the PAH population at nuclear and kpc scales, in particular, the ionization state of the PAH grains. However, PAH sizes are rather similar. The carriers of the ionized PAH bands (6.2 and 7.7 micron) are less resilience than those of neutral PAH bands (11.3 micron), which might be particularly important for strongly AGN-host coupled systems. Therefore, caution must be applied when using PAH bands as star-formation rate indicators in these systems even at kpc scales, with the ionized ones being more affected by the AGN.

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arXiv2024

Peeling Back the Layers of Extinction of Dusty Galaxies in the Era of JWST: Modelling Joint NIRSpec + MIRI Spectra at rest-frame 1.5-28 $μ$m

We present an analysis of the combined NIRSpec and MIRI spectra of dusty galaxies between 1.5 - 28 $μ$m restframe by implementing a differential extinction model, where the strength of extinction varies across the spectrum as different layers of the obscuring dust are probed. Our model is able to recover a 2D distribution of dust temperature and extinction which allows inference of the physical nature of the dust in these environments. We show that differential extinction is necessary to reproduce the spectra of 4 highly obscured Luminous Infrared Galaxies observed with NIRSpec IFU and MIRI MRS, where simple screen or uniformly mixed dust distributions fail to fit the data. We additionally compare the extinction of HII regions in these galaxies via hydrogen recombination lines, the extinction of molecular gas via the H$_2$ lines, Polycyclic Aromatic Hydrocarbons via the 12.7/11.3 PAH ratio and the stellar continuum. We find that the molecular gas is deeply buried with the HII regions in star-forming regions, with a similar extinction to the hottest dust components. However we find the cooler dust to be less obscured, at a similar extinction to the stellar continuum and PAHs. The nuclei show a complex dust distribution with VV114 NE, NGC 3256 S, IIZw96 SW showing a deeply buried continuum source relative to the molecular gas/HII regions. Additionally, NGC 3256 S, NGC 7469 and VV114 SW show an isolated hot dust component, indicative of AGN heating, where NGC 3256 S and NGC 7469 are previously known AGN.

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arXiv2024

Structures Of Dust and gAs (SODA): Constraining the innermost dust properties of II Zw96 with JWST observations of H$_2$O and CO

We analyze JWST NIRSpec$+$MIRI/MRS observations of the infrared (IR) gas-phase molecular bands of the most enshrouded source (D1) within the interacting system and luminous IR galaxy II Zw 096. We report the detection of rovibrational lines of H$_2$O $ν_2$=1-0 ($\sim$5.3-7.2 $μ$m) and $^{12}$CO $ν$=1-0 ($\sim$4.45-4.95 $μ$m) in D1. The CO band shows the R- and P-branches in emission and the spectrum of the H$_2$O band shows the P-branch in emission and the R-branch in absorption. The H$_2$O R-branch in absorption unveils an IR-bright embedded compact source in D1 and the CO broad component features a highly turbulent environment. From both bands, we also identified extended intense star-forming (SF) activity associated with circumnuclear photodissociation regions (PDRs), consistent with the strong emission of the ionised 7.7 $μ$m polycyclic aromatic hydrocarbon band in this source. By including the 4.5-7.0 $μ$m continuum information derived from the H$_2$O and CO analysis, we modelled the IR emission of D1 with a dusty torus and SF component. The torus is very compact (diameter of $\sim$3 pc at 5 $μ$m) and characterised by warm dust ($\sim$ 370 K), giving an IR surface brightness of $\sim$3.6$\times$10$^{8}$ L$_{\rm sun}$/pc$^2$. This result suggests the presence of a dust-obscured active galactic nucleus (AGN) in D1, which has an exceptionally high covering factor that prevents the direct detection of AGN emission. Our results open a new way to investigate the physical conditions of inner dusty tori via modelling the observed IR molecular bands.

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arXiv2023

The Galaxy Activity, Torus, and Outflow Survey (GATOS). III: Revealing the inner icy structure in local AGN

We use JWST/MIRI MRS spectroscopy of a sample of six local obscured type 1.9/2 active galactic nuclei (AGN) to compare their nuclear mid-IR absorption bands with the level of nuclear obscuration traced by X-rays. This study is the first to use sub-arcsecond angular resolution data of local obscured AGN to investigate the nuclear mid-IR absorption bands with a wide wavelength coverage (4.9-28.1 $μ$m). All the nuclei show the 9.7 $μ$m silicate band in absorption. We compare the strength of the 9.7 and 18 $μ$m silicate features with torus model predictions. The observed silicate features are generally well explained by clumpy and smooth torus models. We report the detection of the 6 $μ$m dirty water ice band (i.e., a mix of water and other molecules such as CO and CO$_2$) at sub-arcsecond scales ($\sim$0.26 arcsec at 6 $μ$m; inner $\sim$50 pc) in a sample of local AGN with different levels of nuclear obscuration in the range log N$_{\rm H}^{\rm X-Ray}$(cm$^{-2}$)$\sim22-25$. We find a good correlation between the 6 $μ$m water ice optical depths and N$_{\rm H}^{\rm X-Ray}$. This result indicates that the water ice absorption might be a reliable tracer of the nuclear intrinsic obscuration in AGN. The weak water ice absorption in less obscured AGN (log N$_H^{X-ray}$ (cm$^{-2}$)$\lesssim$23.0 cm$^{-2}$) might be related to the hotter dust temperature ($>$T$_{sub}^{H_2O}\sim$110 K) expected to be reached in the outer layers of the torus due to their more inhomogeneous medium. Our results suggest it might be necessary to include the molecular content, such as, H$_2$O, aliphatic hydrocarbons (CH-) and more complex PAH molecules in torus models to better constrain key parameters such as the torus covering factor (i.e. nuclear obscuration).

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arXiv2022

The Obscured Nucleus and Shocked Environment of VV 114E Revealed by JWST/MIRI Spectroscopy

Compact Obscured Nuclei (CONs) potentially hide extreme supermassive black hole (SMBH) growth behind large column densities of gas/dust. We present a spectroscopic analysis of the heavily obscured nucleus and the surrounding environment of the eastern region of the nearby ($z = 0.02007$) interacting galaxy VV 114 with the JWST Mid-InfraRed Instrument (MIRI). We model the spectrum from 4.9 - 28 $μ$m to extract Polycyclic Aromatic Hydrocarbon (PAH) emission and the underlying obscured continuum. We find that the NE nucleus (A) is highly obscured where the low PAH equivalent width (EW) ratio, EW(12.7)/EW(11.3), reveals a dust enshrouded continuum source. This is confirmed by decomposing the continuum into nuclear and star-forming where the nuclear component is found to be typical of CONs. The 11.3/6.2 PAH flux ratio is consistent with originating in star-forming regions rather than typical AGN. The second nucleus (B) is much less obscured, with PAH flux ratios also typical of star-forming regions. We do not detect any high ionisation lines such as [Ne V] or [Ne VI] which suggests that if an AGN is present it must be highly obscured. Additionally, we detect a shock front south of the secondary nucleus (B) in the [Fe II] (5.34 $μ$m) line and in warm molecular hydrogen. The 6.2 PAH emission does not spatially coincide with the low-J transitions of H$_2$ but rather appears strong at the shock front which may suggest destruction of the ionised PAHs in the post-shock gas behind the shock front.

astro-ph.GA↗

arXiv2022

A Detailed Look at the Most Obscured Galactic Nuclei in the Mid-Infrared

Context. Compact Obscured Nuclei (CONs) are an extreme phase of galaxy evolution where rapid supermassive black hole growth and$/$or compact star-forming activity is completely obscured by gas and dust. Aims. We investigate the properties of CONs in the mid-infrared and explore techniques aimed at identifying these objects such as through the equivalent width (EW) ratios of their Polycyclic Aromatic Hydrocarbon (PAH) features. Methods. We model Spitzer spectra by decomposing the continua into nuclear and star-forming components from which we then measure the nuclear optical depth, $τ_N$, of the $9.8 μ$m silicate absorption feature. We also use Spitzer spectral maps to investigate how PAH EW ratios vary with aperture size for objects hosting CONs. Results. We find that the nuclear optical depth, $τ_N$, strongly correlates with the HCN-vib emission line in the millimetre for CONs with a Pearson correlation coefficient of 0.91. We find the PAH EW ratios technique to be effective at selecting CONs and robust against highly inclined galaxies where strong dust lanes may mimic a CON like spectrum by producing a high $τ_N$. Our analysis of the Spitzer spectral maps showed that the efficacy of the PAH EW ratios to isolate CONs is reduced when there is a strong star-forming component from the host galaxy. In addition, we find that the use of the inferred nuclear optical depth is a reliable method to identify CONs in $36^{+8}_{-7}\%$ of ULIRGs and $17^{+3}_{-3}\%$ of LIRGs, consistent with previous work. Conclusions. We confirm mid-IR spectra to be a powerful diagnostic of CONs where the increased sensitivity of JWST will allow identification of CONs at cosmic noon revealing this extreme but hidden phase of galaxy evolution.

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arXiv2022

A high angular resolution view of the PAH emission in Seyfert galaxies using JWST/MRS data

Polycyclic Aromatic Hydrocarbons (PAHs) are carbon-based molecules that are ubiquitous in a variety of astrophysical objects and environments. In this work, we use JWST/MIRI MRS spectroscopy of three Seyferts to compare their nuclear PAH emission with that of star-forming regions. This study represents the first of its kind using sub-arcsecond angular resolution data of local luminous Seyferts (Lbol>10^44.46 erg/s) on a wide wavelength coverage (4.9-28.1 micron). We present an analysis of their nuclear PAH properties by comparing the observed ratios with PAH diagnostic model grids, derived from theoretical spectra. Our results show that a suite of PAH features is present in the innermost parts (~0.45 arcsec at 12 micron; in the inner ~142-245 pc) of luminous Seyfert galaxies. We find that the nuclear regions of AGN lie at different positions of the PAH diagnostic diagrams, whereas the SF regions are concentrated around the average values of SF galaxies. In particular, we find that the nuclear PAH emission mainly originates in neutral PAHs. In contrast, PAH emission originating in the SF regions favours ionised PAH grains. The observed PAH ratios in the nuclear region of AGN-dominated galaxy NGC 6552 indicate the presence of larger-sized PAH molecules compared with those of the SF regions. Therefore, our results provide evidence that the AGN have a significant impact on the ionization state (and probably the size) of the PAH grains on scales of ~142-245 pc.

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