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F. Schüth

Publications and source records attributed to F. Schüth.

2 recordsLinked to original sources

Fingerprinting the magnetic behavior of antiferromagnetic nanostructures using remanent magnetization curves

Antiferromagnetic (AF) nanostructures from Co3O4, CoO and Cr2O3 were prepared by the nanocasting method and were characterized magnetometrically. The field and temperature dependent magnetization data suggests that the nanostructures consist of a core-shell structure. The core behaves as a regular antiferromagnet and the shell as a two-dimensional diluted antiferromagnet in a field (2d DAFF) as previously shown on Co3O4 nanowires [Benitez et al., Phys. Rev. Lett. 101, 097206 (2008)]. Here we present a more general picture on three different material systems, i.e. Co3O4, CoO and Cr2O3. In particular we consider the thermoremanent (TRM) and the isothermoremanent (IRM) magnetization curves as "fingerprints" in order to identify the irreversible magnetization contribution originating from the shells. The TRM/IRM fingerprints are compared to those of superparamagnetic systems, superspin glasses and 3d DAFFs. We demonstrate that TRM/IRM vs. H plots are generally useful fingerprints to identify irreversible magnetization contributions encountered in particular in nanomagnets.

cond-mat.mes-hall

Zeolite-dye micro lasers

We present a new class of micro lasers based on nanoporous molecular sieve host-guest systems. Organic dye guest molecules of 1-Ethyl-4-(4-(p-Dimethylaminophenyl)-1,3-butadienyl)-pyridinium Perchlorat were inserted into the 0.73-nm-wide channel pores of a zeolite AlPO$_4$-5 host. The zeolitic micro crystal compounds where hydrothermally synthesized according to a particular host-guest chemical process. The dye molecules are found not only to be aligned along the host channel axis, but to be oriented as well. Single mode laser emission at 687 nm was obtained from a whispering gallery mode oscillating in a 8-$μ$m-diameter monolithic micro resonator, in which the field is confined by total internal reflection at the natural hexagonal boundaries inside the zeolitic microcrystals.

physics.optics