arXiv subjects

F. Selsis

Publications and source records attributed to F. Selsis.

At least 19 recordsLinked to original sources

arXiv2023

ATMOSPHERIX: I- An open source high resolution transmission spectroscopy pipeline for exoplanets atmospheres with SPIRou

Atmospheric characterisation of exoplanets from the ground is an actively growing field of research. In this context we have created the ATMOSPHERIX consortium: a research project aimed at characterizing exoplanets atmospheres using ground-based high resolution spectroscopy. This paper presents the publicly-available data analysis pipeline and demonstrates the robustness of the recovered planetary parameters from synthetic data. Simulating planetary transits using synthetic transmission spectra of a hot Jupiter that were injected into real SPIRou observations of the non-transiting system Gl 15 A, we show that our pipeline is successful at recovering the planetary signal and input atmospheric parameters. We also introduce a deep learning algorithm to optimise data reduction which proves to be a reliable, alternative tool to the commonly used principal component analysis. We estimate the level of uncertainties and possible biases when retrieving parameters such as temperature and composition and hence the level of confidence in the case of retrieval from real data. Finally, we apply our pipeline onto two real transits of HD~189733 b observed with SPIRou and obtain similar results than in the literature. In summary, we have developed a publicly available and robust pipeline for the forthcoming studies of the targets to be observed in the framework of the ATMOSPHERIX consortium, which can easily be adapted to other high resolution instruments than SPIRou (e.g. VLT-CRIRES, MAROON-X, ELT-ANDES)

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arXiv2023

ATMOSPHERIX: II- Characterising exoplanet atmospheres through transmission spectroscopy with SPIRou

In a companion paper, we introduced a publicly-available pipeline to characterise exoplanet atmospheres through high-resolution spectroscopy. In this paper, we use this pipeline to study the biases and degeneracies that arise in atmospheric characterisation of exoplanets in near-infrared ground-based transmission spectroscopy. We inject synthetic planetary transits into sequences of SPIRou spectra of the well known M dwarf star Gl 15 A, and study the effects of different assumptions on the retrieval. We focus on (i) mass and radius uncertainties, (ii) non isothermal vertical profiles and (iii) identification and retrieval of multiple species. We show that the uncertainties on mass and radius should be accounted for in retrievals and that depth-dependent temperature information can be derived from high-resolution transmission spectroscopy data. Finally, we discuss the impact of selecting wavelength orders in the retrieval and the issues that arise when trying to identify a single species in a multi-species atmospheric model. This analysis allows us to understand better the results obtained through transmission spectroscopy and their limitations in preparation to the analysis of actual SPIRou data.

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arXiv2020

TRAPPIST-1: Global Results of the Spitzer Exploration Science Program {\it Red Worlds}

With more than 1000 hours of observation from Feb 2016 to Oct 2019, the Spitzer Exploration Program Red Worlds (ID: 13067, 13175 and 14223) exclusively targeted TRAPPIST-1, a nearby (12pc) ultracool dwarf star orbited by seven transiting Earth-sized planets, all well-suited for a detailed atmospheric characterization with the upcoming JWST. In this paper, we present the global results of the project. We analyzed 88 new transits and combined them with 100 previously analyzed transits, for a total of 188 transits observed at 3.6 or 4.5 $μ$m. We also analyzed 29 occultations (secondary eclipses) of planet b and eight occultations of planet c observed at 4.5 $μ$m to constrain the brightness temperatures of their daysides. We identify several orphan transit-like structures in our Spitzer photometry, but all of them are of low significance. We do not confirm any new transiting planets. We estimate for TRAPPIST-1 transit depth measurements mean noise floors of $\sim$35 and 25 ppm in channels 1 and 2 of Spitzer/IRAC, respectively. most of this noise floor is of instrumental origins and due to the large inter-pixel inhomogeneity of IRAC InSb arrays, and that the much better interpixel homogeneity of JWST instruments should result in noise floors as low as 10ppm, which is low enough to enable the atmospheric characterization of the planets by transit transmission spectroscopy. We construct updated broadband transmission spectra for all seven planets which show consistent transit depths between the two Spitzer channels. We identify and model five distinct high energy flares in the whole dataset, and discuss our results in the context of habitability. Finally, we fail to detect occultation signals of planets b and c at 4.5 $μ$m, and can only set 3$σ$ upper limits on their dayside brightness temperatures (611K for b 586K for c).

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arXiv2018

Space-based infrared interferometry to study exoplanetary atmospheres

The quest for other habitable worlds and the search for life among them are major goals of modern astronomy. One way to make progress towards these goals is to obtain high-quality spectra of a large number of exoplanets over a broad range of wavelengths. While concepts currently investigated in the United States are focused on visible/NIR wavelengths, where the planets are probed in reflected light, a compelling alternative to characterize planetary atmospheres is the mid-infrared waveband (5-20~$μ$m). Indeed, mid-infrared observations provide key information on the presence of an atmosphere, the surface conditions (e.g., temperature, pressure, habitability), and the atmospheric composition in important species such as H$_2$O, CO$_2$, O$_3$, CH$_4$, and N$_2$O. This information is essential to investigate the potential habitability of exoplanets and to make progress towards the search for life in the universe. Obtaining high-quality mid-infrared spectra of exoplanets from the ground is however extremely challenging due to the overwhelming brightness and turbulence of Earth's atmosphere. In this paper, we present a concept of space-based mid-infrared interferometer that can tackle this observing challenge and discuss the main technological developments required to launch such a sophisticated instrument.

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arXiv2018

The 0.8-4.5$μ$m broadband transmission spectra of TRAPPIST-1 planets

The TRAPPIST-1 planetary system represents an exceptional opportunity for the atmospheric characterization of temperate terrestrial exoplanets with the upcoming James Webb Space Telescope (JWST). Assessing the potential impact of stellar contamination on the planets' transit transmission spectra is an essential precursor step to this characterization. Planetary transits themselves can be used to scan the stellar photosphere and to constrain its heterogeneity through transit depth variations in time and wavelength. In this context, we present our analysis of 169 transits observed in the optical from space with K2 and from the ground with the SPECULOOS and Liverpool telescopes. Combining our measured transit depths with literature results gathered in the mid/near-IR with Spitzer/IRAC and HST/WFC3, we construct the broadband transmission spectra of the TRAPPIST-1 planets over the 0.8-4.5 $μ$m spectral range. While planets b, d, and f spectra show some structures at the 200-300ppm level, the four others are globally flat. Even if we cannot discard their instrumental origins, two scenarios seem to be favored by the data: a stellar photosphere dominated by a few high-latitude giant (cold) spots, or, alternatively, by a few small and hot (3500-4000K) faculae. In both cases, the stellar contamination of the transit transmission spectra is expected to be less dramatic than predicted in recent papers. Nevertheless, based on our results, stellar contamination can still be of comparable or greater order than planetary atmospheric signals at certain wavelengths. Understanding and correcting the effects of stellar heterogeneity therefore appears essential to prepare the exploration of TRAPPIST-1's with JWST.

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arXiv2018

The contribution of the ARIEL space mission to the study of planetary formation

The study of extrasolar planets and of the Solar System provides complementary pieces of the mosaic represented by the process of planetary formation. Exoplanets are essential to fully grasp the huge diversity of outcomes that planetary formation and the subsequent evolution of the planetary systems can produce. The orbital and basic physical data we currently possess for the bulk of the exoplanetary population, however, do not provide enough information to break the intrinsic degeneracy of their histories, as different evolutionary tracks can result in the same final configurations. The lessons learned from the Solar System indicate us that the solution to this problem lies in the information contained in the composition of planets. The goal of the Atmospheric Remote-Sensing Infrared Exoplanet Large-survey (ARIEL), one of the three candidates as ESA M4 space mission, is to observe a large and diversified population of transiting planets around a range of host star types to collect information on their atmospheric composition. ARIEL will focus on warm and hot planets to take advantage of their well-mixed atmospheres, which should show minimal condensation and sequestration of high-Z materials and thus reveal their bulk composition across all main cosmochemical elements. In this work we will review the most outstanding open questions concerning the way planets form and the mechanisms that contribute to create habitable environments that the compositional information gathered by ARIEL will allow to tackle

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arXiv2018

Atmospheric reconnaissance of the habitable-zone Earth-sized planets orbiting TRAPPIST-1

Seven temperate Earth-sized exoplanets readily amenable for atmospheric studies transit the nearby ultracool dwarf star TRAPPIST-1 (refs 1,2). Their atmospheric regime is unknown and could range from extended primordial hydrogen-dominated to depleted atmospheres (refs 3-6). Hydrogen in particular is a powerful greenhouse gas that may prevent the habitability of inner planets while enabling the habitability of outer ones (refs 6-8). An atmosphere largely dominated by hydrogen, if cloud-free, should yield prominent spectroscopic signatures in the near-infrared detectable during transits. Observations of the innermost planets have ruled out such signatures (ref 9). However, the outermost planets are more likely to have sustained such a Neptune-like atmosphere (refs 10,11). Here, we report observations for the four planets within or near the system's habitable zone, the circumstellar region where liquid water could exist on a planetary surface (refs 12-14). These planets do not exhibit prominent spectroscopic signatures at near-infrared wavelengths either, which rules out cloud-free hydrogen-dominated atmospheres for TRAPPIST-1 d, e and f, with significance of 8, 6 and 4 sigma, respectively. Such an atmosphere is instead not excluded for planet g. As high-altitude clouds and hazes are not expected in hydrogen-dominated atmospheres around planets with such insolation (refs 15,16), these observations further support their terrestrial and potentially habitable nature.

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arXiv2016

Measuring stellar granulation during planet transits

Stellar activity and convection-related surface structures might cause bias in planet detection and characterization that use these transits. Surface convection simulations help to quantify the granulation signal. We used realistic three-dimensional radiative hydrodynamical simulations from the Stagger grid and synthetic images computed with the radiative transfer code Optim3D to model the transits of three prototype planets: a hot Jupiter, a hot Neptune, and a terrestrial planet. We computed intensity maps from RHD simulations of the Sun and a K-dwarf star at different wavelength bands from optical to far-infrared. We modeled the transit using synthetic stellar-disk images and emulated the temporal variation of the granulation intensity. We identified two types of granulation noise that act simultaneously during the planet transit: (i) the intrinsic change in the granulation pattern with timescales smaller than the usual planet transit, and (ii) the fact that the transiting planet occults isolated regions of the photosphere that differ in local surface brightness. Our modeling approach shows that the granulation pattern has a non-negligible effect on the light curve depth during the transit, and, consequentially on the determination of the radius of the planet transiting. The granulation noise appears to be correlated among the different wavelength ranges either in the visible or in the infrared regions. The granulation has to be considered as an intrinsic uncertainty (as a result of stellar variability) on the precise measurements of exoplanet transits of planets. The full characterization of the granulation is essential for determining the degree of uncertainty on the planet parameters. In this context, the use of 3D RHD simulations is important to measure the convection-related fluctuations.

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arXiv2016

Inferring asymmetric limb cloudiness on exoplanets from transit light curves

Clouds have been shown to be present in many exoplanetary atmospheres. Cloud formation modeling predicts considerable inhomogeneities of cloud cover, consistent with optical phase curve observations. However, optical phase curves cannot resolve some existing degeneracies between cloud location and cloud optical properties. We present a conceptually simple technique to detect inhomogeneous cloud cover on exoplanets. Such an inhomogeneous cloud cover produces an asymmetric primary transit of the planet in front of the host star. Asymmetric transits produce characteristic residuals compared to a standard symmetric model. Furthermore, bisector spans can be used to determine asymmetries in the transit light curve. We apply a model of asymmetric transits to the light curves of HAT-P-7b, Kepler-7b and HD209458b and search for possible cloud signatures. The nearly uninterrupted Kepler photometry is particularly well-suited for this method since it allows for a very high time resolution. We do not find any statistically sound cloud signature in the data of the considered planets. For HAT-P-7b, a tentative detection of an asymmetric cloud cover is found, consistent with analysis of the optical phase curve. Based on Bayesian probability arguments, a symmetric model with an offset in the transit ephemeris remains, however, the most viable model. Still, this work demonstrates that for suitable targets, namely low-gravity planets around bright stars, the method can be used to constrain cloud cover characteristics and is thus a helpful additional tool to study exoplanetary atmospheres.

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arXiv2015

Inferring heat recirculation and albedo for exoplanetary atmospheres: Comparing optical phase curves and secondary eclipse data

Basic atmospheric properties such as albedo and heat redistribution between day and nightside have been inferred for a number of planets using observations of secondary eclipses and thermal phase curves. Optical phase curves have not yet been used to constrain these atmospheric properties consistently. We re-model previously published phase curves of CoRoT-1b, TrES-2b and HAT-P-7b and infer albedos and recirculation efficiencies. These are then compared to previous estimates based on secondary eclipse data. We use a physically consistent model to construct optical phase curves. This model takes Lambertian reflection, thermal emission, ellipsoidal variations and Doppler boosting into account. CoRoT-1b shows a non-negligible scattering albedo (0.11<AS<0.3 at 95% confidence) as well as small day-night temperature contrasts, indicative of moderate to high re-distribution of energy between dayside and nightside. These values are contrary to previous secondary eclipse and phase curve analyses. In the case of HAT-P-7b, model results suggest relatively high scattering albedo (AS=0.3). This confirms previous phase curve analysis, however, it is in slight contradiction to values inferred from secondary eclipse data. For TrES-2b, both approaches yield very similar estimates of albedo and heat recirculation. Discrepancies between recirculation and albedo values as inferred from secondary eclipse and optical phase curve analyses might be interpreted as a hint that optical and IR observations probe different atmospheric layers, and hence temperatures.

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arXiv2015

Effect of O3 on the atmospheric temperature structure of early Mars

Ozone is an important radiative trace gas in the Earth's atmosphere. The presence of ozone can significantly influence the thermal structure of an atmosphere, and by this e.g. cloud formation. Photochemical studies suggest that ozone can form in carbon dioxide-rich atmospheres. We investigate the effect of ozone on the temperature structure of simulated early Martian atmospheres. With a 1D radiative-convective model, we calculate temperature-pressure profiles for a 1 bar carbon dioxide atmosphere. Ozone profiles are fixed, parameterized profiles. We vary the location of the ozone layer maximum and the concentration at this maximum. The maximum is placed at different pressure levels in the upper and middle atmosphere (1-10 mbar). Results suggest that the impact of ozone on surface temperatures is relatively small. However, the planetary albedo significantly decreases at large ozone concentrations. Throughout the middle and upper atmospheres, temperatures increase upon introducing ozone due to strong UV absorption. This heating of the middle atmosphere strongly reduces the zone of carbon dioxide condensation, hence the potential formation of carbon dioxide clouds. For high ozone concentrations, the formation of carbon dioxide clouds is inhibited in the entire atmosphere. In addition, due to the heating of the middle atmosphere, the cold trap is located at increasingly higher pressures when increasing ozone. This leads to wetter stratospheres hence might increase water loss rates on early Mars. However, increased stratospheric H2O would lead to more HOx, which could efficiently destroy ozone. This result emphasizes the need for consistent climate-chemistry calculations to assess the feedback between temperature structure, water content and ozone chemistry. Furthermore, convection is inhibited at high ozone amounts, leading to a stably stratified atmosphere.

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arXiv2013

The puzzling chemical composition of GJ 436b's atmosphere: influence of tidal heating on the chemistry

The dissipation of the tidal energy deposited on eccentric planets may induce a heating of the planet that affects its atmospheric thermal structure. Here we study the influence of tidal heating on the atmospheric composition of the eccentric (e = 0.16) "hot Neptune" GJ 436b, for which inconclusive chemical abundances are retrieved from multiwavelength photometric observations carried out during primary transit and secondary eclipse. We build up a one-dimensional model of GJ 436b's atmosphere in the vertical direction and compute the pressure-temperature and molecular abundances profiles for various plausible internal temperatures of the planet (up to 560 K) and metallicities (from solar to 100 times solar), using a radiative-convective model and a chemical model which includes thermochemical kinetics, vertical mixing, and photochemistry. We find that the CO/CH4 abundance ratio increases with metallicity and tidal heating, and ranges from 1/20 to 1000 within the ranges of metallicity and internal temperature explored. Water vapour locks most of the oxygen and reaches a very high abundance, whatever the metallicity and internal temperature of the planet. The CO2/H2O abundance ratio increases dramatically with metallicity, and takes values between 1e-5-1e-4 with solar elemental abundances and 0.1 for a metallicity 100 times solar. None of the atmospheric models based on solid physical and chemical grounds provide a fully satisfactory agreement with available observational data, although the comparison of calculated spectra and observations seem to point to models with a high metallicity and efficient tidal heating, in which high CO/CH4 abundance ratios and warm temperatures in the dayside atmosphere are favoured.

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arXiv2013

First submillimeter observation of CO in the stratosphere of Uranus

Context. Carbon monoxide (CO) has been detected in all Giant Planets and its origin is both internal and external in Jupiter and Neptune. Despite its first detection in Uranus a decade ago, the magnitude of its internal and external sources remains unconstrained. Aims. We targeted CO lines in Uranus in the submillimeter range to constrain its origin. Methods. We recorded disk-averaged spectra of Uranus with a very high spectral resolution at the frequencies of CO rotational lines in the submillimeter range in 2011-2012. We used empirical and diffusion models of the atmosphere of Uranus to constrain the origin of CO. We also used a thermochemical model of its troposphere to derive an upper limit on the O/H ratio in the deep atmosphere of Uranus. Results. We have detected the CO(8-7) rotational line for the first time, with Herschel-HIFI. Both empirical and diffusion model results show that CO has an external origin. An empirical profile in which CO is constant above the 100mbar level with a mole fraction of 7.1-9.0E-9 (depending on the adopted stratospheric thermal structure) reproduces the data. Sporadic and steady source models cannot be differentiated with our data. Taking Teanby & Irwin's internal source model upper limit of a mole fraction of 2.1E-9 [Teanby & Irwin 2013. ApJ, 775, L49], the deep O/H ratio of Uranus is lower than 500 times solar according to our thermochemical computations. Conclusions. Our work shows that the average mole fraction of CO decreases from the stratosphere to the troposphere and thus strongly advocates for an external source of CO in Uranus. Photochemical modeling of oxygen species in the atmosphere of Uranus and more sensitive observations are needed to reveal the nature of the external source.

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arXiv2013

The dependence of the ice-albedo feedback on atmospheric properties

The ice-albedo feedback is a potentially important de-stabilizing effect for the climate of terrestrial planets. It is based on the positive feedback between decreasing surface temperatures, an increase of snow and ice cover and an associated increase in planetary albedo, which then further decreases surface temperature. A recent study shows that for M stars, the strength of the ice-albedo feedback is reduced This study investigates the influence of the atmosphere (in terms of surface pressure and atmospheric composition) for this feedback. A plane-parallel radiative transfer model is used for the calculation of planetary albedos. We varied CO2 partial pressures as well as the H2O, CH4, and O3 content in the atmosphere for planets orbiting Sun-like and M-type stars. Results suggest that for planets around M stars, the ice-albedo effect is significantly reduced, compared to planets around Sun-like stars. Including the effects of an atmosphere further suppresses the sensitivity to the ice-albedo effect. Atmospheric key properties such as surface pressure, but also the abundance of radiative trace gases can considerably change the strength of the ice-albedo feedback. For dense CO2 atmospheres of the order of a few to tens of bar, atmospheric rather than surface properties begin to dominate the planetary radiation budget. At high CO2 pressures, the ice-albedo feedback is strongly reduced for planets around M stars. The presence of trace amounts of H2O and CH4 in the atmosphere also weakens the ice-albedo effect for both stellar types considered. For planets around Sun-like stars, O3 could also lead to a very strong decrease of the ice-albedo feedback at high CO2 pressures. (abridged)

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arXiv2013

The effect of rotation and tidal heating on the thermal lightcurves of Super Mercuries

Short period (<50 days) low-mass (<10Mearth) exoplanets are abundant and the few of them whose radius and mass have been measured already reveal a diversity in composition. Some of these exoplanets are found on eccentric orbits and are subjected to strong tides affecting their rotation and resulting in significant tidal heating. Within this population, some planets are likely to be depleted in volatiles and have no atmosphere. We model the thermal emission of these "Super Mercuries" to study the signatures of rotation and tidal dissipation on their infrared light curve. We compute the time-dependent temperature map at the surface and in the subsurface of the planet and the resulting disk-integrated emission spectrum received by a distant observer for any observation geometry. We calculate the illumination of the planetary surface for any Keplerian orbit and rotation. We include the internal tidal heat flow, vertical heat diffusion in the subsurface and generate synthetic light curves. We show that the different rotation periods predicted by tidal models (spin-orbit resonances, pseudo-synchronization) produce different photometric signatures, which are observable provided that the thermal inertia of the surface is high, like that of solid or melted rocks (but not regolith). Tidal dissipation can also directly affect the light curves and make the inference of the rotation more difficult or easier depending on the existence of hot spots on the surface. Infrared light curve measurement with the James Webb Space Telescope and EChO can be used to infer exoplanets' rotation periods and dissipation rates and thus to test tidal models. This data will also constrain the nature of the (sub)surface by constraining the thermal inertia.

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arXiv2013

Potential Biosignatures in Super-Earth Atmospheres II. Photochemical Responses

Spectral characterization of Super-Earth atmospheres for planets orbiting in the Habitable Zone of M-dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of atmospheric biosignatures (species associated with life). Our work applies a global-mean radiative-convective-photochemical column model assuming a planet with an Earth-like biomass and planetary development. We investigated planets with gravities of 1g and 3g and a surface pressure of one bar around central stars with spectral classes from M0 to M7. The spectral signals of the calculated planetary scenarios have been presented by Rauer et al. (2011). The main motivation of the present work is to perform a deeper analysis of the chemical processes in the planetary atmospheres. We apply a diagnostic tool, the Pathway Analysis Program, to shed light on the photochemical pathways that form and destroy biosignature species. Ozone is a potential biosignature for complex- life. An important result of our analysis is a shift in the ozone photochemistry from mainly Chapman production (which dominates in the terrestrial stratosphere) to smog-dominated ozone production for planets in the Habitable Zone of cooler (M5-M7)-class dwarf stars. This result is associated with a lower energy flux in the UVB wavelength range from the central star, hence slower planetary atmospheric photolysis of molecular oxygen, which slows the Chapman ozone production.

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arXiv2013

Characterization of potentially habitable planets: Retrieval of atmospheric and planetary properties from emission spectra

An increasing number of potentially habitable terrestrial planets and planet candidates are found by ongoing planet search programs. The search for atmospheric signatures to establish planetary habitability and the presence of life might be possible in the future. We want to quantify the accuracy of retrieved atmospheric parameters which might be obtained from infrared emission spectroscopy. We use synthetic observations of hypothetical habitable planets, constructed with a parametrized atmosphere model, a high-resolution radiative transfer model and a simplified noise model. Classic statistical tools such as chi2 statistics and least-square fits were used to analyze the simulated observations. When adopting the design of currently planned or proposed exoplanet characterization missions, we find that emission spectroscopy could provide weak limits on surface conditions of terrestrial planets, hence their potential habitability. However, these mission designs are unlikely to allow to characterize the composition of the atmosphere of a habitable planet, even though CO2 is detected. Upon increasing the signal-to-noise ratios by about a factor of 2-5 (depending on spectral resolution) compared to current mission designs, the CO2 content could be characterized to within two orders of magnitude. The detection of the O3 biosignature remains marginal. The atmospheric temperature structure could not be constrained. Therefore, a full atmospheric characterization seems to be beyond the capabilities of such missions when using only emission spectroscopy during secondary eclipse or target visits. Other methods such as transmission spectroscopy or orbital photometry are probably needed in order to give additional constraints and break degeneracies. (abridged)

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arXiv2012

The impact of atmospheric circulation on the chemistry of the hot Jupiter HD 209458b

We investigate the effects of atmospheric circulation on the chemistry of the hot Jupiter HD 209458b. We use a simplified dynamical model and a robust chemical network, as opposed to previous studies which have used a three dimensional circulation model coupled to a simple chemical kinetics scheme. The temperature structure and distribution of the main atmospheric constituents are calculated in the limit of an atmosphere that rotates as a solid body with an equatorial rotation rate of 1 km/s. Such motion mimics a uniform zonal wind which resembles the equatorial superrotation structure found by three dimensional circulation models. The uneven heating of this tidally locked planet causes, even in the presence of such a strong zonal wind, large temperature contrasts between the dayside and nightside, of up to 800 K. This would result in important longitudinal variations of some molecular abundances if the atmosphere were at chemical equilibrium. The zonal wind, however, acts as a powerful disequilibrium process. We identify the existence of a pressure level of transition between two regimes, which may be located between 100 and 0.1 mbar depending on the molecule. Below this transition layer, chemical equilibrium holds, while above it, the zonal wind tends to homogenize the chemical composition of the atmosphere, bringing molecular abundances in the limb and nightside regions close to chemical equilibrium values characteristic of the dayside, i.e. producing an horizontal quenching effect in the abundances. Reasoning based on timescales arguments indicates that horizontal and vertical mixing are likely to compete in HD 209458b's atmosphere, producing a complex distribution where molecular abundances are quenched horizontally to dayside values and vertically to chemical equilibrium values characteristic of deep layers.

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