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Fabio Marchesoni

Publications and source records attributed to Fabio Marchesoni.

At least 19 recordsLinked to original sources

Understanding quorum sensing self-organization: Clustering and defect-induced ordering of diffusing particles

Quorum sensing (QS) is known in biology as a form of intercellular communication mediated by signaling molecules called autoinducers. The QS protocol governs the transition from individual to collective cell behavior once a critical population density is reached. Using numerical simulations, we investigate how defects influence the QS transition and the structural organization of the resulting colonies. Our model system consists of a mixture of slow ("cold") and fast ("hot") diffusing colloidal particles that obey the QS protocol, together with defect particles characterized by a constant diffusivity. A striking reentrant solidification of QS particles, characterized by long-range order, is induced by hot defects, whereas cold defects give rise to amorphous structures with only short-range order. These findings deepen our understanding of the QS interaction and provide a mechanism to control the degree of organization in QS systems, with potential applications in robotics, social sciences, and medicine -- for instance, in overcoming antimicrobial resistance.

cond-mat.soft

Large-scale dynamics in visual quorum sensing chiral suspensions

Motility induced phase separation is an efficient aggregation mechanism of active matter, yet biological systems exhibit richer organization through communication among constituents. We investigate suspensions of active particles that change chirality when neighbor density within their visual cone exceeds a threshold, a communication based non-reciprocal interaction akin to quorum sensing. Tuning the visual cone triggers programmable transitions: from disorder to phase separation to hyper-uniformity. Notably, phase separation triggers large-scale circulation, with robust edge currents persistently flowing around dense clusters, while particle distributions inside become effectively hyper-uniform. These are genuine non-reciprocal effects which occur even in the absence of steric interactions. Remarkably, in active-passive mixtures, only 5% quorum-sensing chiral particles suffice to induce collective circulation. Thus, simple perception-based rules can generate life-like order, offering design principles for programmable active materials and micro-robotic swarms.

cond-mat.soft

Binary Mixtures in Linear Convection Arrays

We numerically investigated the dynamics of a mixture of finite-size active and passive particles in a linear array of convection rolls. The interplay of advection and steric interactions produces a number of interesting effects, like the stirring of a passive colloidal fluid by a small fraction of slow active particles, or the separation of the mixture active and passive colloidal fractions by increasing the motility of the active one, which eventually clusters in stagnation areas along the array walls. These mechanisms are quantitatively characterized by studying the dependence of the diffusion constants of the active and passive particles on the parameters of the active mixture fraction.

cond-mat.soft

Active Particle Diffusion in Convection Roll Arrays

We numerically investigated the Brownian motion of active Janus particles in a linear array of planar counter-rotating convection rolls at high Péclet numbers. Similarly to passive particles, active microswimmers exhibit advection enhanced diffusion, but only for self-propulsion speeds up to a critical value. The diffusion of faster Janus particles is governed by advection along the array's edges, whereby distinct diffusion regimes are observed and characterized. Contrary to passive particles, the relevant spatial distributions of active Janus particles are inhomogeneous. These peculiar properties of active matter are related to the combined action of noise and self-propulsion in a confined geometry and hold regardless of the actual flow boundary conditions.

cond-mat.stat-mech

Diffusion Transients in Motility-Induced Phase Separation

We numerically investigate normal diffusion in a two-dimensional athermal suspension of active particles undergoing motility-induced phase separation. The particles are modeled as achiral Janus disks with fixed self-propulsion speed and weakly fluctuating orientation. When plotted versus the overall suspension packing fraction, the relevant diffusion constant traces a hysteresis loop with sharp jumps in correspondence with the binodal and spinodal of the gaseous phase. No hysteresis loop is observed between the spinodal and binodal of the dense phase, as they appear to overlap. Moreover, even under steady-state phase separation, the particle displacement distributions exhibit non-Gaussian normal diffusion with transient fat (thin) tails in the presence (absence) of phase separation.

cond-mat.soft

Topological thermal transport

Thermal transport is a fundamental mechanism of energy transfer process quite distinct from wave propagation phenomena. It can be manipulated well beyond the possibilities offered by natural materials with a new generation of artificial metamaterials: thermal metamaterials. Topological physics, a focal point in contemporary condensed matter physics, is closely intertwined with thermal metamaterials in recent years. Inspired by topological photonics and topological acoustics in wave metamaterials, a new research field emerged recently, which we dub `topological thermotics', which encompasses three primary branches: topological thermal conduction, convection, and radiation. For topological thermal conduction, we discuss recent advances in both 1D and higher-dimensional thermal topological phases. For topological thermal convection, we discuss the implementation of thermal exceptional points with their unique properties and non-Hermitian thermal topological states. Finally, we review the most recent demonstration of topological effects in the near-field and far-field radiation. Anticipating future developments, we conclude by discussing potential directions of topological thermotics, including the expansion into other diffusion processes such as particle dynamics and plasma physics, and the integration with machine learning techniques.

physics.app-ph

Controlling mass and energy diffusion with metamaterials

Diffusion driven by temperature or concentration gradients is a fundamental mechanism of energy and mass transport, which inherently differs from wave propagation in both physical foundations and application prospects. Compared with conventional schemes, metamaterials provide an unprecedented potential for governing diffusion processes, based on emerging theories like the transformation and the scattering cancellation theory, which enormously expanded the original concepts and suggest innovative metamaterial-based devices. We hereby use the term "diffusionics" to generalize these remarkable achievements in various energy (e.g., heat) and mass (e.g., particles and plasmas) diffusion systems. For clarity, we categorize the numerous studies appeared during the last decade by diffusion field (i.e., heat, particles, and plasmas) and discuss them from three different perspectives: the theoretical perspective, to detail how the transformation principle is applied to each diffusion field; the application perspective, to introduce various intriguing metamaterial-based devices, such as cloaks and radiative coolers; and the physics perspective, to connect with concepts of recent concern, such as non-Hermitian topology, nonreciprocal transport, and spatiotemporal modulation. We also discuss the possibility of controlling diffusion processes beyond metamaterials. Finally, we point out several future directions for diffusion metamaterial research, including the integration with artificial intelligence and topology concepts.

physics.app-ph

A quorum sensing active matter in a confined geometry

Inspired by the problem of biofilm growth, we numerically investigate clustering in a two-dimensional suspension of active (Janus) particles of finite size confined in a circular cavity. Their dynamics is regulated by a non-reciprocal mechanism that causes them to switch from active to passive above a certain threshold of the perceived near-neighbor density (quorum sensing).A variety of cluster phases -- glassy, solid (hexatic) and liquid -- is observed depending on the particle dynamics at the boundary, the quorum sensing range, and the level of noise

cond-mat.soft

Autonomous Ratcheting by Stochastic Resetting

We propose a generalization of the stochastic resetting mechanism for a Brownian particle diffusing in a one-dimensional periodic potential: randomly in time, the particle gets reset at the bottom of the potential well it was in. Numerical simulations show that in mirror asymmetric potentials, stochastic resetting rectifies the particle's dynamics, with maximum drift speed for an optimal average resetting time. Accordingly, an unbiased Brownian tracer diffusing on an asymmetric substrate can rectify its motion by adopting an adaptive stop-and-go strategy. Our proposed ratchet mechanism can model directed autonomous motion of molecular motors and micro-organisms

cond-mat.stat-mech

Autonomous Circular Heat Engine

A dynamical model of a highly efficient heat engine is proposed, where an applied temperature difference maintains the motion of particles around the circuit consisting of two asymmetric narrow channels, in one of which the current flows against the applied thermodynamic forces. Numerical simulations and linear-response analysis suggest that, in the absence of frictional losses, the Carnot efficiency can be achieved in the thermodynamic limit.

cond-mat.stat-mech

Single file dynamics in soft materials

The term single file (SF) dynamics refers to the motion of an assembly of particles through a channel with cross-section comparable to the particles' diameter. Single file diffusion (SFD) is then the diffusion of a tagged particle in a \emph{single file}, i.e., under the condition that particle passing is not allowed. SFD accounts for a large variety of processes in nature, including diffusion of colloids in synthetic and natural-shaped channels, biological motors along molecular chains, electrons in proteins and liquid helium, ions through membrane, just to mention a few examples. Albeit introduced in '65, over the last decade the classical notion of SF dynamics has been generalized to account through a more realistic modeling of, among others, particles properties, file geometry, particle-particle and channel-particles interactions, thus paving the way to remarkable applications in, for example, the technology of bio-integrated nanodevices. We then provide a comprehensive review of the recent advances in the theory of SF dynamics and the ensuing experimental realisations.

cond-mat.soft

Non-Gaussian Normal Diffusion in Low Dimensional Systems

Brownian particles suspended in disordered crowded environments often exhibit non-Gaussian normal diffusion (NGND), whereby their displacements grow with mean square proportional to the observation time and non-Gaussian statistics. Their distributions appear to decay almost exponentially according to "universal" laws largely insensitive to the observation time. This effect is generically attributed to slow environmental fluctuations, which perturb the local configuration of the suspension medium. To investigate the microscopic mechanisms responsible for the NGND phenomenon, we study Brownian diffusion in low dimensional systems, like the free diffusion of ellipsoidal and active particles, the diffusion of colloidal particles in fluctuating corrugated channels and Brownian motion in arrays of planar convective rolls. NGND appears to be a transient effect related to the time modulation of the instantaneous particle's diffusivity, which can occur even under equilibrium conditions. Consequently, we propose to generalize the definition of NGND to include transient displacement distributions which vary continuously with the observation time. To this purpose, we provide a heuristic one-parameter function, which fits all time-dependent transient displacement distributions corresponding to the same diffusion constant. Moreover, we reveal the existence of low dimensional systems where the NGND distributions are not leptokurtic (fat exponential tails), as often reported in the literature, but platykurtic (thin sub-Gaussian tails), i.e., with negative excess kurtosis. The actual nature of the NGND transients is related to the specific microscopic dynamics of the diffusing particle.

cond-mat.stat-mech

Enhanced motility in a binary mixture of active nano/microswimmers

It is often desirable to enhance the motility of active nano- or microscale swimmers such as, e.g., self-propelled Janus particles as agents of chemical reactions or weak sperm cells for better chances of successful fertilization. Here we tackle this problem based on the idea that motility can be transferred from a more active guest species to a less active host species. We performed numerical simulations of motility transfer in two typical cases, namely for interacting particles with weak inertia effect, by analyzing their velocity distributions, and for interacting overdamped particles, by studying their effusion rate. In both cases we detected motility transfer with a motility enhancement of the host species of up to a factor of four. This technique of motility enhancement can find applications in chemistry, biology and medicine.

cond-mat.soft

Diffusion of Chiral Janus Particles in Convection Rolls

The diffusion of an artificial active particle in a two-dimensional periodic pattern of stationary convection cells is investigated by means of extensive numerical simulations. In the limit of large Péclet numbers, i.e., for self-propulsion speeds below a certain depinning threshold and weak roto-translational fluctuations, the particle undergoes asymptotic normal diffusion with diffusion constant proportional to the square root of its diffusion constant at zero flow. Chirality effects in the propulsion mechanism, modeled here by a tunable applied torque, favors particle's jumping between adjacent convection rolls. Roll jumping is signaled by an excess diffusion peak, which appears to separate two distinct active diffusion regimes for low and high chirality. A qualitative interpretation of our simulation results is proposed as a first step toward a fully analytical study of this phenomenon.

cond-mat.soft

Non-Gaussian Normal Diffusion in a Fluctuating Corrugated Channel

A Brownian particle floating in a narrow corrugated (sinusoidal) channel with fluctuating cross section exhibits non-Gaussian normal diffusion. Its displacements are distributed according to a Gaussian law for very short and asymptotically large observation times, whereas a robust exponential distribution emerges for intermediate observation times of the order of the channel fluctuation correlation time. For intermediate to large observation times the particle undergoes normal diffusion with one and the same effective diffusion constant. These results are analytically interpreted without having recourse to heuristic assumptions. Such a simple model thus reproduces recent experimental and numerical observations obtained by investigating complex biophysical systems.

cond-mat.stat-mech

Diffusion of Colloidal Rods in Corrugated Channels

In many natural and artificial devices diffusive transport takes place in confined geometries with corrugated boundaries. Such boundaries cause both entropic and hydrodynamic effects, which have been studied only for the case of spherical particles. Here we experimentally investigate diffusion of particles of elongated shape confined into a corrugated quasi-two-dimensional channel. Elongated shape causes complex excluded-volume interactions between particle and channel walls which reduce the accessible configuration space and lead to novel entropic free energy effects. The extra rotational degree of freedom also gives rise to a complex diffusivity matrix that depends on both the particle location and its orientation. We further show how to extend the standard Fick-Jacobs theory to incorporate combined hydrodynamic and entropic effects, so as, for instance, to accurately predict experimentally measured mean first passage times along the channel. Our approach can be used as a generic method to describe translational diffusion of anisotropic particles in corrugated channels.

cond-mat.soft

Hydrodynamic and entropic effects on colloidal diffusion in corrugated channels

In the absence of advection, confined diffusion characterizes transport in many natural and artificial devices, such as ionic channels, zeolites, and nanopores. While extensive theoretical and numerical studies on this subject have produced many important predictions, experimental verifications of the predictions are rare. Here, we experimentally measure colloidal diffusion times in microchannels with periodically varying width and contrast results with predictions from the Fick-Jacobs theory and Brownian dynamics simulation. While the theory and simulation correctly predict the entropic effect of the varying channel width, they fail to account for hydrodynamic effects, which include both an overall decrease and a spatial variation of diffusivity in channels. Neglecting such hydrodynamic effects, the theory and simulation underestimate the mean and standard deviation of first passage times by 40\% in channels with a neck width twice the particle diameter. We further show that the validity of the Fick-Jakobs theory can be restored by reformulating it in terms of the experimentally measured diffusivity. Our work thus demonstrates that hydrodynamic effects play a key role in diffusive transport through narrow channels and should be included in theoretical and numerical models.

cond-mat.soft

Taxis of Artificial Swimmers in a Spatio-Temporally Modulated Activation Medium

Contrary to microbial taxis, where a tactic response to external stimuli is controlled by complex chemical pathways acting like sensor-actuator loops, taxis of artificial microswimmers is a purely stochastic effect associated with a non-uniform activation of the particles' self-propulsion. We study the tactic response of such swimmers in a spatio-temporally modulated activating medium by means of both numerical and analytical techniques. In the opposite limits of very fast and very slow rotational particle dynamics, we obtain analytic approximations that closely reproduce the numerical description. A swimmer drifts on average either parallel or anti-parallel to the propagation direction of the activating pulses, depending on their speed and width. The drift in line with the pulses is solely determined by the finite persistence length of the active Brownian motion performed by the swimmer, whereas the drift in the opposite direction results from the combination of ballistic and diffusive properties of the swimmer's dynamics.

cond-mat.soft