arXiv subjects

Falk Röder

Publications and source records attributed to Falk Röder.

2 recordsLinked to original sources

arXiv2026

Electrodeposited Co and Ni Hexacyanoferrates: Insights into Structure and Morphology

Prussian blue (PB) and its analogues (PBAs) are interesting materials for electrochemical applications due to their tunable redox chemistry and open framework structure. In this study, hexacyanoferrates (HCF) containing iron (FeHCF), cobalt (CoHCF) and nickel (NiHCF) were synthesized via potentiostatic electrodeposition. Cyclic voltammetry revealed distinct redox behaviors. Morphological characterization (SEM, EDX) demonstrated uniform, pyramidal film growth for FeHCF and CoHCF. Otherwise, NiHCF presented a cracked film with cubic clusters on top due to residual stress. Despite this, homogeneous element distribution was found for all samples. Structural characterization (TEM and XRD) confirmed a cubic lattice crystal structure for all films, with systematic lattice contraction from Fe to Co to Ni due to decreasing atomic radius. Raman and XPS data revealed a shift toward Fe2+ dominant oxidation states and modifications in CN bonding with the influence of K+ and water occupancy in the PBAs framework. These findings illustrate how metal substitution and deposition parameters can tune the structural and electrochemical properties of PBA films, presenting a strategic route to design tailored electrodes.

cond-mat.mtrl-sci↗

arXiv2016

The role of the internal demagnetizing field in a surface-modulated magnonic crystal

Magnonic crystals with locally alternating properties and specific periodicities exhibit interesting effects, such as a multitude of different spin-wave states and large band gaps. This work aims for demonstrating and understanding the key role of local demagnetizing fields in such systems. To achieve this, hybrid structures are investigated consisting of a continuous thin film with a stripe modulation on top favorable due to the adjustability of the magnonic effects with the modulation size. For a direct access to the spin dynamics, a magnonic crystal was reconstructed from `bottom-up', i.e., the structural shape as well as the internal field landscape of the structure were experimentally obtained on the nanoscale using electron holography. Subsequently, both properties were utilized to perform dynamic response calculations. The simulations yield the frequency-field dependence as well as the angular dependence of spin waves in a magnonic crystal and reveal the governing role of the internal field landscape around the backward-volume geometry. The complex angle-dependent spin-wave behavior is described for a 360 degree in-plane rotation of an external field by connecting the internal field landscape with the individual spin-wave localization.

cond-mat.mtrl-sci↗