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Fang-Qi Hu

Publications and source records attributed to Fang-Qi Hu.

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The controlled exciton transport of the Multi-chain system by cavity-dressed energy level crossings and anticrossings

The performance of various quantum devices is fundamentally linked to the control of exciton transport. To explore this, we study the exciton transport of the two-dimensional multi-chain systems with different coupling configurations in an optical cavity. Two types of the chains--the homogeneous and heterogeneous coupling chain, as well as two inter-chain coupling conformations--the square and triangular arrangements, are considered. The effects of the inter-chain coupling, the dimerization parameter, the cavity, the length and number of the chains on exciton transport are systematically investigated for different coupling configurations through the spectra, the Hopfield coeffcients, and the steady-state dynamics of the system. The results show that in the absence of a cavity the exciton transport currents and effciency are determined by the exciton distribution across the multi-chain system. However, when a cavity is introduced the exciton transport can be significantly enhanced or suppressed by the polariton formation at the cavity-dressed energy level crossings and anticrossings near zero-energy modes, where the coherent excitation and LandauZener transitions occur. Meanwhile, we discover that the discontinuous and extremal points in the second-order partial derivatives of the photon Hopfield coeffcients with respect to the inter-chain coupling and the dimerization parameter correspond respectively to the crossings and anticrossings at the extreme points of the photon occupation number. Additionally, exciton transport effciency is closely related to the odevity of both chain length and chain number, and exhibits oscillatory behaviour. This work provides critical insights into the exciton transport mechanism in multichain-cavity system and theoretical basis for designing high-erformance excitonic devices with tunable transport properties.

quant-ph

The anomalous process in singlet fission kinetic model with time-dependent coefficient

In the third generation photovoltaic device, the main physical mechanism that the photoelectric conversion efficiency is enhanced is the singlet fission (SF). In order to accurately describe the SF and reveal physical process in theoretically, we introduce the anomalous process (AP) in SF dynamics based on previous model, including anomalous fission, anomalous fusion, anomalous dissociation and combination of triplet pair states, anomalous decay and diffusion of single triplet exciton. The effects of the AP on SF are investigated by the kinetic model with time-dependent coefficient. Further, according to the results we make the optimal simulations for the experimental data [G. B. Piland et al., J. Phys. Chem. C, 2013, 117, 1224] by adjusting the rate coefficients and exponents in the mended kinetic equations. The results show that the model considered AP is more accurate than previous that to describe SF dynamics, demonstrating that the AP do exist in SF. The model also provides the theoretical foundation for how varies experimentally physical factors to make SF occur to tend to required direction.

physics.chem-ph