arXiv subjects

Felipe Morales

Publications and source records attributed to Felipe Morales.

At least 19 recordsLinked to original sources

arXiv2025

High-Order Harmonic Generation in Organic Molecular Crystals

High-order harmonic generation (HHG) is a powerful tool for probing electronic structure and ultrafast dynamics in matter. Traditionally studied in atomic and molecular gases, HHG has recently been extended to condensed matter, enabling all-optical investigations of electronic and crystal structures. Here, we experimentally demonstrate HHG in a new class of materials: thin organic molecular crystals with perfectly aligned molecules, using pentacene as a model system. Organic molecular crystals, characterized by weak intermolecular coupling, flat electronic bands, and large unit cells, differ fundamentally from conventional covalent or ionic crystals and have attracted significant interest as promising candidates for organic electronics. We show that pentacene crystals endure laser intensities sufficient for efficient HHG up to the 17th order. The harmonic yield as a function of laser polarization reveals a strong dependence on intermolecular interactions, with higher harmonic orders particularly sensitive to both nearest- and next-nearest-neighbor couplings. Model calculations indicate that weaker intermolecular interactions necessitate probing with higher harmonic orders to resolve the crystal structure. These findings suggest that HHG may serve as a powerful tool for probing the electronic structure of organic molecular crystals, enhancing all-optical techniques for studying electronic properties and ultrafast dynamics in complex organic materials.

physics.optics↗

arXiv2024

Ultrafast TACOS -- Terahertz-Assisted Chiro-Optical Spectroscopy

We bring together the advantages of terahertz (THz) and optical spectroscopies to introduce TACOS (Terahertz-Assisted Chiro-Optical Spectroscopy), a novel approach for ultrafast and highly efficient imaging of molecular chirality and control over chiral electronic dynamics. We show how, using a THz pulse, we can induce a transient electronic orientation in a medium of randomly oriented chiral molecules that breaks the isotropy of the molecular sample. This symmetry breaking twists the nonlinear response of the medium to an ultrashort linearly polarised optical pulse in a highly enantiosensitive manner. As a result, the medium emits elliptically polarised light at new optical frequencies that records the molecular handedness via purely electric-dipole interactions. The long wavelength and period of the THz pulse enable both spatial coherence across the sample and a substantial degree of electronic orientation over the duration of the ultrashort optical pulse. TACOS does not require optical carrier-envelope phase stability or working in vacuum, and it creates exciting avenues for ultrafast and highly efficient chiral sensing and manipulation.

physics.optics↗

arXiv2024

Bidirectional cascaded superfluorescent lasing in air enabled by resonant third harmonic photon exchange from nitrogen to argon

Cavity-free lasing in atmospheric air has stimulated intense research towards fundamental understanding of underlying physical mechanisms. In this Letter, we identify a new mechanism -- third harmonic photon mediated resonant energy transfer pathway leading to population inversion in argon via initial three-photon excitation of nitrogen molecules irradiated by intense 261 nm pulses -- that enables bidirectional two-color cascaded lasing in atmospheric air. By making pump-probe measurements, we conclusively show that such cascaded lasing results from superfluorescence (SF) rather than amplified spontaneous emission (ASE). Such cascaded lasing with the capability of producing bidirectional multicolor coherent pulses opens additional possibilities for remote sensing applications.

physics.optics↗

arXiv2024

Photoionization-induced reflection for benchmarking of the photoionization models in solid

The choice of the most suitable analytic photoionization model in solids is a challenging task with no default solution. Here we show how the best formalism can be determined based on the waveform of the pulse reflected by a sample due to photoionized almost-free electrons in the conduction band. For a typical case of diamond, we compare three simple models and benchmark them against highly accurate first-principle TDDFT simulation, by analysing the fit between the reflected pulses in time and frequency domain. For the aims of this paper, we have developed a software package, called PIGLET, for the FDTD simulation of photoionization-governed propagation, which is now freely available for the scientific community. Furthermore, we show that due to interband contributions for very short sub-10-fs pulses a semi-classical description based on any analytical photoionization model fail to provide an adequate description.

physics.optics↗

arXiv2024

Nonlinear Voltage Regulation of an Auxiliary Energy Storage of a Multiport Interconnection

In this article, we propose a nonlinear voltage control to ensure power exchange in a multiport interconnected system, which consists of a bidirectional DC-DC converter and generating-storing devices. The converter topology under consideration is two-stage, composed of an interconnection of a buck with a boost converter. The motivation for this work is the explosive increase in the use of DC-DC converters due to the massification of renewable energies, electric vehicles powertrains, and energy storage systems, where fuel cells or batteries can be used as power backup or high-power support during transient phenomena. The converter's voltage step-up and step-down capabilities allow the use of supercapacitors with voltage limits that exceed those required by the load, thus enabling its use in a broader range of applications. The control design for this system does not correspond to that in standard applications involving power converters. As it is known, the latter consists of finding a control law such that the closed-loop system has an asymptotically stable equilibrium point fulfilling the voltage regulation objectives. Instead, in this application, the state does not tend to an equilibrium value in order for the system to be regulated. The converter voltage is regulated at desired some setpoint whereas the other variables are only required to be bounded. To achieve a dynamic response that best adapts to changes in system demand and ensure stability over the defined wide operating range we propose a novel control strategy that exploits the partially cascaded structure of the system. Numerical and experimental results validate our approach.

eess.SY↗

arXiv2022

Highly spin-polarized multi-GeV electron beams generated by single-species plasma photocathodes

High-gradient and high-efficiency acceleration in plasma-based accelerators has been demonstrated, showing its potential as the building block for a future collider operating at the energy frontier of particle physics. However, generating and accelerating the required spin-polarized beams in such a collider using plasma-based accelerators has been a long-standing challenge. Here we show that the passage of a highly relativistic, high-current electron beam through a single-species (ytterbium) vapor excites a nonlinear plasma wake by primarily ionizing the two outer 6s electrons. Further photoionization of the resultant Yb2+ ions by a circularly polarized laser injects the 4f14 electrons into this wake generating a highly spin-polarized beam. Combining time-dependent Schrodinger equation simulations with particle-in-cell simulations, we show that a sub-femtosecond, high-current (4 kA) electron beam with up to 56% net spin polarization can be generated and accelerated to 15 GeV in just 41 cm. This relatively simple scheme solves the perplexing problem of producing spin-polarized relativistic electrons in plasma-based accelerators.

physics.plasm-ph↗

arXiv2022

Evidence of ac-Stark-shifted resonances in intense two-color circularly polarized laser fields

We report on the appearance of a structure at low energies in the photo-electron momentum distribution of the hydrogen atom exposed to two-color counter-rotating bi-circular laser fields. These structures, which arise due to AC-Stark shifted resonances, break the three-fold symmetry, typical for the $\omega-2\omega$ bi-circular fields. We discuss the physical origin of this structure in terms of partial-wave interference between direct ionization channels and a resonant pathway, that passes through the AC-Stark shifted state and show how the underlying Rydberg state population depend on the field strength and pulse duration.

physics.atom-ph↗

arXiv2021

Imprinting chirality on atoms using synthetic chiral light fields

Atoms are usually thought of as achiral objects. However, one can construct superpositions of atomic states that are chiral [1]. Here we show how to excite such superpositions with tailored light fields both in the weak-field and strong-field regimes, using realistic laser parameters. First, we use time-dependent Schrodinger equation (TDSE) simulations to demonstrate the creation of a time-dependent bound chiral wavepacket in sodium atoms. Second, we show how the time-dependent handedness of this wavepacket can be probed by photoelectron circular dichroism, in spite of the central symmetry of the core potential. Third, we use TDSE simulations to show how chirality can be directly imprinted on a photoelectron wavepacket created by strong-field ionization and introduce an unambigous chiral measure that allows us to characterize its handedness.

physics.atom-ph↗

arXiv2021

Generation and characterisation of isolated attosecond pulses at 100kHz repetition rate

The generation of coherent light pulses in the extreme ultraviolet (XUV) spectral region with attosecond pulse durations constitutes the foundation of the field of attosecond science. Twenty years after the first demonstration of isolated attosecond pulses, they continue to be a unique tool enabling the observation and control of electron dynamics in atoms, molecules and solids. It has long been identified that an increase in the repetition rate of attosecond light sources is necessary for many applications in atomic and molecular physics, surface science, and imaging. Although high harmonic generation (HHG) at repetition rates exceeding 100 kHz, showing a continuum in the cut-off region of the XUV spectrum was already demonstrated in 2013, the number of photons per pulse was insufficient to perform pulse characterisation via attosecond streaking, let alone to perform a pump-probe experiment. Here we report on the generation and full characterisation of XUV attosecond pulses via HHG driven by near-single-cycle pulses at a repetition rate of 100 kHz. The high number of 10^6 XUV photons per pulse on target enables attosecond electron streaking experiments through which the XUV pulses are determined to consist of a dominant single attosecond pulse. These results open the door for attosecond pump-probe spectroscopy studies at a repetition rate one or two orders of magnitude above current implementations.

physics.optics↗

arXiv2021

In Situ Generation of High-Energy Spin-Polarized Electrons in a Beam-Driven Plasma Wakefield Accelerator

In situ generation of a high-energy, high-current, spin-polarized electron beam is an outstanding scientific challenge to the development of plasma-based accelerators for high-energy colliders. In this Letter we show how such a spin-polarized relativistic beam can be produced by ionization injection of electrons of certain atoms with a circularly polarized laser field into a beam-driven plasma wakefield accelerator, providing a much desired one-step solution to this challenge. Using time-dependent Schr\"odinger equation (TDSE) simulations, we show the propensity rule of spin-dependent ionization of xenon atoms can be reversed in the strong-field multi-photon regime compared with the non-adiabatic tunneling regime, leading to high total spin-polarization. Furthermore, three-dimensional particle-in-cell (PIC) simulations are incorporated with TDSE simulations, providing start-to-end simulations of spin-dependent strong-field ionization of xenon atoms and subsequent trapping, acceleration, and preservation of electron spin-polarization in lithium plasma. We show the generation of a high-current (0.8 kA), ultra-low-normalized-emittance (~37 nm), and high-energy (2.7 GeV) electron beam within just 11 cm distance, with up to ~31% net spin polarization. Higher current, energy, and net spin-polarization beams are possible by optimizing this concept, thus solving a long-standing problem facing the development of plasma accelerators.

physics.plasm-ph↗

arXiv2020

N$_2^+$ Lasing: Gain and Absorption in the Presence of Rotational Coherence

We simulate the pump-probe experiments of lasing in molecular nitrogen ions with particular interest on the effects of rotational wave-packet dynamics. Our computations demonstrate that the coherent preparation of rotational wave packets in N$_2^+$ by an intense short non-resonant pulse results in a modulation of the subsequent emission from $B^2\Sigma_u^+ \rightarrow X^2\Sigma_g^+$ transitions induced by a resonant seed pulse. We model the dynamics of such pumping and emission using density matrix theory to describe the N$_2^+$ dynamics and the Maxwell wave equation to model the seed pulse propagation. We show that the gain and absorption of a delayed seed pulse is dependent on the pump-seed delay, that is, the rotational coherences excited by the pump pulse can modulate the gain and absorption of the delayed seed pulse. Further, we demonstrate that the coherent rotational dynamics of the nitrogen ions can cause lasing without electronic inversion.

physics.optics↗

arXiv2020

Rotational Quantum Beat Lasing Without Inversion

In standard lasers, light amplification requires population inversion between an upper and a lower state to break the reciprocity between absorption and stimulated emission. However, in a medium prepared in a specific superposition state, quantum interference may fully suppress absorption while leaving stimulated emission intact, opening the possibility of lasing without inversion. Here we show that lasing without inversion arises naturally during propagation of intense femtosecond laser pulses in air. It is triggered by the combination of molecular ionization and molecular alignment, both unavoidable in intense light fields. The effect could enable inversionless amplification of broadband radiation in many molecular gases, opening unusual opportunities for remote sensing.

physics.optics↗

arXiv2018

Amplification of intense light fields by nearly free electrons

Light can be used to modify and control properties of media, as in the case of electromagnetically induced transparency or, more recently, for the generation of slow light or bright coherent XUV and X-ray radiation. Particularly unusual states of matter can be created by light fields with strengths comparable to the Coulomb field that binds valence electrons in atoms, leading to nearly-free electrons oscillating in the laser field and yet still loosely bound to the core [1,2]. These are known as Kramers-Henneberger states [3], a specific example of laser-dressed states [2]. Here, we demonstrate that these states arise not only in isolated atoms [4,5], but also in rare gases, at and above atmospheric pressure, where they can act as a gain medium during laser filamentation. Using shaped laser pulses, gain in these states is achieved within just a few cycles of the guided field. The corresponding lasing emission is a signature of population inversion in these states and of their stability against ionization. Our work demonstrates that these unusual states of neutral atoms can be exploited to create a general ultrafast gain mechanism during laser filamentation.

physics.optics↗

arXiv2018

Control of attosecond light polarization in two-color bi-circular fields

We develop theoretically and confirm both numerically and experimentally a comprehensive analytical model which describes the propensity rules in the emission of circularly polarized high harmonics by systems driven by two-color counter-rotating fields, a fundamental and its second harmonic. We identify and confirm the three propensity rules responsible for the contrast between the 3N+1 and 3N+2 harmonic lines in the HHG spectra of noble gas atoms. We demonstrate how these rules depend on the laser parameters and how they can be used in the experiment to shape the polarization properties of the emitted attosecond pulses.

physics.atom-ph↗

arXiv2018

Ultrafast Preparation and Detection of Ring Currents in Single Atoms

Quantum particles can penetrate potential barriers by tunneling (1). If that barrier is rotating, the tunneling process is modified (2,3). This is typical for electrons in atoms, molecules or solids exposed to strong circularly polarized laser pulses (4,5). Here we measure how the transmission probability through a rotating tunnel depends on the sign of the magnetic quantum number m of the electron and thus on the initial sense of rotation of its quantum phase. We further show that the electron keeps part of that rotary motion on its way through the tunnel by measuring m-dependent modification of the electron emission pattern. These findings are relevant for attosecond metrology as well as for interpretation of strong field electron emission from atoms and molecules (6-13) and directly demonstrates the creation of ring currents in bound states of ions with attosecond precision. In solids, this could open a way to inducing and controlling ring-current related topological phenomena (14).

physics.atom-ph↗

arXiv2017

Time-resolved high harmonic spectroscopy of dynamical symmetry breaking in bi-circular laser fields

The bi-circular scheme for high harmonic generation, which combines two counter-rotating circular fields with frequency ratio 2:1, has recently permitted to generate high harmonics with essentially circular polarization, opening the way for ultrafast chiral studies. This scheme produces harmonic lines at 3N + 1 and 3N + 2 multiples of the fundamental driving frequency, while the 3N lines are forbidden owing to the three-fold symmetry of the field. It is generally established that the routinely observed signals at these forbidden harmonic lines come from a slight ellipticity in the driving fields, which breaks the three-fold symmetry. We find that this is neither the only nor it is the dominant mechanism responsible. The forbidden lines can be observed even for perfectly circular, long driving pulses. We show that they encode rich information on the sub-cycle electronic dynamics that occur during the generation process. By varying the time delay and relative intensity between the two drivers, we demonstrate that when the second harmonic either precedes or is more intense than the fundamental field, the dynamical symmetry of the system is broken by electrons trapped in Rydberg orbits (i.e., Freeman resonances), and that the forbidden harmonic lines are a witness of this.

physics.optics↗

arXiv2017

Electron spin polarization in strong-field ionization of Xenon atoms

As a fundamental property of the electron, the spin plays a decisive role in the electronic structure of matter from solids to molecules and atoms, e.g. causing magnetism. Yet, despite its importance, the spin dynamics of electrons released during the interaction of atoms with strong ultrashort laser pulses has remained unexplored. Here we report on the experimental detection of electron spin polarization by strong-field ionization of Xenon atoms and support our results by theoretical analysis. We found up to 30% spin polarization changing its sign with electron energy. This work opens the new dimension of spin to strong-field physics. It paves the way to production of subfemtosecond spin polarized electron pulses with applications ranging from probing magnetic properties of matter at ultrafast time scales to testing chiral molecular systems with subfemtosecond temporal and sub-Ångström spatial resolution.

physics.atom-ph↗

arXiv2016

Attosecond control of spin polarization in electron-ion recollision driven by intense tailored fields

We show that electrons recolliding with the ionic core upon tunnel ionization of noble gas atoms driven by a strong circularly polarized laser field in combination with a counter-rotating second harmonic are spin polarized and that their degree of polarization depends strongly on the recollision time. Spin polarization arises as a consequence of (1) entanglement between the recolliding electron and the ion, and (2) sensitivity of ionization to the sense of electron rotation in the initial state. We demonstrate that one can engineer the degree of spin polarization as a function of time by tuning the relative intensities of the counter-rotating fields, opening the door for attosecond control of spin-resolved dynamics.

physics.atom-ph↗