arXiv subjects

Fernando A. Reboredo

Publications and source records attributed to Fernando A. Reboredo.

40 records · Page 3Linked to original sources

arXiv2008

Jahn-Teller Distortion in Bimetallic Oxalates

A C$_3$-symmetric crystal-field potential in the Fe(II)Fe(III) bimetallic oxalates splits the L=2 Fe(II) multiplet into two doublets and a singlet. In compounds that exhibit magnetic compensation, one of the doublets was predicted to lie lowest in energy and carry a non-quenched orbital angular momentum $\pm \ld $, where $\ld $ exceeds a threshold value. In a range of $\ld $, a Jahn-Teller (JT) distortion increases the energy splitting of the low-lying doublet and breaks the C$_3$ symmetry of the bimetallic planes around the ferrimagnetic transition temperature. At low temperatures, the JT distortion disappears in compounds that display magnetic compensation due to the competition with the spin-orbit coupling. A comparison with recent measurements provides strong evidence for this re-entrant, low-temperature JT transition and a prediction for the normal, high-temperature JT transition. The size of the JT distortion is estimated using first-principles calculations, which suggest that the long-range ordering of smaller, non-C$_3$-symmetric organic cations can eliminate magnetic compensation.

cond-mat.other↗

arXiv2007

Nature of the Perpendicular-to-Parallel Spin Reorientation in a Mn-doped GaAs Quantum Well: Canting or Phase Separation?

It is well known that the magnetic anisotropy in a compressively-strained Mn-doped GaAs film changes from perpendicular to parallel with increasing hole concentration $p$. We study this reorientation transition at T=0 in a quantum well with Mn impurities confined to a single plane. With increasing $p$, the angle $θ$ that minimizes the energy $E$ increases continuously from 0 (perpendicular anisotropy) to $π/2$ (parallel anisotropy) within some range of $p$. The shape of $\Emin (p)$ suggests that the quantum well becomes phase separated with regions containing low hole concentrations and perpendicular moments interspersed with other regions containing high hole concentrations and parallel moments. However, due to the Coulomb energy cost associated with phase separation, the true magnetic state in the transition region is canted with $0 < θ< π/2$.

cond-mat.mtrl-sci↗

arXiv2007

A single layer of Mn in a GaAs quantum well: a ferromagnet with quantum fluctuations

Some of the highest transition temperatures achieved for Mn-doped GaAs have been in delta-doped heterostructures with well-separated planes of Mn. But in the absence of magnetic anisotropy, the Mermin-Wagner theorem implies that a single plane of magnetic ions cannot be ferromagnetic. Using a Heisenberg model, we show that the same mechanism that produces magnetic frustration and suppresses the transition temperature in bulk Mn-doped GaAs, due to the difference between the light and heavy band masses, can stabilize ferromagnetic order for a single layer of Mn in a GaAs quantum well. This comes at the price of quantum fluctuations that suppress the ordered moment from that of a fully saturated ferromagnet. By comparing the predictions of Heisenberg and Kohn-Luttinger models, we conclude that the Heisenberg description of a Mn-doped GaAs quantum well breaks down when the Mn concentration becomes large, but works quite well in the weak-coupling limit of small Mn concentrations. This comparison allows us to estimate the size of the quantum fluctuations in the quantum well.

cond-mat.mtrl-sci↗

arXiv2004

Quantum corral wave function engineering

We present a theoretical method for the design and optimization of quantum corrals with specific electronic properties. Taking advantage that spins are subject to a RKKY interaction that is directly controlled by the scattering of the quantum corral, we design corral structures that reproduce spin Hamiltonians with coupling constants determined a priori. We solve exactly the two-dimensional electron gas scattering problem for each corral configuration within the effective mass approximation and s-wave scattering using a Green function method. Subsequently, the geometry of the quantum corral is optimized with an algorithm that combines simulated annealing and genetic approaches. We demonstrate that it is possible to automatically design quantum corrals with complicated target electronic properties, such as multiple mirages with predefined relative intensities at specific locations. In addition we design structures that are particularly sensitive to the phase shift of impurities at certain positions allowing the measurement of the value of this parameter on the copper surface.

cond-mat.mes-hall↗