arXiv subjects

Fernando Moreno

Publications and source records attributed to Fernando Moreno.

At least 37 records · Page 2Linked to original sources

arXiv2021

Efficient Asymmetric photothermal source: Designing a heating Janus-Nanojet

Janus particles have flourished as subject of intensive research due to their synergetic properties and their promising use in different fields, especially in biomedicine. The combination of materials with radically different physical properties in the same nanostructure gives rise to the so-called Janus effects, allowing phenomena of a contrasting nature to occur in the same architecture. In particular, interesting advantages can be taken from a thermal Janus effect for photoinduced hyperthermia cancer therapies. Such therapies still have limitations associated to the heating control in terms of temperature stability and energy management. While previous studies have shown that some plasmonic single-material nanoparticles are somehow effective at killing cancer cells, it is necessary to investigate alternative plasmonic Janus nanoheaters to improve the heating efficiency and thermal control, mainly because the widespread single-material nanoheaters are highly homogeneous sources of heat, which implies that the surrounding biological medium is isotropically heated, equally affecting cancerous and healthy cells. A detailed thermoplasmonic study of the thermal Janus effect is still missing. Here we perform such study and demonstrate that doughnut-based Janus nanoparticles exhibit an outstanding photothermal control under practical illumination conditions, i.e., unpolarized light. Furthermore, we present novel and effective Janus nanoparticle designs that possess superior photothermal conversion features and unique directional heating capacity, being able to channel up to 91% of the total thermal energy onto a target. We discuss the implications of these innovative nanoparticles with regards to thermoplasmonics hyperthermia cancer therapy.

physics.optics↗

arXiv2021

Gold nanodoughnut as an outstanding nanoheater for photothermal applications

Photoinduced hyperthermia is a cancer therapy technique that induces death to cancerous cells via heat generated by plasmonic nanoparticles. While previous studies have shown that some nanoparticles can be effective at killing cancer cells under certain conditions, there is still a necessity (or the need) to improve its heating efficiency. In this work, we perform a detailed thermoplasmonic study comparing the most effective nanoparticle geometries up to now with a doughnut-shaped nanoparticle, demonstrating that the latter exhibits a superior tunable photothermal response in practical illumination conditions, i.e., unpolarized light. Furthermore, we show that nanoparticle heating in fluidic environments, i.e., nanoparticles undergoing Brownian rotations, strongly depends on the particle orientation with respect to the illumination source. We conclude that the heating performance of nanodoughnuts is outstanding, with a temperature increment 35% higher than the second best nanoheater (nanodisks). Furthermore, nanodoughnuts feature a weak dependence on orientation, being therefore, ideal candidates for photothermal therapy applications. Finally, we present a designing guide, covering a wide range of toroid designs, which can help on its experimental implementation.

physics.optics↗

arXiv2021

Dust environment of active asteroids P/2019 A4 (PANSTARRS) and P/2021 A5 (PANSTARRS)

We report on the characterisation of the dust activity and dynamical evolution of two faint active asteroids, P/2019 A4, and P/2021 A5, observed with the 10.4m GTC using both imaging and spectroscopy. Asteroid P/2019 A4 activity is found to be linked to an impulsive event occurring some $\pm$10 days around perihelion, probably due to a collision or a rotational disruption. Its orbit is stable over 100 Myr timescales. Dust tail models reveal a short-term burst producing (2.0$\pm$0.7)$\times$10$^6$ kg of dust for maximum particle radius rmax=1 cm. The spectrum of P/2019 A4 is featureless, and slightly redder than the Sun. P/2021 A5 was active $\sim$50 days after perihelion, lasting $\sim$5 to $\sim$60 days, and ejecting (8$\pm$2)$\times$10$^6$ kg of dust for rmax=1 cm. The orbital simulations show that a few percent of dynamical clones of P/2021 A5 are unstable on 20-50 Myr timescales. Thus, P/2021 A5 might be an implanted object from the JFC region or beyond. These facts point to water ice sublimation as the activation mechanism. This object also displays a featureless spectrum, but slightly bluer than the Sun. Nuclei sizes are estimated in the few hundred meters range for both asteroids. Particle ejection speeds ($\sim$0.2 m/s) are consistent with escape speeds from those small-sized objects.

astro-ph.EP↗

arXiv2020

High-Q transparency band in all-dielectric metasurfaces induced by a quasi bound state in the continuum

Bound states in the continuum (BICs) emerge throughout Physics as leaky/resonant modes that remain however highly localized. They have attracted much attention in Optics and Photonics, and especially in metasurfaces, i.e. planar arrays of sub-wavelength meta-atoms. One of their most outstanding feature is the arbitrarily large Q-factors they induce upon approaching the BIC condition, which we exploit here to achieve a narrow transparency band. We first show how to shift a canonical BIC in an all-dielectric metasurface, consisting of high-refractive disks exhibiting in- and out-of-plane magnetic dipole (MD) resonances, by tuning the periodicity of the array. By means of our coupled electric/magnetic dipole formulation, we show analytically that when the quasi-BIC overlaps with the broad (in-plane MD) resonance, a full transparency band emerges with diverging Q-factor upon approaching the BIC condition in parameter space. Finally, our experimental measurements in the microwave regime with a large array of high-refractive-index disks confirm the theoretical predictions. Our results reveal a simple mechanism to engineer an ultra-narrow BIC-induced transparency band that could be exploited throughout the electromagnetic spectrum with obvious applications in filtering and sensing.

physics.app-ph↗

arXiv2019

VO2 Nanocrystals for Designer Phase-Change Metamaterials

Subwavelength nanoparticles can support electromagnetic resonances with distinct features depending on their size, shape and nature. For example, electric and magnetic Mie resonances occur in dielectric particles, while plasmonic resonances appear in metals. Here, we experimentally demonstrate that the multipolar resonances hosted by VO2 nanocrystals can be dynamically tuned and switched thanks to the insulator-to-metal transition of VO2. Using both Mie theory and Maxwell Garnett effective medium theory, we retrieve the complex refractive index of the effective medium composed of a slab of VO2 nanospheres embedded in SiO2 and show that such a resulting metamaterial presents distinct optical tunability compared to unpatterned VO2. We further show that this provides a new degree of freedom to design low-loss phase-change metamaterials with designer optical tunability and actively controlled light scattering.

physics.optics↗

arXiv2019

Brewster quasi bound states in the continuum in all-dielectric metasurfaces from single magnetic-dipole resonance meta-atoms

Bound states in the continuum (BICs) are ubiquitous in many areas of physics, attracting especial interest for their ability to confine waves with infinite lifetimes. Metasurfaces provide a suitable platform to realize them in photonics; such BICs are remarkably robust, being however complex to tune in frequency-wavevector space.Here we propose a scheme to engineer BICs and quasi-BICs with single magnetic-dipole resonance meta-atoms. Upon changing the orientation of the magnetic-dipole resonances, we show that the resulting quasi-BICs,emerging from the symmetry-protected BIC at normal incidence, become transparent for plane-wave illumination exactly at the magnetic-dipole angle, due to a Brewster-like effect. While yielding infinite Q-factors at normalincidence(canonical BIC), these are termed Brewster quasi-BICs since a transmission channel is always allowed that slightly widens resonances at oblique incidences. This is demonstrated experimentally through reflectance measurements in the microwave regime with high-refractive-index mm-disk metasurfaces. Such Brewster-inspired configuration is a plausible scenario to achieve quasi-BICs throughout the electromagnetic spectrum inaccessible through plane-wave illumination at given angles, which could be extrapolated to other kind of waves.

physics.optics↗

arXiv2019

Experimental phase function and degree of linear polarization of cometary dust analogs

We present experimental phase function and degree of linear polarization curves for seven samples of cometary dust analogues namely: ground pieces of Allende, DaG521, FRO95002 and FRO99040 meteorites, Mg-rich olivine and pyroxene, and a sample of organic tholins. The experimental curves have been obtained at the IAA Cosmic Dust Laboratory at a wavelength of 520 nm covering a phase angle range from 3° to 175°. We also provide values of the backscattering enhancement (BCE) for our cometary analogue samples. The final goal of this work is to compare our experimental curves with observational data of comets and asteroids to better constrain the nature of cometary and asteroidal dust grains. All measured phase functions present the typical behavior for μm-sized cosmic dust grains. Direct comparison with data provided by the OSIRIS/Rosetta camera for comet 67P Churyumov-Gerasimenko reveals significant differences and supports the idea of a coma dominated by big chunks, larger than one micrometer. The polarization curves are qualitatively similar to ground-based observations of comets and asteroids. The position of the inversion polarization angle seems to be dependent on the composition of the grains.We find opposite dependence of the maximum of the polarization curve for grains sizes in the Rayleigh-resonance and geometric optics domains, respectively.

astro-ph.EP↗

arXiv2018

Models of Rosetta/OSIRIS 67P dust coma phase function

The phase function of the dust coma of comet 67P has been determined from Rosetta/OSIRIS images \citep{Bertini17}. This function show a deep minimum at phase angles near 100$^\circ$, and a strong backscattering enhancement. These two properties cannot be reproduced by regular models of cometary dust, most of them based on wavelength-sized and randomly-oriented aggregate particles. We show, however, that an ensamble of oriented elongated particles of a wide variety of aspect ratios, with radii $r \gtrsim$10 $μ$m, and whose long axes are perpendicular to the direction of the solar radiation, are capable of reproducing the observed phase function. These particles must be absorbing, with an imaginary part of the refractive index of about 0.1 to match the expected geometric albedo, and with porosity in the 60-70\% range.

astro-ph.EP↗

arXiv2017

Evaluation of effective medium theories for spherical nano-shells

Current effective medium theories for nano-shells are reviewed. A new method for calculating the effective dielectric function of a core-shell nanoparticle is presented and compared with existing theories showing clear advantages in most conditions. It consists of introducing radiating effects in the polariz- ability of the effective sphere, and considering the exact polarizability of the core-shell constructed from the Mie scattering coefficient. This new approach can be considered as an useful tool for designing coated particles with desired plasmonic properties and engineering the effective permittivity of composites with core-shell type inclusions which are used in photocatalysis and solar energy harvesting applications.

physics.optics↗

arXiv2017

Physical and dynamical properties of the anomalous comet 249P/LINEAR

Images and low-resolution spectra of the near-Earth Jupiter family comet (JFC) 249P/LINEAR in the visible range obtained with the instrument OSIRIS in the 10.4m Gran Telescopio Canarias on January 3, 4, 6 and February 6, 2016 are presented, together with a series of images obtained with the 0.4m telescope of the Great Shefford Observatory. The reflectance spectrum of 249P is similar to that of a B-type asteroid. The comet has an absolute (visual) nuclear magnitude $H_V=17.0\pm 0.4$, which corresponds to a radius of about 1-1.3 km for a geometric albedo $\sim 0.04-0.07$. From the analysis of GTC images using a Monte Carlo dust tail code we find that the time of maximum dust ejection rate was around 1.6 days before perihelion. We may be in front of a new class of near-Earth JFC whose source region is not the distant trans-neptunian population, but much closer in the asteroid belt. Therefore, 249P/LINEAR may be a near-Earth counterpart of the so-called main-belt comets or active asteroids.

astro-ph.EP↗

arXiv2017

The splitting of double-component active asteroid P/2016 J1 (PANSTARRS)

We present deep imaging observations, orbital dynamics, and dust tail model analyses of the double-component asteroid P/2016 J1 (J1-A and J1-B). The observations were acquired at the Gran Telescopio Canarias (GTC) and the Canada-France-Hawaii Telescope (CFHT) from mid March to late July, 2016. A statistical analysis of backward-in-time integrations of the orbits of a large sample of clone objects of P/2016 J1-A and J1-B shows that the minimum separation between them occurred most likely $\sim$2300 days prior to the current perihelion passage, i.e., during the previous orbit near perihelion. This closest approach was probably linked to a fragmentation event of their parent body. Monte Carlo dust tail models show that those two components became active simultaneously $\sim$250 days before the current perihelion, with comparable maximum loss rates of $\sim$0.7 kg s$^{-1}$ and $\sim$0.5 kg s$^{-1}$, and total ejected masses of 8$\times$10$^{6}$ kg and 6$\times$10$^{6}$ kg for fragments J1-A and J1-B, respectively. In consequence, the fragmentation event and the present dust activity are unrelated. The simultaneous activation times of the two components and the fact that the activity lasted 6 to 9 months or longer, strongly indicate ice sublimation as the most likely mechanism involved in the dust emission process.

astro-ph.EP↗

arXiv2016

Early evolution of disrupted asteroid P/2016 G1 (PANSTARRS)

We present deep imaging observations of activated asteroid P/2016 G1 (PANSTARRS) using the 10.4m Gran Telescopio Canarias (GTC) from late April to early June 2016. The images are best interpreted as the result of a relatively short-duration event with onset about $\mathop{350}_{-30}^{+10}$ days before perihelion (i.e., around 10th February, 2016), starting sharply and decreasing with a $\mathop{24}_{-7}^{+10}$ days (Half-width at half-maximum, HWHM). The results of the modeling imply the emission of $\sim$1.7$\times$10$^7$ kg of dust, if composed of particles of 1 micrometer to 1 cm in radius, distributed following a power-law of index --3, and having a geometric albedo of 0.15. A detailed fitting of a conspicuous westward feature in the head of the comet-like object indicates that a significant fraction of the dust was ejected along a privileged direction right at the beginning of the event, which suggests that the parent body has possibly suffered an impact followed by a partial or total disruption. From the limiting magnitude reachable with the instrumental setup, and assuming a geometric albedo of 0.15 for the parent body, an upper limit for the size of possible fragment debris of $\sim$50 m in radius is derived.

astro-ph.EP↗

arXiv2016

Electromagnetic polarization controlled perfect switching effect with high refractive index dimers. the beam-splitter configuration

High Refractive Index (HRI) dielectric particles smaller than the wavelength, isolated or forming a designed ensemble are ideal candidates as new multifunctional elements for building optical devices. Their directionality effects are traditionally analyzed through forward and backward measurements, even if these directions are not suitable for practical purposes. Here we present unambiguous experimental evidence in the microwave range that, for a dimer of HRI spherical particles, a perfect switching effect (perfect means off = null intensity) is observed out of those directions as a consequence of the mutual particle electric/magnetic interaction. The binary state depends on the excitation polarization (polarization switching). Its analysis is performed through the linear polarization degree of scattered radiation at a detection direction perpendicular to the incident direction: the beam-splitter configuration. The scaling property of Maxwell equations allows generalizing our results to other frequency range and dimension scales, for instance, the visible and the nanometric scale.

physics.optics↗

arXiv2016

Directional Fano Resonances at Light Scattering by a High Refractive Index Dielectric Sphere

In this research, we report the experimental evidence of the directional Fano resonances at the scattering of a plane, linearly polarized electromagnetic wave by a homogeneous dielectric sphere with high refractive index and low losses. We observe a typical asymmetric Fano profile for the intensity scattered in, practically, any given direction, while the overall extinction cross section remains Lorentzian. The phenomenon is originated in the interference of the selectively excited electric dipolar and quadrupolar modes. The selectivity of the excitation is achieved by the proper choice of the frequency of the incident wave. Thanks to the scaling invariance of the Maxwell equations, in these experiments we mimic the scattering of the visible and near IR radiation by a nanoparticle made of common superconductor materials (Si, Ge, GaAs, GaP) by the equivalent scattering of a spherical particle of 18 mm in diameter in the microwave range. The theory developed to explain the experiments extends the conventional Fano approach to the case when both interfering partitions are resonant. The perfect agreement between the experiment and the theory is demonstrated.

physics.optics↗

arXiv2015

Rhodium Nanoparticles for Ultraviolet Plasmonics

The non-oxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Raman spectra and accelerated photo-damage were observed under near-resonant ultraviolet illumination, while charge transfer simultaneously increased fluorescence for up to 13 minutes. The combined local field enhancement and charge transfer demonstrate essential steps toward plasmonically-enhanced ultraviolet photocatalysis.

cond-mat.mes-hall↗

arXiv2015

Short-term variability of comet C/2012 S1 (ISON) at 4.8 AU from the Sun

We observed comet C/2012 S1 (ISON) during six nights in February 2013 when it was at 4.8 AU from the sun. At this distance and time the comet was not very active and it was theoretically possible to detect photometric variations likely due to the rotation of the cometary nucleus. The goal of this work is to obtain differential photometry of the comet inner coma using different aperture radii in order to derive a possible rotational period. Large field of view images were obtained with a 4k x 4k CCD at the f/3 0.77m telescope of La Hita Observatory in Spain. Aperture photometry was performed in order to get relative magnitude variation versus time. Using calibrated star fields we also obtained ISON's R-magnitudes versus time. We applied a Lomb-Scargle periodogram analysis to get possible periodicities for the observed brightness variations, directly related with the rotation of the cometary nucleus. The comet light curve obtained is very shallow, with a peak-to-peak amplitude of 0.03 $\pm$ 0.02 mag. A tentative synodic rotational period (single-peaked) of 14.4 $\pm$ 1.2 hours for ISON's nucleus is obtained from our analysis, but there are other possibilities. We studied the possible effect of the seeing variations in the obtained periodicities during the same night, and from night to night. These seeing variations had no effect on the derived periodicity. We discuss and interpret all possible solutions for the rotational period of ISON's nucleus.

astro-ph.EP↗

arXiv2014

Spectral behavior of localized plasmon resonances in the near- and far-field regimes. Comment on The spectral shift between near- and far-field resonances of optical nano-antennas

In a recent paper by Menzel et al. (Opt. Exp. 22, 9971 (2014)), its authors analyze the spectral red-shift effect of plasmonic resonances of metallic nano-antennas between the far-field and near-field regimes. Here, we demonstrate that their interpretation of this effect is done under the same perspective as one recently reported in Langmuir 29, 6715 (2013); however, the former is incomplete and needs some remarks and clarifications which require additional relevant concepts and arguments of physical significance.

physics.optics↗

arXiv2013

The dust environment of Main-Belt Comet P/2012 T1 (PANSTARRS)

Main-Belt Comet P/2012 T1 (PANSTARRS) has been imaged using the 10.4m Gran Telescopio Canarias (GTC) and the 4.2m William Herschel Telescope (WHT) at six epochs in the period from November 2012 to February 2013, with the aim of monitoring its dust environment. The dust tails brightness and morphology are best interpreted in terms of a model of sustained dust emission spanning 4 to 6 months. The total dust mass ejected is estimated at $\sim$6--25$\times10^6$ kg. We assume a time-independent power-law size distribution function, with particles in the micrometer to centimeter size range. Based on the quality of the fits to the isophote fields, an anisotropic emission pattern is favored against an isotropic one, in which the particle ejection is concentrated toward high latitudes ($\pm45^\circ$ to $\pm90^\circ$) in a high obliquity object ($I$=80$^\circ$). This seasonally-driven ejection behavior, along with the modeled particle ejection velocities, are in remarkable agreement to those we found for P/2010 R2 (La Sagra) \citep{Moreno11a}.

astro-ph.EP↗