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Filippo Fratini

Publications and source records attributed to Filippo Fratini.

18 recordsLinked to original sources

Challenges and Opportunities in Quantum Optimization

Recent advances in quantum computers are demonstrating the ability to solve problems at a scale beyond brute force classical simulation. As such, a widespread interest in quantum algorithms has developed in many areas, with optimization being one of the most pronounced domains. Across computer science and physics, there are a number of different approaches for major classes of optimization problems, such as combinatorial optimization, convex optimization, non-convex optimization, and stochastic extensions. This work draws on multiple approaches to study quantum optimization. Provably exact versus heuristic settings are first explained using computational complexity theory - highlighting where quantum advantage is possible in each context. Then, the core building blocks for quantum optimization algorithms are outlined to subsequently define prominent problem classes and identify key open questions that, if answered, will advance the field. The effects of scaling relevant problems on noisy quantum devices are also outlined in detail, alongside meaningful benchmarking problems. We underscore the importance of benchmarking by proposing clear metrics to conduct appropriate comparisons with classical optimization techniques. Lastly, we highlight two domains - finance and sustainability - as rich sources of optimization problems that could be used to benchmark, and eventually validate, the potential real-world impact of quantum optimization.

quant-ph

Constructing a nanoscale optical polarizer with a graphene stack

Two-dimensional graphene layers exhibit many fascinating properties which have sparkled into applied research with the aim to build innovative electronic devices. Here, we theoretically demonstrate that, when the carriers velocity is constrained along one direction, a monoatomic graphene layer exhibits dichroism. A fraction $2πα$ of the light polarized along the carriers motion is absorbed, while light polarized perpendicularly to that direction is not absorbed. A stack of two-dimensional graphene layers whose carriers velocity is constrained along one direction (such as a stack subjected to a suitable gate voltage) is thus able to polarize light up to the wished degree by selective absorption. These findings pave the way for built-in controllable optical polarizers in upcoming graphene nanoscale devices.

cond-mat.mes-hall

Quantum interference in laser spectroscopy of highly charged lithiumlike ions

We investigate the quantum interference induced shifts between energetically close states in highly charged ions, with the energy structure being observed by laser spectroscopy. In this work, we focus on hyperfine states of lithiumlike heavy-$Z$ isotopes and quantify how much quantum interference changes the observed transition frequencies. The process of photon excitation and subsequent photon decay for the transition $2s\rightarrow2p\rightarrow2s$ is implemented with fully relativistic and full-multipole frameworks, which are relevant for such relativistic atomic systems. We consider the isotopes $^{207}$Pb$^{79+}$ and $^{209}$Bi$^{80+}$ due to experimental interest, as well as other examples of isotopes with lower $Z$, namely $^{141}$Pr$^{56+}$ and $^{165}$Ho$^{64+}$. We conclude that quantum interference can induce shifts up to 11% of the linewidth in the measurable resonances of the considered isotopes, if interference between resonances is neglected. The inclusion of relativity decreases the cross section by 35%, mainly due to the complete retardation form of the electric dipole multipole. However, the contribution of the next higher multipoles (e.g. magnetic quadrupole) to the cross section is negligible. This makes the contribution of relativity and higher-order multipoles to the quantum interference induced shifts a minor effect, even for heavy-$Z$ elements.

physics.atom-ph

Two-photon processes based on quantum commutators

We developed a new method to calculate two-photon processes in quantum mechanics that replaces the infinite summation over the intermediate states by a perturbation expansion. This latter consists of a series of commutators that involve position, momentum and hamiltonian quantum operators. We analyzed several single- and many-particle cases for which a closed form solution to the perturbation expansion exists, as well as more complicated cases for which a solution is found by convergence. Throughout the article, Rayleigh and Raman scattering are taken as examples of two-photon processes. The present method provides a clear distinction between the Thomson scattering, regarded as classical scattering, and quantum contributions. Such a distinction let us derive general results concerning light scattering. Finally, possible extensions to the developed formalism are discussed.

quant-ph

Full-quantum light diode

Unidirectional light transport in one-dimensional nanomaterials at the quantum level is a crucial goal to achieve for upcoming computational devices. We here employ a full-quantum mechanical approach based on master equation to describe unidirectional light transport through a pair of two-level systems coupled to a one-dimensional waveguide. By comparing with published semi-classical results, we find that the nonlinearity of the system is reduced, thereby reducing also the unidirectional light transport efficiency. Albeit not fully efficient, we find that the considered quantum system can work as a light diode with an efficiency of approximately 60%. Our results may be used in quantum computation with classical and quantized light.

quant-ph

Quantum interference shifts in laser spectroscopy with elliptical polarization

We investigate the quantum interference shifts between energetically close states, where the state structure is observed by laser spectroscopy. We report a compact and analytical expression that models the quantum interference induced shift for any admixture of circular polarization of the incident laser and angle of observation. An experimental scenario free of quantum interference can thus be predicted with this formula. Although, this study is exemplified here for muonic deuterium, it can be applied to any other laser spectroscopy measurement of $ns-n'p$ frequencies of a nonrelativistic atomic system, via a $ns\rightarrow n'p \rightarrow n"s $ scheme.

physics.atom-ph

Quantum interference effects in laser spectroscopy of muonic hydrogen, deuterium, and helium-3

Quantum interference between energetically close states is theoretically investigated, with the state structure being observed via laser spectroscopy. In this work, we focus on hyperfine states of selected hydrogenic muonic isotopes, and on how quantum interference affects the measured Lamb shift. The process of photon excitation and subsequent photon decay is implemented within the framework of nonrelativistic second-order perturbation theory. Due to its experimental interest, calculations are performed for muonic hydrogen, deuterium, and helium-3. We restrict our analysis to the case of photon scattering by incident linear polarized photons and the polarization of the scattered photons not being observed. We conclude that while quantum interference effects can be safely neglected in muonic hydrogen and helium-3, in the case of muonic deuterium there are resonances with close proximity, where quantum interference effects can induce shifts up to a few percent of the linewidth, assuming a pointlike detector. However, by taking into account the geometry of the setup used by the CREMA collaboration, this effect is reduced to less than 0.2% of the linewidth in all possible cases, which makes it irrelevant at the present level of accuracy.

physics.atom-ph

Relativistic evaluation of the two-photon decay of the metastable ${1s}^{2} 2s 2p~^3\mbox{P}_0$ state in berylliumlike ions with an active-electron model

The two-photon ${1s}^{2} 2s 2p~^3\mbox{P}_0 \rightarrow {1s}^{2} {2s}^2$ $^1\mbox{S}_0$ transition in berylliumlike ions is theoretically investigated within a full relativistic framework and a second-order perturbation theory. We focus our analysis on how electron correlation, as well as the negative-energy spectrum can affect the forbidden $E1M1$ decay rate. For this purpose we include the electronic correlation by an effective potential and within an active-electron model. Due to its experimental interest, evaluation of decay rates are performed for berylliumlike xenon and uranium. We find that the negative-energy contribution can be neglected in the present decay rate. On the other hand, if contributions of electronic correlation are not carefully taken into account, it may change the lifetime of the metastable state by 20\%. By performing a full-relativistic $jj$-coupling calculation, we found discrepancies for the decay rate of an order of 2 compared to non-relativistic $LS$-coupling calculations, for the selected heavy ions.

physics.atom-ph

Spin effects probed by Rayleigh X-ray scattering off hydrogenic ions

We study the polarization characteristics of x-ray photons scattered by hydrogenic atoms, based on the Dirac equation and second-order perturbation theory. The relativistic states used in calculations are obtained using the finite basis set method and expressed in terms of B-splines and B-polynomials. We derive general analytical expressions for the polarization-dependent total cross sections, which are applicable to any atom and ion, and evaluate them separately for linear and circular polarization of photons. In particular, detailed calculations are performed for the integrated Stokes parameters of the scattered light for hydrogen as well as hydrogenlike neon and argon. Analyzing such integrated Stokes parameters, special attention is given to the electron-photon spin-spin interaction, which mostly stems from the magnetic-dipole contribution of the electron-photon interaction. Subsequently, we find an energy window for the selected targets in which such spin-spin interactions can be probed.

physics.atom-ph

Angular and polarization analysis for two-photon decay of 2s hyperfine states of hydrogenlike Uranium

The amplitude of two-photon transitions between hyperfine states in hydrogenlike ions is derived based on relativistic Dirac equation and second order perturbation theory. We study angular and linear polarization properties of the photon pair emitted in the decay of $2s$ states, where spin-flip and non-spin-flip transitions are highlighted. We pay particular attention to hydrogenlike uranium, since it is an ideal candidate for investigating relativistic and high-multipole effects, such as spin-flip transitions. Two types of emission patterns are identified: i) non-spin-flip transitions are found to be characterized by an angular distribution of the type $W(θ)\sim1+\cos^2θ$ while the polarizations of the emitted photons are parallel; ii) spin-flip transitions have somewhat smaller decay rates and are found to be characterized by an angular distribution of the type $W(θ)\sim1-1/3\cos^2θ$ while the polarizations of the emitted photons are orthogonal, where $θ$ is the angle between photons directions. Deviations due to non-dipole and relativistic contributions are evaluated for both types of transitions. This work is the first step toward exploring the effect of nucleus over the the angular and polarization properties of the photon pairs emitted by two-photon transitions.

physics.atom-ph

Quantum mechanical evolution operator in the presence of a scalar linear potential: discussion on the evolved state

We discuss the form of the wave-function of a state subjected to a scalar linear potential, paying special attention to quantum tunneling. We analyze the phases acquired by the evolved state and show that some of them have a pure quantum mechanical origin. In order to measure one of these phases, we propose a simple experimental scenario. We finally apply the evolution equations to re-analyze the Stern\&Gerlach experiment and to show how to manipulate spin by employing constant electric fields.

quant-ph

Relativistic polarization analysis of Rayleigh scattering by atomic hydrogen

A relativistic analysis of the polarization properties of light elastically scattered by atomic hydrogen is performed, based on the Dirac equation and second order perturbation theory. The relativistic atomic states used for the calculations are obtained by making use of the finite basis set method and expressed in terms of $B$ splines and $B$ polynomials. We introduce two experimental scenarios in which the light is circularly and linearly polarized, respectively. For each of these scenarios, the polarization-dependent angular distribution and the degrees of circular and linear polarization of the scattered light are investigated as a function of scattering angle and photon energy. Analytical expressions are derived for the polarization-dependent angular distribution which can be used for scattering by both hydrogenic as well as many-electron systems. Detailed computations are performed for Rayleigh scattering by atomic hydrogen within the incident photon energy range 0.5 to 10 keV. Particular attention is paid to the effects that arise from higher (nondipole) terms in the expansion of the electron-photon interaction.

physics.atom-ph

Angular and polarization correlations in two--photon decay of hyperfine 2s states in hydrogenlike ions

The angular and polarization properties of the photon pair emitted in the two--photon decay of $2s$ hyperfine states in hydrogenlike ions are investigated within the relativistic Dirac framework and second order perturbation theory. The studied transitions are $2s_{1/2}\,(F=1,0)\to1s_{1/2}\,(F=1,0)$ in Hydrogen atom and $2s_{1/2}\,(F=4,3)\to1s_{1/2}\,(F=4,3)$ in hydrogenlike Uranium ion. Two different emission patterns are found: For non-spin-flip transitions, the angular correlation ($i.e.$ the angular distribution of the emitted photons) is of the type $\sim 1+\cos^2θ$, while the linear polarizations of the emitted photons are approximately parallel one another; For spin-flip transitions, the angular correlation is of the type $\sim 1-1/3\cos^2θ$, while the linear polarizations of the emitted photons are approximately orthogonal one another.

physics.atom-ph

Underlining some limitations of the statistical formalism in quantum mechanics

We show that two chosen ensembles of spin states, which are differently prepared but are described by the same density matrix in quantum mechanics, do not fully share the same measurable characteristics. One characteristic on which they differ is shown to be the variance of the spin along a given direction. We conclude that the statistical description of an ensemble of states as given by its density matrix, although sufficient in many cases, should be considered incomplete, as it does not fully describe the measurable characteristics of the ensemble. A discussion a posteriori on the problem is provided.

quant-ph

Photon-photon polarization correlations as a tool for studying parity non-conservation in heliumlike Uranium

Due to electron-nucleus weak interaction, atomic bound states with different parities turn out to be mixed. We discuss a prospect for measuring the mixing parameter between the nearly degenerate metastable states 1s_{1/2} 2s_{1/2} : J = 0 and 1s_{1/2} 2p_{1/2} : J = 0 in heliumlike Uranium. Our analysis is based on the polarization properties of the photons emitted in the two-photon decays of such states.

physics.atom-ph

Quantum correlations in the two-photon decay of few-electron ions

A theoretical study of the polarization entanglement of two photons emitted in the decay of metastable ionic states is performed within the framework of density matrix theory and second-order perturbative approach. Particular attention is paid to relativistic and non-dipole effects that become important for medium- and high-$Z$ ions. To analyze these effects, the degree of entanglement is evaluated both in the dipole approximation and within the rigorous relativistic theory. Detailed calculations are performed for the two-photon $2s_{1/2}\to 1s_{1/2}$ transition in hydrogen-like, as well as for the $1s_{1/2}\, 2s_{1/2} \; {}^1S_0 \to 1s_{1/2}^2 \; {}^1S_0$, $1s_{1/2} \, 2s_{1/2} \; {}^3S_1\to 1s_{1/2}^2 \; {}^1S_0$ and $1s_{1/2} \, 2p_{1/2} \; {}^3P_0\to 1s_{1/2}^2 \; {}^1S_0$ transitions in helium-like ions.

physics.atom-ph

Polarization correlations in the two--photon decay of hydrogen--like ions

Polarization properties of the photons emitted in the two-photon decay of hydrogen-like ions are studied within the framework of the density matrix and second-order perturbation theory. In particular, we derive the polarization correlation function that gives the probability of the (two-photon) coincidence measurement performed by polarization-sensitive detectors. Detailed calculations of this function are performed for the $2s_{1/2} \to 1s_{1/2}$ transition in neutral hydrogen as well as Xe$^{53+}$ and U$^{91+}$ ions. The obtained results allow us to understand the influence of relativistic and non-dipole effects on the polarization correlations in the bound-bound two-photon transitions in heavy ions.

physics.atom-ph