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Florian Schwarz

Publications and source records attributed to Florian Schwarz.

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Lie groups in tangent join restriction categories

Principal bundles have at least three different definitions, depending on the category of geometric objects studied. In Differential Geometry, they are defined as locally trivial projection map of smooth manifolds with an atlas whose transition maps are given by group multiplication. In Topology they are $G$-equivariantly trivial $G$-spaces. In Algebraic Geometry, they are Étale locally isotrivial geometric quotients of $G$-varieties. The goal of this work is to have a categorical notion that recovers all of them. While they are different structures, they are all locally isomorphic to the Cartesian product of a base space with a group. There are a variety of other results on group objects and their tangent bundle. In particular we show that the tangent bundle is the product of the tangent space and the group object and that the tangent space has an external Lie algebra structure, generalizing the correspondence between Lie groups and Lie algebras. In order to give a purely categorical definition of a principal bundle, we formulate this notion in the language of join restriction categories. Restriction categories were developed by Cockett and Lack to generalize partial maps (maps defined only on a subset of the domain) and have since then found applications in mathematics and computer science. Join restriction categories, as described by Guo are restriction categories where local restrictions can be joined to obtain a global map. Together with a manifold construction due to Grandis, that allows us to glue together objects, we can describe principal bundles entirely in the language of join-restriction categories.

math.CT

The dimension of the tangent bundle and the universality of the vertical lift

This paper explores a new perspective on the universality of the vertical lift in tangent categories by presenting a categorification of the dimension of smooth manifolds. The universality of the vertical lift is a key part of the axioms of a tangent category as presented in [4]. The categorical dimension presented in this paper provides insight into the nature of this property. The main result is Theorem 3.7, showing that if it exists, the dimension of the tangent bundle must fulfill an equation relating the dimension of the tangent bundle to the dimension of the base. In particular, when the dimension function is a strong tangent dimension, Theorem 3.8 shows that the dimension of the tangent bundles is either twice the dimension of the base, or equal to the dimension of the base. Many examples of dimension functions are provided to demonstrate the utility of the definition. In particular, a consequence of Theorem 3.7 is that there are limitations on which functors may be tangent bundle endofunctors for a category. We show that this means that there are no non-trivial tangent structures on sets, as an example.

math.CT

Differential bundles as functors from free modules

This paper explores differential bundles in tangent categories, characterizing them as functors from a structure category. This is analogous to the actegory perspective of Garner and Leung, which we also use to describe the tangent categories of Rosický, Cockett and Cruttwell. We generalize the Garner-Leung equivalence between tangent categories and Weil algebra actegories to include lax functors and non-linear natural transformations. The main result of this paper, is that differential functors between the structure category $\mathbb N^\bullet$ and a tangent category $\mathbb X$ are equivalent to differential bundles in $\mathbb X$. We obtain this result by showing that evaluating a differential functor on the generating object $\mathbb N^1$ of the structure category $\mathbb N^\bullet$ produces a differential bundle in a functorial way. Every differential bundle can be obtained this way. We show that obtaining such a functor from a bundle is a functorial construction. There are variations of these results for linear and additive morphisms of differential bundles.

math.CT

MetaMP: Seamless Metadata Enrichment and AI Application Framework for Enhanced Membrane Protein Visualization and Analysis

Structural biology has made significant progress in determining membrane proteins, leading to a remarkable increase in the number of available structures in dedicated databases. The inherent complexity of membrane protein structures, coupled with challenges such as missing data, inconsistencies, and computational barriers from disparate sources, underscores the need for improved database integration. To address this gap, we present MetaMP, a framework that unifies membrane-protein databases within a web application and uses machine learning for classification. MetaMP improves data quality by enriching metadata, offering a user-friendly interface, and providing eight interactive views for streamlined exploration. MetaMP was effective across tasks of varying difficulty, demonstrating advantages across different levels without compromising speed or accuracy, according to user evaluations. Moreover, MetaMP supports essential functions such as structure classification and outlier detection. We present three practical applications of Artificial Intelligence (AI) in membrane protein research: predicting transmembrane segments, reconciling legacy databases, and classifying structures with explainable AI support. In a validation focused on statistics, MetaMP resolved 77% of data discrepancies and accurately predicted the class of newly identified membrane proteins 98% of the time and overtook expert curation. Altogether, MetaMP is a much-needed resource that harmonizes current knowledge and empowers AI-driven exploration of membrane-protein architecture.

cs.LG

Charge Transport and Conductance Switching of Redox-active Azulene Derivatives

Azulene (Az) is a non-alternating, aromatic hydrocarbon composed of a five-membered, electron-rich and a seven-membered, electron-poor ring; an electron distribution that provides intrinsic redox activity. By varying the attachment points of the two electrode-bridging substituents to the Az centre, the influence of the redox functionality on charge transport is evaluated. The conductance of the 1,3 Az derivative is at least one order of magnitude lower than those of the 2,6 Az and 4,7 Az derivatives, in agreement with density functional theory (DFT) calculations. In addition, only 1,3 Az exhibits pronounced nonlinear current-voltage characteristics with hysteresis, indicating a bias-dependent conductance switching. DFT identifies the LUMO to be nearest to the Fermi energy of the electrodes, but to be an active transport channel only in the case of the 2,6 and the 4,7 Az derivatives, whereas the 1,3 Az derivative uses the HOMO at low and the LUMO+1 at high bias. In return, the localized, weakly coupled LUMO of 1,3 Az creates a slow electron-hopping channel responsible for the voltage-induced switching due to the occupation of a single MO.

cond-mat.mes-hall

Field-induced Conductance Switching by Charge-state Alternation in Organometallic Single-Molecule Junctions

Charge transport through single molecules can be influenced by the charge and spin states of redox-active metal centres placed in the transport pathway. These molecular intrinsic properties are usually addressed by varying the molecules electrochemical and magnetic environment, a procedure that requires complex setups with multiple terminals. Here we show that oxidation and reduction of organometallic compounds containing either Fe, Ru or Mo centres can solely be triggered by the electric field applied to a two-terminal molecular junction. Whereas all compounds exhibit bias-dependent hysteresis, the Mo-containing compound additionally shows an abrupt voltage-induced conductance switching, yielding high to low current ratios exceeding 1000 at voltage stimuli of less than 1.0 V. DFT calculations identify a localized, redox active molecular orbital that is weakly coupled to the electrodes and closely aligned with the Fermi energy of the leads because of the spin-polarised ground state unique to the Mo centre. This situation opens an additional slow and incoherent hopping channel for transport, triggering a transient charging effect of the entire molecule and a strong hysteresis with unprecedented high low-to-high current ratios.

cond-mat.mes-hall

High-Conductive Organometallic Molecular Wires with Delocalized Electron Systems Strongly Coupled to Metal Electrodes

Besides active, functional molecular building blocks such as diodes or switches, passive components as, e.g., molecular wires, are required to realize molecular-scale electronics. Incorporating metal centers in the molecular backbone enables the molecular energy levels to be tuned in respect to the Fermi energy of the electrodes. Furthermore, by using more than one metal center and sp-bridging ligands, a strongly delocalized electron system is formed between these metallic "dopants", facilitating transport along the molecular backbone. Here, we study the influence of molecule--metal coupling on charge transport of dinuclear X(PP)$_2$FeC$_4$Fe(PP)$_2$X molecular wires (PP = Et$_2$PCH$_2$CH$_2$PEt$_2$); X = CN (1), NCS (2), NCSe (3), C$_4$SnMe$_3$ (4) and C$_2$SnMe$_3$ (5)) under ultra-high vacuum and variable temperature conditions. In contrast to 1 which showed unstable junctions at very low conductance ($8.1\cdot10^{-7}$ G$_0$), 4 formed a Au-C$_4$FeC$_4$FeC$_4$-Au junction 4' after SnMe$_3$ extrusion which revealed a conductance of $8.9\cdot10^{-3}$ G$_0$, three orders of magnitude higher than for 2 ($7.9\cdot10^{-6}$ G$_0$) and two orders of magnitude higher than for 3 ($3.8\cdot10^{-4}$ G$_0$). Density functional theory (DFT) confirmed the experimental trend in the conductance for the various anchoring motifs. The strong hybridization of molecular and metal states found in the C--Au coupling case enables the delocalized electronic system of the organometallic Fe$_2$ backbone to be extended over the molecule-metal interfaces to the metal electrodes to establish high-conductive molecular wires.

cond-mat.mes-hall