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François Boulogne

Publications and source records attributed to François Boulogne.

At least 19 recordsLinked to original sources

Stabilising Evaporating Soap Films with Salt

We investigate the effect of a high concentration (32.5 g.L$^{-1}$) of sodium chloride (NaCl) on TTAB (tetradecyltrimethylammonium bromide) vertical soap films also called foam films, pulled out of a bath under controlled humidity conditions. We observe that the film lifetime increases with relative humidity, both in the presence and absence of salt. At any given humidity, the presence of NaCl systematically enhances film stability. Our film thickness measurements show that the thinning dynamics with or without salt are nearly identical down to 100 nm. Down to that thickness, the effect of evaporation can be rationalised by a constant evaporation rate, which becomes non-negligible compared to the drainage rate at film thicknesses below 400 nm. The main effect of salt is the stabilisation of a Newton black film at a thickness of approximately 5~nm, whereas in the absence of salt, the film ruptures upon reaching a critical thickness of about 10 nm.

physics.flu-dyn↗

White light interferometry analysis for measuring thin film thickness down to few nanometers

We present a practical white-light interferometric method, supported by an open-source Python library \textit{optifik} for automated spectrum-to-thickness deduction, enabling foam film measurements down to a few nanometers. We describe three typical spectral scenarii encountered in this method: spectra exhibiting numerous interference fringes, spectra with a moderate number of peaks, and spectra with only a few identifiable features, providing illustrative examples for each case. We also discuss the main limitations of the technique, including spectral range constraints, the necessity of knowing the refractive index, and the influence of spectral resolution and signal quality. Finally, we demonstrate the application of the method in a time-resolved study of a TTAB (tetradecyltrimethylammonium bromide) foam film undergoing elongation and thinning. This method can be adapted to measure any thin non-opaque layer.

physics.optics↗

Crystal growth at a liquid-liquid interface upon drop impact

The crystallisation that occurs when a drop is placed in contact with a cold surface is a particularly challenging phenomenon to capture experimentally and describe theoretically. The situation of a liquid-liquid interface, where crystals appear on a mobile interface is scarcely studied although it provides a defect-free interface. In this paper, we quantify the dynamics of crystals appearing upon the impact of a drop on a cool liquid bath. We rationalize our observations with a model considering that crystals appear at a constant rate depending on the thermal shock on the expanding interface. This model provides dimensionless curves on the number and the surface area of crystals that we compare to our experimental measurements.

physics.flu-dyn↗

Reducing Foam Friction with Self Slippery Liquid-Infused Porous Surfaces

Acquiring a comprehensive understanding of the interplay between foam friction and surface roughness is essential for achieving precise control over their flow dynamics. In particular, a major challenge is to reduce friction, which can be achieved with rough surfaces in the situation where a liquid infuses the asperities. In this study, we propose to explore self-infused surfaces. We first present simple observations to demonstrate the effectiveness of our surface design by recording the motion of a foam puddle on a smooth surface and a self-SLIPS. To quantify friction reduction, we conduct stress measurements on surfaces moved at a constant velocity. Finally, we interpret the variation of the friction force with the velocity by a model considering an effective slip length of the surface. This research paves the way for a novel approach to mitigate dissipation in liquid foam flows, holding significant implications for reducing energy consumption in conveying foams for industrial processes and various end-use applications.

physics.flu-dyn↗

Thermal effects on the lifetime of evaporating drops on fibers

We present an experimental study on the evaporation of drops on fibers. More specifically, we focus on the droplet lifetime both in quiescent air and in an air flow of constant velocity. We propose a model to describe the evaporation rate and lifetime in a purely diffusive regime, which includes the liquid cooling associated with evaporation and the thermal conductivity of the atmosphere and the fiber. Our model effectively captures the primary physical behaviors, demonstrating a semi-quantiative agreement with our measurements across various liquids and fiber materials. Finally, the model is generalized to a convective air flow, which also rationalizes our experimental data.

physics.flu-dyn↗

Flat-cupped transition in freezing drop impacts

We present an experimental study on the freezing of alkane drops impacted on a liquid bath. More specifically, for drops of hexadecane and tetradecane on brine, we found a morphological transition of the solid between a flat disk and a cupped shape. We show that this transition depends mainly on melting temperature and thermal shock, and varies weakly with impact velocity. We observed that the impact dynamics does not depend on the thermal shock before the drop starts to solid ify, which allows a rationalization of the solid size by models established for impact without phase change. Finally, we show that the relevant timescale setting the onset of solidification is associated with the formation of a thin solid layer between the drop and the bath, a timescale much shorter than the total solidification time. These findings offer the possibility to collapse the data for both liquids in a single phase diagram.

cond-mat.soft↗

Straight to zigzag transition of foam pseudo Plateau borders on textured surfaces

The structure of liquid foams follows simple geometric rules formulated by Plateau 150 years ago. By placing such foam on a microtextured hydrophilic surface, we show that the bubble footprint exhibits a morphological transition. This transition concerns the liquid channels, also called pseudo Plateau borders, which are straight between vertices on a smooth surface. We demonstrate experimentally that for a sufficiently large roughness size compared to the width of the liquid channels, the footprint adopts a zigzag shape. This transition is associated with the absence of a wetting film between the pillars caused by capillary suction of the foam, observed by confocal microscopy. We rationalize the number of zigzag segments by a geometric distribution describing the observations made with the footprint perimeter and the mesh size of the asperities.

cond-mat.soft↗

Lifetime of vertical giant soap films: role of the relative humidity and film dimensions

We consider the lifetime of rectangular vertical soap films and we explore the influence of relative humidity and both dimensions on the stability of large soap films, reaching heights of up to 1.2 m. Using an automated rupture detection system, we achieve a robust statistical measurement of their lifetimes and we also measure the film thinning dynamics. We demonstrate that drainage has a negligible impact on the film stability as opposed to evaporation. To do so, we compare the measured lifetimes with predictions from the Boulogne \& Dollet model \cite{BoulogneDollet2018}, originally designed to describe the convective evaporation of hydrogels. Interestingly, we show that this model can predict a maximum film lifetime for all sizes.

cond-mat.soft↗

Interface-templated crystal growth in sodium dodecyl sulfate solutions with NaCl

Many ionic surfactants, such as sodium dodecyl sulphate (SDS) crystallize out of solution if the temperature falls below the crystallization boundary. The crystallization temperature is impacted by solution properties, and can be decreased with the addition of salt. We have studied SDS crystallization a t the liquid/vapor interfaces from solutions at high ionic strength (sodium chloride). We show that the surfactant crystals at the surface grow from adsorbed SDS molecules, as evidenced by the preferential orientation of the crystals identified using grazing incidence X-ray diffraction. We find a unique timescale f or the crystal growth from the evolution of structure, surface tension, and visual inspection, which can be controlled through varying the SDS or NaCl concentrations.

cond-mat.soft↗

Measuring relative humidity from evaporation with a wet-bulb thermometer: the psychrometer

Measuring the relative humidity of air is an important challenge for meteorological measurements, food conservation, building design, and evaporation control, among other applications. Relative humidity can be measured with a psychrometer, which is a hygrometer composed of two identical thermometers. The bulb of one thermometer is covered by a wick soaked with water so that evaporative cooling makes it indicate a lower temperature than the dry-bulb thermometer; it is possible to determine the relative humidity from the difference between these readings. We describe both a model and an experimental setup to illustrate the principle of a psychrometer for a pedagogical laboratory. The science of psychrometry could be more broadly taught at the undergraduate level to help introduce students to aspects of measurement techniques, fluid mechanics, heat transfer, and non-equilibrium thermodynamics.

physics.ed-ph↗

Evaporation-induced temperature gradient in a foam column

Various parameters affect the foam stability: surface and bulk rheology of the solution, gravitational drainage, mechanical vibrations, bubble gas composition, and also evaporation. Evaporation is often considered through the prism of a liquid loss, but it also induces a cooling effect due to the enthalpy of vaporization. In this study, we combine a theoretical and experimental approach to explore the temperature field in a foam column evaporating from the top. We show that a measurable temperature profile exists in this geometry with temperatures at the interface lower than the environmental temperature by few degrees. We demonstrate that the temperature profile is the result of a balance between the enthalpy of vaporization and heat fluxes originating from the thermal conduction of foam and air and the thermal radiation. For small foam thicknesses compared to the radius, we found that the temperature gradient is established over the foam thickness while for large aspect ratios, the gradient is spanning over a lengthscale comparable to the tube radius.

cond-mat.soft↗

Analytical prediction of the temperature and the lifetime of an evaporating spherical droplet

In this paper, we propose to predict analytically the temperature of an evaporating spherical droplet. To do so, we first review, from data in the literature, the effect of temperature on the physical parameters involved in cooling-induced evaporation, namely the saturating vapor pressure, the diffusion coefficient of vapor in air, the liquid density, the enthalpy of vaporization and the thermal conductivity of air. These data support a series of approximations that allows us to derive an implicit equation for the liquid temperature. We propose a quadratic approximation of the variation of the saturating vapor concentration with temperature to obtain an explicit prediction of the drop temperature. As a result, an analytical prediction of the droplet lifetime including the cooling effect is proposed.

physics.flu-dyn↗

Dynamics of bubbles spontaneously entering in a tube

When an open tube of small diameter touches a bubble of a larger diameter, the bubble spontaneously shrinks and pushes a soap film in the tube. We characterize the dynamics for different bubble sizes and number of soap films in the tube. We rationalize this observation from a mechanical force balance involving the Laplace pressure of the bubble and the viscous force from the advancing soap lamellae in the tube. We propose a numerical resolution of this model, and an analytical solution in an asymptotic regime. These predictions are then compared to the experiments. The emptying duration is primarily affected by the initial bubble to tube diameter ratio and by the number of soap films in the tube.

cond-mat.soft↗

Coffee stain effect on a fibre from axisymmetric droplets

The so-called coffee stain effect has been intensively studied over the past decades, but most of the studies are focused on sessile droplets. In this paper, we analyse the origin of the difference between the deposition of suspended particles in a sessile drop and in an axisymmetric drop deposited on a fibre. First, we model the shape of a drop on a fibre and its evaporative flux with some approximations to derive analytical calculations. Then, for pinned contact lines, we solve the hydrodynamics equations in the liquid phase under the lubrication approximation to determine the flow velocity toward the contact lines. We comment these results by comparison to a sessile drop of similar evaporating conditions, and we show that the substrate curvature plays a role on the contact line depinning, the local evaporative flux, and the liquid flow field. The competition between the advection and the Brownian motion indicates that the transport of the particles toward the contact line occurs in a volume localised in the close vicinity of the contact lines for a drop on a fibre. Thus, the fibre geometry induces a weaker accumulation of particles at the contact line compared to a sessile drop, leading to the more homogeneous deposit observed experimentally.

physics.flu-dyn↗

Measurement of the temperature decrease in evaporating soap films

Recent advances have demonstrated that evaporation can play a significant role on soap film stability, which is a key concern in many industrial areas but also for children playing with bubbles. Thus, evaporation leads to a film thinning but also to a film cooling, which has been overlooked for soapy objects. Here, we study the temperature variation of an evaporating soap film for different values of relative humidity and glycerol concentrations. We evidence that the temperature of soap films can decrease after their creation up to 8$~^\text{o}$C. We propose a model describing the temperature drop of soap films after their formation that is in quantitative agreement with our experiments. We emphasize that this cooling effect is significant and must be carefully considered in future studies on the dynamics of soap films.

cond-mat.soft↗

Evaporation of liquid coating a fiber

We investigate theoretically and numerically the diffusion-limited evaporation of a liquid deposited on a fiber in two configurations: a sleeve and a axisymmetric barrel-shaped droplet. For a sleeve, the local flux depends on both the aspect ratio and the smallest length of the problem. By using analytical calculations and 3D finite elements simulations, we predict a divergence of this flux further localized at the edge as the aspect ratio increases. The evaporation of axisymmetric drops on a fiber is studied with numerical simulations. For sufficiently large volumes, we evidence that the evaporation rate is almost independent of the wetting properties of the liquid, even for small contact angles, and that the droplets evaporate as spheres of the same volume.

cond-mat.soft↗

Impact of physical-chemistry on the film thinning in surface bubbles

In this paper, we investigate the thinning dynamics of evaporating surfactant-stabilised surface bubbles by considering the role of the physical-chemistry of solutions used in the liquid bath. We study the impact of the surfactant concentration below and above the cmc (critical micelle concentration) and the role of ambient humidity. First, in a humidity-saturated atmosphere, we show that if the initial thickness depends on the surfactant concentration and is limited by the surface elasticity, the drainage dynamics are very well described from the capillary and gravity contributions. These dynamics are independent of the surfactant concentration. In a second part, our study reveals that the physical-chemistry impacts the thinning dynamics through evaporation. We include in the model the additional contribution due to evaporation, which shows a good description of the experimental data below the cmc. Above the cmc, although this model is unsatisfactory at short times, the dynamics at long times is correctly rendered and we establish that the increase of the surfactant concentration decreases the impact of evaporation. Finally, the addition of a hygroscopic compound, glycerol, can be also rationalized by our model. We demonstrate that glycerol decreases the bubble thinning rate at ambient humidity, thus increasing their stability.

cond-mat.soft↗

Drop freezing: fine detection of contaminants by measuring the tip angle

In this Letter, we show that the shape of a freezing drop of water can be sensitive to the presence of impurities. We measure the tip angle of water drops frozen on a cold plate. The fine changes in tip angle are robustly captured by our image analysis method, which shows a deviation from that of pure water in solutions with salt (NaCl), polymer (PEG) and surfactant (TTAB) starting at concentrations of $10^{-6}$, $10^{-4}$ and $10^{-6}$ M respectively. The method could be adapted into a portable water purity tester, but the work also highlights the complexity of water freezing as it is influenced by trace concentrations of impurities.

cond-mat.soft↗