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François Léonard

Publications and source records attributed to François Léonard.

At least 19 recordsLinked to original sources

Bulk-dissociated topological bands without spin-orbit coupling in hetero-dimensional superconducting metamaterials

Topological superconductors (TSCs) in superconducting hybrid heterostructures, which integrate superconducting and non-superconducting materials, have been intensely investigated with the hope of discovering exotic non-Abelian anyons for fault-tolerant quantum computing. In this effort, a challenge for hybrid superconducting systems is controlling hybridization, which is often a balance between enhancing the superconducting proximity effect at the cost of suppressing desirable electronic properties such as strong spin-orbit interactions. Hence, discovering hybrid superconducting systems with topological properties controlled and enhanced by material geometry design without spin-orbit interactions would be intriguing to explore. In this work, we theoretically study a square superconducting network decorated with spin-polarized magnetic adatoms. We find that localized Yu-Shiba-Rusinov bound states at magnetic adatom sites collectively form a weak topological superconducting phase despite the absence of spin-orbit interactions. We then demonstrate that by tuning the Fermi energy of the network, the system can transition from a weak TSC phase to a bulk-dissociated TSC phase where the edge state bands separate from the bulk, giving rise to unexpected features such as nodal lines and co-existing bulk-dissociated edge and corner modes. Moreover, our findings highlight how hetero-dimensional superconducting metamaterials can serve as a useful template for controlling the coupling and dissociation between electronic degrees of freedom of different dimensionalities.

cond-mat.supr-con↗

A self-heating electrochemical cell with nine decades of programmable linear resistance

A programmable linear resistor with a compact footprint would have profound implications for microelectronics, enabling efficient in-sensor analog signal processing and in-memory computing. Non-volatile memory offers a potential solution but suffers from limitations due to the programming mechanisms that confine switching to nanoscale constrictions or field-sensitive semiconductor junctions, leading to non-linear current-voltage relationships and errors. Here, we introduce a tunable resistor that is programmed into non-volatile, high-precision resistance states spanning nine orders of magnitude, with linear current-voltage characteristics across the entire range -- significantly improving the performance and widening the application space of resistive memory. A key advance is an electrothermal gate that simultaneously spreads heat and electrochemical reactions during programming to enable large, bulk composition modulation. The volumetric modulation can host thousands of linear resistance states with 100x lower conductance errors than other memory. This enables direct processing of analog signals with high fidelity, and we demonstrate variable-gain amplification, division, and multiplication. Integration with CMOS is used to show resilience to electrical and thermal disturb in arrays and to demonstrate retention of analog levels at <1% average loss for more than 2 months across 100 devices. Simulations indicate matrix multiplication efficiency could approach >1,000 TOPS/W.

cs.ET↗

Perfect supercurrent diode efficiency in chiral nanotube-based weak links

The supercurrent diode effect (SDE) describes superconducting systems where the magnitude of the superconducting-to-normal state switching current differs for positive and negative current bias. Despite the ubiquity of such diode effects in Josephson devices, the fundamental conditions to observe a diode effect in a Josephson junction and achieve perfect diode efficiency remain unclear. In this work, we analyze the supercurrent diode properties of a chiral nanotube-based Josephson junction within a Ginzburg-Landau theory. We find a diode effect and anomalous phase develop across the junction when a magnetic field is applied parallel to the tube despite the absence of spin-orbit interactions in the system. Unexpectedly, the SDE in the junction is independent of the anomalous phase. Alternatively, we determine a non-reciprocal persistent current that is protected by fluxoid quantization can activate SDE, even in the absence of higher-order pair tunneling processes. We show this new type of SDE can lead to, in principle, a perfect diode efficiency, highlighting how persistent currents can be used to engineer high efficiency supercurrent diodes.

cond-mat.supr-con↗

ELEQTRONeX: A GPU-Accelerated Exascale Framework for Non-Equilibrium Quantum Transport in Nanomaterials

Non-equilibrium electronic quantum transport is crucial for the operation of existing and envisioned electronic, optoelectronic, and spintronic devices. The ultimate goal of encompassing atomistic to mesoscopic length scales in the same nonequilibrium device simulation approach has traditionally been challenging due to the computational cost of high-fidelity coupled multiphysics and multiscale requirements. In this work, we present ELEQTRONeX (ELEctrostatic Quantum TRansport modeling Of Nanomaterials at eXascale), a massively-parallel GPU-accelerated framework for self-consistently solving the nonequilibrium Green's function formalism and electrostatics in complex device geometries. By customizing algorithms for GPU multithreading, we achieve orders of magnitude improvement in computational time, and excellent scaling on up to 512 GPUs and billions of spatial grid cells. We validate our code by computing band structures, current-voltage characteristics, conductance, and drain-induced barrier lowering for various 3D configurations of carbon nanotube field-effect transistors. We also demonstrate that ELEQTRONeX is suitable for complex device/material geometries where periodic approaches are not feasible, such as modeling of arrays of misaligned carbon nanotubes requiring fully 3D simulations.

physics.comp-ph↗

Ab initio calculations of low-energy quasiparticle lifetimes in bilayer graphene

Motivated by recent experimental results we calculate from first-principles the lifetime of low-energy quasiparticles in bilayer graphene (BLG). We take into account the scattering rate arising from electron-electron interactions within the $GW$ approximation for the electron self-energy and consider several p-type doping levels ranging from $0$ to $ρ\approx 2.4\times 10^{12}$ holes/cm$^2$. In the undoped case we find that the average inverse lifetime scales linearly with energy away from the charge neutrality point, with values in good agreement with experiments. The decay rate is approximately three times larger than in monolayer graphene, a consequence of the enhanced screening in BLG. In the doped case, the dependence of the inverse lifetime on quasiparticle energy acquires a non-linear component due to the opening of an additional decay channel mediated by acoustic plasmons.

cond-mat.mes-hall↗

Nanoscale Architecture for Frequency-Resolving Single-Photon Detectors

Single photon detectors play a key role across several basic science and technology applications. While progress has been made in improving performance, single photon detectors that can maintain high performance while also resolving the photon frequency are still lacking. By means of quantum simulations, we show that nanoscale elements cooperatively interacting with the photon field in a photodetector architecture allow to simultaneously achieve high efficiency, low jitter, and high frequency resolution. We discuss how such cooperative interactions are essential to reach this performance regime, analyzing the factors that impact performance and trade-offs between metrics. We illustrate the potential performance for frequency resolution over a 1 eV bandwidth in the visible range, indicating near perfect detection efficiency, jitter of a few hundred femtoseconds, and frequency resolution of tens of meV. Finally, a potential physical realization of such an architecture is presented based on carbon nanotubes functionalized with quantum dots.

quant-ph↗

Co-Design of Free-Space Metasurface Optical Neuromorphic Classifiers for High Performance

Classification of features in a scene typically requires conversion of the incoming photonic field into the electronic domain. Recently, an alternative approach has emerged whereby passive structured materials can perform classification tasks by directly using free-space propagation and diffraction of light. In this manuscript, we present a theoretical and computational study of such systems and establish the basic features that govern their performance. We show that system architecture, material structure, and input light field are intertwined and need to be co-designed to maximize classification accuracy. Our simulations show that a single layer metasurface can achieve classification accuracy better than conventional linear classifiers, with an order of magnitude fewer diffractive features than previously reported. For a wavelength λ, single layer metasurfaces of size with aperture density achieve ~96% testing accuracy on the MNIST dataset, for an optimized distance ~ to the output plane. This is enabled by an intrinsic nonlinearity in photodetection, despite the use of linear optical metamaterials. Furthermore, we find that once the system is optimized, the number of diffractive features is the main determinant of classification performance. The slow asymptotic scaling with the number of apertures suggests a reason why such systems may benefit from multiple layer designs. Finally, we show a trade-off between the number of apertures and fabrication noise.

physics.optics↗

Nanoscale functionalized superconducting transport channels as photon detectors

Single-photon detectors have typically consisted of macroscopic materials where both the photon absorption and transduction to an electrical signal happen. Newly proposed designs suggest that large arrays of nanoscale detectors could provide improved performance in addition to decoupling the absorption and transduction processes. Here we study the properties of such a detector consisting of a nanoscale superconducting (SC) transport channel functionalized by a photon absorber. We explore two detection mechanisms based on photo-induced electrostatic gating and magnetic effects. To this end we model the narrow channel as a one-dimensional atomic chain and use a self-consistent Keldysh-Nambu Green's function formalism to describe non-equilibrium effects and SC phenomena. We consider cases where the photon creates electrostatic and magnetic changes in the absorber, as well as devices with strong and weak coupling to the metal leads. Our results indicate that the most promising case is when the SC channel is weakly coupled to the leads and in the presence of a background magnetic field, where photo-excitation of a magnetic molecule can trigger a SC-to-normal transition in the channel that leads to a change in the device current several times larger than in the case of a normal-phase channel device.

cond-mat.supr-con↗

Design of High-Performance Photon Number Resolving Photodetectors Based on Coherently Interacting Nanoscale Elements

A number of applications in basic science and technology would benefit from high fidelity photon number resolving photodetectors. While some recent experimental progress has been made in this direction, the requirements for true photon number resolution are stringent, and no design currently exists that achieves this goal. Here we employ techniques from fundamental quantum optics to demonstrate that detectors composed of subwavelength elements interacting collectively with the photon field can achieve high-performance photon number resolution. We propose a new design that simultaneously achieves photon number resolution, high efficiency, low jitter, low dark counts, and high count rate. We discuss specific systems that satisfy the design requirements, pointing to the important role of nanoscale device elements.

quant-ph↗

Quantum dynamics of single-photon detection using functionalized quantum transport electronic channels

Single photon detectors have historically consisted of macroscopic-sized materials but recent experimental and theoretical progress suggests new approaches based on nanoscale and molecular electronics. Here we present a theoretical study of photodetection in a system composed of a quantum electronic transport channel functionalized by a photon absorber. Notably, the photon field, absorption process, transduction mechanism, and measurement process are all treated as part of one fully-coupled quantum system, with explicit interactions. Using non-equilibrium, time-dependent quantum transport simulations, we reveal the unique temporal signatures of the single photon detection process, and show that the system can be described using optical Bloch equations, with a new non-linearity as a consequence of time-dependent detuning caused by the backaction from the transport channel via the dynamical Stark effect. We compute the photodetector signal-to-noise ratio and demonstrate that single photon detection at high count rate is possible for realistic parameters by exploiting a novel non-equilibrium control of backaction.

cond-mat.mes-hall↗

Atomistic study of an ideal metal/thermoelectric contact: the full-Heusler/half-Heusler interface

Half-Heusler alloys such as the (Zr,Hf)NiSn intermetallic compounds are important thermoelectric materials for converting waste heat into electricity. Reduced electrical resistivity at the hot interface between the half-Heusler material and a metal contact is critical for device performance, however this has yet to be achieved in practice. Recent experimental work suggests that a coherent interface between half-Heusler and full-Heusler compounds can form due to diffusion of transition metal atoms into the vacant sublattice of the half-Heusler lattice. We study theoretically the structural and electronic properties of such an interface using a first-principles based approach that combines {\it ab initio} calculations with macroscopic modeling. We find that the prototypical interface HfNi$_2$Sn/HfNiSn provides very low contact resistivity and almost ohmic behavior over a wide range of temperatures and doping levels. Given the potential of these interfaces to remain stable over a wide range of temperatures, our study suggests that full-Heuslers might provide nearly ideal electrical contacts to half-Heuslers that can be harnessed for efficient thermoelectric generator devices.

cond-mat.mtrl-sci↗

General modeling framework for quantum photodetectors

Photodetection plays a key role in basic science and technology, with exquisite performance having been achieved down to the single photon level. Further improvements in photodetectors would open new possibilities across a broad range of scientific disciplines, and enable new types of applications. However, it is still unclear what is possible in terms of ultimate performance, and what properties are needed for a photodetector to achieve such performance. Here, we present a general modeling framework for photodetectors whereby the photon field, the absorption process, and the amplification process are all treated as one coupled quantum system. The formalism naturally handles field states with single or multiple photons as well as a variety of detector configurations, and includes a mathematical definition of ideal photodetector performance. The framework reveals how specific photodetector architectures introduce limitations and tradeoffs for various performance metrics, providing guidance for optimization and design.

quant-ph↗

Atomistic Study of the Electronic Contact Resistivity Between the Half-Heusler Alloys (HfCoSb, HfZrCoSb, HfZrNiSn) and the Metal Ag

Half-Heusler(HH) alloys have shown promising thermoelectric properties in the medium and high temperature range. To harness these material properties for thermoelectric applications, it is important to realize electrical contacts with low electrical contact resistivity. However, little is known about the detailed structural and electronic properties of such contacts, and the expected values of contact resistivity. Here, we employ atomistic ab initio calculations to study electrical contacts in a subclass of HH alloys consisting of the compounds HfCoSb, HfZrCoSb, and HfZrNiSn. By using Ag as a prototypical metal, we show that the termination of the HH material critically determines the presence or absence of strong deformations at the interface. Our study includes contacts to doped materials, and the results indicate that the p-type materials generally form ohmic contacts while the n-type materials have a small Schottky barrier. We calculate the temperature dependence of the contact resistivity in the low to medium temperature range and provide quantitative values that set lower limits for these systems.

cond-mat.mtrl-sci↗

High Efficiency Thin Film Superlattice Thermoelectric Cooler Modules Enabled by Low Resistivity Contacts

V-telluride superlattice thin films have shown promising performance for on-chip cooling devices. Recent experimental studies have indicated that device performance is limited by the metal/semiconductor electrical contacts. One challenge in realizing a low resistivity contacts is the absence of fundamental knowledge of the physical and chemical properties of interfaces between metal and V-telluride materials. Here we present a combination of experimental and theoretical efforts to understand, design and harness low resistivity contacts to V-tellurides. Ab initio calculations are used to explore the effects of interfacial structure and chemical compositions on the electrical contacts, and an ab initio based macroscopic model is employed to predict the fundamental limit of contact resistivity as a function of both carrier concentration and temperature. Under the guidance of theoretical studies, we develop an experimental approach to fabricate low resistivity metal contacts to V-telluride thin film superlattices, achieving a 100-fold reduction compared to previous work. Interfacial characterization and analysis using both scanning transmission electron microscopy and energy-dispersive x-ray spectroscopy show the unusual interfacial morphology and the potential for further improvement in contact resistivity. Finally, we harness the improved contacts to realize an improved high-performance thermoelectric cooling module.

cond-mat.mtrl-sci↗

Fundamental Limits to Single-Photon Detection Determined by Quantum Coherence and Backaction

Single-photon detectors have achieved impressive performance, and have led to a number of new scientific discoveries and technological applications. Existing models of photodetectors are semiclassical in that the field-matter interaction is treated perturbatively and time-separated from physical processes in the absorbing matter. An open question is whether a fully quantum detector, whereby the optical field, the optical absorption, and the amplification are considered as one quantum system, could have improved performance. Here we develop a theoretical model of such photodetectors and employ simulations to reveal the critical role played by quantum coherence and amplification backaction in dictating the performance. We show that coherence and backaction lead to tradeoffs between detector metrics, and also determine optimal system designs through control of the quantum-classical interface. Importantly, we establish the design parameters that result in a perfect photodetector with 100% efficiency, no dark counts, and minimal jitter, thus paving the route for next generation detectors.

physics.optics↗

Strong Photothermoelectric Response and Contact Reactivity of the Dirac Semimetal ZrTe5

The family of three-dimensional topological insulators opens new avenues to discover novel photophysics and to develop novel types of photodetectors. ZrTe5 has been shown to be a Dirac semimetal possessing unique topological electronic and optical properties. Here we present spatially-resolved photocurrent measurements on devices made of nanoplatelets of ZrTe5, demonstrating the photothermoelectric origin of the photoresponse. Due to the high electrical conductivity and good Seebeck coefficient, we obtain noise-equivalent powers as low as 42 pW/Hz1/2 at room temperature for visible light illumination at zero bias. We also show that these devices suffer from significant ambient reactivity such as the formation of a Te-rich surface region driven by Zr oxidation, as well as severe reactions with the metal contacts. This reactivity results in significant stresses in the devices, leading to unusual geometries that are useful for gaining insight into the photocurrent mechanisms. Our results indicate that both the large photothermoelectric response and reactivity must be considered when designing or interpreting photocurrent measurements in these systems.

cond-mat.mes-hall↗

Dynamic Wavelength-Tunable Photodetector Using Subwavelength Graphene Field-Effect Transistors

Dynamic wavelength tunability has long been the holy grail of photodetector technology. Because of its atomic thickness and unique properties, graphene opens up new paradigms to realize this concept, but so far this has been elusive experimentally. Here we employ detailed quantum transport modeling of photocurrent in graphene field-effect transistors (including realistic electromagnetic fields) to show that wavelength tunability is possible by dynamically changing the gate voltage. We reveal the phenomena that govern the behavior of this type of device and show significant departure from the simple expectations based on vertical transitions. We find strong focusing of the electromagnetic fields at the contact edges over the same length scale as the band-bending. Both of these spatially-varying potentials lead to an enhancement of non-vertical optical transitions, which dominate even the absence of phonon or impurity scattering. We also show that the vanishing density of states near the Dirac point leads to contact blocking and a gate-dependent modulation of the photocurrent.

cond-mat.mes-hall↗

Noisy data clusters are hollow

A new vision in multidimensional statistics is proposed impacting severalareas of application. In these applications, a set of noisy measurementscharacterizing the repeatable response of a process is known as a realizationand can be seen as a single point in $\mathbb{R}^N$. The projections of thispoint on the N axes correspond to the N measurements. The contemporary visionof a diffuse cloud of realizations distributed in $\mathbb{R}^N$ is replaced bya cloud in the shape of a shell surrounding a topological manifold. Thismanifold corresponds to the process's stabilized-response domain observedwithout the measurement noise. The measurement noise, which accumulates overseveral dimensions, distances each realization from the manifold. Theprobability density function (PDF) of the realization-to-manifold distancecreates the shell. Considering the central limit theorem as the number ofdimensions increases, the PDF tends toward the normal distribution N($μ$,$σ$^2) where $μ$ fixes the center shell location and $σ$fixes the shell thickness. In vision, the likelihood of a realization is afunction of the realization-to-shell distance rather than therealization-to-manifold distance. The demonstration begins with the work ofClaude Shannon followed by the introduction of the shell manifold and ends withpractical applications to monitoring equipment.

math.ST↗