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Francesco Campaioli

Publications and source records attributed to Francesco Campaioli.

At least 19 recordsLinked to original sources

Superextensive learning in quantum reservoirs at the onset of information scrambling

The idea that information processing is optimised near the boundary between order and chaos has emerged as a recurring principle across neuroscience, complex systems, and machine learning. Here we test this hypothesis in quantum many-body systems, numerically simulating two-dimensional Ising networks of up to $N=20$ spins, operated as quantum reservoirs for time-series forecasting. Using out-of-time-order correlators (OTOCs), we locate the onset of information scrambling as the input strength is swept, separating regimes where information is frozen and scrambled across the whole reservoir state. We show that prediction precision peaks at the onset of scrambling, along with the number of computational-basis states that the reservoir actively populates. We then show that prediction precision grows as a power law $\sim N^α$ in the reservoir size, superextensively $(α>1)$ at the onset of scrambling and only sublinearly $(α<1)$ in either neighbouring regime. Finally, we show that scrambling enhances the nonlinear components of the reservoir memory while reducing its linear capacity. At the onset, the total memory capacity grows superextensively, provided that the necessary ``forgetting'' mechanism is supplied by a collective relaxation channel. These results consolidate the role of information scrambling in learning systems, turning it from an operating point into a scaling law for the performance of quantum reservoirs.

quant-ph

Validation and calibration of quantum hardware through the many-body quantum Mpemba effect

We introduce a validation process that harnesses engineered many-body relaxation to control and calibrate quantum hardware. On two independently developed neutral-atom processors, we realize the many-body quantum Mpemba effect in an open system for the first time. Initial-state engineering creates fast and slow relaxation pathways: the fast pathway opens access to unreachable mixed-state physics before hardware noise obscures the target dynamics, whereas the slow pathway amplifies hidden imperfections in preparation and control. Computational-basis measurements directly and independently benchmark dynamical reliability, revealing each processor's actual operating window as a many-body simulator. The processors are thus judged by the very dynamics they are built to reproduce. Complementary responses disentangle control errors and drive an adaptive, time-resolved scheme that supplies hardware developers directly actionable corrections, enhancing faithful reproduction of the target dynamics. These results establish many-body relaxation as a transferable validation and calibration tool for programmable quantum processors.

quant-ph

Molecular triplets and other metastable states for excitonic quantum batteries

Excitonic quantum batteries, based on organic fluorescent molecules embedded in optical microcavities, offer a room-temperature platform for studying collective effects in energy storage and developing applications. Recent experiments have offered evidence of superabsorption, a collective enhancement to the light absorption rate of organic molecules which leads to a scalable power density. However, they have also highlighted the challenge posed by rapid radiative decay of fluorescent molecules, which limits the energy storage lifetime. Current strategies to overcome this trade-off focus on controlling the coupling between the absorbing manifold and that used for energy storage. In this chapter, we review three implementations of this design principle: transferring energy from optically excited states to long-lived dark triplet states, generating triplet pairs and higher-spin states through singlet exciton fission, and forming charge-separated states. We discuss each mechanism from both theoretical and experimental perspectives, with particular emphasis on recent device implementations that have extended storage times by several orders of magnitude. We conclude with a cross-platform outlook on the role of metastable states across coherent and room-temperature implementations, from neutral atom arrays to masers and colour centres.

quant-ph

Nitrogen-Vacancy Emission from Nanodiamond: Size, Depth, and Surroundings

The negatively charged nitrogen-vacancy (NV) center in diamond is a leading solid-state quantum emitter, offering spin-photon interfaces over a wide temperature range with applications from electromagnetic sensing to bioimaging. While NV centers in bulk diamond are well understood, embedding them in nanodiamond (ND) introduces complexities from size, NV location, and NV polarizations. NVs in ND show altered fluorescence properties including longer lifetimes, lower quantum efficiency, and higher sensitivity to dielectric surroundings, which arise from radiative suppression, surface-induced non-radiative decay, and escape inefficiency at the diamond-background interface. Prior models typically addressed isolated aspects, such as dielectric contrast or surface quenching, without integrating full quantum-optical NV behavior with classical electrodynamics. We present a hybrid framework coupling rigorous electromagnetic simulations with a quantum-optical NV model including phonon sideband dynamics. NV emission is found to depend strongly on ND size, NV position, and surrounding refractive index. Our results explain observations such as shallow NVs in water-coated ND appearing brighter than deeper ones in air. This integrated model provides a unified framework for realistic NV in ND emission scenarios and informs the design of efficient NV-based sensors and quantum devices, advancing understanding of quantum emitter photophysics in nanoscale crystals.

physics.optics

Finite-temperature criticality through quantum annealing

Critical phenomena at finite temperature underpin a broad range of physical systems, yet their study remains challenging due to computational bottlenecks near phase transitions. Quantum annealers have attracted significant interest as a potential tool for accessing finite temperature criticality beyond classical reach, but their utility in precisely resolving criticality has remained limited by noise, hardware constraints, and thermal fluctuations. Here we overcome these challenges, showing that careful calibration and embedding allow quantum annealers to capture the full finite-temperature critical behavior of the paradigmatic two-dimensional Ising ferromagnet. By tuning the energy scale of the system and mitigating device asymmetries, we sample effective Boltzmann distributions and extract both the critical temperature and the associated critical exponents. Our approach opens the study of equilibrium and non-equilibrium critical phenomena in a broad class of systems at finite temperature.

cond-mat.stat-mech

Optimisation of ultrafast singlet fission in 1D rings towards unit efficiency

Singlet fission (SF) is an electronic transition that in the last decade has been under the spotlight for its applications in optoelectronics, from photovoltaics to spintronics. Despite considerable experimental and theoretical advancements, optimising SF in materials like multichromophoric systems and molecular crystals remains a challenge, due to the complexity of its analysis beyond perturbative methods. Here, we tackle the case of 1D rings, aiming to promote singlet fission and prevent its back-reaction. We study ultrafast SF non-perturbatively, by numerically solving a spin-boson model, via exact propagation and tensor network methods. By optimising over a parameter space relevant to organic molecular materials, we identify two classes of solutions that can take SF efficiency beyond 85% in the non-dissipative (coherent) regime, and to 99% when exciton-phonon interactions can be tuned. After discussing the experimental feasibility of the optimised solutions, we conclude by proposing that this approach can be extended to a wider class of optoelectronic optimisation problems.

quant-ph

Charging a quantum spin network towards Heisenberg-limited precision

We present a cooperative protocol to charge quantum spin networks up to the highest-energy configuration, in terms of the network's magnetization. The charging protocol leverages spin-spin interactions and the crossing of a phase transition's critical point. Exploiting collective dynamics of the spin network, the cooperative protocol guarantees a precision advantage over any local charging protocol and leads to fluctuations (standard deviation) of the magnetization that scale as $1/N$, with $N$ being the number of spins in the network, i.e., the size of the spin battery. These findings mirror the Heisenberg limit for precision for parameter estimation in quantum metrology. We test our protocol on the D-Wave's Advantage quantum processing unit by charging sub-lattices with sizes ranging from $40$ to $5\,612$ spins, achieving the maximum magnetization and reaching a scalable charging precision beyond the standard quantum limit of $1/\sqrt{N}$.

quant-ph

Extending the self-discharge time of Dicke quantum batteries using molecular triplets

Quantum batteries, quantum systems for energy storage, have gained interest due to their potential scalable charging power density. A quantum battery proposal based on the Dicke model has been explored using organic microcavities, which enable a cavity-enhanced energy transfer process called superabsorption. However, energy storage lifetime in these devices is limited by fast radiative emission losses, worsened by superradiance. Here, we demonstrate a promising approach to extend the energy storage lifetime of Dicke quantum batteries using molecular triplet states. We examine a type of multi-layer microcavities where an active absorption layer transfers energy to the molecular triplets of a storage layer, identifying two regimes based on exciton-polariton resonances. We tested one of these mechanisms by fabricating and characterising five devices across a triplet-polariton resonance. We conclude by discussing potential optimisation outlooks for this class of devices.

quant-ph

Plasmonically engineered nitrogen-vacancy spin readout

Ultra-precise readout of single nitrogen-vacancy (NV) spins hold promise for major advancements in quantum sensing and computing technologies. We predict significant brightness and contrast enhancements in NV spin qubit readout and optically detected magnetic resonance (ODMR) arising from plasmonic interaction. We present a rigorous theory verified using existing measurements in the literature for such predictions. Plasmonic spin readout enhancements selectively manifest in carefully engineered parameter regions, necessitating rigorous modelling prior to experimentation.

quant-ph

Colloquium: Quantum Batteries

Recent years have witnessed an explosion of interest in quantum devices for the production, storage, and transfer of energy. In this Colloquium, we concentrate on the field of quantum energy storage by reviewing recent theoretical and experimental progress in quantum batteries. We first provide a theoretical background discussing the advantages that quantum batteries offer with respect to their classical analogues. We then review the existing quantum many-body battery models and present a thorough discussion of important issues related to their open nature. We finally conclude by discussing promising experimental implementations, preliminary results available in the literature, and perspectives.

quant-ph

A Tutorial on Quantum Master Equations: Tips and tricks for quantum optics, quantum computing and beyond

Quantum master equations are an invaluable tool to model the dynamics of a plethora of microscopic systems, ranging from quantum optics and quantum information processing, to energy and charge transport, electronic and nuclear spin resonance, photochemistry, and more. This tutorial offers a concise and pedagogical introduction to quantum master equations, accessible to a broad, cross-disciplinary audience. The reader is guided through the basics of quantum dynamics with hands-on examples that build up in complexity. The tutorial covers essential methods like the Lindblad master equation, Redfield relaxation, and Floquet theory, as well as techniques like Suzuki-Trotter expansion and numerical approaches for sparse solvers. These methods are illustrated with code snippets implemented in python and other languages, which can be used as a starting point for generalisation and more sophisticated implementations.

quant-ph

Quintet formation and exchange fluctuations: The role of stochastic resonance in singlet fission

Singlet fission describes the spin-conserving production of two triplet excitons from one singlet exciton. The existence of a spin-2 (quintet) triplet-pair state as a product of singlet fission is well established in the literature, and control of quintet formation is an important step towards applying singlet fission in photovoltaics and quantum information. However, a definitive mechanism for quintet formation is yet to be established, which makes it difficult to design materials for optimal quintet formation. Here we outline a mechanism in which inter-triplet exchange coupling fluctuations drive fast and efficient quintet formation. In contrast with conventional wisdom, we show that quintet population can arise despite strong exchange coupling. We evaluate the performance of this quintet formation mechanism in two regimes of conformational freedom, and relate quintet dynamics to material properties of singlet fission molecules.

cond-mat.mes-hall

Optical interaction of the NV- centre in diamond with a plasmonic metal nanoparticle

We present a rigorous theoretical model for the optical interaction between a nitrogen-vacancy (NV) centre in diamond and a plasmonic metal nanoparticle (MNP), accompanied by a computationally efficient procedure to solve the evolution. The proposed model enables us to successfully explain existing optical emission measurements of NV centres both in the presence and absence of a metal nanoparticle. We show that the NV-plasmon interaction provides a versatile new avenue to enhance and control the optical emission of an NV centre. Changes to the MNP type and size, NV-MNP centre separation, submerging medium permittivity, and NV orientation with respect to the MNP surface can be exploited to improve a plethora of NV centre based nanodevices.

cond-mat.mes-hall

Singlet exciton dynamics of perylene diimide and tetracene based hetero/homogeneous substrates via an \textit{ab initio} kinetic Monte Carlo model

Luminescent solar concentrators (LSCs) are devices that trap a portion of the solar spectrum and funnel it towards photon harvesting devices. The modelling of LSCs at a quantum chemical level however, remains a challenge due to the complexity of exciton and photon dynamic modelling. This study examines singlet exciton dynamics occurring within a typical LSC device. To do this, we use a rejection-free kinetic Monte Carlo method to predict diffusion lengths, diffusion coefficients, substrate anisotropy, and average exciton lifetimes of perylene diimide (PDI) and tetracene based substrates in the low concentration scheme. \textit{Ab initio} rate constants are computed using time-dependant density functional theory based methods. PDI type substrates are observed to display enhanced singlet exciton transport properties when compared to tetracene. Simulations show that substrates with dipole-aligned chromophores are characterised by anisotropic exciton diffusion, with slightly improved transport properties. Finally, a PDI-tetracene substrate is simulated for both disordered and dipole-aligned chromophore configurations. In this multi-dopant substrate transport is predominantly mediated by PDI due to the asymmetry in the transport rates between the two dyes considered. We conclude discussing the properties of multi-dopant substrates and how they can impact the design of next generation LSCs.

cond-mat.mtrl-sci

Exciton transport in amorphous polymers and the role of morphology and thermalisation

Understanding the transport mechanism of electronic excitations in conjugated polymers is key to advancing organic optoelectronic applications, such as solar cells, OLEDs and flexible electronics. While crystalline polymers can be studied using solid-state techniques based on lattice periodicity, the characterisation of amorphous polymers is hindered by an intermediate regime of disorder and the associated lack of symmetries. To overcome these hurdles we use a reduced state quantum master equation approach based on the Merrifield exciton formalism. Using this model we study exciton transport in conjugated polymers and its dependence on morphology and temperature. Exciton dynamics consists of a thermalisation process, whose features depend on the relative strength of thermal energy, electronic couplings and disorder, resulting in remarkably different transport regimes. By applying this method to representative systems based on poly(p-phenylene vinylene) (PPV) we obtain insight into the role of temperature and disorder on localisation, charge separation, non-equilibrium dynamics, and experimental accessibility of thermal equilibrium states of excitons in amorphous polymers.

cond-mat.mtrl-sci

Tightening Time-Energy Uncertainty Relations

The uncertainty principle is a cornerstone of modern physics, and its implications have a fundamental impact on theoretical and applied quantum mechanics. The aim of this thesis is to study and apply the uncertainty relations between time and energy, which are interpreted operationally as the speed limit of quantum evolution. A geometric approach is used to derive improved bounds for the evolution of isolated and open systems and obtain a constructive approach for efficient and fast quantum driving. These results are applied to set the limits for the rate of information transfer and processing, and the power of nanomachines.

quant-ph

Resource speed limits: Maximal rate of resource variation

Recent advances in quantum resource theories have been driven by the fact that many quantum information protocols make use of different facets of the same physical features, e.g. entanglement, coherence, etc. Resource theories formalise the role of these important physical features in a given protocol. One question that remains open until now is: How quickly can a resource be generated or degraded? Using the toolkit of quantum speed limits we construct bounds on the minimum time required for a given resource to change by a fixed increment, which might be thought of as the power of said resource, i.e., rate of resource variation. We show that the derived bounds are tight by considering several examples. Finally, we discuss some applications of our results, which include bounds on thermodynamic power, generalised resource power, and estimating the coupling strength with the environment.

quant-ph

Stabilizing Open Quantum Batteries by Sequential Measurements

A quantum battery is a work reservoir that stores energy in quantum degrees of freedom. When immersed in an environment an open quantum battery needs to be stabilized against free energy leakage into the environment. For this purpose we here propose a simple protocol that relies on projective measurement and obeys a second-law like inequality for the battery entropy production rate.

quant-ph