arXiv subjects

Francesco Ciccarello

Publications and source records attributed to Francesco Ciccarello.

At least 19 recordsLinked to original sources

arXiv2026

Enabling Deterministic Passive Quantum State Transfer with Giant Atoms

Achieving quantum state transfer in passive ways can become a powerful asset for scalable quantum networks. Here, we demonstrate how giant atoms coupled to 1D waveguides provide a platform for such a passive, deterministic transfer. Specifically, we show that when the giant atom's extent is comparable to the width of the emitted wavepacket, this wavepacket can be designed to be time-reversal-symmetric by engineering the positions and strengths of atom-waveguide coupling points. We first derive general analytical conditions under which arbitrary qubit decays can be mapped to wavevector-dependent couplings that guarantee perfect state transfer in the continuum limit of infinitely many coupling points. Then, for experimentally relevant configurations with a finite number of coupling points, we optimize the coupling positions and values. We demonstrate that the transfer fidelity can be boosted well beyond the value for a single coupling point (54%), reaching 87% with only two coupling points and exceeding 99% with ten or more. We further analyze the robustness of the protocol against disorder in the coupling points as well as frequency variations of the qubits and extend the formalism to environments with nonlinear dispersion, showing that dispersion-induced distortions can be fully compensated by judiciously chosen setups. Our results establish giant atoms as a powerful platform for realizing high-fidelity quantum state transfer and demonstrate how time-dependent control can be instead encoded into the device design.

quant-ph↗

arXiv2026

Seeing inside a Plasmonic Nanogap: Few-molecule Orientation and Preferential Adsorption

Molecule-surface interactions are central to many research and technological areas, spanning from heterogeneous catalysis and polymer science to electrochemistry. Of particular relevance are metallic nanogaps used in molecular electronics and near-field spectroscopy. Due to the buried nature of these double interfaces, few methods exist to monitor side-specific interactions and relative molecular orientation inside the gap. In this work, we introduce plasmon-enhanced nonlinear vibrational spectroscopy as an efficient tool to investigate surface molecular adsorption within metallic nanojunctions. By exploiting simultaneous vibrational sum- and difference-frequency generation in dual-resonant nanocavities, we resolve molecular orientation and preferential binding to one of the two gold surfaces, with few-molecule sensitivity. We also discover that the non-resonant (electronic) second-order nonlinear response is not an intrinsic property of the metal surface, but is instead governed by the molecule-surface interaction. Our findings provide a powerful analytical tool, easily implementable as an add-on to Raman spectroscopy, thanks to commercially available mid-infrared quantum cascade lasers.

physics.optics↗

arXiv2026

Molecular Tuning of Charge-Transfer Resonance in Plasmonic Nanocavities

Interfacial charge-transfer processes play a critical role in plasmon-enhanced spectroscopy, yet the energetic conditions governing charge-transfer resonance within molecule-metal nanocavities remain poorly understood. Here, plasmonic nanoparticle-on-mirror junctions incorporating systematically engineered biphenylthiol derivatives monolayers were used to investigate how frontier orbital alignment influences chemical enhancement mechanisms. A molecular library spanning a broad range of electronically tuned acceptor states was examined using surface-enhanced Raman scattering (SERS), vibrational sum frequency generation (vSFG) spectroscopy, and density functional theory calculations. By combining different excitation wavelengths with controlled variation of substrate composition and molecular electronic structure, the energetic relationship between plasmon-enhanced charge transfer excitation and molecular orbital alignment was quantitatively evaluated. The results reveal that charge-transfer enhancement of Raman scattering is governed by a well-defined interfacial resonance condition dependent on substrate work function and excitation energy. We further probe a subset of molecular-metal systems by nanocavity-enhanced vSFG and identify the same resonance conditions as in SERS, consistent with expectations. These findings establish an experimentally accessible framework for probing and engineering charge-transfer processes in plasmonic molecular junctions and provide mechanistic insight relevant to molecular plasmonics, charge carrier photophysics, and nanoscale interfacial spectroscopy.

physics.chem-ph↗

arXiv2026

Emergent cavity-QED dynamics along the edge of a photonic lattice

We investigate qubits coupled to the boundary of a two dimensional photonic lattice that supports dispersionless edge modes, unlike conventional edge modes that sustain propagating photons. As a case study, we consider a honeycomb lattice (photonic graphene) of coupled resonators with a zigzag edge, where the edge modes form a flat band defined only over a restricted region of momentum space. We show that light matter interactions are effectively captured by a dissipative cavity QED model, wherein the emitter coherently couples to a fictitious cavity mode emerging as a superposition of edge modes. This mode has support on only one sublattice and, most notably, displays an unconventional power law localization around the qubit, yet remaining normalizable in the thermodynamic limit, with a spatial range that can be tuned by introducing lattice anisotropy We predict occurrence of vacuum Rabi oscillations and efficient state transfer between distant emitters. An experimental demonstration using superconducting circuits is proposed.

quant-ph↗

arXiv2026

Multimode-cavity picture of non-Markovian waveguide QED

We introduce a picture to describe and intrepret waveguide-QED problems in the non-Markovian regime of long photonic retardation times resulting in delayed coherent feedback. The framework is based on an intuitive spatial decomposition of the waveguide into blocks. Among these, the block directly coupled to the atoms embodies an effective lossy multimode cavity leaking into the rest of the waveguide, in turn embodying an effective white-noise bath. The dynamics can be approximated by retaining only a finite number of cavity modes which grows with the time delay. This description captures the atomic as well as the field's dynamics, even with many excitations, in both emission and scattering processes. As an application, we show that the recently identified non-Markovian steady states can be understood by retaining very few or even only one cavity modes.

quant-ph↗

arXiv2026

Giant-atom-enabled quantum optics with valley-polarized photons

Valleytronics and valley photonics exploit the valley degree of freedom to encode and manipulate information. Here we show that photonic valleys can be selectively addressed in quantum optics using a simple two-level emitter, provided it is coupled nonlocally to the field, thereby realizing a so-called giant atom. Specifically, we consider a qubit coupled at multiple points to an engineered honeycomb lattice of resonators with detuned sublattice frequencies. By tailoring the geometry of the coupling points, the giant atom can be made to emit selectively into a single valley. The emitted photons thereby acquire a well-defined valley character and inherit the associated Berry curvature. By placing the qubit near a domain wall between regions of opposite sublattice detuning, whose interface supports valley-polarized edge modes, emission becomes chiral along the domain wall. This provides a promising route toward implementation of single-photon disorder-robust chiral emission without breaking time-reversal symmetry of the electromagnetic medium in platforms such as circuit QED.

quant-ph↗

arXiv2026

Continuous-wave, high-resolution, ultra-broadband mid-infrared nonlinear spectroscopy with tunable plasmonic nanocavities

Vibrational sum- and difference-frequency generation (SFG and DFG) spectroscopy probes the nonlinear response of interfaces at mid-infrared (MIR) wavelengths while detecting upconverted signals in the visible. Recent work has moved from large-area films and colloids to nanoscale structures using dual-resonant plasmonic nanocavities that co-confine light and matter in deep-subwavelength volumes. Here we implement high-resolution ($<1$~cm$^{-1}$), continuous-wave ultrabroadband vSFG, vDFG, and four-wave mixing (FWM) coherent spectroscopy from 860 to 1670~cm$^{-1}$ on dual-resonant antennas under ambient conditions. Using a commercial, broadly tunable quantum-cascade laser and eliminating geometric phase matching simplify acquisition and expand spectral reach. The resulting spectra exhibit coherent interference between resonant (vibrational) and nonresonant (electronic) contributions to the effective $χ^{(2)}$, previously accessible only under fs/ps excitation. Simultaneous measurement of SFG and DFG enables a {ratiometric} analysis that suppresses common-mode drifts and helps reveal vibrational resonances. We demonstrate versatility and reproducibility across several analytes that span distinct relative strengths of vibrational vs. electronic nonlinearities. Together, these capabilities position our approach as a scalable route to multiplexed, high-resolution MIR sensing and a practical basis for chip-level, label-free coherent spectroscopy. It opens a feasible path toward single- and few-molecule optomechanical studies using nanoscale trapping strategies.

physics.optics↗

arXiv2025

Superstrong Dynamics and Directional Emission of a Giant Atom in a Structured Bath

Quantum emitters coupled to waveguides with nonlinear dispersion show rich quantum dynamics with the promise of implementing non-trivial non-Markovian quantum models. Recent advances in engineered photonic environments now allow the realization of discrete-site waveguides with tailored dispersion, yet most implementations of waveguide QED remain limited to a local qubit-waveguide coupling. Here, we study a transmon qubit non-locally coupled to a high-impedance coupled cavity array (CCA), thus implementing a \emph{giant atom} in a structured photonic environment. The non-local coupling produces interference with the CCA modes, selectively enhancing interaction with even and long-wavelength modes, while suppressing coupling to odd and short-wavelength modes. For a subset of symmetric, long-wavelength modes, we reach the superstrong coupling regime. In this regime, measurements of the atomic participation ratio reveal strongly hybridized eigenmodes on a par with a strongly reduced qubit participation at the frequency of maximum hybridization with the qubit, in agreement with theory. Time-domain measurements of the qubit dynamics show clear deviations from the single-mode Jaynes--Cummings model, marked by the emergence of mode--mode interactions. By breaking spatial inversion symmetry of the CCA, the qubit seeds dressed eigenmodes confined to either the right or left of the qubit, which we exploit to implement and characterize a directional photon-emission protocol. These results demonstrate precise control over multimode light--matter interaction in a structured photonic environment.

quant-ph↗

arXiv2025

Dipole-dipole interactions mediated by a photonic flat band

Flat bands (FBs) are energy bands with zero group velocity, which in electronic systems were shown to favor strongly correlated phenomena. Indeed, a FB can be spanned with a basis of strictly localized states, the so called "compact localized states" (CLSs), which are yet generally non-orthogonal. Here, we study emergent dipole-dipole interactions between emitters dispersively coupled to the photonic analogue of a FB, a setup within reach in state-of the-art experimental platforms. We show that the strength of such photon-mediated interactions decays exponentially with distance with a characteristic localization length which, unlike typical behaviours with standard bands, saturates to a finite value as the emitter's energy approaches the FB. Remarkably, we find that the localization length grows with the overlap between CLSs according to an analytically-derived universal scaling law valid for a large class of FBs both in 1D and 2D. Using giant atoms (non-local atom-field coupling) allows to tailor interaction potentials having the same shape of a CLS or a superposition of a few of these.

quant-ph↗

arXiv2025

Non-Markovian dynamics of a qubit due to accelerated light in a lattice

We investigate the emission of a qubit weakly coupled to a one-band coupled-cavity array where, due to an engineered gradient in the cavity frequencies, photons are effectively accelerated by a synthetic force F. For strong F, a reversible emission described by an effective Jaynes-Cummings model occurs, causing a chiral time-periodic excitation of an extensive region of the array, either to the right or to the left of the qubit depending on its frequency. For weak values of F instead, a complex non-Markovian decay with revivals shows up. This is reminiscent of dynamics induced by mirrors in standard waveguides, despite the absence of actual mirrors, and can be attributed to the finite width of the energy band which confines the motion of the emitted photon. In a suitable regime, the decay is well described by a delay differential equation formally analogous to the one governing the decay of an atom in a multi-mode cavity where the cavity length and time taken by a photon to travel between the two mirrors are now embodied by the amplitude and period of Bloch oscillations, respectively.

quant-ph↗

arXiv2024

Critical non-Hermitian topology induced quantum sensing

Non-Hermitian physics predicts open quantum system dynamics with unique topological features such as exceptional points and the non-Hermitian skin effect. We show that this new paradigm of topological systems can serve as probes for bulk Hamiltonian parameters with quantum-enhanced sensitivity reaching Heisenberg scaling. Such enhancement occurs close to a spectral topological phase transition, where the entire spectrum undergoes a delocalization transition. We provide an explanation for this enhanced sensitivity based on the closing of point gap, which is a genuinely non-Hermitian energy gap with no Hermitian counterpart. This establishes a direct connection between energy-gap closing and quantum enhancement in the non-Hermitian realm. Our findings are demonstrated through several paradigmatic non-Hermitian topological models in various dimensions and potential experimental implementations.

quant-ph↗

arXiv2024

How to use the dispersion in the $χ^{(3)}$ tensor for broadband generation of polarization-entangled photons

Polarization-entangled photon pairs are a widely used resource in quantum optics and technologies, and are often produced using a nonlinear process. Most sources based on spontaneous parametric downconversion have relatively narrow optical bandwidth because the pump, signal and idler frequencies must satisfy a phase-matching condition. Extending the bandwidth, for example to achieve spectral multiplexing, requires changing some experimental parameters such as temperature, crystal angle, poling period, etc. Here, we demonstrate broadband (tens of THz for each photon) generation of polarization-entangled photon pairs by spontaneous four-wave mixing in a diamond crystal, with a simple colinear geometry requiring no further optical engineering. Our approach leverages the quantum interference between electronic and vibrational contributions to the $χ^{(3)}$ tensor. Entanglement is characterized in a single realization of a Bell test over the entire bandwidth using fiber dispersion spectroscopy and fast single-photon detectors. The results agree with the biphoton wavefunction predicted from the knowledge of the $χ^{(3)}$ and Raman tensors and demonstrate the general applicability of our approach to other crystalline materials.

quant-ph↗

arXiv2023

Hermitian and Non-Hermitian Topology from Photon-Mediated Interactions

Light can mediate effective dipole-dipole interactions between atoms or quantum emitters coupled to a common environment. Exploiting them to tailor a desired effective Hamiltonian can have major applications and advance the search for many-body phases. Quantum technologies are mature enough to engineer large photonic lattices with sophisticated structures coupled to quantum emitters. In this context, a fundamental problem is to find general criteria to tailor a photonic environment that mediates a desired effective Hamiltonian of the atoms. Among these criteria, topological properties are of utmost importance since an effective atomic Hamiltonian endowed with a non-trivial topology can be protected against disorder and imperfections. Here, we find general theorems that govern the topological properties (if any) of photon-mediated Hamiltonians in terms of both Hermitian and non-Hermitian topological invariants, thus unveiling a system-bath topological correspondence. The results depend on the number of emitters relative to the number of resonators. For a photonic lattice where each mode is coupled to a single quantum emitter, the Altland-Zirnbauer classification of topological insulators allows us to link the topology of the atoms to that of the photonic bath: we unveil the phenomena of topological preservation and reversal to the effect that the atomic topology can be the same or opposite to the photonic one, depending on Hermiticity of the photonic system and on the parity of the spatial dimension. As a consequence, the bulk-edge correspondence implies the existence of atomic boundary modes with the group velocity opposite to the photonic ones in a 2D Hermitian topological system. If there are fewer emitters than photonic modes, the atomic system is less constrained and no general photon-atom topological correspondence can be found. We show this with two counterexamples.

quant-ph↗

arXiv2022

Quantum correlations in dissipative gain-loss systems across exceptional points

We investigate the behavior of correlations dynamics in a dissipative gain-loss system. First, we consider a setup made of two coupled lossy oscillators, with one of them subject to a local gain. This provides a more realistic platform to implement parity-time (PT) symmetry circumventing the implementation of a pure gain. We show how the qualitative dynamics of correlations resembles that for a pure-gain-loss setup. The major quantitative effect is that quantum correlations are reduced, while total ones are enhanced. Second, we study the behavior of these correlations across an exceptional point (EP) outside of the PT-symmetric regime of parameters, observing how different behaviors across the EP occur only in the transient dynamics. This shows how PT symmetry plays a relevant role at large times.

quant-ph↗

arXiv2022

Stochastic versus periodic quantum collision models

Most literature on quantum collision models (CMs) usually considers periodic weak collisions featuring a fixed waiting time between two next collisions. Some works have yet addressed CMs with random waiting time and strong collisions (stochastic CMs). This short paper discusses how the open dynamics arising from these two types of models can be formally mapped with one another. This can be achieved for a given stochastic CM by constructing an associated periodic CM such that the waiting time randomness of the former is turned into the mixedness of the ancilla's initial state of the latter, introducing at the same time an additional state of the ancilla. Through this mapping, non-Markovian behaviour arising from a constrained number of stochatic collisions can be linked to initial ancilla-ancilla correlations of the associated periodic CM.

quant-ph↗

arXiv2022

Quantum correlations beyond entanglement in a classical-channel model of gravity

A direct quantization of the Newtonian interaction between two masses is known to establish entanglement, which if detected would witness the quantum nature of the gravitational field. Gravitational interaction is yet compatible also with gravitational decoherence models relying on classical channels, hence unable to create entanglement. Here, we show in paradigmatic cases that, despite the absence of entanglement, a classical-channel model of gravity can still establish quantum correlations in the form of quantum discord between two masses. This is demonstrated for the Kafri-Taylor-Milburn (KTM) model and a recently proposed dissipative extension of this. In both cases, starting from an uncorrelated state, a significant amount of discord is generally created. This eventually decays in the KTM model, while it converges to a small stationary value in its dissipative extension. We also find that initial local squeezing on the state of the masses can significanlty enhance the generated discord.

quant-ph↗

arXiv2022

Exotic interactions mediated by a non-Hermitian photonic bath

Photon-mediated interactions between quantum emitters in engineered photonic baths is an emerging area of quantum optics. At the same time, non-Hermitian (NH) physics is currently thriving, spurred by the exciting possibility to access new physics in systems ruled by non-trivial NH Hamiltonians - in particular photonic lattices - which can challenge longstanding tenets such as the Bloch theory of bands. Here, we combine these two fields and study the exotic interaction between emitters mediated by the photonic modes of a lossy photonic lattice described by a NH Hamiltonian. We show in a paradigmatic case study that structured losses in the field can seed exotic emission properties. Photons can mediate dissipative, fully non-reciprocal, interactions between the emitters with range critically dependent on the loss rate. When this loss rate corresponds to a bare-lattice exceptional point, the effective couplings are exactly nearest-neighbour, implementing a dissipative, fully non-reciprocal, Hatano-Nelson model. Counter-intuitively, this occurs irrespective of the lattice boundary conditions. Thus photons can mediate an effective emitters' Hamiltonian which is translationally-invariant despite the fact that the field is not. We interpret these effects in terms of metastable atom-photon dressed states, which can be exactly localized on only two lattice cells or extended across the entire lattice. These findings introduce a new paradigm of light-mediated interactions with unprecedented features such as non-reciprocity, non-trivial dependence on the field boundary conditions and range tunability via a loss rate.

quant-ph↗

arXiv2022

Quantum collision models: open system dynamics from repeated interactions

We present an extensive introduction to quantum collision models (CMs), also known as repeated interactions schemes: a class of microscopic system-bath models for investigating open quantum systems dynamics whose use is currently spreading in a number of research areas. Through dedicated sections and a pedagogical approach, we discuss the CMs definition and general properties, their use for the derivation of master equations, their connection with quantum trajectories, their application in non-equilibrium quantum thermodynamics, their non-Markovian generalizations, their emergence from conventional system-bath microscopic models and link to the input-output formalism. The state of the art of each involved research area is reviewed through dedicated sections. The article is supported by several complementary appendices, which review standard concepts/tools of open quantum systems used in the main text with the goal of making the material accessible even to readers possessing only a basic background in quantum mechanics. The paper could also be seen itself as a friendly, physically intuitive, introduction to fundamentals of open quantum systems theory since most main concepts of this are treated such as quantum maps, Lindblad master equation, steady states, POVMs, quantum trajectories and stochastic Schrodinger equation.

quant-ph↗