arXiv subjects

Francisco J. Galindo-Rosales

Publications and source records attributed to Francisco J. Galindo-Rosales.

10 recordsLinked to original sources

arXiv2024

Characterization of low-viscosity electrorheological fluids: Technical Issues and Challenges

The electrorheological (ER) characterization of low-viscosity fluids is paramount for producing micro- and nanoscale products through electrohydrodynamic (EHD) techniques, such as EHD-jet printing, electrospray, and electrospinning. Key properties such as viscosity, surface tension, dielectric properties, electrical conductivity, and relaxation time significantly influence both the quality and properties of the final products and the efficiency of the industrial process. ER characterization is essential for studying the macroscopic effects of the interaction between these physicochemical properties under controlled flow kinematics. Researchers may face several technical challenges in performing rigorous ER characterization of low-viscosity fluids. This characterization is crucial for formulating inks compatible with the EHD process and for understanding fluid dynamics in EHD processes to ensure stable printing conditions and achieve high-resolution, accurate prints. This work highlights the inherent limitations of current ER cells and proposes methodologies to mitigate their impact on measurement accuracy. Furthermore, we explore the potential of microfluidic technologies to offer innovative solutions for the ER characterization of low-viscosity fluids.

physics.flu-dyn↗

arXiv2024

Rheological behavior of molybdenum disulfide (MoS2) inks under electric fields: influence of concentration and voltage

This work provides a complete rheological characterization of molybdenum disulfide (MoS2) inks in the presence of electric fields. Several concentrations of MoS2 are studied and dispersed in a viscoelastic fluid. The lubrication effects are present in the ink when the MoS2 concentration is higher than 0.10% w/w. The dielectric properties show the impossibility of a positive electrorheological effect for all MoS2-inks studied. The formation of vortices and electromigration of MoS2 particles occur under the influence of an external electric field. These two phenomena affect the rheological behavior of MoS2-inks under shear flow condition. Relatively to the extensional rheology experiments, the particle migration and the vortex formation promote anisotropy on the rheological properties of the inks which affects the relaxation time, the formation of beads-on-a-string and the uniaxial elongational flow condition is no longer valid. When the electric field strength is 1.5 kV/mm, the formation of Taylor's cone is observed and independent of MoS2 concentration.

physics.flu-dyn↗

arXiv2024

Pressure drop non-linearities in material extrusion additive manufacturing: a novel approach for pressure monitoring and numerical modeling

Fused Filament Fabrication is an additive manufacturing technique in which molten thermoplastic polymers are extruded through a nozzle. Therefore, the interplay between the viscoelastic nature of the polymer melt, temperature, printing conditions and nozzle shape may lead to inconsistent extrusion. To improve the extrusion control and optimize the print-head performance, a better understanding of the flow process of the polymer melt both in the nozzle and the liquefier is needed. However, several challenges need to be overcome due to the complexity of gathering experimental data on the melt pressure in the nozzle and the lack of numerical models able to capture the full rheology of the molten polymer. This research introduces an innovative approach for monitoring the pressure within a material extrusion 3D printer's nozzle. This method involves utilizing a pin in direct contact with the molten material, which then transmits the applied force from the material to an externally mounted load cell. The setup provides reliable, repeatable pressure data in steady-state conditions for two nozzle geometries and at different extrusion flows and temperatures. Moreover, the Giesekus model enabled capturing the viscoelastic rheometric features of the melt, and the numerical predictions have been compared with the experimental data. Results show that the numerical model accurately describes the flow conditions in the nozzle and allows the estimation of the behaviour of the melt in the liquefier zone, the area of the print-head where the filament is molten. It could be concluded that the backflow, which is the backward flow of the molten polymer in the gap between the filament and the liquefier towards the cold end, caused significant non-linearities in the total pressure drop measured in the feeders, which were related to normal forces induced by shear in that region.

physics.flu-dyn↗

arXiv2024

Optimal shape design of printing nozzles for extrusion-based additive manufacturing

The optimal design seeks the best possible solution(s) for a mechanical structure, device, or system, satisfying a series of requirements and leading to the best performance. In this work, optimized nozzle shapes have been designed for a wide range of polymer melts to be used in extrusion-based additive manufacturing, which aims to minimize pressure drop and allow greater flow control at large extrusion velocities. This is achieved with a twofold approach, combining a global optimization algorithm with computational fluid dynamics for optimizing a contraction geometry for viscoelastic fluids and validating these geometries experimentally. In the optimization process, variable coordinates for the nozzle's contraction section are defined, the objective function is selected, and the optimization algorithm is guided within manufacturing constraints. Comparisons of flow-type and streamline plots reveal that the nozzle shape significantly influences flow patterns. Depending on the rheological properties, the optimized solution either promotes shear or extensional flow, enhancing the material flow rate. Finally, experimental validation of the nozzle performance assessed the actual printing flow, the extrusion force and the overall print control. It is shown that optimizing the nozzle can significantly reduce backflow-related pressure drop, positively impacting total pressure drop (up to 41%) and reducing backflow effects. This work has real-world implications for the additive manufacturing industry, offering opportunities for increased printing speeds, enhanced productivity, and improved printing quality and reliability. Our research contributes to advancing extrusion-based printing processes technology, addressing industry demands and enhancing the field of additive manufacturing.

physics.flu-dyn↗

arXiv2023

Numerical analysis of the entry flow for continuous shear thickening fluids in circular microtubes

Due to their nature, using shear thickening fluids (STFs) in engineering applications has sparked an interest in developing energy-dissipating systems, such as damping devices or shock absorbers. The Rheinforce technology allows the design of customized energy dissipative composites by embedding microfluidic channels filled with STFs in a scaffold material. One of the reasons for using microfluidic channels is that their shape can be numerically optimized to control pressure drop (also known as rectifiers); thus, by controlling the pressure drop, it is possible to control the energy dissipated by the viscous effect. Upon impact, the fluid is forced to flow through the microchannel, experiencing the typical entry flow until it reaches the fully developed flow. It is well-known for Newtonian fluid that the entrance flow is responsible for a non-negligible percentage of the total pressure drop in the fluid; therefore, an analysis of the fluid flow at the entry region for STFs is of paramount importance for an accurate design of the Rheinforce composites. This analysis has been numerically performed before for shear thickening fluids modelled by a power-law model; however, as this constitutive model represents a continuously growing viscosity between end-viscosity plateau values, it is not representative of the characteristic viscosity curve of shear thickening fluids, which typically exhibit a three-regions shape (thinning-thickening-thinning). For the first time, the influence of these three regions on the entry flow on an axisymmetric pipe is analysed. 2D numerical simulations have been performed for four STFs consisting of four dispersions of fumed silica nanoparticles in polypropylene glycol varying concentration (7.5-20wt%) modelled by Khandavalli, et al. [1].

physics.flu-dyn↗

arXiv2023

The building blocks behind the Electrohydrodynamics of non-polar 2Dinks

This work provides a complete rheological characterization of 2D-inks in electric fields with different intensities and orientations to the imposed flow field. 2D nanomaterials used in this study are graphene nanoplatelets, hexagonal boron-nitride, and molybdenum disulfide. These materials with different electric properties are dispersed in a non-polar solvent (Toluene) with different concentrations of Ethyl Cellulose (EC), providing Newtonian or viscoelastic characteristics. Shear rheology tests show that the presence of nanoparticles barely changes the fluid behavior from the carrier fluid, and the application of an electric field perpendicular to the flow does not result in electrorheological behavior. However, extensional experiments, which mimic the actual EHD jet printing conditions, allowed the observation of the influence of both the particles and the electric field aligned on the filament thinning process. It was observed that the electric field generates vortices due to an electrophoretic effect in the carrier fluid when EC is present in the formulations, which has severe consequences on the stability of the liquid bridges, whereas it scarcely affects the shear viscosity; additionally, the kind of 2D nanoparticles modifies also the conductivity and permittivity of the solution, inducing Maxwell stresses that also make the filament more stable against surface tension.

physics.flu-dyn↗

arXiv2023

Correlation between the rheology of 2D-inks precursors and the droplet size generated from a capillary nozzle in dripping regime

This study provides a complete rheological characterization of 2D nanomaterial dispersions, employed as 2D-inks precursors in printed electronics. Three different 2D nanomaterials (molybdenum disulfide (MoS2), graphene, and hexagonal boron nitride(hBN)) were dispersed in a Newtonian fluid (toluene) and a viscoelastic fluid (toluene + ethyl cellulose) with different polymer concentrations. The presence of nanoparticles does not change the shear rheology of the carrier fluid. Regarding the extensional rheology, the results showed that the pinch-off phenomenon is present in all Toluene suspensions; however, the presence of the ethyl cellulose introduces elasticity in the system, even leading to the formation of beads-on-a-string, and the relaxation times of the suspensions depends on the kind of nanoparticles present in the fluid. As controlling the droplet size when dispensing 2D-inks is of paramount importance for printed electronics, as well as for many other applications, here it is presented a correlation between the rheological properties of these 2D-inks precursors and their droplet size when generated from a capillary nozzle in dripping regime.

physics.flu-dyn↗

arXiv2020

Breakup of an electrified viscoelastic liquid bridge

We study both numerically and experimentally the breakup of a viscoelastic liquid bridge between two parallel electrodes. We solve the leaky-dielectric FENE-P model to describe the dynamical response of the liquid bridge under isothermal conditions. The results show that the surface charge screens the inner electric field perpendicular to the free surface over the entire dynamical process. The liquid bridge deformation produces a normal electric field on the outer side of the free surface that is commensurate with the axial one. The surface conduction does not significantly affect the current intensity in the time interval analyzed in the experiments. The force due to the shear electric stress becomes comparable to both the viscoelastic and surface tension forces in the last stage of the filament. However, it does not alter the elasto-capillary balance in the filament. The extensional relaxation times approximately coincides with the stress relaxation time prescribed in the FENE-P model. We measure experimentally the filament electrical conductivity and extensional relaxation time for PEO dissolved in deionized water and in a mixture of water and glycerine. We compare the filament electrical conductivity with the value measured in hydrostatic conditions for the same estimated temperature. Good agreement was found for PEO dissolved in water+glycerine, which indicates that the change of the filament microscopic structure due to the presence of stretched polymeric chains does not significantly alter the ion mobility in the stretching direction. Significant deviations are found for PEO dissolved in deionized water that may be attributed to the heat transferred to the ambient, neglected in the calculation of the filament temperature. The extensional relaxation time measured from the images acquired during the filament thinning hardly depends on the applied voltage.

physics.flu-dyn↗

arXiv2020

Numerical assessment of the penetroviscometer approach for large, rapid and transient shear deformations

The rheological characterisation of complex fluids is mostly performed under simple shear flow in rotational rheometers. Their modern commercial versions are extremely sensitive instruments which are able to provide very accurate measurements of low values of different material functions, such as viscosity, viscoelastic moduli, etc., under certain ideal flow conditions. Nevertheless, they fail in providing reliable data when characterising the response of complex fluids at short time scales, due to artefacts induced by either instrument or fluid inertia. This is crucial in the analysis of the rheological properties of new formulations of shear thickening fluids specifically developed for protective applications, in which the performance is extremely linked to the time dependent structural changes provoked by the sudden impact loads. Thus, the necessity of providing a reliable experimental tool able to impose large, rapid, transient shear deformation for their rheological characterisation in conditions similar to those of the applications becomes evident. This numerical study aims at assessing the potential use of the penetroviscometer for the measurement of the transient shear viscosity of complex fluids at short time scales beyond the current limits of commercial rotational rheometers.

physics.flu-dyn↗

arXiv2020

Dilatancy in dense suspensions of model hard-sphere-like colloids under shear and extensional flow

Dense suspensions of model hard-sphere-like colloids, with different particle sizes, are examined experimentally in the glass state, under shear and extensional rheology. Under steady shear flow we detect Discontinuous Shear Thickening (DST) above a critical shear rate. Start-up shear experiments show stress overshoots in the vicinity of the onset of DST related with a change in microscopic morphology, as the sample shows dilatancy effects. The analysis of the normal stress together with direct sample observation by high speed camera, indicates the appearance of positive N1 and dilation behavior at the shear thickening onset. Dilatancy effects are detected also under extensional flow. The latter was studied through capillary breakup and filament stretching experimental setups, where liquid-like response is seen for strain rate lower than a critical strain rate and solid like-behavior for higher strain rates. Monitoring the filament thinning processes under different conditions (volume fractions and strain rates) we have created a state diagram where all responses of a hard-sphere suspension (Newtonian, shear thinning, shear thickening, dilatant) are shown. We finally compare the shear thickening response of these hard-sphere-like suspensions and glasses in shear with that in extensional flow.

cond-mat.soft↗