arXiv subjects

Francisco J. Garcia-Vidal

Publications and source records attributed to Francisco J. Garcia-Vidal.

At least 19 recordsLinked to original sources

arXiv2026

Twin reflections from a moving space-time boundary

An interluminal interface, a space-time boundary propagating at a velocity between the group velocities of the surrounding media, enables extraordinary wave phenomena such as nonreciprocal amplification and analogues of Hawking radiation. A particularly intriguing prediction is that such an interface splits an incident wave into three outgoing waves: one transmitted and two reflected. Yet, despite decades of theoretical study, this triple-wave scattering has remained experimentally unobserved, owing to stringent requirements on interface velocity and modulation speed. Here, we introduce a programmable spatiotemporal microstrip transmission-line platform that realizes step-modulated interluminal interfaces with controlled velocity. Using this system, we report the direct observation of bi-reflection from an interluminal interface, confirming the emergence of two distinct reflected waves alongside a transmitted one. Measured frequencies and scattering coefficients show excellent agreement with longstanding theoretical predictions. Furthermore, we reveal that the two reflections possess fundamentally different causal symmetries: one is spatially inverted, while the other is time-reversed. These findings resolve a half-century-old puzzle in moving-boundary electrodynamics and establish a versatile experimental platform for studying wave interaction with dynamic interfaces. Our work opens pathways to velocity-independent scattering devices, broadband frequency conversion, and advanced spatiotemporal wave engineering.

physics.optics↗

arXiv2026

Room-temperature tuning and probing of Fermi polarons in atomically thin semiconductors on a plasmonic metasurface

The Fermi polaron, arising from interactions between a mobile impurity and a degenerate Fermi sea, is a many-body quasiparticle that provides a sensitive probe of strongly correlated electronic phases in atomically thin semiconductors. In doped transition-metal dichalcogenides, the attractive and repulsive polaron branches are well established in monolayers. However, extending active control and quantitative, branch-resolved probing to stacked geometries has remained elusive because spectral quenching and weak optical contrast restrict access to Fermi polaron signatures. Here, we integrate electron-doped WS$_2$ flakes from monolayer to quadrilayer with a strain-tunable plasmonic metasurface, enabling high-contrast scattering readout at room temperature through coupling between Fermi polaron resonances and surface plasmons. This platform enables quantitative extraction of polaron branch spectral weights and coupling strengths across different layer numbers. We uncover a systematic thickness dependence of the spectral-weight distribution and demonstrate continuous and fully reversible spectral-weight transfer between attractive and repulsive branches in bilayers and quadrilayers, with near-complete transfer achieved in bilayers. By identifying layer number and strain as complementary control parameters for Fermi polarons, our results establish metasurface-enabled scattering spectroscopy as a practical route to resolve and manipulate many-body resonances in stacked van der Waals semiconductors, bridging idealized monolayer polaron physics and device-relevant architectures.

cond-mat.mes-hall↗

arXiv2025

Entangled Polariton States in the Visible and Mid-Infrared Spectral Ranges

Entanglement generation in polariton systems is fundamentally constrained by high losses and decoherence, which typically outweigh polariton nonlinearities. Here, we propose a conceptually different approach that uses optomechanical interactions, rather than polariton-polariton interactions, to generate entangled polaritons. Our double-resonant scheme relies on strong exciton-phonon coupling, found in both inorganic and molecular semiconductors, enabling room-temperature generation of spectrally disparate photon pairs. The quantum coherent and delocalized nature of polariton states inside optical cavities ensures efficient single-mode outcoupling and allows for unconditional quantum state preparation - not relying on any post-selection or projective measurements. When conditioned on exciton-polariton emission, single phonon-polariton states can be prepared that subsequently yield bright, heralded single-photon emission in the mid-IR/THz. We introduce a double-resonant optomechanical platform that enables scalable, room-temperature quantum polaritonics without relying on conventional excitonic nonlinearities.

quant-ph↗

arXiv2025

Probing dynamics of time-varying media: Beyond abrupt temporal interfaces

This work investigates the effects of time-varying media, where optical properties change over time, on electromagnetic wave propagation, focusing on plane waves and free-electron evanescent waves. We introduce a switching parameter, $τ$, to model ultrafast switching in the femtosecond to nanosecond range. For plane-wave incidence at angular frequency $ω_0$, we derive a generalized expression for the backward-to-forward flux ratio as a function of $ω_0$ and $τ$, aligning with recent experimental data and providing a unified interpretation framework. For free-electron incidence, we observe intensity saturation in temporal transition radiation at $I_{\textrm{max}}$ for $τ\leq τ_{\textrm{0}}$, with both $I_{\textrm{max}}$ and $τ_{\textrm{0}}$ depending on electron speed. These results highlight the importance of precise $τ$ control in experiments to probe time-varying media effectively.

physics.optics↗

arXiv2025

Topologically protected edge states in time photonic crystals with chiral symmetry

Time photonic crystals are media in which their electromagnetic parameters are modulated periodically in time, showing promising applications in non-resonant lasers and particle accelerators, among others. Traditionally utilized to study space photonic crystals, topological band theory has also been translated recently to analyze time photonic crystals with time inversion symmetry, enabling the construction of the temporal version of topological edge states. However, temporal disorder can readily break time inversion symmetry in practice, hence likely destroying the edge states associated with this type of time photonic crystals. To overcome this limitation, here we propose a new class of time photonic crystals presenting chiral symmetry instead, whose edge states exhibit superior robustness over the time-reversal-symmetry-protected counterparts. Our time photonic crystal is equivalent to a temporal version of the Su-Schrieffer-Heeger model, and the chiral symmetry of this type of time photonic crystals quantizes the winding number defined in the Bloch frequency band. Remarkably, random temporal disorders do not impact the eigenfrequencies of these chiral-symmetry-protected edge states, while instead enhancing their temporal localizations. Our findings thus provide a promising paradigm to control field amplification with exceptional robustness as well as being a feasible platform to investigate various topological phases in time-varying media.

physics.optics↗

arXiv2024

Enhanced Cherenkov radiation in twisted hyperbolic Van der Waals crystals

Cherenkov radiation in artificial structures experiencing strong radiation enhancements promises important applications in free-electron quantum emitters, broadband light sources, miniaturized particle detectors, etc. However, the momentum matching condition between the swift electron and emitted photons generally restricts the radiation enhancement to a particular momentum. Efficient Cherenkov radiation over a wide range of momenta is highly demanded for many applications but has still remained a challenging task. To this end, we explore the interaction between a swift electron and twisted hyperbolic Van der Waals crystals, and observe enhanced Cherenkov radiation at the flatband resonance frequency. We show that, at the photonic magic angle of the twisted crystals, the electron momentum, once matching with that of the flatband photon, gives rise to a maximum energy loss (corresponding to the surface phonon generation), one-order of magnitude higher than that in conventional hyperbolic materials. Such a significant enhancement is attributed to the excitation of flatband surface phonon polaritons over a broad momentum range. Our findings provide a feasible route to highly directional free-electron radiation and radiation shaping.

physics.optics↗

arXiv2023

Electroluminescence as a probe of strong exciton-plasmon coupling in few-layer WSe2

The manipulation of coupled quantum excitations is of fundamental importance in realizing novel photonic and optoelectronic devices. We use electroluminescence to probe plasmon-exciton coupling in hybrid structures consisting of a nanoscale plasmonic tunnel junction and few-layer two-dimensional transition-metal dichalcogenide transferred onto the junction. The resulting hybrid states act as a novel dielectric environment that affects the radiative recombination of hot carriers in the plasmonic nanostructure. We determine the plexcitonic spectrum from the electroluminescence and find Rabi splittings exceeding 50 meV in strong coupling regime. Our experimental findings are supported by electromagnetic simulations that enable us to explore systematically, and in detail, the emergence of plexciton polaritons as well as the polarization characteristics of their far-field emission. Electroluminescence modulated by plexciton coupling provides potential applications for engineering compact photonic devices with tunable optical and electrical properties.

cond-mat.mes-hall↗

arXiv2023

Strong light-matter coupling in lead halide perovskite quantum dot solids

Strong coupling between lead halide perovskite materials and optical resonators enables both the polaritonic control of the photophysical properties of these emerging semiconductors and the observation of novel fundamental physical phenomena. However, the difficulty to achieve optical-quality perovskite quantum dot (PQD) films showing well-defined excitonic transitions has prevented the study of strong light-matter coupling in these materials, central to the field of optoelectronics. Herein we demonstrate the formation at room temperature of multiple cavity exciton-polaritons in metallic resonators embedding highly transparent Cesium Lead Bromide quantum dot (CsPbBr3-QD) solids, revealed by a significant reconfiguration of the absorption and emission properties of the system. Our results indicate that the effects of biexciton interaction or large polaron formation, frequently invoked to explain the properties of PQDs, are seemingly absent or compensated by other more conspicuous effects in the CsPbBr3-QD optical cavity. We observe that strong coupling enables a significant reduction of the photoemission linewidth, as well as the ultrafast switching of the optical absorption, controllable by means of the excitation fluence. We find that the interplay of the polariton states with the large dark state reservoir play a decisive role in determining the dynamics of the emission and transient absorption properties of the hybridized light-quantum dot solid system. Our results open the route for the investigation of PQD solids as polaritonic optoelectronic materials.

cond-mat.mtrl-sci↗

arXiv2020

Reconfigurable photon sources based on quantum plexcitonic systems

A single photon in a strongly nonlinear cavity is able to block the transmission of the second photon, thereby converting incident coherent light into anti-bunched light, which is known as photon blockade effect. On the other hand, photon anti-pairing, where only the entry of two photons is blocked and the emission of bunches of three or more photons is allowed, is based on an unconventional photon blockade mechanism due to destructive interference of two distinct excitation pathways. We propose quantum plexcitonic systems with moderate nonlinearity to generate both anti-bunched and anti-paired photons. The proposed plexitonic systems benefit from subwavelength field localizations that make quantum emitters spatially distinguishable, thus enabling a reconfigurable photon source between anti-bunched and anti-paired states via tailoring the energy bands. For a realistic nanoprism plexitonic system, two schemes of reconfiguration are suggested: (i) the chemical means by partially changing the type of the emitters; or (ii) the optical approach by rotating the polarization angle of the incident light to tune the coupling rate of the emitters. These results pave the way to realize reconfigurable nonclassical photon sources in a simple quantum plexcitonic platform with readily accessible experimental conditions.

quant-ph↗

arXiv2019

Tensor network simulation of non-Markovian dynamics in organic polaritons

We calculate the exact many-body time dynamics of polaritonic states supported by an optical cavity filled with organic molecules. Optical, vibrational and radiative processes are treated on an equal footing employing the Time-Dependent Variational Matrix Product States algorithm. We demonstrate signatures of non-Markovian vibronic dynamics and its fingerprints in the far-field photon emission spectrum at arbitrary light-matter interaction scales, ranging from the weak to the strong coupling regimes. We analyse both the single and many-molecule cases, showing the crucial role played by the collective motion of molecular nuclei and dark states in determining the polariton dynamics and the subsequent photon emission.

cond-mat.mes-hall↗

arXiv2019

Cavity Casimir-Polder forces and their effects in ground state chemical reactivity

Here we present a fundamental study on how the ground-state chemical reactivity of a molecule can be modified in a QED scenario, i.e., when it is placed inside a cavity and there is strong coupling between the cavity field and vibrational modes within the molecule. We work with a model system for the molecule (Shin-Metiu model) in which nuclear, electronic and photonic degrees of freedom are treated on the same footing. This simplified model allows the comparison of exact quantum reaction rate calculations with predictions emerging from transition state theory based on the cavity Born-Oppenheimer approach. We demonstrate that QED effects are indeed able to significantly modify activation barriers in chemical reactions and, as a consequence, reaction rates. The critical physical parameter controlling this effect is the permanent dipole of the molecule and how this magnitude changes along the reaction coordinate. We show that the effective coupling can lead to significant single-molecule energy shifts in an experimentally available nanoparticle-on-mirror cavity. We then apply the validated theory to a realistic case (internal rotation in the 1,2-dichloroethane molecule), showing how reactions can be inhibited or catalyzed depending on the profile of the molecular dipole. Furthermore, we discuss the absence of resonance effects in this process, which can be understood through its connection to Casimir-Polder forces. Finally, we treat the case of many-molecule strong coupling, and find collective modifications of reaction rates if the molecular permanent dipole moments are oriented with respected to the cavity field. This demonstrates that collective coupling can also provide a mechanism for modifying ground-state chemical reactivity of an ensemble of molecules coupled to a cavity mode.

quant-ph↗

arXiv2018

Tensor Network simulation of polaron-polaritons in organic microcavities

In the regime of strong coupling between molecular excitons and confined optical modes, the intra-molecular degrees of freedom are profoundly affected, leading to a reduced vibrational dressing of polaritons compared to bare electronically excited states. However, existing models only describe a single vibrational mode in each molecule, while actual molecules possess a large number of vibrational degrees of freedom and additionally interact with a continuous bath of phononic modes in the host medium in typical experiments. In this work, we investigate a small ensemble of molecules with an arbitrary number of vibrational degrees of freedom under strong coupling to a microcavity mode. We demonstrate that reduced vibrational dressing is still present in this case, and show that the influence of the phononic environment on most electronic and photonic observables in the lowest excited state can be predicted from just two collective parameters of the vibrational modes. Besides, we explore vibrational features that can be addressed exclusively by our extended model and could be experimentally tested. Our findings indicate that vibronic coupling is more efficiently suppressed for environments characterised by low-frequency (sub-Ohmic) modes.

cond-mat.mes-hall↗

arXiv2017

Many-molecule reaction triggered by a single photon in polaritonic chemistry

The second law of photochemistry states that in most cases, no more than one molecule is activated for an excited-state reaction for each photon absorbed by a collection of molecules. In this work, we demonstrate that it is possible to trigger a many-molecule reaction using only one photon by strongly coupling the molecular ensemble to a confined light mode. The collective nature of the resulting hybrid states of the system (the so-called polaritons) leads to the formation of a polaritonic "supermolecule" involving the degrees of freedom of all molecules, opening a reaction path on which all involved molecules undergo a chemical transformation. We theoretically investigate the system conditions for this effect to take place and be enhanced.

physics.chem-ph↗

arXiv2017

Enhancing Near-Field Radiative Heat Transfer with Si-based Metasurfaces

We demonstrate in this work that the use of metasurfaces provides a viable strategy to largely tune and enhance near-field radiative heat transfer between extended structures. In particular, using a rigorous coupled wave analysis, we predict that Si-based metasurfaces featuring two-dimensional periodic arrays of holes can exhibit a room-temperature near-field radiative heat conductance much larger than any unstructured material to date. We show that this enhancement, which takes place in a broad range of separations, relies on the possibility to largely tune the properties of the surface plasmon polaritons that dominate the radiative heat transfer in the near-field regime.

physics.optics↗

arXiv2017

Plasmon-Exciton-Polariton Lasing

Metallic nanostructures provide a toolkit for the generation of coherent light below the diffraction limit. Plasmonic based lasing relies on the population inversion of emitters (such as organic fluorophores) along with feedback provided by plasmonic resonances. In this regime, known as weak light matter coupling, the radiative characteristics of the system can be described by the Purcell effect. Strong light matter coupling between the molecular excitons and electromagnetic field generated by the plasmonic structures leads to the formation of hybrid quasi-particles known as plasmon exciton polaritons (PEPs). Due to the bosonic character of these quasi particles, exciton polariton condensation can lead to laser-like emission at much lower threshold powers than in conventional photon lasers. Here, we observe PEP lasing through a dark plasmonic mode in an array of metallic nanoparticles with a low threshold in an optically pumped organic system. Interestingly, the threshold power of the lasing is reduced by increasing the degree of light matter coupling in spite of the degradation of the quantum efficiency of the active material, highlighting the ultrafast dynamic responsible for the lasing, i.e., stimulated scattering. These results demonstrate a unique roomtemperature platform for exploring the physics of exciton polaritons in an open cavity architecture and pave the road toward the integration of this on-chip lasing device with the current photonics and active metamaterial planar technologies.

cond-mat.mes-hall↗

arXiv2016

When polarons meet polaritons: Exciton-vibration interactions in organic molecules strongly coupled to confined light fields

We present a microscopic semi-analytical theory for the description of organic molecules interacting strongly with a cavity mode. Exciton-vibration coupling within the molecule and exciton-cavity interaction are treated on an equal footing by employing a temperature-dependent variational approach. The interplay between strong exciton-vibration coupling and strong exciton-cavity coupling gives rise to a hybrid ground state, which we refer to as the lower polaron polariton. Explicit expressions for the ground-state wave function, the zero-temperature quasiparticle weight of the lower polaron polariton, the photoluminescence line strength, and the mean number of vibrational quanta are obtained in terms of the optimal variational parameters. The dependence of these quantities upon the exciton-cavity coupling strength reveals that strong cavity coupling leads to an enhanced vibrational dressing of the cavity mode, and at the same time a vibrational decoupling of the dark excitons, which in turn results in a lower polaron polariton resembling a single-mode dressed bare lower polariton in the strong-coupling regime. Thermal effects on several observables are briefly discussed.

cond-mat.mes-hall↗

arXiv2016

Exploiting vibrational strong coupling to make an optical parametric oscillator out of a Raman laser

When the collective coupling of the rovibrational states in organic molecules and confined electromagnetic modes is sufficiently strong, the system enters into vibrational strong coupling, leading to the formation of hybrid light-matter quasiparticles. In this work we demonstrate theoretically how this hybridization in combination with stimulated Raman scattering can be utilized to widen the capabilities of Raman laser devices. We explore the conditions under which the lasing threshold can be diminished and the system can be transformed into an optical parametric oscillator. Finally, we show how the dramatic reduction of the many final molecular states into two collective excitations can be used to create an all-optical switch with output in the mid-infrared.

cond-mat.mes-hall↗

arXiv2016

Suppressing photochemical reactions with quantized light fields

Photoisomerization, i.e., a change of molecular structure after absorption of a photon, is one of the most fundamental photochemical processes. It can perform desirable functionality, e.g., as the primary photochemical event in human vision, where it stores electronic energy in the molecular structure, or for possible applications in solar energy storage and as memories, switches, and actuators; but it can also have detrimental effects, for example as an important damage pathway under solar irradiation of DNA, or as a limiting factor for the efficiency of organic solar cells. While photoisomerization can be avoided by shielding the system from light, this is of course not a viable pathway for approaches that rely on the interaction with external light (such as solar cells or solar energy storage). Here, we show that strong coupling of organic molecules to a confined light mode can be used to strongly suppress photoisomerization, and thus convert molecules that normally show fast photodegradation into photostable forms.

cond-mat.mes-hall↗