arXiv subjects

Frank Schlawin

Publications and source records attributed to Frank Schlawin.

At least 37 records · Page 2Linked to original sources

arXiv2021

How to optimize the absorption of two entangled photons

We investigate how entanglement can enhance two-photon absorption in a three-level system. First, we employ the Schmidt decomposition to determine the entanglement properties of the optimal two-photon state to drive such a transition, and the maximum enhancement which can be achieved in comparison to the optimal classical pulse. We then adapt the optimization problem to realistic experimental constraints, where photon pairs from a down-conversion source are manipulated by local operations such as spatial light modulators. We derive optimal pulse shaping functions to enhance the absorption efficiency, and compare the maximal enhancement achievable by entanglement to the yield of optimally shaped, separable pulses.

quant-ph↗

arXiv2021

Quantum metrology of two-photon absorption

Two-photon absorption (TPA) is of fundamental importance in super-resolution imaging and spectroscopy. Its nonlinear character allows for the prospect of using quantum resources, such as entanglement, to improve measurement precision or to gain new information on, e.g., ultrafast molecular dynamics. Here, we establish the metrological properties of nonclassical squeezed light sources for precision measurements of TPA cross sections. We find that there is no fundamental limit for the precision achievable with squeezed states in the limit of very small cross sections. Considering the most relevant measurement strategies -- namely photon counting and quadrature measurements -- we determine the quantum advantage provided by squeezed states as compared to coherent states. We find that squeezed states outperform the precision achievable by coherent states when performing quadrature measurements, which provide improved scaling of the Fisher information with respect to the mean photon number $\sim n^4$. Due to the interplay of the incoherent nature and the nonlinearity of the TPA process, unusual scaling can also be obtained with coherent states, which feature a $\sim n^3$ scaling in both quadrature and photon-counting measurements.

quant-ph↗

arXiv2021

Continuously parametrized quantum simulation of molecular electron transfer reactions

A comprehensive description of molecular electron transfer reactions is essential for our understanding of fundamental phenomena in bio-energetics and molecular electronics. Experimental studies of molecular systems in condensed-phase environments, however, face difficulties to independently control the parameters that govern the transfer mechanism with high precision. We show that trapped-ion experiments instead allow to reproduce and continuously connect vastly different regimes of molecular charge transfer through precise tuning of, e.g., phonon temperature, electron-phonon interactions, and electronic couplings. Such a setting allows not only to reproduce widely-used transport models, such as Marcus theory. It also provides access to transfer regimes that are unattainable for molecular experiments, while controlling and measuring the relevant observables on the level of individual quanta. Our numerical simulations predict an unconventional quantum transfer regime, featuring a transition from quantum adiabatic- to resonance-assisted transfer as a function of the donor-acceptor energy gap, that can be reached by increasing the electronic coupling at low temperatures. Trapped ion-based quantum simulations thus promise to enhance our microscopic understanding of molecular electron transfer processes, and may help to reveal efficient design principles for synthetic devices.

quant-ph↗

arXiv2021

Analytical Solution for the Steady States of the Driven Hubbard model

Under the action of coherent periodic driving a generic quantum system will undergo Floquet heating and continously absorb energy until it reaches a featureless thermal state. The phase-space constraints induced by certain symmetries can, however, prevent this and allow the system to dynamically form robust steady states with off-diagonal long-range order. In this work, we take the Hubbard model on an arbitrary lattice with arbitrary filling and, by simultaneously diagonalising the two possible SU(2) symmetries of the system, we analytically construct the correlated steady states for different symmetry classes of driving. This construction allows us to make verifiable, quantitative predictions about the long-range particle-hole and spin-exchange correlations that these states can possess. In the case when both SU(2) symmetries are preserved in the thermodynamic limit we show how the driving can be used to form a unique condensate which simultaneously hosts particle-hole and spin-wave order.

cond-mat.str-el↗

arXiv2020

Photo-induced electron pairing in a driven cavity

We demonstrate how virtual scattering of laser photons inside a cavity via two-photon processes can induce controllable long-range electron interactions in two-dimensional materials. We show that laser light that is red(blue)-detuned from the cavity yields attractive(repulsive) interactions, whose strength is proportional to the laser intensity. Furthermore, we find that the interactions are not screened effectively except at very low frequencies. For realistic cavity parameters, laser-induced heating of the electrons by inelastic photon scattering is suppressed and coherent electron interactions dominate. When the interactions are attractive, they cause an instability in the Cooper channel at a temperature proportional to the square root of the driving intensity. Our results provide a novel route for engineering electron interactions in a wide range of two-dimensional materials including AB-stacked bilayer graphene and the conducting interface between LaAlO3 and SrTiO3.

cond-mat.mes-hall↗

arXiv2020

Photon correlation spectroscopy as a witness for quantum coherence

The development of spectroscopic techniques able to detect and verify quantum coherence is a goal of increasing importance given the rapid progress of new quantum technologies, the advances in the field of quantum thermodynamics, and the emergence of new questions in chemistry and biology regarding the possible relevance of quantum coherence in biochemical processes. Ideally, these tools should be able to detect and verify the presence of quantum coherence in both the transient dynamics and the steady state of driven-dissipative systems, such as light-harvesting complexes driven by thermal photons in natural conditions. This requirement poses a challenge for standard laser spectroscopy methods. Here, we propose photon correlation measurements as a new tool to analyse quantum dynamics in molecular aggregates in driven-dissipative situations. We show that the photon correlation statistics on the light emitted by a molecular dimer model can signal the presence of coherent dynamics. Deviations from the counting statistics of independent emitters constitute a direct fingerprint of quantum coherence in the steady state. Furthermore, the analysis of frequency resolved photon correlations can signal the presence of coherent dynamics even in the absence of steady state coherence, providing direct spectroscopic access to the much sought-after site energies in molecular aggregates.

quant-ph↗

arXiv2019

Cavity-mediated unconventional pairing in ultracold fermionic atoms

We investigate long-range pairing interactions between ultracold fermionic atoms confined in an optical lattice which are mediated by the coupling to a cavity. In the absence of other perturbations, we find three degenerate pairing symmetries for a two-dimensional square lattice. By tuning a weak local atomic interaction via a Feshbach resonance or by tuning a weak magnetic field, the superfluid system can be driven from a topologically trivial s-wave to topologically ordered, chiral superfluids containing Majorana edge states. Our work points out a novel path towards the creation of exotic superfluid states by exploiting the competition between long-range and short-range interactions.

cond-mat.quant-gas↗

arXiv2019

Optical control of the current-voltage relation in stacked superconductors

We simulate the current-voltage relation of short layered superconductors, which we model as stacks of capacitively coupled Josephson junctions. The system is driven by external laser fields, in order to optically control the voltage drop across the junction. We identify parameter regimes in which supercurrents can be stabilised against thermally induced phase slips, thus reducing the effective voltage across the superconductor. Furthermore, single driven Josephson junctions are known to exhibit phase-locked states, where the superconducting phase is locked to the driving field. We numerically observe their persistence in the presence of thermal fluctuations and capacitive coupling between adjacent Josephson junctions. Our results indicate how macroscopic material properties can be manipulated by exploiting the large optical nonlinearities of Josephson plasmons.

cond-mat.supr-con↗

arXiv2019

Mott polaritons in cavity-coupled quantum materials

We show that strong electron-electron interactions in cavity-coupled quantum materials can enable collectively enhanced light-matter interactions with ultrastrong effective coupling strengths. As a paradigmatic example we consider a Fermi-Hubbard model coupled to a single-mode cavity and find that resonant electron-cavity interactions result in the formation of a quasi-continuum of polariton branches. The vacuum Rabi splitting of the two outermost branches is collectively enhanced and scales with $g_{\text{eff}}\propto\sqrt{2L}$, where $L$ is the number of electronic sites, and the maximal achievable value for $g_{\text{eff}}$ is determined by the volume of the unit cell of the crystal. We find that $g_{\text{eff}}$ for existing quantum materials can by far exceed the width of the first excited Hubbard band. This effect can be experimentally observed via measurements of the optical conductivity and does not require ultra-strong coupling on the single-electron level. Quantum correlations in the electronic ground state as well as the microscopic nature of the light-matter interaction enhance the collective light-matter interaction compared to an ensemble of independent two-level atoms interacting with a cavity mode.

cond-mat.str-el↗

arXiv2019

Manipulating quantum materials with quantum light

We show that the macroscopic magnetic and electronic properties of strongly correlated electron systems can be manipulated by coupling them to a cavity mode. As a paradigmatic example we consider the Fermi-Hubbard model and find that the electron-cavity coupling enhances the magnetic interaction between the electron spins in the ground-state manifold. At half filling this effect can be observed by a change in the magnetic susceptibility. At less than half filling, the cavity introduces a next-nearest neighbour hopping and mediates a long-range electron-electron interaction between distant sites. We study the ground state properties with Tensor Network methods and find that the cavity coupling can induce a new phase characterized by a momentum-space pairing effect for electrons.

cond-mat.str-el↗

arXiv2018

Coherence turned on by incoherent light

One of the most pertinent problems in the debate on non-trivial quantum effects in biology concerns natural photosynthesis. Since sunlight is composed of thermal photons, it was argued to be unable to induce quantum coherence in matter, and that quantum mechanics is therefore irrelevant for the dynamical processes following photoabsorption. Our present analysis of a toy ``molecular aggregate" -- composed of two dipole-dipole interacting two-level atoms treated as an open quantum system -- however shows that incoherent excitations indeed can trigger coherent dynamics that persist: We demonstrate that collective decay processes induced by the dipole-dipole interaction create coherent intermolecular transport -- regardless of the coherence properties of the incoming radiation. Our analysis shows that the steady state coherence is mediated by the population imbalance between the molecules and, therefore, {\it increases} with the energy difference between the two-level atoms. Our results establish the importance of collective decay processes in the study of ultrafast photophysics, and especially their potential role to generate stationary coherence in incoherently driven quantum transport.

quant-ph↗

arXiv2018

Cavity-mediated electron-photon superconductivity

We investigate electron paring in a two-dimensional electron system mediated by vacuum fluctuations inside a nanoplasmonic terahertz cavity. We show that the structured cavity vacuum can induce long-range attractive interactions between current fluctuations which lead to pairing in generic materials with critical temperatures in the low-Kelvin regime for realistic parameters. The induced state is a pair density wave superconductor which can show a transition from a fully gapped to a partially gapped phase - akin to the pseudogap phase in high-$T_c$ superconductors. Our findings provide a promising tool for engineering intrinsic electron interactions in two-dimensional materials.

cond-mat.mes-hall↗

arXiv2017

Terahertz field control of interlayer transport modes in cuprate superconductors

We theoretically show that terahertz pulses with controlled amplitude and frequency can be used to switch between stable transport modes in layered superconductors, modelled as stacks of Josephson junctions. We find pulse shapes that deterministically switch the transport mode between superconducting, resistive and solitonic states. We develop a simple model that explains the switching mechanism as a destablization of the centre of mass excitation of the Josephson phase, made possible by the highly non-linear nature of the light-matter coupling.

cond-mat.supr-con↗

arXiv2016

Nonlinear optical signals and spectroscopy with quantum light

Conventional nonlinear spectroscopy uses classical light to detect matter properties through the variation of its response with frequencies or time delays. Quantum light opens up new avenues for spectroscopy by utilizing parameters of the quantum state of light as novel control knobs and through the variation of photon statistics by coupling to matter. We present an intuitive diagrammatic approach for calculating ultrafast spectroscopy signals induced by quantum light, focusing on applications involving entangled photons with nonclassical bandwidth properties - known as "time-energy entanglement". Nonlinear optical signals induced by quantized light fields are expressed using time ordered multipoint correlation functions of superoperators. These are different from Glauber's g- functions for photon counting which use normally ordered products of ordinary operators. Entangled photon pairs are not subjected to the classical Fourier limitations on the joint temporal and spectral resolution. After a brief survey of properties of entangled photon pairs relevant to their spectroscopic applications, different optical signals, and photon counting setups are discussed and illustrated for simple multi-level model systems.

quant-ph↗

arXiv2015

Enhancement of two-photon transitions with tailored quantum light

We examine a fundamental problem in quantum optics: What is the optimal pulse form to drive a two-photon-transition? We show that entangled photons in general do so more efficiently than optimal classical pulses, and provide the first example of enhanced coherent control through quantum correlations. In ensembles of collectively driven two-level systems, such enhancement requires non-vanishing interactions.

quant-ph↗

arXiv2015

Probing Polariton Dynamics in Trapped Ions with Phase-Coherent Two-Dimensional Spectroscopy

We devise a phase-coherent three-pulse protocol to probe the polariton dynamics in a trapped-ion quantum simulation. In contrast to conventional nonlinear signals, the presented scheme does not change the number of excitations in the system, allowing for the investigation of the dynamics within an $N$-excitation manifold. In the particular case of a filling factor one ($N$ excitations in an $N$-ion chain), the proposed interaction induces coherent transitions between a delocalized phonon superfluid and a localized atomic insulator phase. Numerical simulations of a two-ion chain demonstrate that the resulting two-dimensional spectra allow for the unambiguous identification of the distinct phases, and the two-dimensional lineshapes efficiently characterize the relevant decoherence mechanism.

quant-ph↗

arXiv2014

Nonlinear Spectroscopy of Trapped Ions

Nonlinear spectroscopy employs a series of laser pulses to interrogate dynamics in large interacting many-body systems, and has become a highly successful method for experiments in chemical physics. Current quantum optical experiments approach system sizes and levels of complexity which require the development of efficient techniques to assess spectral and dynamical features with scalable experimental overhead. However, established methods from optical spectroscopy of macroscopic ensembles cannot be applied straightforwardly to few-atom systems. Based on the ideas proposed in [M. Gessner et al. New J. Phys. 16 092001 (2014)], we develop a diagrammatic approach to construct nonlinear measurement protocols for controlled quantum systems and discuss experimental implementations with trapped ion technology in detail. These methods in combination with distinct features of ultra-cold matter systems allow us to monitor and analyze excitation dynamics in both the electronic and vibrational degrees of freedom. They are independent of system size, and can therefore reliably probe systems where, e.g., quantum state tomography becomes prohibitively expensive. We propose signals that can probe steady state currents, detect the influence of anharmonicities on phonon transport, and identify signatures of chaotic dynamics near a quantum phase transition in an Ising-type spin chain.

quant-ph↗

arXiv2014

Stimulated Raman Spectroscopy with Entangled Light; Enhanced Resolution and Pathway Selection

We propose a novel femtosecond stimulated Raman spectroscopy (FSRS) technique that combines entangled photons with interference detection to select matter pathways and enhance the resolution. Following photo excitation by an actinic pump, the measurement uses a pair of broadband entangled photons, one (signal) interacts with the molecule together with a third narrowband pulse induces the Raman process. The other (idler) photon provides a reference for the coincidence measurement. This interferometric photon-coincidence counting detection allows to separately measure Raman gain and loss signals, which is not possible with conventional probe transmission detection. Entangled photons further provide a unique temporal and spectral detection window that can better resolve fast excited state dynamics compared to classical and correlated disentangled states of light.

quant-ph↗