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Franz Schreier

Publications and source records attributed to Franz Schreier.

At least 19 recordsLinked to original sources

Detectability of biosignatures in warm, water-rich atmospheres

Warm rocky exoplanets within the habitable zone of Sun-like stars are favoured targets for current and future missions. Theory indicates these planets could be wet at formation and remain habitable long enough for life to develop. In this work we test the climate-chemistry response, maintenance, and detectability of biosignatures in warm, water-rich atmospheres with Earth biomass fluxes within the framework of the planned LIFE mission. We used the coupled climate-chemistry column model 1D-TERRA to simulate the composition of planetary atmospheres at different distances from the Sun, assuming Earth's planetary parameters and evolution. We increased the incoming instellation by up to 50 percent in steps of 10 percent, corresponding to orbits of 1.00 to 0.82 AU. Simulations were performed with and without modern Earth's biomass fluxes. Emission spectra of all simulations were produced using the GARLIC radiative transfer model. LIFEsim was then used to add noise to and simulate observations of these spectra to assess how biotic and abiotic atmospheres of Earth-like planets can be distinguished. Increasing instellation leads to surface water vapour pressures rising from 0.01 bar (1.13%) to 0.61 bar (34.72%). In the biotic scenarios, the ozone layer survives because hydrogen oxide reactions with nitrogen oxides prevent the net ozone chemical sink from increasing. Synthetic observations with LIFEsim, assuming a 2.0 m aperture and resolving power of R = 50, show that O3 signatures at 9.6 micron reliably point to Earth-like biosphere surface fluxes of O2 only for systems within 10 parsecs. Increasing the aperture to 3.5 m increases this range to 22.5 pc. The differences in atmospheric temperature due to differing H2O profiles also enables observations at 15.0 micron to reliably identify planets with a CH4 surface flux equal to that of Earth's biosphere.

astro-ph.EP

A Generalized Variable Projection Algorithm for Least Squares Problems in Atmospheric Remote Sensing

This paper presents a solution for efficiently and accurately solving separable least squares problems with multiple datasets. These problems involve determining linear parameters that are specific to each dataset while ensuring that the nonlinear parameters remain consistent across all datasets. A well-established approach for solving such problems is the variable projection algorithm introduced by Golub and LeVeque, which effectively reduces a separable problem to its nonlinear component. However, this algorithm assumes that the datasets have equal sizes and identical auxiliary model parameters. This article is motivated by a real-world remote sensing application where these assumptions do not apply. Consequently, we propose a generalized algorithm that extends the original theory to overcome these limitations. The new algorithm has been implemented and tested using both synthetic and real satellite data for atmospheric carbon dioxide retrievals. It has also been compared to conventional state-of-the-art solvers, and its advantages are thoroughly discussed. The experimental results demonstrate that the proposed algorithm significantly outperforms all other methods in terms of computation time, while maintaining comparable accuracy and stability. Hence, this novel method can have a positive impact on future applications in remote sensing and could be valuable for other scientific fitting problems with similar properties.

math.NA

Impact of Cosmic Rays on Atmospheric Ion Chemistry and Spectral Transmission Features of TRAPPIST-1e

Ongoing observing projects like the James Webb Space Telescope (JWST) and future missions offer the chance to characterize Earth-like exoplanetary atmospheres. Thereby, M-dwarfs are preferred targets for transit observations, for example, due to their favorable planet-star contrast ratio. However, the radiation and particle environment of these cool stars could be far more extreme than what we know from the Sun. Thus, knowing the stellar radiation and particle environment and its possible influence on detectable biosignatures - particularly signs of life like ozone and methane - is crucial to understanding upcoming transit spectra. In this study, with the help of our unique model suite INCREASE, we investigate the impact of a strong stellar energetic particle event on the atmospheric ionization, neutral and ion chemistry, and atmospheric biosignatures of TRAPPIST-1e. Therefore, transit spectra for six scenarios are simulated. We find that a Carrington-like event drastically increases atmospheric ionization and induces substantial changes in ion chemistry and spectral transmission features: all scenarios show high event-induced amounts of nitrogen dioxide (i.e., at 6.2 $μ$m), a reduction of the atmospheric transit depth in all water bands (i.e., at 5.5 -- 7.0 $μ$m), a decrease of the methane bands (i.e., at 3.0 -- 3.5 $μ$m), and depletion of ozone (i.e., at $\sim$ 9.6 $μ$m). Therefore, it is essential to include high-energy particle effects to correctly assign biosignature signals from, e.g., ozone and methane. We further show that the nitric acid feature at 11.0 - 12.0 $μ$m, discussed as a proxy for stellar particle contamination, is absent in wet-dead atmospheres.

astro-ph.EP

Assessment of a Physics-based Retrieval of Exoplanet Atmospheric Temperatures from Infrared Emission Spectra

Atmospheric temperatures are to be estimated from thermal emission spectra of Earth-like exoplanets orbiting M-stars as observed by current and future planned missions. To this end, a line-by-line radiative transfer code is used to generate synthetic thermal infrared (TIR) observations. The range of 'observed' intensities provides a rough hint of the atmospheric temperature range without any a priori knowledge. The equivalent brightness temperature (related to intensities by Planck's function) at certain wavenumbers can be used to estimate the atmospheric temperature at corresponding altitudes. To exploit the full information provided by the measurement we generalize Chahine's original approach and infer atmospheric temperatures from all spectral data using the wavenumber-to-altitude mapping defined by the weighting functions. Chahine relaxation allows an iterative refinement of this 'first guess'. Analysis of the 4.3μm and 15μm carbon dioxide TIR bands enables an estimate of atmospheric temperatures for rocky exoplanets even for low signal to noise ratios of 10 and medium resolution. Inference of Trappist-1e temperatures is, however, more challenging especially for CO2 dominated atmospheres: the 'standard' 4.3μm and 15μm regions are optically thick and an extension of the spectral range towards atmospheric window regions is important. If atmospheric composition (essentially CO2 concentration) is known temperatures can be estimated remarkably well, quality measures such as the residual norm provide hints on incorrect abundances. In conclusion, temperature in the mid atmosphere of Earth-like planets orbiting cooler stars can be quickly estimated from thermal IR emission spectra with moderate resolution.

astro-ph.EP

Computational Aspects of Speed-Dependent Voigt and Rautian Profiles

For accurate line-by-line modeling of molecular cross sections several physical processes "beyond Voigt" have to be considered. For the speed-dependent Voigt and Rautian profiles (SDV, SDR) and the Hartmann-Tran profile the difference $w(i z_-)-w(i z_+)$ of two complex error functions (essentially Voigt functions) has to be evaluated where the function arguments $z_\pm$ are given by the sum and difference of two square roots. These two terms describing $z_\pm$ can be huge and the default implementation of the difference can lead to large cancellation errors. First we demonstrate that these problems can be avoided by a simple reformulation of $z_-$. Furthermore we show that a single rational approximation of the complex error function valid in the whole complex plane (e.g. by Humlicek, 1979 or Weideman, 1994) enables computation of the SDV and SDR with four significant digits or better. Our benchmarks indicate that the SDV and SDR functions are about a factor 2.2 slower compared to the Voigt function, but for evaluation of molecular cross sections this time lag does not significantly prolong the overall program execution because speed-dependent parameters are available only for a fraction of strong lines.

physics.comp-ph

Influence of Biomass Emissions upon Habitability, Biosignatures and Detectability in Earth-like Atmospheres

We investigate atmospheric responses of modeled hypothetical Earth-like planets in the habitable zone of the M-dwarf AD Leonis to reduced oxygen (O2), removed biomass (dead Earth), varying carbon dioxide (CO2) and surface relative humidity (sRH). Results suggest large O2 differences between the reduced O2 and dead scenarios in the lower but not the upper atmosphere. Ozone (O3) and nitrous oxide (N2O) also show this behavior. Methane depends on hydroxyl (OH), its main sink. Abiotic production of N2O occurs in the upper layers. Chloromethane (CH3Cl) decreases everywhere on decreasing biomass. Changing CO2 (from x1 to x100 present atmospheric level (PAL)) and surface relative humidity (sRH) (from 0.1 percent to 100 percent) does not influence CH3Cl as much as lowering biomass. Therefore, CH3Cl can be considered a good biosignature. Changing sRH and CO2 has a greater influence on temperature than O2 and biomass alone. Changing the biomass produces ~6 kilometer (km) in effective height (H) in transmission compared with changing CO2 and sRH ( about 25km). In transmission O2 is discernible at 0.76 microns for greater than 0.1 PAL. The O3 9.6 micron band was weak for the low O2 runs and difficult to discern from dead Earth, however O3 at 0.3 microns could serve as an indicator to distinguish between reduced O2 and dead Earth. Spectral features of N2O and CH3Cl corresponded to some km H. CH4 could be detectable tens of parsecs away with ELT except for the 10-4 and 10-6 PAL O2 scenarios. O2 is barely detectable for the 1 PAL O2 case and unfeasible at lower abundances.

astro-ph.EP

Detectability of biosignatures on LHS 1140 b

Terrestrial extrasolar planets around low-mass stars are prime targets when searching for atmospheric biosignatures with current and near-future telescopes. The habitable-zone Super-Earth LHS 1140 b could hold a hydrogen-dominated atmosphere and is an excellent candidate for detecting atmospheric features. In this study, we investigate how the instellation and planetary parameters influence the atmospheric climate, chemistry, and spectral appearance of LHS 1140 b. We study the detectability of selected molecules, in particular potential biosignatures, with the upcoming James Webb Space Telescope (JWST) and Extremely Large Telescope (ELT). In a first step we use the coupled climate-chemistry model, 1D-TERRA, to simulate a range of assumed atmospheric chemical compositions dominated by H$_2$ and CO$_2$. Further, we vary the concentrations of CH$_4$ by several orders of magnitude. In a second step we calculate transmission spectra of the simulated atmospheres and compare them to recent transit observations. Finally, we determine the observation time required to detect spectral bands with low resolution spectroscopy using JWST and the cross-correlation technique using ELT. In H$_2$-dominated and CH$_4$-rich atmospheres O$_2$ has strong chemical sinks, leading to low concentrations of O$_2$ and O$_3$. The potential biosignatures NH$_3$, PH$_3$, CH$_3$Cl and N$_2$O are less sensitive to the concentration of H$_2$, CO$_2$ and CH$_4$ in the atmosphere. In the simulated H$_2$-dominated atmosphere the detection of these gases might be feasible within 20 to 100 observation hours with ELT or JWST, when assuming weak extinction by hazes. If further observations of LHS 1140 b suggest a thin, clear, hydrogen-dominated atmosphere, the planet would be one of the best known targets to detect biosignature gases in the atmosphere of a habitable-zone rocky exoplanet with upcoming telescopes.

astro-ph.EP

Effect of mantle oxidation state and escape upon the evolution of Earth's magma ocean atmosphere

The magma ocean period was a critical phase determining how Earth atmosphere developed into habitability. However there are major uncertainties in the role of key processes such as outgassing from the planetary interior and escape of species to space that play a major role in determining the atmosphere of early Earth. We investigate the influence of outgassing of various species and escape of H$_2$ for different mantle redox states upon the composition and evolution of the atmosphere for the magma ocean period. We include an important new atmosphere-interior coupling mechanism namely the redox evolution of the mantle which strongly affects the outgassing of species. We simulate the volatile outgassing and chemical speciation at the surface for various redox states of the mantle by employing a C-H-O based chemical speciation model combined with an interior outgassing model. We then apply a line-by-line radiative transfer model to study the remote appearance of the planet in terms of the infrared emission and transmission. Finally, we use a parameterized diffusion-limited and XUV energy-driven atmospheric escape model to calculate the loss of H$_2$ to space. We have simulated the thermal emission and transmission spectra for reduced or oxidized atmospheres present during the magma ocean period of Earth. Reduced or thin atmospheres consisting of H$_2$ in abundance emit more radiation to space and have larger effective height as compared to oxidized or thick atmospheres which are abundant in H$_2$O and CO$_2$. We obtain the outgassing rates of H2 from the mantle into the atmosphere to be a factor of ten times larger than the rates of diffusion-limited escape to space. Our work presents useful insight into the development of Earth atmosphere during the magma ocean period as well as input to guide future studies discussing exoplanetary interior compositions.

astro-ph.EP

Distinguishing between wet and dry atmospheres of TRAPPIST-1 e and f

The nearby TRAPPIST-1 planetary system is an exciting target for characterizing the atmospheres of terrestrial planets. The planets e, f and g lie in the circumstellar habitable zone and could sustain liquid water on their surfaces. During the extended pre-main sequence phase of TRAPPIST-1, however, the planets may have experienced extreme water loss, leading to a desiccated mantle. The presence or absence of an ocean is challenging to determine with current and next generation telescopes. Therefore, we investigate whether indirect evidence of an ocean and/or a biosphere can be inferred from observations of the planetary atmosphere. We introduce a newly developed photochemical model for planetary atmospheres, coupled to a radiative-convective model and validate it against modern Earth, Venus and Mars. The coupled model is applied to the TRAPPIST-1 planets e and f, assuming different surface conditions and varying amounts of CO$_2$ in the atmosphere. As input for the model we use a constructed spectrum of TRAPPIST-1, based on near-simultaneous data from X-ray to optical wavelengths. We compute cloud-free transmission spectra of the planetary atmospheres and determine the detectability of molecular features using the Extremely Large Telescope (ELT) and the James Webb Space Telescope (JWST). We find that under certain conditions, the existence or non-existence of a biosphere and/or an ocean can be inferred by combining 30 transit observations with ELT and JWST within the K-band. A non-detection of CO could suggest the existence of an ocean, whereas significant CH$_4$ hints at the presence of a biosphere.

astro-ph.EP

SVEEEETIES: Singular vector expansion to estimate Earth-like exoplanet temperatures from infrared emission spectra

Context. Detailed characterizations of exoplanets are moving to the forefront of planetary science. Temperature is a key marker for understanding atmospheric physics and chemistry. Aims. We aim to retrieve temperatures of N2-O2 dominated atmospheres from secondary eclipse spectroscopic observations of the thermal emission of Earth-like exoplanets orbiting G-, K-, and M-stars using large future space telescopes. Methods. Line-by-line radiative transfer was used to generate synthetic thermal infrared (TIR) observations. Atmospheric temperature is approximated by an expansion with base vectors defined by a singular value decomposition of a matrix comprising representative profiles. Nonlinear least squares fitting is used to estimate the expansion coefficients. Results. Analysis of the $4.3 \rm\,μm$ and $15 \rm\,μm$ CO2 bands in the TIR permits inference of temperatures even for low signal-to-noise (S/N) ~5 at medium resolution. Deviations from the true temperature in the upper troposphere and stratosphere are usually a few Kelvin, with larger deviations in the upper atmosphere and, less often, in the lower troposphere. Although the performance of the two bands is equivalent in most cases, the longwave TIR is more favorable than the shortwave due to increased star-planet contrast. A high spectral resolution, as provided by JWST instruments, is important for retaining sensitivity to the upper atmosphere. Furthermore, the selection of an appropriate set of base functions is also key. Conclusions. Temperature in the mid-atmosphere can be suitably characterized by IR spectroscopy with a resolution of at least 1000 (ideally ~2500). Obtaining the necessary S/N could be feasible with future missions, such as the Origins Space Telescope or the Large Interferometer for Exoplanets. Meanwhile a least squares fitting with appropriate base functions is also applicable for other classes of planets.

astro-ph.EP

A New Model Suite to Determine the Influence of Cosmic Rays on (Exo)planetary Atmospheric Biosignatures -- Validation based on Modern Earth

The first opportunity to detect indications for life outside the Solar System may be provided already within the next decade with upcoming missions such as the James Webb Space Telescope (JWST), the European Extremely Large Telescope (E-ELT) and/or the Atmospheric Remote-sensing Infrared Exoplanet Large-survey (ARIEL) mission, searching for atmospheric biosignatures on planets in the habitable zone of cool K- and M-stars. Nevertheless, their harsh stellar radiation and particle environment could lead to photochemical loss of atmospheric biosignatures. We aim to study the influence of cosmic rays on exoplanetary atmospheric biosignatures and the radiation environment considering feedbacks between energetic particle precipitation, climate, atmospheric ionization, neutral and ion chemistry, and secondary particle generation. We describe newly-combined state-of-the-art modeling tools to study the impact of the radiation and particle environment on atmospheric particle interaction, the influence on the atmospheric chemistry, and the climate-chemistry coupling in a self-consistent model suite. To this end, models like the Atmospheric Radiation Interaction Simulator (AtRIS), the Exoplanetary Terrestrial Ion Chemistry model (ExoTIC), and the updated coupled climate-chemistry model are combined. Amongst others, we model the atmospheric response during quiescent solar periods and during a strong solar energetic particle event as well as the scenario-dependent terrestrial transit spectra, as seen by the NIR-Spec infrared spectrometer onboard the JWST. We find that the comparatively weak solar event drastically increases the spectral signal of HNO$_3$, while significantly suppressing the spectral feature of ozone. Because of the slow recovery after such events, the latter indicates that ozone might not be a good biomarker for planets orbiting stars with high flaring rates.

astro-ph.EP

Evolution and Spectral Response of a Steam Atmosphere for Early Earth with a coupled climate-interior model

The evolution of Earth's early atmosphere and the emergence of habitable conditions on our planet are intricately coupled with the development and duration of the magma ocean phase during the early Hadean period (4 to 4.5 Ga). In this paper, we deal with the evolution of the steam atmosphere during the magma ocean period. We obtain the outgoing longwave radiation using a line-by-line radiative transfer code GARLIC. Our study suggests that an atmosphere consisting of pure H$_{2}$O, built as a result of outgassing extends the magma ocean lifetime to several million years. The thermal emission as a function of solidification timescale of magma ocean is shown. We study the effect of thermal dissociation of H$_{2}$O at higher temperatures by applying atmospheric chemical equilibrium which results in the formation of H$_{2}$ and O$_{2}$ during the early phase of the magma ocean. A 1-6\% reduction in the OLR is seen. We also obtain the effective height of the atmosphere by calculating the transmission spectra for the whole duration of the magma ocean. An atmosphere of depth ~100 km is seen for pure water atmospheres. The effect of thermal dissociation on the effective height of the atmosphere is also shown. Due to the difference in the absorption behavior at different altitudes, the spectral features of H$_{2}$ and O$_{2}$ are seen at different altitudes of the atmosphere. Therefore, these species along with H$_{2}$O have a significant contribution to the transmission spectra and could be useful for placing observational constraints upon magma ocean exoplanets.

astro-ph.EP

Notes: An assessment of some closed-form expressions for the Voigt function III: Combinations of the Lorentz and Gauss functions

A variety of "pseudo-Voigt" functions, i.e. a linear combination of the Lorentz and Gauss function (occasionally augmented with a correction term), have been proposed as a closed-form approximation for the convolution of the Lorentz and Gauss function known as the Voigt function. First, a compact review of several approximations using a consistent notation is presented. The comparison with accurate reference values indicates relative errors as large as some percent.

physics.comp-ph

The Voigt and complex error function: Humlíček's rational approximation generalized

Accurate yet efficient computation of the Voigt and complex error function is a challenge since decades in astrophysics and other areas of physics. Rational approximations have attracted considerable attention and are used in many codes, often in combination with other techniques. The 12-term code "cpf12" of Humlíček (1979) achieves an accuracy of five to six significant digits throughout the entire complex plane. Here we generalize this algorithm to a larger (even) number of terms. The $n=16$ approximation has a relative accuracy better than $10^{-5}$ for almost the entire complex plane except for very small imaginary values of the argument even without the correction term required for the cpf12 algorithm. With 20 terms the accuracy is better than $10^{-6}$. In addition to the accuracy assessment we discuss methods for optimization and propose a combination of the 16-term approximation with the asymptotic approximation of Humlíček (1982) for high efficiency.

physics.comp-ph

Comments on the Voigt function implementation in the Astropy and SpectraPlot.com packages

The Voigt profile is important for spectroscopy, astrophysics, and many other fields of physics, but is notoriously difficult to compute. McLean et al. [J. Electron Spectrosc. & Relat. Phenom., 1994] have proposed an approximation using a sum of Lorentzians. Our assessment indicates that this algorithm has significant errors for small arguments. After a brief survey of the requirements for spectroscopy we give a short list of both efficient and accurate codes and recommend implementations based on rational approximations.

astro-ph.IM

Transmission Spectroscopy with the ACE-FTS Infrared Spectral Atlas of Earth: A Model Validation and Feasibility Study

Infrared solar occultation measurements are well established for remote sensing of Earth's atmosphere, and the corresponding primary transit spectroscopy has turned out to be valuable for characterization of extrasolar planets. Our objective is an assessment of the detectability of molecular signatures in Earth's transit spectra. To this end, we take a limb sequence of representative cloud-free transmission spectra recorded by the space-borne ACE-FTS Earth observation mission (Hughes et al., ACE infrared spectral atlases of the Earth's atmosphere, JQSRT 2014) and combine these spectra to the effective height of the atmosphere. These data are compared to spectra modeled with an atmospheric radiative transfer line-by-line infrared code to study the impact of individual molecules, spectral resolution, the choice of auxiliary data, and numerical approximations. Moreover, the study serves as a validation of our infrared radiative transfer code. The largest impact is due to water, carbon dioxide, ozone, methane, nitrous oxide, nitrogen, nitric acid, oxygen, and some chlorofluorocarbons (CFC11 and CFC12). The effect of further molecules considered in the modeling is either marginal or absent. The best matching model has a mean residuum of 0.4 km and a maximum difference of 2 km to the measured effective height. For a quantitative estimate of visibility and detectability we consider the maximum change of the residual spectrum, the relative change of the residual norm, the additional transit depth, and signal-to-noise ratios for a JWST setup. In conclusion, our study provides a list of molecules that are relevant for modeling transmission spectra of Earth-like exoplanets and discusses the feasibility of retrieval.

astro-ph.EP

Response of Atmospheric Biomarkers to NOx-induced Photochemistry Generated by Stellar Cosmic Rays for Earth-like Planets in the Habitable Zone of M-Dwarf Stars

Understanding whether M-dwarf stars may host habitable planets with Earth-like atmospheres and biospheres is a major goal in exoplanet research. If such planets exist, the question remains as to whether they could be identified via spectral signatures of biomarkers. Such planets may be exposed to extreme intensities of cosmic rays that could perturb their atmospheric photochemistry. Here, we consider stellar activity of M-dwarfs ranging from quiet up to strong flaring conditions and investigate one particular effect upon biomarkers, namely, the ability of secondary electrons caused by stellar cosmic rays to break up atmospheric molecular nitrogen (N2), which leads to production of nitrogen oxides in the planetary atmosphere, hence affecting biomarkers such as ozone. We apply a stationary model, that is, without a time-dependence, hence we are calculating the limiting case where the atmospheric chemistry response time of the biomarkers is assumed to be slow and remains constant compared with rapid forcing by the impinging stellar flares. This point should be further explored in future work with time-dependent models. For the flaring case O3 is mainly destroyed via direct titration with nitrogen oxides and not via the familiar catalytic cycle photochemistry, which occurs on Earth. For scenarios with low O3, Rayleigh scattering by the main atmospheric gases became more important for shielding the planetary surface from ultra-violet radiation. A major result of this work is that the biomarker O3 survived all the stellar-activity scenarios considered except for the strong case, whereas the biomarker nitrous oxide could survive in the planetary atmosphere under all conditions of stellar activity considered here, which clearly has important implications for missions that aim to detect spectroscopic biomarkers.

astro-ph.EP

Spectral features of Earth-like planets and their detectability at different orbital distances around F, G, and K-type stars

We investigate the spectral appearance of Earth-like exoplanets in the HZ of different main sequence stars at different orbital distances. We furthermore discuss for which of these scenarios biomarker absorption bands may be detected during primary or secondary transit with near-future telescopes and instruments.We analyze the spectra taking into account different filter bandpasses of two photometric instruments planned to be mounted to the JWST. We analyze in which filters and for which scenarios molecular absorption bands are detectable when using the space-borne JWST or the ground-based telescope E-ELT. Absorption bands of CO2, H2O, CH4 and O3 are clearly visible in high-resolution spectra as well as in the filters of photometric instruments. However, only during primary eclipse bands of CO2, H2O and O3 are detectable for all scenarios when using photometric instruments and an E-ELT telescope setup. CH4 is only detectable at the outer HZ of the K star since here the atmospheric modeling results in very high abundances. Since the detectable CO2 and H2O bands overlap, separate bands need to be observed to prove their existence in the atmosphere. In order to detect H2O in a separate band, a S/N>7 needs to be achieved for E-ELT observations, e.g. by co-adding at least 10 transit observations. Using a spaceborne telescope like the JWST enables the detection of CO2 at 4.3mu, which is not possible for ground-based observations due to the Earth's atmospheric absorption. Hence combining observations of spaceborne and groundbased telescopes might allow to detect the presence of the biomarker molecule O3 and the related compounds H2O and CO2 in a planetary atmosphere. Other absorption bands using the JWST can only be detected for much higher S/Ns, which is not achievable by just co-adding transit observations since this would be far beyond the planned mission time of JWST.(abridged)

astro-ph.EP