Fu Mo | Searcharxiv

arXiv2026

NO molecule in massive star forming regions

Context. Among diatomic molecules composed of the abundant elements C, N and O, NO has been detected far less than the well studied CN and CO, making it a crucial yet under-observed component in nitrogen-containing chemical networks. NO was thought to serve as a potential tracer of shocks, as evidenced with orders abundance enhancements reported in literature. Aims. Large-sample observations for NO molecule in widespread interstellar environments are needed to confirm if the enhancement of NO is due to shock chemistry or not. Methods. Single-point survey for NO lines around 150 GHz was carried out by Arizona Radio Observatory 12-meter telescope towards a sample of 36 massive star forming regions containing SiO emission, which include three evolutionary stages: 4 IRDCs, 6 protostars and 26 H II regions. Results. The NO emission was detected in 28 sources with a detection rate of 78%. Beam-averaged NO column densities and abundances relative to H2 were derived from integrated intensities of two main hyperfine lines. Correlations between NO and SiO in integrated intensity and relative abundance are similar to the corresponding correlations of c-C3H2, indicating that NO enrichment may not significantly involve pronounced shock activities, which coincides with the trend in line widths: NO is close to c-C3H2, both smaller than H2CO and far smaller than SiO. Conclusions. Observational evidence does not strongly support significant NO enhancement by shock chemistry in the observed sources, indicating that the formation of NO does not necessarily require shocks.

astro-ph.GA↗

arXiv2025

DCO$^+$ and DCN 1-0 survey toward a sample of Planck cold clumps

Deuterated molecules can be used to study the physical conditions and the astro-chemical evolution of molecular clouds. large-sample surveys for deuterated molecules are needed to understand the enhancement of deuterated molecules from diffuse molecular gas to cold cores. A single-pointing survey toward the 559 Planck cold clumps of the Early Cold Core Catalogue (ECC) has been conducted using the Arizona Radio Observatory 12-meter telescope, focusing on the $J$=1-0 transitions of DCO$^+$ and DCN. The survey included observations of 309 cores for DCO$^+$ and DCN 1-0 simultaneously, followed by 71 of these cores where DCO$^+$ 1-0 was detected for H$^{13}$CO$^+$ and H$^{13}$CN 1-0 simultaneously, aiming to determine the deuterated fraction ($D_{\rm frac}$). Additionally, 250 cores were observed for DCO$^+$, DCN, H$^{13}$CO$^+$ and H$^{13}$CN 1-0 simultaneously. Among the 309 sources, DCO$^+$ and DCN 1-0 were detected in 79 and 11 sources, with a detection rates of 25.6 % and 3.6 % respectively. In the 250 sources observed for all four species, DCO$^+$, DCN, H$^{13}$CO$^+$ and H$^{13}$CN 1-0 were detected in 58, 9, 57 and 13 sources, with a detection rate of 23.2 %, 3.6 %, 22.8 % and 5.2 % respectively. The $D_{\rm frac}$(HCO$^+$) values in 112 sources range from 0.89 % to 7.4 % with a median value of 3.1 %, while $D_{\rm frac}$(HCN) values in 11 sources range from 1.5 % to 5.5 % with a median value of 2.3 %. The line widths of DCO$^+$ and H$^{13}$CO$^+$ 1-0 detections are mostly within 1 km s$^{-1}$. The similarity in $D_{\rm frac}$ values between HCO$^+$ and HCN indicates that the higher detection rate of DCO$^+$ 1-0 compared with DCN 1-0 is due to the lower critical density of DCO$^+$ 1-0. We suggest that the enhancement of DCO$^+$ and DCN likely begins in the early diffuse stage of the molecular cloud, rather than during the cold core formation stage.

astro-ph.GA↗