arXiv subjects

Fumitaka Kagawa

Publications and source records attributed to Fumitaka Kagawa.

At least 19 recordsLinked to original sources

arXiv2026

Thermally quenched metastability in metal-insulator transitions via elemental substitution

Thermal quenching inhibits equilibration toward the thermodynamic ground state during phase transitions, revealing metastable phases such as structural glasses and quenched alloys. Whether such thermally quenched metastability can be realized in metal-insulator transitions has remained an open question because these transformations are governed by collective electronic reorganization rather than atomic diffusion. We demonstrate that rapid cooling exceeding 10$^9$ K s$^{-1}$ kinetically avoids the metal-insulator transition, stabilizing a long-lived metastable metallic phase in tungsten-substituted VO$_2$. Temperature-dependent relaxation reveals nucleation-dominated kinetics with a thermal activation barrier introduced by tungsten substitution. Our results establish elemental substitution as a route to thermally quenched metastability in metal-insulator transitions, expanding metastable phase control to electronic phases.

cond-mat.str-el↗

arXiv2026

Volatile resistive-switched state in a bulk organic conductor with a sharp metal-insulator transition

Volatile resistive switching in correlated-electron systems, characterized by an abrupt resistance decrease under applied current, is crucial for developing next-generation electronics. Despite its technological significance, the underlying physics remains elusive. Inorganic thin films on substrates---the widely studied platform for resistive switching---usually exhibit broad temperature-induced metal-insulator transitions (MITs) and substantial heat dissipation. These factors complicate the nonlinear thermal effect induced by Joule heating, a key contributor to resistive switching, rendering it excessively complex and difficult to decipher. Here we investigate a resistive-switched state in the bulk organic conductor ($d$7-DMe-DCNQI)$_{2}$Cu, which undergoes an extremely sharp first-order MIT and exhibits weak heat dissipation, using resistance and $^{1}$H-NMR measurements. These extreme conditions make the Joule heating effect vivid, allowing us to observe peculiar phenomena, including temperature locking to the MIT and `inverse Ohm's law'---an inverse proportionality between voltage and current. These findings provide fundamental insights into the nonlinear thermal effect in resistive switching, offering a pathway to efficient resistive-switching technologies.

cond-mat.str-el↗

arXiv2025

Magnetoelectric coupling and its impact on the multicaloric effect

The multicaloric effect, which represents the reversible entropy change that occurs when both external magnetic and electric fields are applied, is an interesting phenomenon characteristic to multiferroics. Targeting the multicaloric effect in the typical multiferroic (Fe$_{0.95}$Zn$_{0.05}$)$_2$Mo$_3$O$_8$, we experimentally evaluate the isothermal entropy change due to a magnetoelectric cross-correlation. A pronounced cross-correlation-derived isothermal entropy change is found at the magnetic ordering temperature. By exploring the literature, we suggest that a magnetic phase transition may tend to involve a considerably larger cross-correlation-derived entropy change than that derived from the linear magnetoelectric effect.

cond-mat.mtrl-sci↗

arXiv2025

Reply to "Comment on "Reconsidering the nonlinear emergent inductance: time-varying Joule heating and its impact on the AC electrical response"" by Yokouch et al

This is a response to the comments [arXiv:2407.15682 and Phys.Rev.B 111, 146401 (2025)] by Yokouchi et al. on our paper in Phys.Rev.B 110, 174402 (2024). In this Reply, we note that (i) their arguments lack a discussion of whether the overall characteristics of the observed nonlinear impedance, including its magnitude and unphysical negative inductance interpretation, can be explained by the emergent induction scenario, whereas the Joule heating model can, (ii) they incorrectly refer to the Joule heating model, and (iii) their new data in the Comment are also quantitatively explained by the Joule heating model. These findings suggest that, contrary to the opinion by Yokouchi et al., the overall behavior of the observed impedance is irrelevant to emergent induction.

cond-mat.mtrl-sci↗

arXiv2025

Thermally quenched metastable phase in the Ising model with competing interactions

Thermal quenching has been used to find metastable materials such as hard steels and metallic glasses. More recently, quenching-based phase control has been applied to correlated electron systems that exhibit metal--insulator, magnetic or superconducting transitions. Despite the discovery of metastable electronic phases, however, how metastability is achieved through the degrees of freedom, which can vary even at low temperatures such as those of an electron, is unclear. Here, we show a thermally quenched metastable phase in the Ising model without conservation of magnetization by Monte Carlo simulations. When multiple types of interactions that stabilize different long-range orders are introduced, the ordering kinetics divergently slow toward low temperatures, meaning that the system will reach a low temperature without ordering if the cooling rate is high enough. Quantitative analysis of the divergent behavior suggests that the energy barrier for eliminating the local structure of competing orders is the origin of this metastability. Thus, the present simulations show that competing interactions play a key role in realizing metastability.

cond-mat.mtrl-sci↗

arXiv2025

Ultrahigh room-temperature hole conductivity in a perovskite cuprate with vanishing electron-correlation

Electron-correlated two-dimensional (2D) cuprates have been extensively studied since the discovery of high-Tc superconductivity, in contrast, the three-dimensional (3D) counterpart perovskite cuprates remain largely unexplored due to their chemical instability and synthesis challenges. Herein, we develop an efficient two-step approach that combines symmetry-selective growth and topotactic oxidization to synthesize high-quality perovskite LaCuO3 films, and furthermore reveal its exotic electronic states. The compressively strained LaCuO3 films exhibit an unexpected ultrahigh p-type conductivity of ~1.5*10^5 S/cm with a hole mobility of ~30 cm2 V-1 s-1 at room-temperature. X-ray absorption spectra and first-principles calculations unveil a ligand-hole state of p-d hybridization with degenerate eg orbitals and light effective mass, indicating nearly-vanishing electron-correlation. These features contrast sharply with 2D cuprates and offer physical insights into the design of high-performance electronic devices.

cond-mat.str-el↗

arXiv2025

Observation of the nonlinear chiral thermoelectric Hall effect in tellurium

The nonlinear thermoelectric effect is a key factor for realising unconventional thermoelectric phenomena, such as heat rectification and power generation using thermal fluctuations. Recent theoretical advances have indicated that chiral materials can host a variety of exotic nonlinear thermoelectric transport arising from inversion-symmetry breaking. However, experimental demonstration has yet to be achieved. Here, we report the observation of the nonlinear chiral thermoelectric Hall effect in chiral tellurium at room temperature, where a voltage is generated as a cross product of the temperature gradient and electric field. The resulting thermoelectric Hall voltage is on the order of μV, consistent with the prediction from the ab initio calculation. Furthermore, the sign of the thermoelectric Hall voltage is reversed depending on the crystal chirality, demonstrating a novel functionality of sign control of the thermoelectric effect by the chirality degrees of freedom. Our findings reveal the potential of chiral systems as nonlinear thermoelectric materials for advanced thermal management and energy harvesting.

cond-mat.mes-hall↗

arXiv2025

Unveiling an in-plane Hall effect in rutile RuO$_2$ films

The in-plane-magnetic-field-induced Hall effect (IPHE) observed in Weyl semimetals and PT-symmetric antiferromagnets has attracted increasing attention, as it breaks the stereotype that the Hall effect is induced by an out-of-plane magnetic field or magnetization. To date, the IPHE has been discussed mainly for materials with low-symmetry crystal/magnetic point groups. Here, we show that even if symmetry forbids an inherent IPHE that arises from any mechanism, an apparent IPHE can be generated by selecting a low-symmetry crystalline plane for measurement. For rutile RuO$_2$, although its high symmetry forbids an inherent IPHE, films grown along the low-symmetry (1 1 1) and (1 0 1) orientations are found to exhibit a distinct IPHE. The in-plane Hall coefficients are quantitatively reproduced by referring to the out-of-plane Hall coefficients measured for the high-symmetry (1 0 0) and (0 0 1) planes, indicating that the observed IPHE is caused by a superposition of inequivalent out-of-plane Hall effects. Similar behaviour is also observed for paramagnetic rutile systems, indicating the ubiquity of the apparent IPHE in electronic and spintronic devices with low-symmetry crystalline planes.

cond-mat.mtrl-sci↗

arXiv2024

Reconsidering the nonlinear emergent inductance: time-varying Joule heating and its impact on the AC electrical response

A nonlinearly enhanced electrical reactance, $\Im Z$, under a large AC current has been measured to explore emergent inductors, which constitute a new class of inductors based on the spin-transfer torque effect. A nonlinear $\Im Z$ has been observed in conducting magnets that contain noncollinear spin textures and interpreted as the realization of an inductance due to current-induced spin dynamics. However, curious behavior has concomitantly been observed. For instance, the nonlinear $\Im Z$ always has a cutoff frequency of $10^0$--$10^4$ Hz, which is much lower than the resonance frequency of a ferromagnetic domain wall, $\sim$10$^7$ Hz; furthermore, the temperature and magnetic field variations in $\Im Z$ appear to be considerably correlated with those in the temperature derivative of resistance. This behavior appears to be difficult to understand in terms of the current-induced spin dynamics, and therefore, the earlier interpretation of the nonlinear $\Im Z$ should be further verified. Here, we theoretically and experimentally show that time-varying Joule heating and its impact on the AC electrical response can naturally explain these observations. In the experimental approach, we study the nonlinear AC electrical response of two conducting materials that exhibit no magnetic order, CuIr$_2$S$_4$ and 1$T$'-MoTe$_2$. Under time-varying Joule heating, a nonlinearly enhanced $\Im Z$ with the curious behavior mentioned above is observed in both systems. Our study implies that the nonlinear $\Im Z$ previously observed in noncollinear magnets includes a considerable contribution of the Joule-heating-induced apparent AC impedance.

cond-mat.mtrl-sci↗

arXiv2024

Quantum liquid states of spin solitons in a ferroelectric spin-Peierls state

In this study, we performed high-magnetic-field magnetization, dielectric, and ultrasound measurements on an organic salt showing a ferroelectric spin-Peierls (FSP) state, which is in close proximity to a quantum critical point. In contrast to the sparsely distributed gas-like spin solitons typically observed in conventional spin-Peierls (SP) states, the FSP state exhibits dense liquid-like spin solitons resulting from strong quantum fluctuations, even at low fields. Nevertheless, akin to conventional SP systems, a magnetic-field-induced transition is observed in the FSP state. In conventional high-field SP states, an emergent wave vector results in the formation of a spin-soliton lattice. However, in the present high-field FSP state, the strong quantum fluctuations preclude the formation of such a soliton lattice, causing the dense solitons to remain in a quantum-mechanically melted state. This observation implies the realization of a quantum liquid--liquid transition of topological particles carrying spin and charge in a ferroelectric insulator.

cond-mat.str-el↗

arXiv2023

Signature of geometry modulation on interface magnetism emerged in isomeric IrO2-CoFe2O4 heterostructures

The interface composed of magnets and strong spin-orbit coupling (SOC) materials forms an important platform for spintronic devices and intriguing magnetic phenomena, such as the chiral spin textures and magnetic proximity effect (MPE). The interface exchange interaction and Dzyaloshinskii-Moriya interaction (DMI) have been discussed in a wide range of heterostructures, while the crystal stacking geometry modulation on these interface interactions has rarely been considered. Here, we show a pronounced geometry modulation on the interface magnetism through comparing a rutile and an anatase IrO2 capping on a ferrimagnetic CoFe2O4. The rutile heterostructure with a high-symmetry interface shows a conventional anomalous Hall effect (AHE) profile due to the MPE. In contrast, the anatase one with a low-symmetry interface exhibits a topological-like AHE even at zero-field, suggesting the emergence of non-coplanar magnetic order at the interface. Our results suggest that the influence of DMI at the interface can be more accentuated by forming a low-symmetry interface and raises a new means of designing interface magnetism via the geometry modulation.

cond-mat.mtrl-sci↗

arXiv2023

Multiple Magnetoelectric Plateaux in Polar Magnet Fe$_2$Mo$_3$O$_8$

The magnetization and electric polarization of a polar antiferromagnet Fe$_2$Mo$_3$O$_8$ are studied up to 66 T for spin-saturation magnetic fields applied along the polar axis. The magnetization process at 1.4 K exhibited multistep structures below the saturation field of 65 T. The electric polarization along the polar axis exhibits a similar multistep behavior with a total change of 1.2 $\rmμC/cm^{2}$. A combined triangular-lattice antiferromagnetic model with strong Ising-type spin anisotropy reproduces this multistep magnetoelectric (ME) effect. The exchange striction mechanism explains the remarkable ME response in the two sub-lattice type-I multiferroic materials. These results and interpretation demonstrate a method for realizing multistage magnetoelectric effects in hybrid spin systems.

cond-mat.str-el↗

arXiv2023

Low-temperature hysteresis broadening emerging from domain-wall creep dynamics in a two-phase competing system

Hysteretic behaviour accompanies any first-order phase transition, forming a basis for many applications. However, its quantitative understanding remains challenging, and even a qualitative understanding of pronounced hysteresis broadening at low temperature, which is often observed in magnetic-field-induced first-order phase transition materials, is unclear. Here, we show that such pronounced hysteresis broadening emerges if the phase-front velocity during the first-order phase transition exhibits an activated behaviour as a function of both temperature and magnetic field. This is demonstrated by using real-space magnetic imaging techniques, for the magnetic-field-induced first-order phase transition between antiferromagnetic and ferrimagnetic phases in (Fe$_{0.95}$Zn$_{0.05}$)$_{2}$Mo$_{3}$O$_{8}$. When combined with the Kolmogorov-Avrami-Ishibashi model, the observed activated temperature- and field-dependences of the growth velocity of the emerging antiferromagnetic domain quantitatively reproduce the pronounced hysteresis broadening. Furthermore, the same approach also reproduces the field-sweep-rate dependence of the transition field observed in the experiment. Our findings thus provide a quantitative and comprehensive understanding of pronounced hysteresis broadening from the microscopic perspective of domain growth.

cond-mat.mtrl-sci↗

arXiv2023

Symmetry of the emergent inductance tensor exhibited by magnetic textures

Metals hosting gradually varying spatial magnetic textures are attracting attention as a new class of inductor. Under the application of an alternating current, the spin-transfer-torque effect induces oscillating dynamics of the magnetic texture, which subsequently yields the spin-motive force as a back action, resulting in an inductive voltage response. In general, a second-order tensor representing a material's response can have an off-diagonal component. However, it is unclear what symmetries the emergent inductance tensor has and also which magnetic textures can exhibit a transverse inductance response. Here we reveal both analytically and numerically that the emergent inductance tensor should be a symmetric tensor in the so-called adiabatic limit. By considering this symmetric tensor in terms of symmetry operations that a magnetic texture has, we further characterize the magnetic textures in which the transverse inductance response can appear. This finding provides a basis for exploring the transverse response of emergent inductors, which has yet to be discovered.

cond-mat.mtrl-sci↗

arXiv2023

Emergent zero-field anomalous Hall effect in a reconstructedrutileantiferromagnetic metal

Anomalous Hall effect (AHE) emerged in antiferromagnetic metals shows intriguing physics and application potential. In contrast to certain noncollinear antiferromagnets, rutile RuO$_2$ has been proposed recently to exhibit a crystal-assisted AHE with collinear antiferromagnetism. However, in RuO$_2$, the on-site magnetic moment accompanying itinerant 4d electrons is quite small, and more importantly, the AHE at zero external field is prohibited by symmetry because of the high-symmetry [001] direction of the Néel vector. Here, we show the AHE at zero field in the collinear antiferromagnet, Cr-doped RuO$_2$. The appropriate doping of Cr at Ru sites results in a rotation of the Néel vector from [001] to [110] and enhancement of the on-site magnetic moment by one order of magnitude while maintaining a metallic state with the collinear antiferromagnetism. The AHE with vanishing net moment in the Ru$_{0.8}$Cr$_{0.2}$O$_2$ exhibits an orientation dependence consistent with the [110]-oriented Néel vector. These results open a new avenue to manipulate AHE in antiferromagnetic metals.

cond-mat.mtrl-sci↗

arXiv2023

Thermodynamic determination of the equilibrium first-order phase-transition line hidden by hysteresis in a phase diagram

Phase diagrams form the basis for the study of material science, and the profiles of phase-transition lines separating different thermodynamic phases include comprehensive information about thermodynamic quantities, such as latent heat. However, in some materials exhibiting field-induced first-order transitions (FOTs), the equilibrium phase-transition line is hidden by the hysteresis region associated with the FOT; thus, it cannot be directly determined from measurements of resistivity, magnetization, etc. Here, we demonstrate a thermodynamics-based method for determining the hidden equilibrium FOT line. This method is verified for the FOT between antiferromagnetic and ferrimagnetic states in magneto-electric compounds (Fe$_{0.95}$Zn$_{0.05}$)$_{2}$Mo$_{3}$O$_{8}$. The equilibrium FOT line determined based on the Clausius-Clapeyron equation exhibits a reasonable profile in terms of the third law of thermodynamics, and it shows marked differences from the midpoints of the hysteresis region. Our findings highlight that care should be taken for referring to the hysteresis midpoint line when discussing field-induced latent heat or magnetocaloric effects.

cond-mat.mtrl-sci↗

arXiv2022

Unveiling the anisotropic fractal magnetic domain structure in bulk crystal of antiskyrmion-host (Fe,Ni,Pd)$_3$P by small-angle neutron scattering

Intermetallic Pd-doped (Fe,Ni)$_3$P, that crystalizes in a non-centrosymmetric tetragonal structure with $S_4$ symmetry, has recently been discovered to host magnetic antiskyrmions, antivortex-like topological spin textures. In this material, uniaxial magnetic anisotropy and dipolar interactions play a significant role, giving rise to finely branched magnetic domain patterns near the surface of bulk crystals, as revealed by a previous magnetic force microscopy (MFM) measurement. However, small-angle neutron scattering (SANS) is a more suitable method for characterizing bulk properties and fractal structures at the mesoscopic length scale. In this study, using SANS and MFM, we quantitatively investigate the magnetic domain structure in bulk single crystals of (Fe$_{0.63}$Ni$_{0.30}$Pd$_{0.07}$)$_3$P. The SANS results demonstrate that the magnetic domain structure exhibits anisotropic fractal character on the length scale down to the width of the magnetic domain walls. The fractal features are gradually lost in magnetic fields, and different field dependences are observed at 300 K and 2 K due to a temperature-dependent anisotropy. This study quantifies the fractality of the highly anisotropic magnetic domain structures in an antiskyrmion material, and highlights the versatility of SANS for the study of fractal structures in magnetic systems.

cond-mat.str-el↗

arXiv2022

Spin-charge coupling and decoupling in perovskite-type iron oxides (Sr$_{1-x}$Ba$_x$)$_{2/3}$La$_{1/3}$FeO$_3$

The perovskite-type iron oxide Sr$_{2/3}$La$_{1/3}$FeO$_3$ is known to show characteristic spin-charge ordering (SCO), where sixfold collinear spin ordering and threefold charge ordering are coupled with each other. Here, we report the discovery of a spin-charge decoupling and an antiferromagnetic (AFM) state competing with the SCO phase in perovskites (Sr$_{1-x}$Ba$_x$)$_{2/3}$La$_{1/3}$FeO$_3$. By comprehensive measurements including neutron diffraction, M$ö$ssbauer spectroscopy, and x-ray absorption spectroscopy, we found that the isovalent Ba$^{2+}$ substitution systematically reduces the critical temperature of the SCO phase and additionally yields the spin-charge decoupling in $x$ > 0.75. Whereas the ground state remains in the SCO phase in the whole $x$ region, an unexpected G-type AFM phase with incoherent charge ordering or charge fluctuation appears as the high-temperature phase in the range of $x$ > 0.75. Reflecting the competing nature between them, the G-type AFM phase partially exists as a metastable state in the SCO phase at low temperatures. We discuss the origin of the spin-charge decoupling and the emergence of the G-type AFM phase with charge fluctuation in terms of the bandwidth reduction by the Ba substitution.

cond-mat.str-el↗