Searcharxiv⌕ Search

arXiv subjects

G. Andrew D. Briggs

Publications and source records attributed to G. Andrew D. Briggs.

44 records · Page 3Linked to original sources

Efficient Dynamic Nuclear Polarization at High Magnetic Fields

By applying a new technique for dynamic nuclear polarization involving simultaneous excitation of electronic and nuclear transitions, we have enhanced the nuclear polarization of the nitrogen nuclei in 15N@C60 by a factor of 1000 at a fixed temperature of 3 K and a magnetic field of 8.6 T, more than twice the maximum enhancement reported to date. This methodology will allow the initialization of the nuclear qubit in schemes exploiting N@C60 molecules as components of a quantum information processing device.

quant-ph↗

The effects of a pyrrolidine functional group on the magnetic properties of N@C60

A new stable pyrrolidine functionalized fullerene derivative, C69H10N2O2, has been synthesized, purified by high performance liquid chromatography, and characterized by MALDI mass spectrometry, ultraviolet-visible spectroscopy, Fourier transform infrared, 1H and 13C nuclear magnetic resonance. The magnetic properties of the analogous endohedral species have been studied by both continuous wave (CW) and pulsed EPR. CW-EPR spectra indicated an anisotropic hyperfine interaction and a permanent zero-field-splitting (ZFS). Both CW and pulsed EPR showed the ZFS parameter Deff to be around 17 MHz. Pulsed EPR revealed a biexponential decay in both T1 and T2, yielding a molecular tumbling correlation time of 31.4 +/- 2.5 ps.

physics.chem-ph↗

Bang-bang control of fullerene qubits using ultra-fast phase gates

Quantum mechanics permits an entity, such as an atom, to exist in a superposition of multiple states simultaneously. Quantum information processing (QIP) harnesses this profound phenomenon to manipulate information in radically new ways. A fundamental challenge in all QIP technologies is the corruption of superposition in a quantum bit (qubit) through interaction with its environment. Quantum bang-bang control provides a solution by repeatedly applying `kicks' to a qubit, thus disrupting an environmental interaction. However, the speed and precision required for the kick operations has presented an obstacle to experimental realization. Here we demonstrate a phase gate of unprecedented speed on a nuclear spin qubit in a fullerene molecule (N@C60), and use it to bang-bang decouple the qubit from a strong environmental interaction. We can thus trap the qubit in closed cycles on the Bloch sphere, or lock it in a given state for an arbitrary period. Our procedure uses operations on a second qubit, an electron spin, in order to generate an arbitrary phase on the nuclear qubit. We anticipate the approach will be vital for QIP technologies, especially at the molecular scale where other strategies, such as electrode switching, are unfeasible.

quant-ph↗

Electron spin relaxation of N@C60 in CS2

We examine the temperature dependence of the relaxation times of the molecules N@C60 and N@C70 (which comprise atomic nitrogen trapped within a carbon cage) in liquid CS2 solution. The results are inconsistent with the fluctuating zero field splitting (ZFS) mechanism, which is commonly invoked to explain electron spin relaxation for S > 1/2 spins in liquid solution, and is the mechanism postulated in the literature for these systems. Instead, we find a clear Arrhenius temperature dependence for N@C60, indicating the spin relaxation is driven primarily by an Orbach process. For the asymmetric N@C70 molecule, which has a permanent non-zero ZFS, we resolve an additional relaxation mechanism caused by the rapid reorientation of its ZFS. We also report the longest coherence time (T2) ever observed for a molecular electron spin, being 0.25 ms at 170K.

cond-mat.mtrl-sci↗

High Fidelity Single Qubit Operations using Pulsed EPR

Systematic errors in spin rotation operations using simple RF pulses place severe limitations on the usefulness of the pulsed magnetic resonance methods in quantum computing applications. In particular, the fidelity of quantum logic operations performed on electron spin qubits falls well below the threshold for the application of quantum algorithms. Using three independent techniques, we demonstrate the use of composite pulses to improve this fidelity by several orders of magnitude. The observed high-fidelity operations are limited by pulse phase errors, but nevertheless fall within the limits required for the application of quantum error correction.

quant-ph↗

Quantum Computing with Spin Qubits Interacting Through Delocalized Excitons: Overcoming Hole Mixing

As a candidate scheme for controllably coupled qubits, we consider two quantum dots, each doped with a single electron. The spin of the electron defines our qubit basis and trion states can be created by using polarized light; we show that the form of the excited trion depends on the state of the qubit. By using the Luttinger-Kohn Hamiltonian we calculate the form of these trion states in the presence of light-heavy hole mixing, and show that they can interact through both the Förster transfer and static dipole-dipole interactions. Finally, we demonstrate that by using chirped laser pulses, it is possible to perform a two-qubit gate in this system by adiabatically following the eigenstates as a function of laser detuning. These gates are robust in that they operate with any realistic degree of hole mixing, and for either type of trion-trion coupling.

quant-ph↗

A new mechanism for electron spin echo envelope modulation

Electron spin echo envelope modulation (ESEEM) has been observed for the first time from a coupled hetero-spin pair of electron and nucleus in liquid solution. Previously, modulation effects in spin echo experiments have only been described in liquid solutions for a coupled pair of homonuclear spins in NMR or a pair of resonant electron spins in EPR. We observe low-frequency ESEEM (26 and 52 kHz) due to a new mechanism present for any electron spin with S>1/2 that is hyperfine coupled to a nuclear spin. In our case these are electron spin (S=3/2) and nuclear spin (I=1) in the endohedral fullerene N@C60. The modulation is shown to arise from second order effects in the isotropic hyperfine coupling of an electron and 14N nucleus.

quant-ph↗

Measuring errors in single qubit rotations by pulsed electron paramagnetic resonance

The ability to measure and reduce systematic errors in single-qubit logic gates is crucial when evaluating quantum computing implementations. We describe pulsed electron paramagnetic resonance (EPR) sequences that can be used to measure precisely even small systematic errors in rotations of electron-spin-based qubits. Using these sequences we obtain values for errors in rotation angle and axis for single-qubit rotations using a commercial EPR spectrometer. We conclude that errors in qubit operations by pulsed EPR are not limiting factors in the implementation of electron-spin based quantum computers.

quant-ph↗