arXiv subjects

G. Biroli

Publications and source records attributed to G. Biroli.

36 records · Page 2Linked to original sources

arXiv2009

Mode-Coupling as a Landau Theory of the Glass Transition

We derive the Mode Coupling Theory (MCT) of the glass transition as a Landau theory, formulated as an expansion of the exact dynamical equations in the difference between the correlation function and its plateau value. This sheds light on the universality of MCT predictions. While our expansion generates higher order non-local corrections that modify the standard MCT equations, we find that the square root singularity of the order parameter, the scaling function in the βregime and the functional relation between the exponents defining the αand βtimescales are universal and left intact by these corrections.

cond-mat.stat-mech↗

arXiv2009

The building blocks of dynamical heterogeneities in dense granular media

We investigate experimentally the connection between short time dynamics and long time dynamical heterogeneities within a dense granular media under cyclic shear. We show that dynamical heterogeneities result from a two timescales process. Short time but already collective events consisting in clustered cage jumps concentrate most of the non affine displacements. On larger timescales such clusters appear aggregated both temporally and spatially in avalanches which eventually build the large scales dynamical heterogeneities. Our results indicate that facilitation plays an important role in the relaxation process although it does not appear to be conserved as proposed in many models studied in the literature.

cond-mat.soft↗

arXiv2008

Thermodynamic signature of growing amorphous order in glass-forming liquids

Although several theories relate the steep slowdown of glass formers to increasing spatial correlations of some sort, standard static correlation functions show no evidence for this. We present results that reveal for the first time a qualitative thermodynamic difference between the high temperature and deeply supercooled equilibrium glass-forming liquid: the influence of boundary conditions propagates into the bulk over larger and larger lengthscales upon cooling, and, as this static correlation length grows, the influence decays nonexponentially. Increasingly long-range susceptibility to boundary conditions is expected within the random firt-order theory (RFOT) of the glass transition, but a quantitative account of our numerical results requires a generalization of RFOT where the surface tension between states fluctuates.

cond-mat.dis-nn↗

arXiv2008

Critical scaling and heterogeneous superdiffusion across the jamming/rigidity transition of a granular glass

The dynamical properties of a dense horizontally vibrated bidisperse granular monolayer are experimentally investigated. The quench protocol produces states with a frozen structure of the assembly, but the remaining degrees of freedom associated with contact dynamics control the appearance of macroscopic rigidity. We provide decisive experimental evidence that this transition is a critical phenomenon, with increasingly collective and heterogeneous rearrangements occurring at length scales much smaller than the grains' diameter, presumably reflecting the contact force network fluctuations. Dynamical correlation time and length scales soar on both sides of the transition, as the volume fraction varies over a remarkably tiny range ($δϕ/ϕ\sim 10^{-3}$). We characterize the motion of individual grains, which becomes super-diffusive at the jamming transition $ϕ_J$, signaling long-ranged temporal correlations. Correspondingly, the system exhibits long-ranged four-point dynamical correlations in space that obey critical scaling at the transition density.

cond-mat.soft↗

arXiv2008

The Valence Bond Glass phase

We show that a new glassy phase can emerge in presence of strong magnetic frustration and quantum fluctuations. It is a Valence Bond Glass. We study its properties solving the Hubbard-Heisenberg model on a Bethe lattice within the large $N$ limit introduced by Affleck and Marston. We work out the phase diagram that contains Fermi liquid, dimer and valence bond glass phases. This new glassy phase has no electronic or spin gap (although a pseudo-gap is observed), it is characterized by long-range critical valence bond correlations and is not related to any magnetic ordering. As a consequence it is quite different from both valence bond crystals and spin glasses.

cond-mat.str-el↗

arXiv2007

Lower bound on the four-point dynamical susceptibility: Direct experimental test on a granular packing

We track the motion of a horizontally vibrated amorphous assembly of bidisperse hard disks, for densities ranging across the jamming transition. We derive on very general grounds a bound on the dynamical susceptibility in terms of the response of the dynamics to a change in density. This generalizes a similar bound recently derived for equilibrium liquids. We find that in our experimental system the bound is tight and reproduces the non-monotonic behavior of the dynamical susceptibility both in time and density across the jamming transition. The underlying scaling behavior reveals an intimate connection between anomalous diffusion and dynamical heterogeneity.

cond-mat.soft↗

arXiv2006

Dynamical field theory for glass-forming liquids, self-consistent resummations and time-reversal symmetry

We analyse the symmetries and the self-consistent perturbative approaches of dynamical field theories for glassforming liquids. In particular, we focus on the time-reversal symmetry (TRS), which is crucial to obtain fluctuation-dissipation relations (FDRs). Previous field theoretical treatment violated this symmetry, whereas others pointed out that constructing symmetry preserving perturbation theories is a crucial and open issue. In this work we solve this problem and then apply our results to the mode-coupling theory of the glass transition (MCT). We show that in the context of dynamical field theories for glass-forming liquids TRS is expressed as a nonlinear field transformation that leaves the action invariant. Because of this nonlinearity, standard perturbation theories generically do not preserve TRS and in particular FDRs. We show how one can cure this problem and set up symmetry-preserving perturbation theories by introducing some auxiliary fields. As an outcome we obtain Schwinger-Dyson dynamical equations that automatically preserve FDRs and that serve as a basis for carrying out symmetry-preserving approximations. We apply our results to MCT, revisiting previous field theory derivations of MCT equations and showing that they generically violate FDR. We obtain symmetry-preserving mode-coupling equations and discuss their advantages and drawbacks. Furthermore, we show, contrary to previous works, that the structure of the dynamic equations is such that the ideal glass transition is not cut off at any finite order of perturbation theory, even in the presence of coupling between current and density. The opposite results found in previous field theoretical works, such as the ones based on nonlinear fluctuating hydrodynamics, were only due to an incorrect treatment of TRS.

cond-mat.stat-mech↗

arXiv2005

Dynamical Heterogeneity close to the Jamming Transition in a Sheared Granular Material

The dynamics of a bi-dimensional dense granular packing under cyclic shear is experimentally investigated close to the jamming transition. Measurement of multi-point correlation functions are produced. The self-intermediate scattering function, displaying slower than exponential relaxation, suggests dynamic heterogeneity. Further analysis of four point correlation functions reveal that the grain relaxations are strongly correlated and spatially heterogeneous, especially at the time scale of the collective rearrangements. Finally, a dynamical correlation length is extracted from spatio-temporal pattern of mobility. Our experimental results open the way to a systematic study of dynamic correlation functions in granular materials.

cond-mat.stat-mech↗

arXiv2005

Are defect models consistent with the entropy and specific heat of glass-formers?

We show that point-like defect model of glasses cannot explain thermodynamic properties of glass-formers, as for example the excess specific heat close to the glass transition, contrary to the claim of J.P. Garrahan, D. Chandler [Proc. Natl. Acad. Sci. 100, 9710 (2003)]. More general models and approaches in terms of extended defects are also discussed.

cond-mat.stat-mech↗

arXiv2004

Cooperative Behavior of Kinetically Constrained Lattice Gas Models of Glassy Dynamics

Kinetically constrained lattice models of glasses introduced by Kob and Andersen (KA) are analyzed. It is proved that only two behaviors are possible on hypercubic lattices: either ergodicity at all densities or trivial non-ergodicity, depending on the constraint parameter and the dimensionality. But in the ergodic cases, the dynamics is shown to be intrinsically cooperative at high densities giving rise to glassy dynamics as observed in simulations. The cooperativity is characterized by two length scales whose behavior controls finite-size effects: these are essential for interpreting simulations. In contrast to hypercubic lattices, on Bethe lattices KA models undergo a dynamical (jamming) phase transition at a critical density: this is characterized by diverging time and length scales and a discontinuous jump in the long-time limit of the density autocorrelation function. By analyzing generalized Bethe lattices (with loops) that interpolate between hypercubic lattices and standard Bethe lattices, the crossover between the dynamical transition that exists on these lattices and its absence in the hypercubic lattice limit is explored. Contact with earlier results are made via analysis of the related Fredrickson-Andersen models, followed by brief discussions of universality, of other approaches to glass transitions, and of some issues relevant for experiments.

cond-mat.stat-mech↗

arXiv2004

On the Adam-Gibbs-Wolynes scenario for the viscosity increase in glasses

We reformulate the interpretation of the mean-field glass transition scenario for finite dimensional systems, proposed by Wolynes and collaborators. This allows us to establish clearly a temperature dependent length xi* above which the mean-field glass transition picture has to be modified. We argue in favor of the mosaic state introduced by Wolynes and collaborators, which leads to the Adam-Gibbs relation between the viscosity and configurational entropy of glass forming liquids. Our argument is a mixture of thermodynamics and kinetics, partly inspired by the Random Energy Model: small clusters of particles are thermodynamically frozen in low energy states, whereas large clusters are kinetically frozen by large activation energies. The relevant relaxation time is that of the smallest `liquid' clusters. Some physical consequences are discussed.

cond-mat.stat-mech↗

arXiv2004

Exponential Convergence of Cellular Dynamical Mean Field Theory: Reply to the comment by K. Aryanpour, Th. Maier and M. Jarrell (cond-mat/0301460)

We reply to the comment by K. Aryanpour, Th. Maier and M. Jarrell (cond-mat/0301460) on our paper (Phys. Rev. B {\bf 65} 155112 (2002)). We demonstrate using general arguments and explicit examples that whenever the correlation length is finite, local observables converge exponentially fast in the cluster size, $L_{c}$, within Cellular Dynamical Mean Field Theory (CDMFT). This is a faster rate of convergence than the $1/L_{c}^{2}$ behavior of the Dynamical Cluster approximation (DCA) thus refuting the central assertion of their comment.

cond-mat.str-el↗

arXiv2003

Glass models on Bethe lattices

We consider ``lattice glass models'' in which each site can be occupied by at most one particle, and any particle may have at most l occupied nearest neighbors. Using the cavity method for locally tree-like lattices, we derive the phase diagram, with a particular focus on the vitreous phase and the highest packing limit. We also study the energy landscape via the configurational entropy, and discuss different equilibrium glassy phases. Finally, we show that a kinetic freezing, depending on the particular dynamical rules chosen for the model, can prevent the equilibrium glass transitions.

cond-mat.stat-mech↗

arXiv2003

Cluster Dynamical Mean Field analysis of the Mott transition

We investigate the Mott transition using a cluster extension of dynamical mean field theory (DMFT). In the absence of frustration we find no evidence for a finite temperature Mott transition. Instead, in a frustrated model, we observe signatures of a finite temperature Mott critical point in agreement with experimental studies of kappa-organics and with single site DMFT. As the Mott transition is approached, a clear momentum dependence of the electron lifetime develops on the Fermi surface with the formation of cold regions along the diagonal direction of the Brillouin zone. Furthermore the variation of the effective mass is no longer equal to the inverse of the quasi particle residue, as in DMFT, and is reduced approaching the Mott transition.

cond-mat.str-el↗

arXiv2003

Cluster Dynamical Mean Field Theories

Cluster Dynamical Mean Field Theories are analyzed in terms of their semiclassical limit and their causality properties, and a translation invariant formulation of the cellular dynamical mean field theory, PCDMFT, is presented. The semiclassical limit of the cluster methods is analyzed by applying them to the Falikov-Kimball model in the limit of infinite Hubbard interaction U where they map to different classical cluster schemes for the Ising model. Furthermore the Cutkosky-t'Hooft-Veltman cutting equations are generalized and derived for non translation invariant systems using the Schwinger-Keldysh formalism. This provides a general setting to discuss causality properties of cluster methods. To illustrate the method, we prove that PCDMFT is causal while the nested cluster schemes (NCS) in general and the pair scheme in particular are not. Constraints on further extension of these schemes are discussed.

cond-mat.str-el↗

arXiv2001

Out of equilibrium dynamics of a Quantum Heisenberg Spin Glass

We study the out of equilibrium dynamics of the infinite range quantum Heisenberg spin glass model coupled to a thermal relaxation bath. The SU(2) spin algebra is generalized to SU(N) and we analyse the large-N limit. The model displays a dynamical phase transition between a paramagnetic and a glassy phase. In the latter, the system remains out of equilibrium and displays an aging phenomenon, which we characterize using both analytical and numerical methods. In the aging regime, the quantum fluctuation-dissipation relation is violated and replaced at very long time by its classical generalization, as in models involving simple spin algebras studied previously. We also discuss the effect of a finite coupling to the relaxation baths and their possible forms. This work completes and justifies previous studies on this model using a static approach.

cond-mat.str-el↗

arXiv1999

A single defect approximation for localized states on random lattices

Geometrical disorder is present in many physical situations giving rise to eigenvalue problems. The simplest case of diffusion on a random lattice with fluctuating site connectivities is studied analytically and by exact numerical diagonalizations. Localization of eigenmodes is shown to be induced by geometrical defects, that is sites with abnormally low or large connectivities. We expose a ``single defect approximation'' (SDA) scheme founded on this mechanism that provides an accurate quantitative description of both extended and localized regions of the spectrum. We then present a systematic diagrammatic expansion allowing to use SDA for finite-dimensional problems, e.g. to determine the localized harmonic modes of amorphous media.

cond-mat.stat-mech↗

arXiv1998

Relationship between long time scales and the static free-energy in the Hopfield model

The Glauber dynamics of the Hopfield model at low storage level is considered. We analytically derive the spectrum of relaxation times for large system sizes. The longest time scales are gathered in families, each family being in one to one correspondence with a stationary (not necessarily stable) point of the static mean-field free-energy. Inside a family, the time scales are given by the reciprocals (of the absolute values) of the eigenvalues of the free-energy Hessian matrix.

cond-mat.dis-nn↗