arXiv subjects

G. D. Tsibidis

Publications and source records attributed to G. D. Tsibidis.

12 recordsLinked to original sources

arXiv2026

Impact of Plasmonic Modes and Thermophysical Properties on the Double-Pulse Structuring of Highly-Ordered LIPSS for Biosensing Applications

The fabrication of highly ordered laser-induced periodic surface structures (LIPSS) on thin metallic films is dictated, predomaninatly, by a synergy of periodic electromagnetic energy deposition and complex fluid dynamics. In this work, we present a combined experimental and theoretical study on the formation of ultra-regular LIPSS on 32-nm-thick Au films using a double-pulse femtosecond laser scheme. We demonstrate that for thin films, the excitation of coupled Surface Plasmon Polaritons (SPPs) at both interfaces dictates the initial energy distribution. On the othe hand, the final morphology is greatly influenced by hydrodynamical processes. Interestingly, due to the low electron-phonon coupling of Au and the high thermal confinement of the thin film, single-pulse irradiation leads to uncontrolled hydrodynamic instabilities a non uniform topographies. Thus, we demonstrate that a double-pulse approach with an optimized interpulse delay (Δτ=1.2 ns) effectively controls the melt duration and viscosity, suppressing complex fluid motion and promoting the growth of highly ordered arrays. These structures support narrow surface lattice resonances (SLRs) suitable for high-sensitivity plasmonic biosensing.

physics.optics↗

arXiv2022

Tailoring surface topographies on solids with Mid-IR femtosecond laser pulses

Irradiation of solids with ultrashort pulses using laser sources in the mid-infrared (mid-IR) spectral region is a yet predominantly unexplored field that opens broad possibilities for efficient and precise surface texturing for a wide range of applications. In the present work, we investigate both experimentally and theoretically the impact of laser sources on the generation of surface modification related effects and on the subsequent surface patterning of metallic and semiconducting materials. Through a parametric study we correlate the mid-IR pulsed laser parameters with the onset of material damage and the formation of a variety of periodic surface structures at a laser wavelength of λL=3200 nm and a pulse duration of τp=45 fs. Results for nickel and silicon indicate that the produced topographies comprise both high and low spatial frequency induced periodic structures, similar to those observed at lower wavelengths, while groove formation is absent. The investigation of the damage thresholds suggests the incorporation of nonlinear effects generated from three-photon-assisted excitation (for silicon) and the consideration of the role of the non-thermal excited electron population (for nickel) at very short pulse durations. The results demonstrate the potential of surface structuring with mid-IR pulses, which can constitute a systematic novel engineering approach with strong fields at long-wavelength spectral regions that can be used for advanced industrial laser applications.

physics.optics↗

arXiv2021

Ultrashort pulsed laser induced complex surface structures generated by tailoring the melt hydrodynamics

We present a novel approach for tailoring the laser induced surface topography upon femtosecond-fs pulsed laser irradiation. The method employs spatially controlled double fs laser pulses to actively regulate the hydrodynamic microfluidic motion of the melted layer that gives rise to the structures formation. The pulse train used, in particular, consists of a previously unexplored spatiotemporal intensity combination including one pulse with Gaussian and another with periodically modulated intensity distribution created by Direct Laser Interference Patterning (DLIP). The interpulse delay is appropriately chosen to reveal the contribution of the microfluidic melt flow, while it is found that the sequence of the Gaussian and DLIP pulses remarkably influences the surface profile attained. Results also demonstrate that both the spatial intensity of the double pulse and the effective number of pulses per irradiation spot can further be modulated to control the formation of complex surface morphologies. The underlying physical processes behind the complex patterns generation were interpreted in terms of a multiscale model combining electrodynamic excitation with melt hydrodynamics. We believe that this work can constitute a significant step forward towards producing laser induced surface structures on demand by tailoring the melt microfluidic phenomena.

physics.optics↗

arXiv2020

Laser engineering of biomimetic surfaces

The exciting properties of micro- and nano-patterned surfaces found in natural species hide a virtually endless potential of technological ideas, opening new opportunities for innovation and exploitation in materials science and engineering. Due to the diversity of biomimetic surface functionalities, inspirations from natural surfaces are interesting for a broad range of applications in engineering, including phenomena of adhesion, friction, wear, lubrication, wetting phenomena, self-cleaning, antifouling, antibacterial phenomena, thermoregulation and optics. Lasers are increasingly proving to be promising tools for the precise and controlled structuring of materials at micro- and nano-scales. When ultrashort-pulsed lasers are used, the optimal interplay between laser and material parameters enables structuring down to the nanometer scale. Besides this, a unique aspect of laser processing technology is the possibility for material modifications at multiple (hierarchical) length scales, leading to the complex biomimetic micro- and nano-scale patterns, while adding a new dimension to structure optimization. This article reviews the current state of the art of laser processing methodologies, which are being used for the fabrication of bioinspired artificial surfaces to realize extraordinary wetting, optical, mechanical, and biological-active properties for numerous applications. The innovative aspect of laser functionalized biomimetic surfaces for a wide variety of current and future applications is particularly demonstrated and discussed. The article concludes with illustrating the wealth of arising possibilities and the number of new laser micro/nano fabrication approaches for obtaining complex high-resolution features, which prescribe a future where control of structures and subsequent functionalities are beyond our current imagination.

physics.optics↗

arXiv2020

Modelling ultrafast non-equilibrium carrier dynamics and relaxation processes upon irradiation of hexagonal Silicon-Carbide with femtosecond laser pulses

We present a theoretical investigation of the yet unexplored dynamics of the produced excited carriers upon irradiation of hexagonal Silicon Carbide (6H-SiC) with femtosecond laser pulses. To describe the ultrafast behaviour of laser induced out-of-equilibrium carriers, a real time simulation based on Density Functional Theory (DFT) methodology is used to compute both the hot carrier dynamics and transient change of the optical properties. A Two-Temperature model (TTM) is also employed to derive the relaxation processes for laser pulses of wavelength 401 nm, duration 50 fs at normal incidence irradiation which indicate that surface damage on the material occurs for fluence ~1.88 Jcm-2. This approach of linking, for the first time, real time calculations, transient optical properties and TTM modelling, has strong implications for understanding both the ultrafast dynamics and relaxation processes and providing a precise investigation of the impact of hot carrier population in surface damage mechanisms in solids.

cond-mat.mtrl-sci↗

arXiv2019

Ultrafast dynamics and surface plasmon properties of Silicon upon irradiation with mid-infrared femtosecond laser pulses

We present a theoretical investigation of the yet unexplored ultrafast processes and dynamics of the produced excited carriers upon irradiation of Silicon with femtosecond pulsed lasers in the mid-infrared (mid-IR) spectral region. The evolution of the carrier density and thermal response of the electron-hole and lattice subsystems are analysed for various wavelengths λL in the range between 2.2 μm and 3.3 μm where the influence of two and three-photon absorption mechanisms is explored. The role of induced Kerr effect is highlighted and it manifests a more pronounced influence at smaller wavelengths in the mid-IR range. Elaboration on the conditions that leads to surface plasmon (SP) excitation indicate the formation of weakly bound SP waves on the material surface. The lifetime of the excited SP is shown to rise upon increasing wavelength yielding a larger than the one predicted for higher laser frequencies. Calculation of damage thresholds for various pulse durations τp show that they rise according to a power law (~τ_p^{ζ(λ_L) ) where the increasing rate is determined by the exponent ζ(λ_L). Investigation of the multi-photon absorption rates and impact ionization contribution at different τp manifests a lower damage for λL=2.5 μm compared to that for λL=2.2 μm for long τp.

physics.optics↗

arXiv2019

Partial ablation of Ti/Al nano-layer thin film by single femtosecond laser pulse

The effects of ultra-short laser pulses on reactive Ti/Al nano-layered thin film were investigated. The thin film composed of alternated titanium and aluminium nano-layers, was deposited by ion-sputtering. Single pulse irradiation was conducted in the air with focused and linearly polarized femtosecond laser beam - of 1026 nm wavelength and pulse duration of 170 fs. Laser induced composition and morphological changes, using different microscopy techniques and energy dispersive X-ray spectroscopy, were investigated. Following results were obtained: (i) one step partial/selective ablation of upper Ti layer from nano-layer Ti/Al at low laser fluence and (ii) two step ablation or entire ablation of nano-layer Ti/Al at higher laser fluence. Single pulse selective ablation of the upper Ti layer was confirmed based on profiling (AFM) along the ablation steps and reduction of Ti concentration (EDX) in the ablated areas. Ablation threshold was estimated using well known procedure for ultra-short laser pulses - spot diameter square versus logarithm of pulse energy. To interpret the experimental observations, simulations have been performed to explore the thermal response of the multiple layered structure (Ti(5x(Al/Ti))) after irradiation with a characteristic value of single laser pulse of fluence F = 320 mJ/cm2. The results are in agreement with the calculations.

cond-mat.mtrl-sci↗

arXiv2018

Ultrafast dynamics and sub-wavelength periodic structure formation following irradiation of GaAs with femtosecond laser pulses

A theoretical investigation of the ultrafast processes and dynamics of the excited carriers upon irradiation of GaAs with femtosecond (fs) pulsed lasers is performed in conditions that induce material damage and eventually surface modification of the heated solid. A parametric study is followed to correlate the produced transient carrier density with the damage threshold for various pulse duration values τp (it increases as ~ at relatively small values of τp while it drops for pulse durations of the order of some picoseconds) based on the investigation of the fundamental multiscale physical processes following fs-laser irradiation. Moreover, fluence values for which the originally semiconducting material demonstrates a metallic behaviour are estimated. It is shown that a sufficient number of carriers in the conduction band are produced to excite Surface Plasmon (SP) waves that upon coupling with the incident beam and a fluid-based surface modification mechanism lead to the formation of sub-wavelength periodic structures orientated perpendicularly to the laser beam polarization. Experimental results for the damage threshold and the frequencies of induced periodic structures show a good agreement with the theoretical predictions.

cond-mat.mtrl-sci↗

arXiv2015

Ultrafast laser induced surface modification in absence of non-thermal melting and evaporation

The present paper elucidates the physical mechanism that accounts for the principal/primary stages of the structuring process taking place upon irradiation of a conductive solid with multiple identical femtosecond laser pulses, based on the consideration of a hybrid theoretical model. Heat transfer along with hydrodynamics simulations demonstrate that it is possible to create morphology change conditions by solely exploiting capillary effects, in the absence of either non-thermal melting or evaporation. Simulation results, confirmed by experiments, reveal the intermediate surface modification stage acting as a predecessor of microcones formation.

cond-mat.mtrl-sci↗

arXiv2015

Hysteresis and metastability of Bose-Einstein condensed clouds of atoms confined in ring potentials

We consider a Bose-Einstein condensed cloud of atoms which rotate in a toroidal/annular potential. Assuming one-dimensional motion, we evaluate the critical frequencies associated with the effect of hysteresis and the critical coupling for stability of the persistent currents. We perform these calculations using both the mean-field approximation and the method of numerical diagonalization of the many-body Hamiltonian which includes corrections due to the finiteness of the atom number.

cond-mat.quant-gas↗

arXiv2013

The influence of ultrafast temporal energy regulation on the morphology of Si surfaces through femtosecond double pulse laser irradiation

The effect of ultrashort laser-induced morphological changes upon irradiation of silicon with double pulse sequences is investigated under conditions that lead to mass removal. The temporal delay between twelve double and equal-energy pulses (Ep=0.24J/cm2 each, with pulse duration tp=430fs, 800nm laser wavelength) was varied between 0 and 14ps and a decrease of the damaged area, crater depth size and periodicity of the induced subwavelength ripples (by 3-4%) was observed with increasing pulse delay. The proposed underlying mechanism is based on the combination of carrier excitation and energy thermalization and capillary wave solidification and aims to provide an alternative explanation to the control of ripple periodicity by temporal pulse tailoring. This work demonstrates the potential of pulse shaping technology to improve nano/micro processing.

cond-mat.mtrl-sci↗

arXiv2012

Thermoplastic deformation of silicon surfaces induced by ultrashort pulsed lasers in submelting conditions

A hybrid 2D theoretical model is presented to describe thermoplastic deformation effects on silicon surfaces induced by single and multiple ultrashort pulsed laser irradiation in submelting conditions. An approximation of the Boltzmann transport equation is adopted to describe the laser irradiation process. The evolution of the induced deformation field is described initially by adopting the differential equations of dynamic thermoelasticity while the onset of plastic yielding is described by the von Mise's stress. Details of the resulting picometre sized crater, produced by irradiation with a single pulse, are then discussed as a function of the imposed conditions and thresholds for the onset of plasticity are computed. Irradiation with multiple pulses leads to ripple formation of nanometre size that originates from the interference of the incident and a surface scattered wave. It is suggested that ultrafast laser induced surface modification in semiconductors is feasible in submelting conditions, and it may act as a precursor of the incubation effects observed at multiple pulse irradiation of materials surfaces.

cond-mat.mtrl-sci↗