arXiv subjects

G. Eguchi

Publications and source records attributed to G. Eguchi.

14 recordsLinked to original sources

arXiv2024

Magnetic properties of AlB$_2$-type holmium silicides and germanides

Discovery of the large magnetocaloric effect in HoB$_2$ has highlighted the practical advantage of heavy rare-earth ions. Other holmium compounds are of interest, and we here report the synthesis and the magnetic properties of HoSi$_{1.67}$ and HoGe$_{1.67}$ which form the same AlB$_2$-type structure but with vacancies. They are found to show the antiferromagnetic order with the Neel temperature 17.6(2)K for HoSi$_{1.67}$ and 9.9(2)K for HoGe$_{1.67}$, and the magnetic entropy changes at the temperature are 0.05(1)J/cm$^3$K for HoSi$_{1.67}$ and 0.08(1)J/cm$^3$K for HoGe$_{1.67}$. Magnetic orders were suppressed by replacing vacancies with nickel, resulting in an increase of magnetic entropy changes. Distance between the in-plane Ho$^{3+}$ ions appears to be an important parameter leading to the transition between the antiferromagnetic (HoSi$_{1.67}$) and the ferromagnetic (HoB$_2$) order. The finding may aid the exploration of other heavy rare-earth compounds for similar applications.

cond-mat.str-el↗

arXiv2023

Evidence of 3D Dirac conical bands in TlBiSSe by optical and magneto-optical spectroscopy

TlBiSSe is a rare realization of a 3D semimetal with a conically dispersing band that has an optical response which is well isolated from other contributions in a broad range of photon eneries. We report optical and magneto-optical spectroscopy on this material. When the compound is chemically tuned into a state of the lowest carrier concentration, we find a nearly linear frequency dependence of the optical conductivity below 0.5~eV. Landau level spectroscopy allows us to describe the system with a massive Dirac model, giving a gap $2\Delta =32$~meV and an in-plane velocity parameter $v= 4.0\times 10^5$~m/s. % Finally, we provide a theoretical recipe to extract all parameters of the anisotropic Dirac band, including the Fermi energy and band degeneracy.

cond-mat.mtrl-sci↗

arXiv2020

Switching on surface conduction in a topological insulator

The protected surface conduction of topological insulators is in high demand for the next generation of electronic devices. What is needed to move forward are robust settings where topological surface currents can be controlled by simple means, ideally by the application of external stimuli. Surprisingly, this direction is only little explored. In this work we demonstrate that we can boost the surface conduction of a topological insulator by both light and electric field. This happens in a fully controlled way, and the additional Dirac carriers exhibit ultra-long lifetimes. We provide a comprehensive understanding, namely that carriers are injected from the bulk to the surface states across an intrinsic Schottky barrier. We expect this mechanism to be at play in a broad range of materials and experimental settings.

cond-mat.mtrl-sci↗

arXiv2019

Two-dimensional conical dispersion in ZrTe5 evidenced by optical spectroscopy

Zirconium pentatelluride was recently reported to be a 3D Dirac semimetal, with a single conical band, located at the center of the Brillouin zone. The cone's lack of protection by the lattice symmetry immediately sparked vast discussions about the size and topological/trivial nature of a possible gap opening. Here we report on a combined optical and transport study of ZrTe5, which reveals an alternative view of electronic bands in this material. We conclude that the dispersion is approximately linear only in the a-c plane, while remaining relatively flat and parabolic in the third direction (along the b axis). Therefore, the electronic states in ZrTe5 cannot be described using the model of 3D Dirac massless electrons, even when staying at energies well above the band gap 6 meV found in our experiments at low temperatures.

cond-mat.mes-hall↗

arXiv2019

Highly anisotropic interlayer magnetoresistance in ZrSiS nodal-line Dirac semimetal

We instigate the angle-dependent magnetoresistance (AMR) of the layered nodal-line Dirac semimetal ZrSiS for the in-plane and out-of-plane current directions. This material has recently revealed an intriguing butterfly-shaped in-plane AMR that is not well understood. Our measurements of the polar out-of-plane AMR show a surprisingly different response with a pronounced cusp-like feature. The maximum of the cusp-like anisotropy is reached when the magnetic field is oriented in the $a$-$b$ plane. Moreover, the AMR for the azimuthal out-of-plane current direction exhibits a very strong four-fold $a$-$b$ plane anisotropy. Combining the Fermi surfaces calculated from first principles with the Boltzmann's semiclassical transport theory we reproduce and explain all the prominent features of the unusual behavior of the in-plane and out-of-plane AMR. We are also able to clarify the origin of the strong non-saturating transverse magnetoresistance as an effect of imperfect charge-carrier compensation and open orbits. Finally, by combining our theoretical model and experimental data we estimate the average relaxation time of $2.6\times10^{-14}$~s and the mean free path of $15$~nm at 1.8~K in our samples of ZrSiS.

cond-mat.mtrl-sci↗

arXiv2019

Robust scheme for magnetotransport analysis in topological insulators

The recent excitement about Dirac and Weyl fermion systems has renewed interest in magnetotransport properties of multi-carrier systems. However, the complexity of their analysis, even in the simplest two-carrier case, has hampered a good understanding of the underlying phenomena. Here we propose a new analysis scheme for two independent conduction channels, that strongly reduces previous ambiguities and allows to draw robust conclusions. This is demonstrated explicitly for the example of three-dimensional topological insulators. Their temperature and gate voltage-dependent Hall coefficient and transverse magnetoresistance behavior, including the phenomenon of huge linear transverse magnetoresistance, can be traced back to two conduction channels, with fully determined carrier concentrations and mobilities. We further derive an upper limit for the transverse magnetoresistance. Its violation implies field dependences in the electronic band structure or scattering processes, or the presence of more than two effective carrier types. Remarkably, none of the three-dimensional topological insulators or semimetals with particularly large transverse magnetoresistance violates this limit.

cond-mat.mes-hall↗

arXiv2017

Kondo Insulator to Semimetal Transformation Tuned by Spin-Orbit Coupling

Recent theoretical studies of topologically nontrivial electronic states in Kondo insulators have pointed to the importance of spin-orbit coupling (SOC) for stabilizing these states. However, systematic experimental studies that tune the SOC parameter $λ_{\rm{SOC}}$ in Kondo insulators remain elusive. The main reason is that variations of (chemical) pressure or doping strongly influence the Kondo coupling $J_{\text{K}}$ and the chemical potential $μ$ -- both essential parameters determining the ground state of the material -- and thus possible $λ_{\rm{SOC}}$ tuning effects have remained unnoticed. Here we present the successful growth of the substitution series Ce$_3$Bi$_4$(Pt$_{1-x}$Pd$_x$)$_3$ ($0 \le x \le 1$) of the archetypal (noncentrosymmetric) Kondo insulator Ce$_3$Bi$_4$Pt$_3$. The Pt-Pd substitution is isostructural, isoelectronic, and isosize, and therefore likely to leave $J_{\text{K}}$ and $μ$ essentially unchanged. By contrast, the large mass difference between the $5d$ element Pt and the $4d$ element Pd leads to a large difference in $λ_{\rm{SOC}}$, which thus is the dominating tuning parameter in the series. Surprisingly, with increasing $x$ (decreasing $λ_{\rm{SOC}}$), we observe a Kondo insulator to semimetal transition, demonstrating an unprecedented drastic influence of the SOC. The fully substituted end compound Ce$_3$Bi$_4$Pd$_3$ shows thermodynamic signatures of a recently predicted Weyl-Kondo semimetal.

cond-mat.str-el↗

arXiv2015

Precise determination of two-carrier transport properties in the topological insulator TlBiSe$_2$

We report the electric transport study of the three-dimensional topological insulator TlBiSe$_2$. We applied a newly developed analysis procedure and precisely determined two-carrier transport properties. Magnetotransport properties revealed a multicarrier conduction of high- and low-mobility electrons in the bulk, which was in qualitative agreement with angle-resolved photoemission results~[K. Kuroda $et~al.$, Phys. Rev. Lett. $\bm{105}$, 146801 (2010)]. The temperature dependence of the Hall mobility was explained well with the conventional Bloch-Gr{ü}neisen formula and yielded the Debye temperature $\varTheta_{\rm{D}}=113 \pm 14$~K. The results indicate that the scattering of bulk electrons is dominated by acoustic phonons.

cond-mat.mtrl-sci↗

arXiv2014

Surface Shubnikov-de Hass oscillations and non-zero Berry phases of the topological hole conduction in Tl$_{1-x}$Bi$_{1+x}$Se$_2$

We report the observation of two-dimensional Shubnikov-de Hass (SdH) oscillations in the topological insulator Tl$_{1-x}$Bi$_{1+x}$Se$_2$. Hall effect measurements exhibited electron-hole inversion in samples with bulk insulating properties. The SdH oscillations accompanying the hole conduction yielded a large surface carrier density of $n_{\rm{s}}=5.1 \times10^{12}$/cm$^2$, with the Landau-level fan diagram exhibiting the $π$ Berry phase. These results showed the electron-hole reversibility around the in-gap Dirac point and the hole conduction on the surface Dirac cone without involving the bulk metallic conduction.

cond-mat.mes-hall↗

arXiv2013

Influence on superconductivity in the parity mixing superconductor Li2T3B(T:Pt,Pd) by non-magnetic impurity and defect doping

Superconductors with noncentrosymmetric crystal structures such as Li2T3B(T:Pd,Pt) have been the focus of in-depth research with their parity mixing nature. In this study, we focused our research on non-magnetic impurity effect in Li2T3B (T: Pd, Pt). The nature of the pair breaking by non-magnetic impurity in the parity mixing superconducting state is still unclear. We prepared different quality samples of Li2Pd3B and Li2Pt3B by changing conditions in synthesizing, and sample qualities were estimated by residual resistivity. Spin singlet dominant superconductor Li2Pd3B exhibits the weak Tc suppression attributed by nonmagnetic impurity and defects, while Hc2 (0) value increased. This behavior is similar in ordinary s-wave superconductor. On the other hand, for the spin triplet dominant superconductor Li2Pt3B, it was suggested that the Cooper pair was broken and superconducting gap was decreased by non-magnetic impurities and defects. Li2Pt3B is similar to unconventional superconducting state.

cond-mat.supr-con↗

arXiv2013

Phonon anomaly and anisotropic superconducting gap in non-centrosymmetric Li2(Pd1-xPtx)3B

We report the systematic investigation of the specific heat of the noncentrosymmetric supercon- ductor Li2(Pd1-xPtx)3B as a function of x. There is a large deviation of the phononic specific heat from the conventional Debye specific heat for Pt-rich samples. In contrast with the fully-gapped con- ventional behavior for small x, a power-law temperature dependence of the electronic specific heat is observed even at x = 0.5. This results manifest a strongly-anisotropic or nodal superconducting gap even at x = 0.5 and a nodal superconducting gap for x >~ 0.9.

cond-mat.supr-con↗

arXiv2012

Large spin-orbit splitting and weakly-anisotropic superconductivity revealed with single-crystalline noncentrosymmetric CaIrSi3

We report normal and superconducting properties of the Rashba-type noncentrosymmetric com- pound CaIrSi3, using single crystalline samples with nearly 100% superconducting volume fraction. The electronic density of states revealed by the hard x-ray photoemission spectroscopy can be well explained by the relativistic first-principle band calculation. This indicates that strong spin-orbit interaction indeed affects the electronic states of this compound. The obtained H - T phase diagram exhibits only approximately 10% anisotropy, indicating that the superconducting properties are almost three dimensional. Nevertheless, strongly anisotropic vortex pinning is observed.

cond-mat.supr-con↗

arXiv2011

Magnetic Phase Diagram of Li_2(Pd_{1-x}Pt_x)_3B by AC Susceptometry

The H-T phase diagram and several superconducting parameters for Li_2(Pd_{1-x}Pt_x)_3B have been determined as a function of cation substitution x. Notably, the coherence length may be linear in platinum concentration. Despite the superconducting pairing state and band structure apparently changing fundamentally, the H-T phase diagram is essentially unchanged. Unusual aspects of the shape of the H-T phase diagram are discussed. The upper critical field H_c2(0) is not anomalously high for any Pt content, likely due to an absence of high carrier masses - in such a case, the value of H_c2(0) would not serve as a probe for novel physics.

cond-mat.supr-con↗

arXiv2011

Crystallographic and superconducting properties of the fully-gapped noncentrosymmetric 5d-electron superconductors CaMSi3 (M=Ir, Pt)

We report crystallographic, specific heat, transport, and magnetic properties of the recently discovered noncentrosymmetric 5d-electron superconductors CaIrSi3 (Tc = 3.6 K) and CaPtSi3 (Tc = 2.3 K). The specific heat suggests that these superconductors are fully gapped. The upper critical fields are less than 1 T, consistent with limitation by conventional orbital depairing. High, non-Pauli-limited μ0 Hc2 values, often taken as a key signature of novel noncentrosymmetric physics, are not observed in these materials because the high carrier masses required to suppress orbital depairing and reveal the violated Pauli limit are not present.

cond-mat.supr-con↗