arXiv subjects

G. Gebreyesus

Publications and source records attributed to G. Gebreyesus.

9 recordsLinked to original sources

arXiv2025

Prediction of amino acid content in live black soldier fly larvae using near infrared spectroscopy

Black soldier fly (Hermetia illucens) larvae are emerging as a sustainable protein source for animal feed and human nutrition. Ensuring consistent amino acid composition is crucial for quality control, necessitating rapid, non-destructive assessment methods, particularly for selective breeding. This study validates near-infrared (NIR) spectroscopy with partial least squares (PLS) regression as a reliable tool for predicting free amino acid (FAA) profiles in live larvae. Using a FOSS DS2500 spectrometer (400-2500 nm), 204 live larval samples reared on 17 diets with varying protein (2.3-89.8 percent) and sugar (8.5-96.0 percent) levels were scanned, followed by FAA extraction. Alanine (6.50 +/- 3.52 mg/g) and proline (5.61 +/- 4.45 mg/g) were the most abundant FAAs, with key NIR absorption bands at 1670-1786 nm and 2300-2366 nm enabling accurate predictions. PLS models showed strong predictive power for individual FAAs (e.g., glutamate: R^2 = 0.88; asparagine: R^2 = 0.78; alanine: R^2 = 0.65) and total FAAs (R^2 = 0.64). These results highlight NIR's potential for real-time quality control and phenotyping in BSF production and breeding.

q-bio.QM↗

arXiv2023

Understanding the role of Hubbard corrections in the rhombohedral phase of BaTiO$_3$

We present a first-principles study of the low-temperature rhombohedral phase of BaTiO$_3$ using Hubbard-corrected density-functional theory. By employing density-functional perturbation theory, we compute the onsite Hubbard $U$ for Ti($3d$) states and the intersite Hubbard $V$ between Ti($3d$) and O($2p$) states. We show that applying the onsite Hubbard $U$ correction alone to Ti($3d$) states proves detrimental, as it suppresses the Ti($3d$)-O($2p$) hybridization and drives the system towards a cubic phase. Conversely, when both onsite $U$ and intersite $V$ are considered, the localized character of the Ti($3d$) states is maintained, while also preserving the Ti($3d$)-O($2p$) hybridization, restoring the rhombohedral phase of BaTiO$_3$. The generalized PBEsol+$U$+$V$ functional yields good agreement with experimental results for the band gap and dielectric constant, while the optimized geometry is slightly less accurate compared to PBEsol. Zone-center phonon frequencies and Raman spectra are found to be significantly influenced by the underlying geometry. PBEsol and PBEsol+$U$+$V$ provide satisfactory agreement with the experimental Raman spectrum when the PBEsol geometry is used, while PBEsol+$U$ Raman spectrum diverges strongly from experimental data highlighting the adverse impact of the $U$ correction alone in BaTiO$_3$. Our findings underscore the promise of the extended Hubbard PBEsol+$U$+$V$ functional with first-principles $U$ and $V$ for the investigation of other ferroelectric perovskites with mixed ionic-covalent interactions.

cond-mat.mtrl-sci↗

arXiv2023

Layer-dependent spin-resolved electronic structure of ferromagnetic triple-layered ruthenate Sr$_4$Ru$_3$O$_{10}$

High-resolution angle- and spin-resolved photoemission spectroscopy (ARPES) of the triple-layered ruthenate Sr$_4$Ru$_3$O$_{10}$ reveals features of the electronic structure that extend our understanding of the layered strontium ruthenates. The spectra near the Fermi energy are very different from the non-magnetic analogues Sr$_2$RuO$_4$ and Sr$_3$Ru$_2$O$_7$ with distinct Fermi surfaces for wide electron-like minority spin bands around the zone center and narrow hole-like majority spin Fermi surface contours around the zone corners. The most dramatic results are two narrow spectral peaks $\sim$30 meV below the Fermi-level, a spin-minority hole-like band at the Brillouin zone center, and a spin-majority saddle-band van Hove singularity at the zone edge, which exhibits almost 100\% spin-polarization at low temperature, and a strong temperature dependent coherence-incoherence crossover attributed to Hund metal correlations. Quantitative comparison of the ARPES to spin-polarized density functional theory (DFT) calculations identify the specific antibonding and nonbonding orbital origins of the narrow bands, with a prediction of different spatial localization in the central and outer layers. This is shown to be consistent with experimental ARPES multi-zone matrix element intensity variations, and implicates outer-layer-specific control of the in-plane metamagnetism. The renormalization of the bands relative to the mean-field DFT, the demonstration of spin-polarized oxygen bands, and of spin-minority and spin-majority band-crossing hybridization, provide a more complete picture of the magnetism which displays aspects of both delocalized and local moment behavior.

cond-mat.str-el↗

arXiv2022

Electronic Structure and Magnetism of the Triple-layered Ruthenate Sr$_{4}$Ru$_{3}$O$_{10}$

We report electronic band structure calculations for Sr$_{4}$Ru$_{3}$O$_{10}$ that displays both ferromagnetic and metamagnetic behavior. The density functional calculations find the ground state to be ferromagnetic in agreement with the experiment and we find that the inclusion of Coulomb Hubbard interaction U applied to the Ru 4d states has dramatic effects on the Fermi surface, which reveal the role of Coulomb interactions and correlated many-body physics. The minority spin bands are mainly empty with Fermi surfaces in the outer areas of the Brillouin zone away from the $Γ$ point with bands that disperse steeply upward. The majority spin bands are full or nearly fully occupied and form narrow bands near the Fermi energy around the $Γ$ point, which could be the electronic origin of the metamagnetism. The results are in qualitative agreement with recent angle resolved photoemission spectroscopy (ARPES) experiments and show the need for a combined theoretical study and experimental ARPES investigation with better energy resolution to reveal the nature of the narrow bands close to the Fermi-level, which is critical for understanding the exotic magnetic properties observed in this material.

cond-mat.str-el↗

arXiv2013

Spontaneous symmetry breaking in spinor Bose-Einstein condensates

We present an analytical model for the theoretical analysis of spin dynamics and spontaneous symmetry breaking in a spinor Bose-Einstein condensate (BEC). This allows for an excellent intuitive understanding of the processes and provides good quantitative agreement with experimental results in Phys. Rev. Lett. 105, 135302 (2010). It is shown that the dynamics of a spinor BEC initially prepared in an unstable Zeeman state mF=0 (|0>) can be understood by approximating the effective trapping potential for the state |+-1> with a cylindrical box potential. The resonances in the creation efficiency of these atom pairs can be traced back to excitation modes of this confinement. The understanding of these excitation modes allows for a detailed characterization of the symmetry breaking mechanism, showing how a twofold spontaneous breaking of spatial and spin symmetry can occur. In addition a detailed account of the experimental methods for the preparation and analysis of spinor quantum gases is given.

quant-ph↗

arXiv2010

Spontaneous breaking of spatial and spin symmetry in spinor condensates

Parametric amplification of quantum fluctuations constitutes a fundamental mechanism for spontaneous symmetry breaking. In our experiments, a spinor condensate acts as a parametric amplifier of spin modes, resulting in a twofold spontaneous breaking of spatial and spin symmetry in the amplified clouds. Our experiments permit a precise analysis of the amplification in specific spatial Bessel-like modes, allowing for the detailed understanding of the double symmetry breaking. On resonances that create vortex-antivortex superpositions, we show that the cylindrical spatial symmetry is spontaneously broken, but phase squeezing prevents spin-symmetry breaking. If, however, nondegenerate spin modes contribute to the amplification, quantum interferences lead to spin-dependent density profiles and hence spontaneously-formed patterns in the longitudinal magnetization.

cond-mat.quant-gas↗

arXiv2010

Parametric amplification of matter waves in dipolar spinor Bose-Einstein condensates

Spin-changing collisions may lead under proper conditions to the parametric amplification of matter waves in spinor Bose-Einstein condensates. Magnetic dipole-dipole interactions, although typically very weak in alkaline atoms, are shown to play a very relevant role in the amplification process. We show that these interactions may lead to a strong dependence of the amplification dynamics on the angle between the trap axis and the magnetic-field orientation. We analyze as well the important role played by magnetic-field gradients, which modify also strongly the amplification process. Magnetic-field gradients must be hence carefully controlled in future experiments, in order to observe clearly the effects of the dipolar interactions in the amplification dynamics.

cond-mat.quant-gas↗

arXiv2009

Multi-resonant spinor dynamics in a Bose-Einstein condensate

We analyze the spinor dynamics of a Rb-87 F=2 condensate initially prepared in the m_F=0 Zeeman sublevel. We show that this dynamics, characterized by the creation of correlated atomic pairs in m_F=+/-1, presents an intriguing multi-resonant magnetic field dependence induced by the trap inhomogeneity. This dependence is directly linked to the most unstable Bogoliubov spin excitations of the initial m_F = 0 condensate, showing that, in general, even a qualitative understanding of the pair creation efficiency in a spinor condensate requires a careful consideration of the confinement.

quant-ph↗

arXiv2009

Parametric amplification of vacuum fluctuations in a spinor condensate

Parametric amplification of vacuum fluctuations is crucial in modern quantum optics, enabling the creation of squeezing and entanglement. We demonstrate the parametric amplification of vacuum fluctuations for matter waves using a spinor F=2 Rb-87 condensate. Interatomic interactions lead to correlated pair creation in the m_F= +/- 1 states from an initial unstable m_F=0 condensate, which acts as a vacuum for m_F unequal 0. Although this pair creation from a pure m_F=0 condensate is ideally triggered by vacuum fluctuations, unavoidable spurious initial m_F= +/- 1 atoms induce a classical seed which may become the dominant triggering mechanism. We show that pair creation is insensitive to a classical seed for sufficiently large magnetic fields, demonstrating the dominant role of vacuum fluctuations. The presented system thus provides a direct path towards the generation of non-classical states of matter on the basis of spinor condensates.

cond-mat.quant-gas↗