arXiv subjects

G. H. Cao

Publications and source records attributed to G. H. Cao.

50 records · Page 3Linked to original sources

arXiv2009

Universal Decomposition of the Low-Frequency Conductivity Spectra of Iron-Pnictides Uncovering Fermi-Liquid Behavior

Infrared reflectivity measurements on 122 iron-pnictides reveal the existence of two electronic subsystems. The one gapped due to the spin-density-wave transition in the parent materials, such as EuFe$_2$As$_{2}$, is responsible for superconductivity in the doped compounds, like Ba(Fe$_{0.92}$Co$_{0.08})_2$As$_{2}$ and Ba(Fe$_{0.95}$Ni$_{0.05})_2$As$_{2}$. Analyzing the dc resistivity and scattering rate of this contribution, a hidden $T^2$ dependence is found, indicating that superconductivity evolves out of a Fermi-liquid state. The second subsystem gives rise to incoherent background, present in all 122 compounds, which is basically temperature independent, but affected by the superconducting transition.

cond-mat.supr-con↗

arXiv2009

Superfluid density of Ba(Fe$_{1-x}M_x$)$_2$As$_2$ from optical experiments

The temperature dependence of the $ab$-plane optical reflectivity of Ba(Fe$_{0.92}$Co$_{0.08})_2$As$_{2}$ and Ba(Fe$_{0.95}$Ni$_{0.05})_2$As$_{2}$ single crystals is measured in a wide spectral range. Upon entering the superconducting regime, the reflectivity in both compounds increases considerably at low frequency, leading to a clear gap in the optical conductivity below 100 cm$^{-1}$. From the analysis of the complex conductivity spectra we obtain the penetration depth $λ(T)=(3500\pm 350)$ Åfor Ba(Fe$_{0.92}$Co$_{0.08})_2$As$_{2}$ and $(3000\pm 300)$ Åfor Ba(Fe$_{0.95}$Ni$_{0.05})_2$As$_{2}$. The calculated superfluid density $ρ_s$ of both compounds nicely fits the scaling relation $ρ_s=(125\pm 25)σ_{dc}T_c$.

cond-mat.supr-con↗

arXiv2009

Phonon anomaly in BaFe2As2

The detailed optical properties of BaFe2As2 have been determined over a wide frequency range above and below the structural and magnetic transition at T_N = 138 K. A prominent in-plane infrared-active mode is observed at 253 cm^{-1} (31.4 meV) at 295 K. The frequency of this vibration shifts discontinuously at T_N; for T < T_N the frequency of this mode displays almost no temperature dependence, yet it nearly doubles in intensity. This anomalous behavior appears to be a consequence of orbital ordering in the Fe-As layers.

cond-mat.str-el↗

arXiv2009

Nodeless superconducting gap in electron-doped BaFe$_{1.9}$Ni$_{0.1}$As$_2$ probed by quasiparticle heat transport

The in-plane thermal conductivity $κ$ of electron-doped iron-arsenide superconductor BaFe$_{1.9}$Ni$_{0.1}$As$_2$ ($T_c$ = 20.3 K) single crystal was measured down to 70 mK. In zero field, the absence of a residual linear term $κ_0/T$ at $ T \to 0$ is strong evidence for nodeless superconducting gap. In magnetic field, $κ_0/T$ shows a slow field dependence up to $H$ = 14.5 T ($\approx$ 30% $H_{c_2}$). This is consistent with the superconducting gap structure demonstrated by angle-resolved photoemission spectroscopy experiments in BaFe$_{1.85}$Co$_{0.15}$As$_2$ ($T_c$ = 25.5 K), where isotropic superconducting gaps with similar size on hole and electron pockets were observed.

cond-mat.supr-con↗

arXiv2009

Fermi surface nesting induced strong pairing in iron-based superconductors

The discovery of high-temperature superconductivity in iron pnictides raised the possibility of an unconventional superconducting mechanism in multiband materials. The observation of Fermi-surface(FS)-dependent nodeless superconducting gaps suggested that inter-FS interactions may play a crucial role in superconducting pairing. In the optimally hole-doped Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$, the pairing strength is enhanced simultaneously (2$Δ$/Tc$\sim$7) on the nearly nested FS pockets, i.e. the inner holelike ($α$) FS and the two hybridized electronlike FSs, while the pairing remains weak (2$Δ$/Tc$\sim$3.6) in the poorly-nested outer hole-like ($β$) FS. Here we report that in the electron-doped BaFe$_{1.85}$Co$_{0.15}$As$_2$ the FS nesting condition switches from the $α$ to the $β$ FS due to the opposite size changes for hole- and electron-like FSs upon electron doping. The strong pairing strength (2$Δ$/Tc$\sim$6) is also found to switch to the nested $β$ FS, indicating an intimate connection between FS nesting and superconducting pairing, and strongly supporting the inter-FS pairing mechanism in the iron-based superconductors.

cond-mat.supr-con↗

arXiv2009

Electronic structure of heavily electron-doped BaFe$_{1.7}$Co$_{0.3}$As$_2$ studied by angle-resolved photoemission

We have performed high-resolution angle-resolved photoemission spectroscopy on heavily electron-doped non-superconducting (SC) BaFe$_{1.7}$Co$_{0.3}$As$_2$. We find that the two hole Fermi surface pockets at the zone center observed in the hole-doped superconducting Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$ are absent or very small in this compound, while the two electron pockets at the M point significantly expand due to electron doping by the Co substitution. Comparison of the Fermi surface between non-SC and SC samples indicates that the coexistence of hole and electron pockets connected via the antiferromagnetic wave vector is essential in realizing the mechanism of superconductivity in the iron-based superconductors.

cond-mat.supr-con↗

arXiv2009

Effects of the magnetic orderings on the dynamical conductivity: optical investigations of EuFe$_2$As$_2$ single crystals

The magnetic, transport and optical properties of EuFe$_2$As$_2$ single crystals have been investigated parallel and perpendicular to the $ab$-plane. The anisotropy $ρ_c/ρ_{ab}\approx 8$ depends only slightly on temperature. In both orientations, the spin-density wave transition at $T_{\rm SDW}=189$ K shows up as a considerable increase in the dc resistivity. Susceptibility measurements evidence the magnetic order of the Eu$^{2+}$ moments at $T_N=19$ K with little influence on the electronic transport taking place in the FeAs layers. Polarization-dependent infrared spectroscopy reveals strongly anisotropic optical properties and yields a carrier density of only $4.2\times 10^{21} {\rm cm}^{-3}$ and a bandmass of $m_b=2m_0$. A sizeable Drude contribution is present at all temperatures and narrows upon cooling. Below $T_{\rm SDW}$, the spin-density-wave gap develops in the in-plane optical conductivity; no appreciable change is detected for the perpendicular polarization. Modifications in the phonon features are associated with changes of the electronic properties at $T_{\rm SDW}$. The extended Drude analysis yields a linear behavior of the frequency-dependent scattering rate below $T_{\rm SDW}$, indicating an interaction between the charge carriers and spin fluctuations in the spin-density-wave state.

cond-mat.supr-con↗

arXiv2008

Superconductivity induced by Ni doping in BaFe$_2$As$_2$

A series of 122 phase BaFe$_{2-x}$Ni$_x$As$_2$ ($x$ = 0, 0.055, 0.096, 0.18, 0.23) single crystals were grown by self flux method and a dome-like Ni doping dependence of superconducting transition temperature is discovered. The transition temperature $T_c^{on}$ reaches a maximum of 20.5 K at $x$ = 0.096, and it drops to below 4 K as $x$ $\geq$ 0.23. The negative thermopower in the normal state indicates that electron-like charge carrier indeed dominates in this system. This Ni-doped system provides another example of superconductivity induced by electron doping in the 122 phase.

cond-mat.supr-con↗

arXiv2008

Superconductivity induced by cobalt doping in iron-based oxyarsenides

Chemical doping has recently become a very important strategy to induce superconductivity especially in complex compounds. Distinguished examples include Ba-doped La$_2$CuO$_4$ (the first high temperature superconductor), K-doped BaBiO$_3$, K-doped C$_{60}$ and Na$_{x}$CoO$_{2}\cdot y$H$_{2}$O. The most recent example is F-doped LaFeAsO, which leads to a new class of high temperature superconductors. One notes that all the above dopants are non-magnetic, because magnetic atoms generally break superconducting Cooper pairs. In addition, the doping site was out of the (super)conducting structural unit (layer or framework). Here we report that superconductivity was realized by doping magnetic element cobalt into the (super)conducting-active Fe$_2$As$_2$ layers in LaFe$_{1-x}$Co$_{x}$AsO. At surprisingly small Co-doping level of $x$=0.025, the antiferromagnetic spin-density-wave transition in the parent compound is completely suppressed, and superconductivity with $T_c\sim $ 10 K emerges. With increasing Co content, $T_c$ shows a maximum of 13 K at $x\sim 0.075$, and then drops to below 2 K at $x$=0.15. This result suggests essential differences between previous cuprate superconductor and the present iron-based arsenide one.

cond-mat.supr-con↗

arXiv2008

Nernst effect of the new iron-based superconductor LaO$_{1-x}$F$_{x}$FeAs

We report the first Nernst effect measurement on the new iron-based superconductor LaO$_{1-x}$F$_{x}$FeAs $(x=0.1)$. In the normal state, the Nernst signal is negative and very small. Below $T_{c}$ a large positive peak caused by vortex motion is observed. The flux flowing regime is quite large compared to conventional type-II superconductors. However, a clear deviation of the Nernst signal from normal state background and an anomalous depression of off-diagonal thermoelectric current in the normal state between $T_{c}$ and 50 K are observed. We propose that this anomaly in the normal state Nernst effect could correlate with the SDW fluctuations.

cond-mat.supr-con↗

arXiv2007

Ti-rich and Cu-poor grain-boundary layers of CaCu$_3$Ti$_4$O$_{12}$ detected by x-ray photoelectron spectroscopy

Cleaved and polished surfaces of CaCu$_3$Ti$_4$O$_{12}$ ceramics have been investigated by x-ray photoelectron spectroscopy (XPS) and energy dispersive x-ray spectroscopy (EDX), respectively. While EDX technique shows the identical CaCu$_3$Ti$_4$O$_{12}$ stoichiometry for the two surfaces, XPS indicates that the cleaved surface with grain-boundary layers is remarkably Ti-rich and Cu-poor. The core-level spectrum of Cu 2$p$ unambiguously shows the existence of monovalent copper only for the cleaved surface. Possible grain-boundary structure and its formation are discussed.

cond-mat.mtrl-sci↗

arXiv2004

Preparation and transport properties of non-hydrated Na$_{0.5}$CoO$_2$ single crystals

Single crystals of Na$_{0.5}$CoO$_2$ were obtained through a flux method followed by de-intercalation of sodium. The Na$_{0.5}$CoO$_2$ samples were found to be vulnerable to water in the air and a hydration process in which H$_2$O molecules fill oxygen vacancies in CoO$_2$ layers is suggested to be responsible for the unusual vulnerability to water. The transport properties, including resistivity (\emph{$ρ$}), thermopower (\emph{S}) and Hall coefficient (\emph{R$_H$}), were studied in a temperature range of 5-300 K. The compound shows a weak localization of carriers just below 200 K and Co$^{3+}$-Co$^{4+}$ charge ordering at about 30 K, a relatively lower temperature than previously reported. The results seem to be quite different from those previously reported for this system [Foo et al, Phys. Rev. Lett. 92 (2004) 247001]. Possible mechanism underlying this kind of inconsistency is discussed.

cond-mat.str-el↗

arXiv2004

Optical study of the metal-insulator transition in CuIr$_2$S$_4$ crystals

We present measurements of the optical spectra on single crystals of spinel-type compound \cis. This material undergoes a sharp metal-insulator transition at 230 K. Upon entering the insulating state, the optical conductivity shows an abrupt spectral weight transfer and an optical excitation gap opens. In the metallic phase, Drude components in low frequencies and an interband transition peak at $\sim 2 eV$ are observed. In the insulating phase, a new peak emerges around $0.5 eV$. This peak is attributed to the transition of electrons from the occupied Ir$^{3+}$ $t_{2g}$ state to upper Ir$^{4+}$ $t_{2g}$ subband resulting from the dimerization of Ir$^{4+}$ ions in association with the simultaneous formations of Ir$^{3+}$ and Ir$^{4+}$ octamers as recently revealed by the x-ray diffraction experiment. Our experiments indicate that the band structure is reconstructed in the insulating phase due to the sudden structural transition.

cond-mat.str-el↗

arXiv2003

Tunneling spectroscopy of Na$_{x}$CoO$_2$ and Na$_{x}$CoO$_2$$\cdot$ yH$_2$O

The single electron tunneling spectroscopy on superconductor Na$_{x}$CoO$_2$$\cdot$ yH$_2$O and its starting compound Na$_{x}$CoO$_2$ has been studied with point-contact method. The spectra of Na$_{x}$CoO$_2$ have two types of distinct shapes at different random locations, this is attributed to the non-uniformly distributed sodium escaped from the inner part of the sample. While all the measured spectra of the superconducting samples Na$_{x}$CoO$_2$$\cdot$ yH$_2$O have a good spatial reproducibility, and show a remarkable zero bias conductance depression appearing below an onset temperature which associates very well with the resistance upturn at around 45 K. The latter behavior resembles in some way the pseudogap feature in high-T$_c$ cuprate uperconductors.

cond-mat.supr-con↗