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G. Mattioli

Publications and source records attributed to G. Mattioli.

2 recordsLinked to original sources

Scientific performances of the XGIS instrument on-board THESEUS

The Transient High Energy Sky and Early Universe Surveyor (THESEUS) satellite, currently undergoing a Phase-A study for the M7 ESA mission selection, will mainly rely on the XGIS (X and Gamma Imaging Spectrometer) instrument to discover and precisely localise gamma-ray bursts and other high-energy transients. The XGIS instrument has been designed to provide accurate sky images in a wide field of view (>2 steradians) in the 2-150 keV band, coupled to coverage of nearly half of the sky with good timing and spectroscopic capabilities up to several MeV. This will be achieved thanks to the combination of two identical cameras, based on the coded mask imaging technique, oriented to provide partially overlapping fields of view. We present the capabilities of the XGIS, focussing in particular on the sensitivity and source location accuracy. We discuss the expected scientific advances in the GRB field, estimated through detailed Monte-Carlo simulations which take into account the design of the XGIS imaging system and the properties of the GRB population at high redshifts.

astro-ph.IM

Electron-Hole Separation Dynamics and Optoelectronic Properties of a PCE10:FOIC Blend

Understanding charge separation dynamics in organic semiconductor blends is crucial for optimizing the performance of organic photovoltaic solar cells. In this study, we explored the optoelectronic properties and charge separation dynamics of a PCE10:FOIC blend, by combining steady-state and time-resolved spectroscopies with high-level DFT calculations. Femtosecond transient absorption spectroscopy revealed a significant reduction of the exciton-exciton annihilation recombination rate in the acceptor when incorporated into the blend, compared to its pristine form. This reduction was attributed to a decrease in exciton density within the acceptor, driven by an efficient hole-separation process that was characterized by following the temporal evolution of the transient signals associated with the excited states of the donor when the acceptor was selectively excited within the blend. The analysis of these dynamics enabled the estimation of the hole separation time constant from the acceptor to the donor, yielding a time constant of (1.3 +- 0.3) ps. Additionally, this study allowed the quantification of exciton diffusion and revealed a charge separation efficiency of approximately 60%, providing valuable insights for the design of next-generation organic photovoltaic materials with enhanced charge separation and improved device efficiency.

cond-mat.mtrl-sci