arXiv subjects

G. Negro

Publications and source records attributed to G. Negro.

9 recordsLinked to original sources

arXiv2026

Geometry and relaxation dynamics of nematic loops

Disclination lines in three-dimensional nematic liquid crystals generically form closed loops whose topology is classified by homotopy theory. While this classification successfully captures global topological features, it does not encode the geometry of the defect profile along the loop, which can strongly influence defect dynamics. Here, we propose a geometric description of nematic disclination loops using the Clifford algebra Cl(3,0). This approach naturally captures the geometry of the local defect profile, as well as changes along the loop, which is mathematically a SU(2) holonomy. Simulations of the dynamics of defect loops with specified geometries embedded in nematic liquid crystals demonstrate that loops nucleate the growth of "topological blobs" of defects, which later dissipate leaving uniform nematic textures. Self-twist of the defect profile leads to nucleation of additional linking disclination lines, with a simple arithmetic relation between total self-twist and linking number. In contrast, loops with an even number of discrete profile transitions generate patterns with threading between loops, but no linking. These results establish a direct connection between the geometric holonomy of a disclination loop and its subsequent evolution, and may be extendable to more complex order parameter manifolds, such as cholesterics or smectics.

cond-mat.soft↗

arXiv2026

Braiding and exchange statistics of liquid crystalline Majorana quasiparticles

Liquid crystalline defects in 3D can be viewed as geometric spinors, whose emergent properties are reminiscent of those of topological excitations in quantum condensed matter, such as Majorana quasiparticles. However, it is unclear how deep this analogy is, and whether this is a purely mathematical mapping, or it extends to key physical features, such as the exchange statistics or braiding behaviour. To address this question, here we consider a simple pattern made up of four nematic Majorana-like defect profiles, and ask how the defect profiles change as we braid them repeatedly around each other. Surprisingly, we find that in a large range of parameter space the defect profiles behave as classical analogues of non-Abelian anyons, which can be described in our case by defect bivectors moving on a Bloch-like hemisphere. Elastic interactions and dynamical effects enhance the complexity of the gates which can be performed by braiding these quasiparticles, making these liquid crystalline spinors promising candidates as components of topological computers.

cond-mat.soft↗

arXiv2026

Spontaneous phase separation and pattern formation in a lyotropic nematic mixture

Lyotropic liquid crystals can display rich phase behaviour and self-organisation, yet the physical principles underlying their self-assembly into large scale patterns remains understudied. Here, we combine theory, simulations and experiments on Sunset Yellow-water chromonic mixtures to show that such materials spontaneously phase separate, even without assuming any underlying microscopic attraction between the molecular species. In our minimal model, demixing depends solely on the Onsager-like coupling between local nematogen density and orientational order. If such a coupling is sufficiently strong, nematic defects trigger the nucleation of isotropic droplets, which then coalesce due to elastic or interfacial tensions. We further show that strong anchoring of the director field at the interface arrests this coarsening process, resulting in a stable microphase separated lamellar pattern. This self-assembled smectic phase has striking and unusual features, including spontaneous undulations, heterogeneous layer spacing, long-lived glassy defect patterns and lamellar onions. Our results identify orientational-density coupling and elastocapillarity as fundamental mechanisms to guide self-assembly in lyotropic and chromonic liquid crystals.

cond-mat.soft↗

arXiv2025

Clifford algebras and liquid crystalline fermions

We show that Clifford algebras provide a natural language to describe the physics of liquid crystal defects in 3D. This framework shows that most of these defects have fermionic nature, as the director field profile on a 2D cross section can algebraically be represented by a spinor. Defects in uniaxial, biaxial nematics and cholesterics are represented by elements belonging to different Clifford algebras, suggesting that there are fundamental distinctions between topological defects in each of these phases. Our theory allows nematic defects to be interpreted as Majorana-like spinors, as defects and antidefects are topologically equivalent, whilst some cholesteric defects, such as screw dislocations, are better viewed as Weyl-like spinors of well-defined chirality. Defects can be described by a ``defect bivector'', an algebraic element which quantifies the rototranslation associated with them. In cholesterics, fermionic defects of different types can combine to yield composite quasiparticles with either fermionic or bosonic nature. Under cylindrical confinement, these quasiparticles provide the way to understand the structure of screw dislocations. In the bulk, they may condensate to form topological phases, such as blue phases or skyrmion lattices. Our results provide a surprising link between liquid crystals, particle physics, and topological quantum matter.

cond-mat.soft↗

arXiv2023

Phase behaviour and dynamics of three-dimensional active dumbbell systems

We present a comprehensive numerical study of the phase behavior and dynamics of a three-dimensional active dumbbell system with attractive interactions. We demonstrate that attraction is essential for the system to exhibit nontrivial phases. We construct a detailed phase diagram by exploring the effects of the system's activity, density, and attraction strength. We identify several distinct phases, including a disordered, a gel, and a completely phase-separated phase. Additionally, we discover a novel dynamical phase, that we name percolating network, which is characterized by the presence of a spanning network of connected dumbbells. In the phase-separated phase we characterize numerically and describe analytically the helical motion of the dense cluster.

cond-mat.soft↗

arXiv2022

Motility and self propulsion of active droplets

In the last years self-motile droplets attracted the attention of scientists from different fields ranging from applied biology to theoretical physics, because of their promising technological applications and important biological implications. In this Chapter we review the state of the art of the research on active droplets with a particular focus on theoretical and numerical studies. In particular, we reviewed the active gel theory, namely a generalization of the standard Landau-de Gennes theory for liquid crystals adapted to take into account internal active injection due to the presence of self-motile constituents. When confined in finite geometries, liquid crystalline-like systems are also subject to topological constraints. Because of the relevance of topology in many different realizations of active droplets, we also reviewed some fundamental topological concepts. We review how motility arises in different realizations of active droplet both in 2d and 3d as the result of the breaking of specific symmetries, by looking in particular detail at the case of polar and nematic droplets and shells of active liquid crystals.

cond-mat.soft↗

arXiv2020

Lattice Boltzmann simulations of self-propelling chiral active droplets

Active matter describes materials whose constituents are driven out of equilibrium by continuous energy consumption, for instance from ATP. Due to the orientable character of the constituents, active suspensions can attain liquid crystalline order and can be theoretically described as active liquid crystals. Their inherently nonequilibrium dynamics causes a range of new striking effects, that in most cases have been characterized with numerical simulations, using lattice Boltzmann models (LB). In many active biological systems chirality plays an important role. Biomolecules such as DNA, actin, or microtubules form helical structures which, at sufficiently high density and in the absence of active forces, tend to self-assemble into twisted cholesteric phases. Understanding the outcome of the interplay between chirality and activity is therefore an important and timely question. Studying a droplet of chiral matter in 3D, we have found evidence of a new motility mode, where the rotational motion of surface topological defects, that arrange in a fan-like pattern. The resulting regular propulsive motion due to the underlying chirality is a striking phenomenon that can be also used in practical applications. The use of a parallel (MPI) implementation of lattice Boltzmann models, and available HPC resources, have been of fundamental importance in conducting the study. We have used different HPC clusters and among these RECAS. This allowed us to conduct a scaling test performed on different computational infrastructures.

cond-mat.soft↗

arXiv2020

Soft channel formation and symmetry breaking in exotic active emulsions

We use computer simulations to study the morphology and rheological properties of a bidimensional emulsion resulting from a mixture of a passive isotropic fluid and an active contractile polar gel, in the presence of a surfactant that favours the emulsification of the two phases. By varying the intensity of the contractile activity and of an externally imposed shear flow, we find three possible morphologies. For low shear rates, a simple lamellar state is obtained. For intermediate activity and shear rate, an asymmetric state emerges, which is characterized by shear and concentration banding at the polar/isotropic interface. A further increment in the active forcing leads to the self-assembly of a soft channel where an isotropic fluid flows between two layers of active material. We characterize the stability of this state by performing a dynamical test varying the intensity of the active forcing and shear rate. Finally, we address the rheological properties of the system by measuring the effective shear viscosity, finding that this increases as active forcing is increased, so that the fluid thickens with activity.

cond-mat.soft↗

arXiv2020

Activity induced isotropic-polar transition in active liquid crystals

Active fluids are intrinsically out-of-equilibrium systems due to the internal energy injection of the active constituents. We show here that a transition from a motion-less isotropic state towards a flowing polar one can be possibly driven by the sole active injection through the action of polar-hydrodynamic interactions in absence of an ad hoc free-energy which favors the development of an ordered phase. In particular, we propose an analytical argument and we perform lattice Boltzmann simulations where the appearance of large temporal fluctuations in the polar fraction of the system is observed at the transition point. Moreover, we make use of a scale-to-scale analysis to unveil the energy transfer mechanism, proving that elastic absorption plays a relevant role in the overall dynamics of the system, contrary to what reported in previous works on the usual active gel theory where this term could be factually neglected.

cond-mat.soft↗