arXiv subjects

G. Pineau des Forets

Publications and source records attributed to G. Pineau des Forets.

26 records · Page 2Linked to original sources

arXiv2006

The abundances of nitrogen-containing molecules during pre-protostellar collapse

We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed the chemical evolution of a medium comprising gas and dust as it underwent free--fall gravitational collapse. Chemical processes which determine the relative populations of the nuclear spin states of molecules and molecular ions were included explicitly, as were reactions which lead ultimately to the deuteration of the nitrogen--containing species N2H+ and NH3. The freeze-out of `heavy' molecules onto grains was taken into account. We found that the timescale required for the nitrogen--containing species to attain their steady--state values was much larger than the free--fall time and even comparable with the probable lifetime of the precursor molecular cloud. However, it transpires that the chemical evolution of the gas during gravitational collapse is insensitive to its initial composition. If we suppose that the grain--sticking probabilities of atomic nitrogen and oxygen are both less than unity (S less than 0.3), we find that the observed differential freeze--out of nitrogen- and carbon--bearing species can be reproduced by the model of free--fall collapse when a sufficiently large grain radius (a_{g}= 0.5 micron) is adopted. Furthermore, the results of our collapse model are consistent with the high levels of deuteration of N2H+ and NH3 which have been observed in L1544 providing that 0.5<a_{g}<1 micron. We note that the o/p H2D+ ratio and fractional abundance of ortho-H2D+ should be largest when ND3 is most abundant.

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arXiv2006

The importance of the ortho:para H2 ratio for the deuteration of molecules during pre-protostellar collapse

We have studied the evolution of molecular gas during the early stages of protostellar collapse. In addition to allowing for the freeze out of `heavy' species on to grains, we have computed the variation of population densities of the different nuclear spin states of ``tracer'' molecular ions such as H2D+ and D2H+. Processes which determine the relative populations of the nuclear spin states of molecules and molecular ions have received much less attention in the literature than those involved in their deuteration; but in fact the former processes are as significant as the latter and often involve the same reactants. We find that the ortho:para ratio of some species, e.g. H2D+, vary considerably as the density increases. Because the dynamical timescale is much shorter than some of the chemical timescales, there can be large departures of the predictions of the free--fall model from the steady state solution at the same density and temperature. In the case of H2, it seems unlikely that the steady state value of the ortho:para ratio is attained before protostellar collapse from the progenitor molecular cloud commences. Values of the ortho:para H2 ratio much higher than in steady state, which would prevail in ``young'' molecular clouds, are found to be inconsistent with high levels of deuteration of the gas. The internal energy of ortho--H2 acts as a reservoir of chemical energy which inhibits the deuteration of H3+ and hence of other species, such as N2H+ and NH3. In essence, the deuteration of molecular ions and molecules is sensitive to the ortho:para H2 ratio and hence to the chemical and thermal history of the parent molecular cloud.

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arXiv2004

A far UV study of interstellar gas towards HD34078: high excitation H2 and small scale structure - Based on observations performed by the FUSE mission and at the CFHT telescope

To investigate the presence of small scale structure in the spatial distribution of H2 molecules we have undertaken repeated FUSE UV observations of the runaway O9.5V star, HD34078. In this paper we present five spectra obtained between January 2000 and October 2002. These observations reveal an unexpectedly large amount of highly excited H2. Column densities for H2 levels from (v = 0, J = 0) up to (v = 0, J = 11) and for several v = 1 and v = 2 levels are determined. These results are interpreted in the frame of a model involving essentially two components: i) a foreground cloud (unaffected by HD34078) responsible for the H2 (J = 0, 1), CI, CH, CH+ and CO absorptions; ii) a dense layer of gas (n = 10E4 cm-3) close to the O star and strongly illuminated by its UV flux which accounts for the presence of highly excited H2. Our model successfully reproduces the H2 excitation, the CI fine-structure level populations as well as the CH, CH+ and CO column densities. We also examine the time variability of H2 absorption lines tracing each of these two components. From the stability of the J = 0, 1 and 2 damped H2 profiles we infer a 3 sigma upper limit on column density variations Delta(N(H2))/N(H2) of 5% over scales ranging from 5 to 50 AU. This result clearly rules out any pronounced ubiquitous small scale "density" structure of the kind apparently seen in HI. The lines from highly excited gas are also quite stable (equivalent to Delta(N)/N <= 30%) indicating i) that the ambient gas through which HD34078 is moving is relatively uniform and ii) that the gas flow along the shocked layer is not subject to marked instabilities

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arXiv2004

Complete Depletion in prestellar cores

We have carried out calculations of ionization equilibrium and deuterium fractionation for conditions appropriate to a completely depleted, low mass pre--protostellar core, where heavy elements such as C, N, and O have vanished from the gas phase and are incorporated in ice mantles frozen on dust grain surfaces. We put particular emphasis on the interpretation of recent observations of H2D+ towards the centre of the prestellar core L1544 (Caselli et al. 2003) and also compute the ambipolar diffusion timescale. We consider explicitly the ortho and para forms of H2,H3+, and H2D+. Our results show that the ionization degree under such conditions depends sensitively on the grain size distribution or, more precisely, on the mean grain surface area per hydrogen nucleus. Depending upon this parameter and upon density, the major ion may be H+, H3+, or D3+. We show that the abundance of ortho-H2D+ observed towards L1544 can be explained satisfactorily in terms of a complete depletion model and that this species is, as a consequence, an important tracer of the kinematics of prestellar cores.

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arXiv2003

Some empirical estimates of the H2 formation rate in photon-dominated regions

We combine recent ISO observations of the vibrational ground state lines of H2 towards Photon-Dominated Regions (PDRs) with observations of vibrationally excited states made with ground-based telescopes in order to constrain the formation rate of H2 on grain surfaces under the physical conditions in the layers responsible for H2 emission. We use steady state PDR models in order to examine the sensitivity of different H2 line ratios to the H2 formation rate Rf. We show that the ratio of the 0-0 S(3) to the 1-0 S(1) line increases with Rf but that one requires independent estimates of the radiation field incident upon the PDR and the density in order to infer Rf from the H2 line data. We confirm the earlier result of Habart et al. (2003) that the H2 formation rate in regions of moderate excitation such as Oph W, S140 and IC 63 is a factor of 5 times larger than the standard rate inferred from UV observations of diffuse clouds. On the other hand, towards regions of higher radiation field such as the Orion Bar and NGC 2023, we derive H2 formation rates consistent with the standard value. We find also a correlation between the H2 1-0 S(1) line and PAH emission suggesting that Rf scales with the PAH abundance. With the aim of explaining these results, we consider some empirical models of the H2 formation process. Here we consider both formation on big (a~0.1 microns) and small (a~10 Angstroms) grains by either direct recombination from the gas phase or recombination of physisorbed H atoms with atoms in a chemisorbed site. We conclude that indirect chemisorption is most promising in PDRs. Moreover small grains which dominate the total grain surface and spend most of their time at relatively low temperatures may be the most promising surface for forming H2 in PDRs.

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arXiv2002

Detection of FeO towards SgrB2

We have observed the J=5-4 ground state transition of FeO at a frequency of 153 GHz towards a selection of galactic sources. Towards the galactic center source SgrB2, we see weak absorption at approximately the velocity of other features towards this source (62 km s$^{-1}$ LSR). Towards other sources, the results were negative as they were also for MgOH(3-2) and FeC(6-5). We tentatively conclude that the absorption seen toward SgrB2 is due to FeO in the hot ($\sim $ 500 K) relatively low density absorbing gas known to be present in this line of sight. This is the first (albeit tentative) detection of FeO or any iron--containing molecule in the interstellar gas. Assuming the observed absorption to be due to FeO, we estimate [FeO]/[SiO] to be of order or less than 0.002 and [FeO]/[H$_{2}$] of order $3 10^{-11}$. This is compatible with our negative results in other sources. Our results suggest that the iron liberated from grains in the shocks associated with SgrB2 remains atomic and is not processed into molecular form.

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arXiv2001

Photoelectric effect on dust grains across the L1721 cloud in the rho Ophiuchi molecular complex

We present ISO-LWS measurements of the main gas cooling lines, C+ 158 mum and O 63 mum towards a moderate opacity molecular cloud (Av=3), L1721, illuminated by the B2 star nu Sco (X = 5-10). These data are combined with an extinction map and IRAS dust emission images to test our understanding of gas heating and cooling in photo-dissociation regions (PDRs). This nearby PDR is spatially resolved in the IRAS images; variations in the IRAS colors across the cloud indicate an enhanced abundance of small dust grains within the PDR. A spatial correlation between the gas cooling lines and the infrared emission from small dust grains illustrates the dominant role of small dust grains in the gas heating through the photoelectric effect. The photoelectric efficiency, determined from the observations by ratioing the power radiated by gas and small dust grains, is in the range 2 to 3% in close agreement with recent theoretical estimates. The brightness profiles across the PDR in the C+ 158 mum and O 63 mum lines are compared with model calculations where the density profile is constrained by the extinction data and where the gas chemical and thermal balances are solved at each position. We show that abundance variations of small dust grains across the PDR must be considered to account for the LWS observations.

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arXiv1999

ISOCAM spectro-imaging of the H2 rotational lines in the supernova remnant IC443

We report spectro-imaging observations of the bright western ridge of the supernova remnant IC 443 obtained with the ISOCAM circular variable filter (CVF) on board the Infrared Space Observatory (ISO). This ridge corresponds to a location where the interaction between the blast wave of the supernova and ambient molecular gas is amongst the strongest. The CVF data show that the 5 to 14 micron spectrum is dominated by the pure rotational lines of molecular hydrogen (v = 0--0, S(2) to S(8) transitions). At all positions along the ridge, the H2 rotational lines are very strong with typical line fluxes of 10^{-4} to 10^{-3} erg/sec/cm2/sr. We compare the data to a new time-dependent shock model; the rotational line fluxes in IC 443 are reproduced within factors of 2 for evolutionary times between 1,000 and 2,000 years with a shock velocity of 30 km/sec and a pre-shock density of 10^4 /cm3.

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