arXiv subjects

G. Quintana-Lacaci

Publications and source records attributed to G. Quintana-Lacaci.

At least 19 recordsLinked to original sources

arXiv2026

The formation radius of HCN in O-rich asymptotic giant branch stars

Molecules detected in circumstellar envelopes around asymptotic giant branch (AGB) stars are generally well explained in terms of formation under chemical equilibrium in the stellar atmosphere or photochemistry in the outer expanding layers. However, several molecules are detected in the inner circumstellar regions with abundances orders of magnitude above the predictions of chemical equilibrium. Anomalously abundant molecules comprise H2O, NH3, SiH4, and PH3 in C-rich envelopes and HCN, CS, and NH3 in O-rich sources. These molecules are formed by some yet unknown nonequilibrium processes. Aims: We aim to shed light on the nonequilibrium process that enhances the abundance of anomalously abundant molecules in the inner regions of circumstellar envelopes. Here, we focus on HCN in O-rich stars to constrain its formation radius. Method: We observed the O-rich AGB stars RCrt and IKTau with ALMA at high angular resolution (HPBW=~0.05") in the J=4-3 line of HCN in both the ground and the ν_2=1 vibrational states. The radial distribution of the emission was modeled using a large velocity gradient radiative transfer code in which we considered an abundance profile with a central hole. Results: The models with a hole in the abundance distribution of HCN reproduce the specific shape of the radial emission distribution around the two studied O-rich stars. The best models locate the formation radius of HCN at 4-6 Rstar in RCrt and 3-5 Rstar in IKTau. Conclusion: The formation radius of HCN inferred from observations is consistent with models that invoke shocked-induced chemistry but also with models where photochemistry acts as the solely disequilibrium process. High angular resolution observations of more O-rich stars and tailored shocked-induced and/or photochemical models are needed to unambiguously unveil the underlying mechanism behind anomalously abundant molecules in AGB envelopes.

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arXiv2026

Chemistry in the High expansion-velocity C-rich evolved star AFGL2233. Isotopic ratios, peculiarities and evolutionary status

High expansion velocity carbon stars (HVCs) are a rare class of evolved stars whose circumstellar envelopes (CSEs) combine C-rich chemistry with unusually high expansion velocities typical of O-rich massive evolved stars. AFGL2233 has been proposed as a high-mass evolved object that exhausted hot-bottom burning. Studying its chemistry is essential to understand the nature and evolution of these objects. We characterize the chemical composition and isotopic ratios of the CSE of AFGL2233 and investigate chemical peculiarities, including the presence of N- and O-bearing species in a C-rich environment. We carried out a complete line survey at 3 mm and 1 mm using the IRAM 30m telescope, complemented by Herschel/HIFI FIR observations and interferometric maps of SiO, C2H, and HCN. Molecular emission was analyzed using rotational diagrams and radiative transfer modeling under the LVG approximation. Column densities and fractional abundances were derived for more than 30 molecular species, including isotopologues, and compared with other evolved stars. The Gaia DR3 distance of 1.236 kpc implies a luminosity of ~2 Lsun, consistent with an initial mass of 4.5-9 Msun. The molecular inventory confirms C-rich chemistry but reveals unusually high abundances of NH3, H2O, and SiN. The isotopic ratios vary among species, with 12C/13C ranging from 7 to 55. The C2H/C4H ratio is abnormally high compared with C-rich AGB stars. The presence of SiN and high NH3 may indicate N-enrichment or the influence of a companion. AFGL2233 is likely a high-mass AGB or super-AGB star with a complex evolutionary history involving nucleosynthesis, shocks, and possible binary interaction.

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arXiv2025

Exploring circumstellar chemistry in X-ray emitting AGB stars

Aims. Our goal is to characterize the chemistry and physical conditions of the circumstellar envelopes (CSEs) of Asymptotic Giant Branch (AGB) binary candidate stars with UV-excess and X-ray emission, in particular, to identify the effects of the internal X-ray emission in the abundance of certain key molecules. Methods. We observed the 86.0-94.0 and 260.0-272.5 GHz spectral ranges searching for rotational transitions of the X-ray sensitive molecule $HCO^{+}$ in four AGB stars, two of them detected in both UV and X-ray emission and the other two detected only in UV. We derived the CSEs's physical parameters from previous CO observations and determined the molecular abundances of the detected species using radiative transfer models. We developed chemical kinetics models that account for the effects of internal X-ray emission (as well as UV radiation) and compared our predictions with observations. Results. We report the detection of $HCO^{+}$ in the X-ray emitting C-rich AGB T\,Dra, while it remains undetected in the spectra of the other three sources. In T\,Dra we also detect SiO, HCN, HNC, $HC_{3}N$, $SiC_{2}$, $C_{2}H$ and SiS. For the other targets only HCN and SiO are detected. The high fractional abundance of $HCO^{+}$ derived for T\,Dra ($[1.5-3.0]\times 10^{-8}$) is in good agreement with the predictions from our chemical kinetics models including the effects of internal X-ray emission, and one order of magnitude higher than the values expected for C-rich AGB stars. Additionally, we identify abundance enhancements for HNC, and $HC_{3}N$ alongside a depletion of CO in the innermost regions of T\,Dra's envelope. Conclusions. An internal X-ray source can significantly alter molecular abundances in AGB CSEs, enhancing $HCO^{+}$, $N_{2}H^{+}$, HNC, and $HC_{3}N$ while depleting parent species like CO. UV radiation has a weaker effect unless the envelope is optically thin or porous.

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arXiv2025

The circumstellar environment around the extreme Galactic red supergiant NML Cygni: Dense, dusty, and asymmetric

Supernova observations imply the presence of a dense and asymmetric circumstellar environment around SN Type II progenitors, whereas the mass loss from these progenitors, namely, red supergiants, is still poorly constrained. We aim to characterise the dust and gas in the circumstellar environment of the extreme Galactic red supergiant \nmlcyg in terms of mass, morphology, and kinematics. Based on interferometric observations with NOEMA at 230 GHz we estimated dust masses and temperatures, and measured the extent and morphological complexity of the circumstellar environment. We detected two strong continuum components, amounting to an estimated total dust mass of $\sim2\times10^{-3}M_{\odot}$ located out to ~2000 AU from the star, largely beyond the dust detected at optical/infrared wavelengths. The extent of the detected CO emission supports the notion that the outflow is formed by a mass-loss rate of several $10^{-4}\,M_{\odot}$/year and that it is not primarily shaped by extreme irradiation from the Cyg OB2 cluster it has been associated with. We have detected, but not resolved, previously unseen high-velocity components close to the star. The observations reveal a very complex circumstellar morphology and we propose that some of the detected components could be the imprint of a hitherto unknown binary companion.

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arXiv2024

Atmospheric molecular blobs shape up circumstellar envelopes of AGB stars

During their thermally pulsing phase, Asymptotic Giant Branch (AGB) stars eject material that forms extended dusty envelopes. Visible polarimetric imaging found clumpy dust clouds within two stellar radii of several oxygen-rich stars. Inhomogeneous molecular gas has also been observed in multiple emission lines within several stellar radii of different oxygen rich stars, including W Hya and Mira. At the stellar surface level, infrared images have revealed intricate structures around the carbon semi-regular variable R Scl and in the S-type star $π^{\mathrm{1}}$ Gru. Infrared images have also shown clumpy dust structures within a few stellar radii of the prototypical carbon AGB star IRC+10216, and studies of the molecular gas distribution beyond the dust formation zone have also shown complex circumstellar structures. Because of the lack of sufficient spatial resolution, however, the distribution of molecular gas in the stellar atmosphere and the dust formation zone of AGB carbon stars is not known, nor is how it is subsequently expelled. Here we report observations with a resolution of one stellar radius of the recently formed dust and molecular gas in the atmosphere of IRC+10216. Lines of HCN, SiS, and SiC$_2$ appear at different radii and in different clumps, which we interpret as large convective cells in the photosphere, as seen in Betelgeuse. The convective cells coalesce with pulsation causing anisotropies that, together with companions, shape its circumstellar envelope.

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arXiv2022

History of two mass loss processes in VY CMa. Fast outflows carving older ejecta

Red supergiant stars (RSGs, Minit = 10-40Msun) are known to eject large amounts of material, as much as half of their initial mass during this evolutionary phase. However, the processes powering the mass ejection in low- and intermediate-mass stars do not work for RSGs and the mechanism that drives the ejection remains unknown. Different mechanisms have been proposed as responsible for this mass ejection but so far little is known about the actual processes taking place in these objects. Here we present high angular resolution interferometric ALMA maps of VY CMa continuum and molecular emission, which resolve the structure of the ejecta with unprecedented detail. The study of the molecular emission from the ejecta around evolved stars has been shown to be an essential tool in determining the characteristics of the mass loss ejections. Our aim is thus to use the information provided by these observations to understand the ejections undergone by VY CMa and to determine their possible origins. We inspected the kinematics of molecular emission observed. We obtained position-velocity diagrams and reconstructed the 3D structure of the gas traced by the different species. It allowed us to study the morphology and kinematics of the gas traced by the different species surrounding VY CMa. Two types of ejecta are clearly observed: extended, irregular, and vast ejecta surrounding the star that are carved by localized fast outflows. The structure of the outflows is found to be particularly flat. We present a 3D reconstruction of these outflows and proof of the carving. This indicates that two different mass loss processes take place in this massive star. We tentatively propose the physical cause for the formation of both types of structures. These results provide essential information on the mass loss processes of RSGs and thus of their further evolution.

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arXiv2022

First detection of silicon-bearing molecules in $η$ Car

We present ALMA band 6 observations of the luminous blue variable Eta Car, obtained within the ALMAGAL program. We report SiO J=5-4, SiS J=12-11 and SiN N=5-4 emission in the equatorial region of the Homunculus nebula, constituting the first detection of silicon- and sulphur-bearing molecules in the outskirts of a highly evolved, early-type massive star. SiO, SiS and SiN trace a clumpy equatorial ring that surrounds the central binary at a projected distance of 2 arcsec, delineating the inner rims of the butterfly-shaped dusty region. The formation of silicon-bearing compounds is presumably related to the continuous recycling of dust due to the variable wind regime of Eta Car, that destroys grains and releases silicon back to gas phase. We discuss possible formation routes for the observed species, contextualizing them within the current molecular inventory of Eta Car. We find that the SiO and SiS fractional abundances in localised clumps of the ring, $6.7\times10^{-9}$ and $1.2\times10^{-8}$ respectively, are exceptionally lower than those measured in C- and O-rich AGB stars and cool supergiants; while the higher SiN abundance, $3.6\times10^{-8}$, evidences the nitrogen-rich chemistry of the ejecta. These abundances must be regarded as strict upper limits, since the distribution of H2 in the Homunculus is unknown. In any case, these findings shed new light onto the peculiar molecular ecosystem of Eta Car, and establish its surroundings as a new laboratory to investigate the lifecycle of silicate dust in extreme astrophysical conditions.

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arXiv2022

Dissecting the central regions of OH 231.8 + 4.2 with ALMA: a salty rotating disk at the base of a young bipolar outflow

We present ALMA continuum and molecular line emission maps at $\sim$1 mm of OH 231.8, a well studied bipolar nebula around an AGB star. The excellent angular resolution of our maps ($\sim$20 mas) allows us to scrutinise the central nebular regions of OH 231.8, which hold the clues to unravel how this iconic object assembled its complex nebular architecture. We report, for the first time in this object and others of its kind, the discovery of a rotating circumbinary disk selectively traced by NaCl, KCl, and H$_2$O emission lines. This represents the first detection of KCl in an oxygen-rich AGB circumstellar envelope. The rotating disk, of radius $\sim$30 au, lies at the base of a young bipolar wind traced by SiO and SiS emission, which also presents signs of rotation at its base. The NaCl equatorial structure is characterised by a mean rotation velocity of $\sim$4 km s$^{-1}$ and extremely low expansion speeds, $\sim$3 km s$^{-1}$. The outflow has a predominantly expansive kinematics characterised by a constant radial velocity gradient of $\sim$65 km s$^{-1}$ arcsec$^{-1}$ at its base. Beyond $r$$\sim$350 au, the gas in the outflow continues radially flowing at a constant terminal speed of $\sim$16 km s$^{-1}$. Our continuum maps reveal a spatially resolved dust disk-like structure perpendicular to the outflow, with the NaCl, KCl and H$_2$O emission arising from the disk's surface layers. Within the disk, we also identify an unresolved point continuum source, which likely represents the central Mira-type star QX Pup enshrouded by a $\sim$3 $R_{\star}$ component of hot ($\sim$1400 K) freshly formed dust. The point source is slightly off-centered from the disk centroid, enabling us for the first time to place constraints to the orbital separation and period of the central binary system, $a$$\sim$20 au and $P_{\rm orb}$$\sim$55 yr, respectively. (abridged).

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arXiv2021

DEATHSTAR: Nearby AGB stars with the Atacama Compact Array II. CO envelope sizes and asymmetries: The S-type stars

We aim to constrain the sizes of the CO circumstellar envelopes (CSEs) of 16 S-type stars, along with an additional 7 and 4 CSEs of C-type and M-type AGB stars, respectively. We map the emission from the CO J=2-1 and 3-2 lines observed with the Atacama Compact Array (ACA) and its total power (TP) antennas, and fit with a Gaussian distribution in the uv- and image planes for ACA-only and TP observations, respectively. The major axis of the fitted Gaussian for the CO(2-1) line data gives a first estimate of the size of the CO-line-emitting CSE. We investigate possible signs of deviation from spherical symmetry by analysing the line profiles, the results from visibility fitting, and by investigating the deconvolved images. The sizes of the CO-line-emitting CSEs of low-mass-loss-rate (low-MLR) S-stars fall between the sizes of the CSEs of C-stars, which are larger, and those of M-stars, which are smaller, as expected because of the differences in their respective CO abundances. The sizes of the low-MLR S-type stars show no dependence on circumstellar density, while a steeper density dependence is observed at high MLR. Furthermore, our results show that the CO CSEs of most of the S-stars in our sample are consistent with a spherically symmetric and smooth outflow. The CO envelope sizes obtained in this paper will be used to constrain detailed radiative transfer modelling to directly determine more accurate MLR estimates for the stars in our sample. For several of our sources that present signs of deviation from spherical symmetry, further high-resolution observations would be necessary to investigate the nature of, and the physical processes behind, these asymmetrical structures. This will provide further insight into the mass-loss process and its related chemistry in S-type AGB stars.

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arXiv2020

DEATHSTAR: Nearby AGB stars with the Atacama Compact Array I. CO envelope sizes and asymmetries: A new hope for accurate mass-loss-rate estimates

This is the first publication of the DEATHSTAR project. The goal of the project is to reduce the uncertainties of observational estimates of mass-loss rates from Asymptotic Giant Branch (AGB) stars. Line emission from 12CO J=2-1 and 3-2 were mapped using the ACA. In this initial analysis, the emission distribution was fit to a Gaussian distribution in the uv-plane. Detailed radiative transfer analysis will be presented in the future. The axes of the best-fit Gaussian at the line center of the 12CO J=2-1 emission gives a first indication of the size of the emitting region. Furthermore, the fitting results, such as the major and minor axis, center position, and the goodness of fit across both lines, constrain the symmetry of the emission distribution. We find that the CO envelope sizes are, in general, larger for C-type than for M-type AGB stars, which is expected if the CO/H2 ratio is larger in C-type stars. Furthermore, a relation between the 12CO J=2-1 size and circumstellar density is shown that, while in broad agreement with photodissociation calculations, reveals large scatter and systematic differences between the stellar types. The majority of the sources have CO envelopes that are consistent with a spherically symmetric, smooth outflow. For about a third of the sources, indications of strong asymmetries are found. This is consistent with previous interferometric investigations of northern sources. Smaller scale asymmetries are found in a larger fraction of sources. These results for CO envelope radii and shapes can be used to constrain detailed radiative transfer modeling of the same stars so as to determine mass-loss rates that are independent of photodissociation models. For a large fraction of the sources, observations at higher spatial resolution will be necessary to further investigate the complex circumstellar dynamics revealed by our ACA observations.

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arXiv2019

IRC+10216 mass loss properties through the study of $λ$3mm emission: Large spatial scale distribution of SiO, SiS, and CS

The study of the gas in the envelopes surrounding asymptotic giant branch (AGB) stars through observations in the millimetre wavelength range provides information about the history and nature of these molecular factories. Here we present ALMA observations at subarsecond resolution, complemented with IRAM-30m data, of several lines of SiO, SiS, and CS towards the best-studied AGB circumstellar envelope, IRC+10216. We aim to characterise their spatial distribution and determine their fractional abundances mainly through radiative transfer and chemical modelling. The three species display extended emission with several enhanced emission shells. CS displays the most extended distribution reaching distances up to approximately 20''. SiS and SiO emission have similar sizes of approximately 11'', but SiS emission is slightly more compact. We have estimated fractional abundances relative to H$_2$, which on average are equal to f(SiO)$\sim$10$^{-7}$, f(SiS)$\sim$10$^{-6}$, and f(CS)$\sim$10$^{-6}$ up to the photo-dissociation region. The observations and analysis presented here show evidence that the circumstellar material displays clear deviations from an homogeneous spherical wind, with clumps and low density shells that may allow UV photons from the interstellar medium (ISM) to penetrate deep into the envelope, shifting the photo-dissociation radius inwards. Our chemical model predicts photo-dissociation radii compatible with those derived from the observations, although it is unable to predict abundance variations from the starting radius of the calculations ($\sim$10$R_{*}$), which may reflect the simplicity of the model. We conclude that the spatial distribution of the gas proves the episodic and variable nature of the mass loss mechanism of IRC+10216, on timescales of hundreds of years.

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arXiv2019

Discovery of the first Ca-bearing molecule in space: CaNC

We report on the detection of calcium isocyanide, CaNC, in the carbon-rich evolved star IRC+10216. We derived a column density for this species of (2.0$\pm$0.5)$\times$10$^{11}$ cm$^{-2}$. Based on the observed line profiles and the modelling of its emission through the envelope, the molecule has to be produced in the intermediate and outer layers of the circumstellar envelope where other metal-isocyanides have previously been found in this source. The abundance ratio of CaNC relative to MgNC and FeCN is $\simeq$1/60 and $\simeq$1, respectively. We searched for the species CaF, CaCl, CaC, CaCCH, and CaCH$_3$ for which accurate frequency predictions are available. Only upper limits have been obtained for these molecules.

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arXiv2019

Gas infall and possible circumstellar rotation in R Leo

We present new interferometer molecular observations of R Leo taken at 1.2 mm with the Atacama Large Millimeter Array with an angular resolution up to ~0.026 arcsec. These observations permit us to resolve the innermost envelope of this star revealing the existence of a complex structure that involves extended continuum emission and molecular emission showing a non-radial gas velocity distribution. This molecular emission displays prominent red-shifted absorptions located right in front to the star typical of material infall and lateral gas motions compatible with the presence of a torus-like structure.

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arXiv2018

Through the magnifying glass: ALMA acute viewing of the intricate nebular architecture of OH231.8+4.2

We present continuum and molecular line emission ALMA observations of OH 231.8+4.2, a well studied bipolar nebula around an asymptotic giant branch (AGB) star. The high angular resolution (~0.2-0.3 arcsec) and sensitivity of our ALMA maps provide the most detailed and accurate description of the overall nebular structure and kinematics of this object to date. We have identified a number of outflow components previously unknown. Species studied in this work include 12CO, 13CO, CS, SO, SO2, OCS, SiO, SiS, H3O+, Na37Cl, and CH3OH. The molecules Na37Cl and CH3OH are first detections in OH 231.8+4.2, with CH3OH being also a first detection in an AGB star. Our ALMA maps bring to light the totally unexpected position of the mass-losing AGB star (QX Pup) relative to the large-scale outflow. QX Pup is enshrouded within a compact (<60 AU) parcel of dust and gas (clump S) in expansion (V~5-7 km/s) that is displaced by 0.6arcsec to the south of the dense equatorial region (or waist) where the bipolar lobes join. Our SiO maps disclose a compact bipolar outflow that emerges from QX Pup's vicinity. This outflow is oriented similarly to the large-scale nebula but the expansion velocities are about ten times lower (~35 km/s). We deduce short kinematical ages for the SiO outflow, ranging from ~50-80 yr, in regions within ~150 AU, to ~400-500 yr at the lobe tips (~3500 AU). Adjacent to the SiO outflow, we identify a small-scale hourglass-shaped structure (mini-hourglass) that is probably made of compressed ambient material formed as the SiO outflow penetrates the dense, central regions of the nebula. The lobes and the equatorial waist of the mini-hourglass are both radially expanding with a constant velocity gradient. The mini-waist is characterized by extremely low velocities, down to ~1 km/s at ~150 AU, which tentatively suggest the presence of a stable structure. (abridged)

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arXiv2018

The maser emitting structure and time variability of the SiS lines J=14-13 and 15-14 in IRC+10216

We present new high angular resolution interferometer observations of the v=0 J=14-13 and 15-14 SiS lines towards IRC+10216, carried out with CARMA and ALMA. The maps, with angular resolutions of ~0.25"and 0.55", reveal (1) an extended, roughly uniform, and weak emission with a size of ~0.5", (2) a component elongated approximately along the East-West direction peaking at ~0.13" and 0.17" at both sides of the central star, and (3) two blue- and red-shifted compact components peaking around 0.07" to the NW of the star. We have modeled the emission with a 3D radiation transfer code finding that the observations cannot be explained only by thermal emission. Several maser clumps and one arc-shaped maser feature arranged from 5 to 20R* from the central star, in addition to a thin shell-like maser structure at ~13R* are required to explain the observations. This maser emitting set of structures accounts for 75% of the total emission while the other 25% is produced by thermally excited molecules. About 60% of the maser emission comes from the extended emission and the rest from the set of clumps and the arc. The analysis of a time monitoring of these and other SiS and 29SiS lines carried out with the IRAM 30m telescope from 2015 to present suggests that the intensity of some spectral components of the maser emission strongly depends on the stellar pulsation while other components show a mild variability. This monitoring evidences a significant phase lag of ~0.2 between the maser and NIR light-curves.

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arXiv2018

The Abundance of SiC2 in Carbon Star Envelopes: Evidence that SiC2 is a gas-phase precursor of SiC dust

Silicon carbide dust is ubiquitous in circumstellar envelopes around C-rich AGB stars. However, the main gas-phase precursors leading to the formation of SiC dust have not yet been identified. The most obvious candidates among the molecules containing an Si--C bond detected in C-rich AGB stars are SiC2, SiC, and Si2C. We aim to study how widespread and abundant SiC2, SiC, and Si2C are in envelopes around C-rich AGB stars and whether or not these species play an active role as gas-phase precursors of silicon carbide dust in the ejecta of carbon stars. We carried out sensitive observations with the IRAM 30m telescope of a sample of 25 C-rich AGB stars to search for emission lines of SiC2, SiC, and Si2C in the 2 mm band. We performed non-LTE excitation and radiative transfer calculations based on the LVG method to model the observed lines of SiC2 and to derive SiC2 fractional abundances in the observed envelopes. We detect SiC2 in most of the sources, SiC in about half of them, and do not detect Si2C in any source, at the exception of IRC +10216. Most of these detections are reported for the first time in this work. We find a positive correlation between the SiC and SiC2 line emission, which suggests that both species are chemically linked, the SiC radical probably being the photodissociation product of SiC2 in the external layer of the envelope. We find a clear trend in which the denser the envelope, the less abundant SiC2 is. The observed trend is interpreted as an evidence of efficient incorporation of SiC2 onto dust grains, a process which is favored at high densities owing to the higher rate at which collisions between particles take place. The observed behavior of a decline in the SiC2 abundance with increasing density strongly suggests that SiC2 is an important gas-phase precursor of SiC dust in envelopes around carbon stars.

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arXiv2017

Clues to NaCN formation

ALMA is providing us essential information on where certain molecules form. Observing where these molecules emission arises from, the physical conditions of the gas, and how this relates with the presence of other species allows us to understand the formation of many species, and to significantly improve our knowledge of the chemistry that occurs in the space. We studied the molecular distribution of NaCN around IRC +10216, a molecule detected previously, but whose origin is not clear. High angular resolution maps allow us to model the abundance distribution of this molecule and check suggested formation paths. We modeled the emission of NaCN assuming local thermal equilibrium (LTE) conditions. These profiles were fitted to azimuthal averaged intensity profiles to obtain an abundance distribution of NaCN. We found that the presence of NaCN seems compatible with the presence of CN, probably as a result of the photodissociation of HCN, in the inner layers of the ejecta of IRC +10216. However, similar as for CH 3 CN, current photochemical models fail to reproduce this CN reservoir. We also found that the abundance peak of NaCN appears at a radius of 3 x 10 15 cm, approximately where the abundance of NaCl, suggested to be the parent species, starts to decay. However, the abundance ratio shows that the NaCl abundance is lower than that obtained for NaCN. We expect that the LTE assumption might result in NaCN abundances higher than the real ones. Updated photochemical models, collisional rates, and reaction rates are essential to determine the possible paths of the NaCN formation.

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arXiv2017

The circumstellar envelope around the S-type AGB star W Aql Effects of an eccentric binary orbit

The CO(J=3-2) emission from the CSE of the binary S-type AGB star W Aql has been observed at subarcsecond resolution using ALMA. The aim of this paper is to investigate the wind properties of the AGB star and to analyse how the known companion has shaped the CSE. The average mass-loss rate during the creation of the detected CSE is estimated through modelling, using the ALMA brightness distribution and previously published single-dish measurements as observational constraints. The ALMA observations are presented and compared to the results from a 3D smoothed particle hydrodynamics (SPH) binary interaction model with the same properties as the W Aql system and with two different orbital eccentricities. Three-dimensional radiative transfer modelling is performed and the response of the interferometer is modelled and discussed. The estimated average mass-loss rate of W~Aql agrees with previous results. The size of the emitting region is consistent with photodissociation models. The CO(J=3-2) emission is dominated by a smooth component overlayed with two weak arc patterns with different separations. The larger pattern is predicted by the binary interaction model with separations of 10" and therefore likely due to the known companion. It is consistent with a binary orbit with low eccentricity. The smaller separation pattern is asymmetric and coincides with the dust distribution, but the separation timescale (200 yrs) is not consistent with any known process of the system. The separation of the known companions of the system is large enough to not have a very strong effect on the circumstellar morphology. The density contrast across the envelope of a binary with an even larger separation will not be easily detectable, even with ALMA, unless the orbit is strongly asymmetric or the AGB star has a much larger mass-loss rate.

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