Narrow band UV emission from direct band gap Si nanoclusters embedded in bulk Si
This paper has been withdrawn keeping in view of publication elsewhere with some appropriate modifications.
arXiv subjects
Publications and source records attributed to G. Sahu.
This paper has been withdrawn keeping in view of publication elsewhere with some appropriate modifications.
Two exponents, $δ$, for size distribution of $n$-atom clusters, $Y(n)\sim n^{-δ}$, have been found in Au clusters sputtered from embedded Au nanoparticles under swift heavy ion irradiation. For small clusters, below 12.5 nm in size, $δ$ has been found to be 3/2, which can be rationalized as occurring from a steady state aggregation process with size independent aggregation. For larger clusters, a $δ$ value of 7/2 is suggested, which might come from a dynamical transition to another steady state where aggregation and evaporation rates are size dependent. In the present case, the observed decay exponents do not support any possibility of a thermodynamic liquid-gas type phase transition taking place, resulting in cluster formation.
Some results on damage build up in, and amorphization of, Si, induced by 25-30 keV Al$_5^-$, Si$_5^-$ and Cs$^-$ ions, at room temperature, are reported. We show that at low energy, amorphization is a nucleation and growth process, based on the direct impact mechanism. With an Avrami exponent $\sim 1.6$, the growth towards amorphization seems to be diffusion limited. A transition to a completely amorphized state is indicated at a dose exceeding 17 eV/atom, which is higher than 6-12 eV/atom as predicted by simulations. The observed higher threshold could be due to temperature effects although an underestimation of keV-energy recoils, in simulation, may not be ruled out.
The damage growth and surface modifications in Si(100), induced by 25 keV Si$_5^-$ cluster ions, as a function of fluence, $ϕ$, has been studied using atomic force microscopy (AFM) and channeling Rutherford backscattering spectrometry (CRBS). CRBS results indicate a nonlinear growth in damage from which it has been possible to get a threshold fluence, $ϕ_0$, for amorphization as $2.5\times 10^{13}$ ions-cm$^{-2}$. For $ϕ$ below $ϕ_0$, a growth in damage as well as surface roughness has been observed. At a $ϕ$ of $1\times 10^{14}$ ions-cm$^{-2}$, damage saturation coupled with a much reduced surface roughness has been found. In this case a power spectrum analysis of AFM data showed a significant drop, in spectral density, as compared to the same obtained for a fluence, $ϕ< ϕ_0$. This drop, together with damage saturation, can be correlated with a transition to a stress relaxed amorphous phase. Irradiation with similar mass Cs$^-$ ions, at the same energy and fluence, has been found to result in a reduced accumulation of defects in the near surface region leading to reduced surface features.